ES2133837T3 - Procedimiento para la carbonilzacion de etileno y sistema catalitico para usar en el mismo. - Google Patents

Procedimiento para la carbonilzacion de etileno y sistema catalitico para usar en el mismo.

Info

Publication number
ES2133837T3
ES2133837T3 ES95941792T ES95941792T ES2133837T3 ES 2133837 T3 ES2133837 T3 ES 2133837T3 ES 95941792 T ES95941792 T ES 95941792T ES 95941792 T ES95941792 T ES 95941792T ES 2133837 T3 ES2133837 T3 ES 2133837T3
Authority
ES
Spain
Prior art keywords
ethylene
carbonilzation
procedure
catalytic system
catalyst system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95941792T
Other languages
English (en)
Inventor
Xiao Lan Wang
Graham Ronald Eastham
Keith Whiston
Robert Paul Tooze
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of ES2133837T3 publication Critical patent/ES2133837T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

UN SISTEMA CATALIZADOR CAPAZ DE CATALIZAR LA CARBONILACION DE ETILENO Y UN PROCESO EN EL QUE SE UTILIZA DICHO SISTEMA EN DONDE EL SISTEMA CATALIZADOR SE PUEDE OBTENER COMBINANDO UN METAL DEL GRUPO VIII, P. EJ. PALADIO, O UN COMPUESTO DEL MISMO, Y UNA FOSFINA BIDENTADA, P. EJ. BIS (DI - T - BUTIL FOSFINO) O XILENO.
ES95941792T 1994-12-22 1995-12-22 Procedimiento para la carbonilzacion de etileno y sistema catalitico para usar en el mismo. Expired - Lifetime ES2133837T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9425911.6A GB9425911D0 (en) 1994-12-22 1994-12-22 Process for the carbonylation of olefins and catalyst system for use therein

Publications (1)

Publication Number Publication Date
ES2133837T3 true ES2133837T3 (es) 1999-09-16

Family

ID=10766369

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95941792T Expired - Lifetime ES2133837T3 (es) 1994-12-22 1995-12-22 Procedimiento para la carbonilzacion de etileno y sistema catalitico para usar en el mismo.

Country Status (18)

Country Link
US (1) US6348621B1 (es)
EP (1) EP0799180B1 (es)
JP (1) JP3949716B2 (es)
KR (1) KR100423212B1 (es)
CN (1) CN1073546C (es)
AT (1) ATE181725T1 (es)
AU (1) AU701935B2 (es)
BR (1) BR9510249A (es)
CA (1) CA2207672C (es)
CZ (1) CZ288904B6 (es)
DE (1) DE69510563T2 (es)
DK (1) DK0799180T3 (es)
ES (1) ES2133837T3 (es)
GB (1) GB9425911D0 (es)
HU (1) HU215407B (es)
NZ (1) NZ297842A (es)
TW (1) TW318839B (es)
WO (1) WO1996019434A1 (es)

