ES2128671T3 - Proceso para polimerizar olefinas. - Google Patents

Proceso para polimerizar olefinas.

Info

Publication number
ES2128671T3
ES2128671T3 ES95309334T ES95309334T ES2128671T3 ES 2128671 T3 ES2128671 T3 ES 2128671T3 ES 95309334 T ES95309334 T ES 95309334T ES 95309334 T ES95309334 T ES 95309334T ES 2128671 T3 ES2128671 T3 ES 2128671T3
Authority
ES
Spain
Prior art keywords
polymerization
hydrogen
catalyst
polymerize
polymerize olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95309334T
Other languages
English (en)
Inventor
Erick Daire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Application granted granted Critical
Publication of ES2128671T3 publication Critical patent/ES2128671T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/905Polymerization in presence of transition metal containing catalyst in presence of hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA POLIMERIZAR AL MENOS UNA OLEFINA CON LA AYUDA DE UN CATALIZADOR QUE CONTIENE AL MENOS UN COMPUESTO ORGANOMETALICO DE UN METAL DE TRANSICION QUE POSEE AL MENOS UN LIGANTE DE CICLOPENTADIENILO O DE CICLOPENTADIENILO SUSTITUIDO. LA POLIMERIZACION SE LLEVA A CABO EN UNA FASE DE GAS O EN SUSPENSION EN UN MEDIO DE POLIMERIZACION LIQUIDO SELECCIONADO ENTRE HIDROCARBUROS SATURADOS O INSATURADOS, EN LA PRESENCIA DE HIDROGENO O DE UN COMPONENTE DE POLIMERIZACION SELECCIONADO ENTRE HIDROCARBUROS HALOGENADOS. EL USO COMBINADO DE HIDROGENO Y DE HIDROCARBURO HALOGENADO EN EL PROCESO DE POLIMERIZACION MEJORA SIMULTANEAMENTE LA ACTIVIDAD DEL CATALIZADOR Y EL CONTROL DEL PESO MOLECULAR DEL POLIMERO.
ES95309334T 1995-01-18 1995-12-21 Proceso para polimerizar olefinas. Expired - Lifetime ES2128671T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9500788A FR2729393B1 (fr) 1995-01-18 1995-01-18 Procede de polymerisation d'olefine

Publications (1)

Publication Number Publication Date
ES2128671T3 true ES2128671T3 (es) 1999-05-16

Family

ID=9475441

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95309334T Expired - Lifetime ES2128671T3 (es) 1995-01-18 1995-12-21 Proceso para polimerizar olefinas.

Country Status (16)

Country Link
US (1) US6174972B1 (es)
EP (1) EP0722955B1 (es)
JP (1) JP3974202B2 (es)
KR (1) KR100409411B1 (es)
CN (1) CN1124288C (es)
AT (1) ATE176247T1 (es)
CA (1) CA2166598C (es)
DE (1) DE69507584T2 (es)
DK (1) DK0722955T3 (es)
ES (1) ES2128671T3 (es)
FI (1) FI118769B (es)
FR (1) FR2729393B1 (es)
IN (1) IN191827B (es)
MY (1) MY113420A (es)
NO (1) NO310199B1 (es)
TW (1) TW357160B (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19719517A1 (de) * 1997-05-09 1998-11-12 Basf Ag Katalysatorlösung zur Polymerisation von alpha-Olefinen
JP2002512276A (ja) * 1998-04-21 2002-04-23 バーゼル、ポリプロピレン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 特定のメタロセンを使用するポリプロピレンの製造方法
US6288181B1 (en) * 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
WO2005113615A2 (en) 2004-05-20 2005-12-01 Univation Technologies, Llc Gas olefin polymerization process
US7683140B2 (en) 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
CN101128257B (zh) * 2004-11-12 2010-10-27 万罗赛斯公司 使用微通道技术进行烷化或酰化反应的方法
KR20090063245A (ko) 2006-09-07 2009-06-17 유니베이션 테크놀로지즈, 엘엘씨 용융개시온도 저하 모델을 사용하여 수지 점착도를 온-라인으로 결정하는 방법
JP2010502813A (ja) 2006-09-07 2010-01-28 ユニベーション・テクノロジーズ・エルエルシー 重合反応監視によって生成したデータから樹脂粘着性を示す温度値を決定するための方法
US9272961B2 (en) * 2006-12-27 2016-03-01 Mitsubishi Chemical Corporation Production method of polyolefin, polyolefin and 1-hexene for linear low density polyethylene production raw material
CN105143285B (zh) * 2013-02-07 2019-03-08 尤尼威蒂恩技术有限责任公司 聚烯烃的制备

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
JPS63218707A (ja) * 1987-03-07 1988-09-12 Showa Denko Kk ポリオレフインの製造方法
US4939217A (en) * 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
DE3743322A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag Polyethylenwachs und verfahren zu seiner herstellung
IT1237398B (it) * 1989-01-31 1993-06-01 Ausimont Srl Catalizzatori per la polimerizzazione di olefine.
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
DE4017331A1 (de) * 1990-05-30 1991-12-05 Hoechst Ag Verfahren zur herstellung eines polyolefins
US5245370A (en) * 1992-10-22 1993-09-14 Minnesota Mining And Manufacturing Company Overhead projector focus arm adjustment mechanism
TW322495B (es) * 1992-12-15 1997-12-11 Hoechst Ag
BR9402553A (pt) * 1993-06-28 1995-03-28 Union Carbide Chem Plastic Processo para controlar de forma reversível a atividade de uma reação de polimerização de olefina; processo para finalizar de forma reversível uma reação de polimerização de olefina; processo para finalizar e reiniciar uma reação de polimerização de olefina
JPH0733821A (ja) * 1993-07-22 1995-02-03 Nippon Oil Co Ltd オレフィン類重合用触媒成分
US5397757A (en) * 1993-10-27 1995-03-14 Mobil Oil Corporation Cocatalysts for metallocene-based olefin polymerization catalyst systems
US5486632A (en) * 1994-06-28 1996-01-23 The Dow Chemical Company Group 4 metal diene complexes and addition polymerization catalysts therefrom

Also Published As

Publication number Publication date
CA2166598C (en) 2007-09-04
IN191827B (es) 2004-01-10
CA2166598A1 (en) 1996-07-19
FI960229L (fi) 1996-07-19
NO310199B1 (no) 2001-06-05
FR2729393A1 (fr) 1996-07-19
ATE176247T1 (de) 1999-02-15
TW357160B (en) 1999-05-01
CN1140179A (zh) 1997-01-15
EP0722955A1 (en) 1996-07-24
JPH08231619A (ja) 1996-09-10
FI118769B (fi) 2008-03-14
DE69507584D1 (de) 1999-03-11
NO960210D0 (no) 1996-01-17
MY113420A (en) 2002-02-28
US6174972B1 (en) 2001-01-16
DE69507584T2 (de) 1999-06-17
FR2729393B1 (fr) 1997-03-21
DK0722955T3 (da) 1999-09-13
FI960229A0 (fi) 1996-01-17
EP0722955B1 (en) 1999-01-27
KR100409411B1 (ko) 2004-05-17
NO960210L (no) 1996-07-19
CN1124288C (zh) 2003-10-15
JP3974202B2 (ja) 2007-09-12
KR960029354A (ko) 1996-08-17

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