ES2124940T3 - Estabilizacion de los ligandos fosfitos en el procedimiento de hidroformilacion. - Google Patents

Estabilizacion de los ligandos fosfitos en el procedimiento de hidroformilacion.

Info

Publication number
ES2124940T3
ES2124940T3 ES95113051T ES95113051T ES2124940T3 ES 2124940 T3 ES2124940 T3 ES 2124940T3 ES 95113051 T ES95113051 T ES 95113051T ES 95113051 T ES95113051 T ES 95113051T ES 2124940 T3 ES2124940 T3 ES 2124940T3
Authority
ES
Spain
Prior art keywords
rhodium
atom
bonded
hydrogen
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95113051T
Other languages
English (en)
Inventor
Anthony George Abatjoglou
David Robert Bryant
John Michael Maher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Application granted granted Critical
Publication of ES2124940T3 publication Critical patent/ES2124940T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B01J2531/0288—Sterically demanding or shielding ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

LA PRESENTE INVENCION PROPORCIONA UN PROCESO DE HIDROFORMILACION QUE CONSTA DE: 1) LA FORMACION DE UNA MEZCLA DE REACCION QUE CONTIENE: A) UN COMPUESTO OLEFINICO, B) HIDROGENO, C) MONOXIDO DE CARBONO, D) UN FOSFITO EN EL QUE CADA ATOMO DE FOSFORO ES LIGADO A TRES ATOMOS DE OXIGENO, Y AL MENOS UNO DE TALES ATOMOS DE OXIGENO LIGADO A UN ATOMO DE CARBONO DE UN ANILLO AROMATICO ADYACENTE AL OTRO ATOMO DE CARBONO DE DICHO ANILLO CON UN GRUPO MONOVALENTE PENDENTE CON UNA RESISTENCIA ESTERICA, AL MENOS TAN GRANDE COMO LA RESISTENCIA ESTERICA DE UN GRUPO DE ISOPROPIL, E) UNA CANTIDAD CATALITICA DE RODIO, Y F) UN METAL DEL GRUPO VIII (QUE NO SEA RODIO) EN UNA CANTIDAD SUFICIENTE PARA REDUCIR LA DESCOMPOSICION DEL RODIO CATALIZADA DEL FOSFITO DURANTE EL PROCESO DE HIDROFORMILACION; Y 2) EL MANTENIMIENTO DE LA MEZCLA DE REACCION BAJO CONDICIONES EN LAS QUE EL COMPUESTO OLEFINICO REACCIONA CON EL HIDROGENO Y CON EL MONOXIDO DE CARBONO PARA FORMAR UN ALDEHIDO.
ES95113051T 1994-08-19 1995-08-18 Estabilizacion de los ligandos fosfitos en el procedimiento de hidroformilacion. Expired - Lifetime ES2124940T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/293,028 US5756855A (en) 1994-08-19 1994-08-19 Stabilization of phosphite ligands in hydroformylation process

Publications (1)

Publication Number Publication Date
ES2124940T3 true ES2124940T3 (es) 1999-02-16

Family

ID=23127321

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95113051T Expired - Lifetime ES2124940T3 (es) 1994-08-19 1995-08-18 Estabilizacion de los ligandos fosfitos en el procedimiento de hidroformilacion.

Country Status (6)

Country Link
US (2) US5756855A (es)
EP (1) EP0697391B1 (es)
AT (1) ATE172708T1 (es)
DE (1) DE69505612T2 (es)
DK (1) DK0697391T3 (es)
ES (1) ES2124940T3 (es)

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CN109071394B (zh) 2016-03-18 2022-02-08 陶氏技术投资有限责任公司 加氢甲酰化工艺
US9975833B2 (en) 2016-08-31 2018-05-22 Eastman Chemical Company Efficient catalyst for the formation of polyaryl hydrocarbons suitable as precursors for polydentate organophosphorus catalyst ligands
US9687837B1 (en) 2016-08-31 2017-06-27 Eastman Chemical Company Stable hydroformylation catalyst for preparation of high N/Iso ratio aldehyde product
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TWI788364B (zh) 2017-06-23 2023-01-01 美商陶氏科技投資有限公司 氫甲醯化反應製程
CN111212826B (zh) 2017-10-25 2023-05-23 陶氏技术投资有限责任公司 减少在加氢甲酰化过程中形成的包含醛化合物的溶液中重物质形成的方法
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JP2021525165A (ja) 2018-05-30 2021-09-24 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセスにおける触媒失活を遅らせるための方法、および／またはテトラホスフィン配位子の使用を遅らせるための方法
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TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
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Also Published As

Publication number Publication date
US5929289A (en) 1999-07-27
EP0697391A1 (en) 1996-02-21
DE69505612D1 (de) 1998-12-03
DK0697391T3 (da) 1999-07-05
DE69505612T2 (de) 1999-05-20
ATE172708T1 (de) 1998-11-15
EP0697391B1 (en) 1998-10-28
US5756855A (en) 1998-05-26

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