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US6489506B2 (en) 1997-03-19 2002-12-03 Lucite International Uk Limited Process for the palladium and phosphine ligand catalyzed carbonylation of ethylene
GB9705699D0 (en) * 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
GB9717059D0 (en) 1997-08-13 1997-10-15 Ici Plc Method of manufacturing phosphine compound
GB9722733D0 (en) 1997-10-29 1998-10-28 Ici Plc Production of esters
GB9800915D0 (en) * 1998-01-17 1998-03-11 Ici Plc Production of alkyl esters
GB9805348D0 (en) 1998-03-16 1998-05-06 Ici Plc Compound
GB9918229D0 (en) * 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
MY133839A (en) 2000-03-14 2007-11-30 Shell Int Research Process for the carbonylation of pentenenitrile
MY127358A (en) 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
MY127093A (en) * 2000-05-17 2006-11-30 Lucite Int Uk Ltd Bidentate ligands useful in catalyst systems
DE10048874A1 (de) 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
DE10106348A1 (de) 2001-02-09 2002-08-14 Basf Ag Als Katalysator oder zur Herstellung eines Katalysatorsystems geeignete Verbindung
DE10228293A1 (de) 2001-07-28 2003-02-13 Basf Ag Verfahren zur Herstellung von Dialkylketonen
US20030105348A1 (en) 2001-11-19 2003-06-05 Bunel Emilio E. Process for making 5-cyanovaleric acid, adipic acid or dimethyl adipate
CN100516017C (zh) * 2002-02-19 2009-07-22 国际壳牌研究有限公司 使烯键式不饱和化合物羰基化的方法以及用于该方法的催化剂
GB0218613D0 (en) * 2002-08-10 2002-09-18 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds
TWI301481B (en) 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
GB0228018D0 (en) * 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
AU2003269119B2 (en) 2002-09-12 2009-06-18 Lucite International Uk Limited A catalyst system comprising a metallocene ligand
WO2005003070A1 (en) * 2003-07-03 2005-01-13 Lucite International Uk Limited Process for the hydroformylation of ethylenically unsaturated compounds
GB0315536D0 (en) * 2003-07-03 2003-08-06 Lucite Int Uk Ltd Process for the hydroformylation of ethylenically unsaturated compounds
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
US7265242B2 (en) 2004-02-26 2007-09-04 Shell Oil Company Process for the carbonylation of ethylenically or acetylenically unsaturated compounds
GB0411951D0 (en) * 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
GB0516556D0 (en) 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
CA2626107C (en) 2005-11-17 2016-06-21 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
MX2009005568A (es) * 2006-12-02 2009-06-05 Lucite Int Uk Ltd Nuevos ligandos de carbonilacion y su uso en la carbonilacion de compuestos etilenicamente insaturados.
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
GB0713624D0 (en) * 2007-07-13 2007-08-22 Lucite Int Uk Ltd Improved solvent for catalyst system
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
IN2012DN02308A (es) * 2009-09-03 2015-08-21 Univ Denmark Tech Dtu
GB0921876D0 (en) 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
GB0921875D0 (en) 2009-12-15 2010-01-27 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
GB0922255D0 (en) 2009-12-21 2010-02-03 Lucite Int Uk Ltd Method of producing acrylic and methacrylic acid
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
DE102010002809A1 (de) 2010-03-12 2011-11-17 Evonik Degussa Gmbh Verfahren zur Herstellung von linearen alpha,omega-Dicarbonsäurediestern
BR112013012861B1 (pt) 2010-11-24 2019-10-08 Lucite International Uk Limited Processo para a produção de ácido metacrílico e método para preparar polímeros ou copolímeros de ácido metacrílico ou ésteres do ácido metacrílico
SG191982A1 (en) 2011-02-09 2013-08-30 Lucite Int Uk Ltd A process for the production of (meth)acrylic acid and derivatives and polymers produced therefrom
GB201122054D0 (en) 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
WO2013107902A1 (en) 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
SG11201601587UA (en) 2013-09-30 2016-04-28 Dow Global Technologies Llc Gas phase production of alkyl alkanoate
WO2015200088A1 (en) 2014-06-24 2015-12-30 Dow Global Technologies Llc Process for producing low voc coalescing aids
WO2017135897A1 (en) * 2016-02-02 2017-08-10 Agency For Science, Technology And Research A catalyst for the carbonylation of alkenes
EP3272730B1 (de) * 2016-07-19 2019-01-02 Evonik Degussa GmbH Verfahren zur alkoxycarbonylierung von ethern
JP7136321B2 (ja) 2019-03-12 2022-09-13 三菱ケミカル株式会社 触媒、触媒の製造方法、並びに不飽和カルボン酸及び／又は不飽和カルボン酸エステルの製造方法
CN111087306B (zh) 2019-12-27 2021-08-03 南京诚志清洁能源有限公司 芳基双齿膦配体组合催化制备有机羧酸酯的方法
EP4192807A1 (en) 2020-08-04 2023-06-14 Eastman Chemical Company Propionic acid process
CN113912646B (zh) * 2021-11-18 2024-05-17 浙江新化化工股份有限公司 一种双齿膦配体的制备方法
CN115819234B (zh) * 2021-12-21 2025-04-29 浙江新和成股份有限公司 一种烯烃羰基化反应的方法
EP4452919A1 (de) 2021-12-23 2024-10-30 Röhm GmbH Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen
CN121729404A (zh) 2023-08-22 2026-03-24 罗姆化学有限责任公司 (甲基)丙烯酸酯生产的脱碳

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US4960949A (en) * 1988-12-22 1990-10-02 Eastman Kodak Company Low pressure rhodium catalyzed hydroformylation of olefins
DE69204691T2 (de) * 1991-01-15 1996-04-11 Shell Int Research Verfahren zur Karbonylierung von Olefin.
CA2093470C (en) * 1992-04-08 2003-12-09 Peter Arnoldy Carbonylation process using palladium phosphine catalyst

Also Published As

Publication number Publication date
CA2207672C (en) 2006-10-10
NZ297842A (en) 2000-01-28
CZ193297A3 (cs) 1998-02-18
HU215407B (hu) 1998-12-28
CN1073546C (zh) 2001-10-24
DK0799180T3 (da) 2000-01-31
US6348621B1 (en) 2002-02-19
AU4309596A (en) 1996-07-10
KR987000251A (en) 1998-03-30
AU701935B2 (en) 1999-02-11
EP0799180B1 (en) 1999-06-30
BR9510249A (pt) 1997-11-04
EP0799180A1 (en) 1997-10-08
TW318839B (en) 1997-11-01
CA2207672A1 (en) 1996-06-27
GB9425911D0 (en) 1995-02-22
JPH10511034A (ja) 1998-10-27
KR100423212B1 (ko) 2004-05-20
DE69510563T2 (de) 1999-11-25
CZ288904B6 (cs) 2001-09-12
HUT77016A (hu) 1998-03-02
ATE181725T1 (de) 1999-07-15
WO1996019434A1 (en) 1996-06-27
DE69510563D1 (de) 1999-08-05
JP3949716B2 (ja) 2007-07-25
CN1171098A (zh) 1998-01-21

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