ES2134261T3 - Mejoras en la descontaminacion de tereftalato de polietileno. - Google Patents
Mejoras en la descontaminacion de tereftalato de polietileno.Info
- Publication number
- ES2134261T3 ES2134261T3 ES93911683T ES93911683T ES2134261T3 ES 2134261 T3 ES2134261 T3 ES 2134261T3 ES 93911683 T ES93911683 T ES 93911683T ES 93911683 T ES93911683 T ES 93911683T ES 2134261 T3 ES2134261 T3 ES 2134261T3
- Authority
- ES
- Spain
- Prior art keywords
- pet
- ethanediol
- bht
- short chain
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 POLYETHYLENE Polymers 0.000 title abstract 3
- 239000004698 Polyethylene Substances 0.000 title 1
- 238000005202 decontamination Methods 0.000 title 1
- 230000003588 decontaminative effect Effects 0.000 title 1
- 229920000573 polyethylene Polymers 0.000 title 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 7
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 238000009835 boiling Methods 0.000 abstract 1
- 239000000356 contaminant Substances 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/02—Recovery or working-up of waste materials of solvents, plasticisers or unreacted monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
- C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
- C08J11/18—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material
- C08J11/22—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds
- C08J11/24—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with organic material by treatment with organic oxygen-containing compounds containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Polyesters Or Polycarbonates (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Gas Separation By Absorption (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Materials For Medical Uses (AREA)
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
UN PROCESO PARA ELIMINAR LOS CONTAMINANTES DE COMPONENTES DE PET DESPOLIMERIZANDO TEREFTALATO DE POLIETILENO ("PET") QUE CONSISTE EN TRANSESTERIFICAR MATERIAL QUE CONTIENE PET REACCIONADO ETANEDIOL QUE TIENE UNA TEMPERATURA A O ALREDEDOR DEL PUNTO DE EBULLICION DE ETADENIL CON EL MATERIAL DURANTE UN PERIODO PREDETERMINADO DE TIEMPO PARA FORMAR UNA SOLUCION QUE CONTIENE POLIMERO DE PET DE CADENA CORTA Y/O BIS ESTER DE (HIDROXIETILO) TEREFTALATO ("BHT"); RECUPERAR LOS POLIMEROS DE PET DE CADENA CORTA Y/O BHT Y ETADENIL; E HIDROLIZAR LOS POLIMEROS DE PET DE CADENA CORTA Y/O BHT A PRESION ELEVADA Y TEMPERATURA ELEVADA DURANTE UN PERIODO PREDETERMINADO DE TIEMPO PARA FORMAR UNA SOLUCION DE ETANEDIOL Y CRISTALES DE ACIDO TEREFTALICO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPL247092 | 1992-05-18 | ||
| AUPL695193 | 1993-01-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2134261T3 true ES2134261T3 (es) | 1999-10-01 |
Family
ID=25644250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93911683T Expired - Lifetime ES2134261T3 (es) | 1992-05-18 | 1993-05-04 | Mejoras en la descontaminacion de tereftalato de polietileno. |
Country Status (17)
| Country | Link |
|---|---|
| EP (1) | EP0641366B1 (es) |
| JP (1) | JP3510885B2 (es) |
| KR (1) | KR100271405B1 (es) |
| AT (1) | ATE182578T1 (es) |
| AU (1) | AU659021B2 (es) |
| BR (1) | BR9306379A (es) |
| CA (1) | CA2136080C (es) |
| DE (1) | DE69325803T2 (es) |
| ES (1) | ES2134261T3 (es) |
| HU (1) | HU214090B (es) |
| MY (1) | MY110079A (es) |
| NZ (1) | NZ252649A (es) |
| PL (1) | PL181832B1 (es) |
| SG (1) | SG74541A1 (es) |
| TW (1) | TW242150B (es) |
| UA (1) | UA27907C2 (es) |
| WO (1) | WO1993023465A1 (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE176780T1 (de) * | 1993-07-05 | 1999-03-15 | Du Pont | Herstellung von dicarbonsäuren oder ihren estern |
| US5635584A (en) * | 1995-12-07 | 1997-06-03 | Eastman Chemical Company | Process including glycolysis and subsequent purification for recycling polyester materials |
| AU716552B2 (en) * | 1996-04-01 | 2000-03-02 | Phoenix Technologies International, Llc | Improved decontamination of RPET through particle size reduction |
| DE19643479B4 (de) * | 1996-10-22 | 2006-04-20 | Zimmer Ag | Verfahren zur Herstellung von Polyethylenterephthalat aus Polyethylenterephthalat-Abfall |
| DE19646378C2 (de) * | 1996-11-09 | 1999-11-11 | Brown John Deutsche Eng Gmbh | Verfahren und Vorrichtung zur Rückgewinnung von Dicarbonsäuren und Diolen aus Polyesterabfällen, insbesondere aus Polyethylenterephthalat(PET)-Abfällen beliebigen Polymerisationsgrades |
| AUPP261498A0 (en) * | 1998-03-27 | 1998-04-23 | Swig Pty Ltd | Improved conversion of contaminated polyethylene terephthalate to polybutylene terephthalate |
| JP3715812B2 (ja) * | 1998-12-10 | 2005-11-16 | 株式会社アイエス | ポリエチレンテレフタレート廃棄物のケミカルリサイクル方法 |
| DE10348144A1 (de) | 2003-10-13 | 2005-05-19 | Krones Ag | PET-Flaschen-Recycling |
| US9234074B2 (en) | 2012-04-20 | 2016-01-12 | Perpetual Global Technologies Limited | Flakes of ester mixtures and methods for their production |
| PL228319B1 (pl) * | 2014-06-10 | 2018-03-30 | Rs Pet Spolka Z Ograniczona Odpowiedzialnoscia | Sposób recyklingu odpadów politereftalanu etylenu PET |
| US10316163B2 (en) * | 2014-12-23 | 2019-06-11 | Ioniqa Technologies B.V. | Polymer degradation |
| PL411850A1 (pl) * | 2015-04-01 | 2016-10-10 | Rs Pet Spółka Z Ograniczoną Odpowiedzialnością | Sposób odbarwiania odpadów politereftalanu etylenu PET |
| CN106831390A (zh) * | 2016-12-16 | 2017-06-13 | 树业环保科技股份有限公司 | 一种利用废旧pet薄膜制备单体pta的方法 |
| KR102435249B1 (ko) * | 2018-01-08 | 2022-08-22 | 현대모비스 주식회사 | 전동식 브레이크의 과열 방지장치 및 그 방법 |
| DE102018122210B4 (de) | 2018-09-12 | 2023-06-29 | Rittec Umwelttechnik Gmbh | Verfahren und Verwendung einer Vorrichtung zur Wiederaufarbeitung von Polyalkylenterephthalat enthaltenden Abfällen |
| TWI694064B (zh) * | 2018-09-26 | 2020-05-21 | 遠東新世紀股份有限公司 | 對苯二甲酸的製造方法及其系統 |
| FR3092324B1 (fr) * | 2019-02-01 | 2021-04-23 | Ifp Energies Now | Procédé de production d’un polyester téréphtalate intégrant un procédé de dépolymérisation |
| US12522695B2 (en) | 2019-10-08 | 2026-01-13 | Eastman Chemical Company | Catalyst systems for crystallizable reactor grade resins with recycled content |
| KR20210067555A (ko) * | 2019-11-29 | 2021-06-08 | 롯데케미칼 주식회사 | 결정화를 포함하는 폐플라스틱의 화학적 재활용 방법 |
| US11952467B2 (en) * | 2021-02-09 | 2024-04-09 | National Taiwan University | Method for processing polyalkylene benzenedicarboxylate material |
| TWI786787B (zh) | 2021-08-26 | 2022-12-11 | 南亞塑膠工業股份有限公司 | 利用離子液體觸媒回收聚酯織物的方法 |
| EP4342943B1 (en) | 2022-09-20 | 2024-07-17 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate using a selected feedstock |
| ES2987868T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando material filtrante de partículas porosas |
| ES2987865T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando coordenadas de color específicas para el procesamiento de oligómeros |
| ES2987897T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando un intervalo de temperatura seleccionado para elprocesamiento de oligómeros |
| EP4342946B1 (en) | 2022-09-20 | 2024-07-17 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate using a washing reactor |
| ES2987863T3 (es) * | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando una materia prima separada |
| EP4342942B1 (en) | 2022-09-20 | 2024-07-10 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate determined by intrinsic viscosity of polyethylene terephthalate |
| EP4342945B1 (en) | 2022-09-20 | 2024-07-17 | revalyu Resources GmbH | Process for recycling polyethylene terephthalate using different mono-ethylene glycol levels |
| ES2987870T3 (es) | 2022-09-20 | 2024-11-18 | Revalyu Resources Gmbh | Proceso para reciclar tereftalato de polietileno utilizando un gradiente de concentración de impurezas |
| CN116554025B (zh) * | 2023-05-19 | 2026-02-03 | 广东绿王新材料有限公司 | 一种聚酯瓶片化学制备bhet粉料的方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB610136A (en) * | 1946-03-28 | 1948-10-12 | Royden Lewis Heath | Degradation of aromatic linear polyesters |
| FR1081681A (fr) * | 1952-08-09 | 1954-12-22 | Perfogit | Procédé de récupération de chutes de polyesters synthétiques |
| NL301426A (es) * | 1962-12-06 | |||
| DE1443876A1 (de) * | 1964-02-18 | 1968-11-07 | Hoechst Ag | Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester |
| DE1247291B (de) * | 1964-04-28 | 1967-08-17 | Schwarza Chemiefaser | Verfahren und Vorrichtung zur Herstellung von Dialkylterephthalaten durch Abbau von Polyaethylenglykolterephthalaten |
| US3544622A (en) * | 1965-03-10 | 1970-12-01 | Du Pont | Alkaline saponification of polyethylene terephthalate at high temperatures using controlled amount of sodium hydroxide |
| CH550753A (it) * | 1970-11-26 | 1974-06-28 | Sir Soc Italiana Resine Spa | Procedimento per la depolimerizzazione di polietilentereftalato. |
| US4078143A (en) * | 1976-01-09 | 1978-03-07 | E. I. Du Pont De Nemours And Company | Process for depolymerizing waste ethylene terephthalate polyester |
| GB2123403A (en) * | 1982-07-09 | 1984-02-01 | Celanese Mexicana Sa | Continuous procedure for obtaining pure terephthalic acid and glycol starting from polyethylene terephthalate waste |
-
1993
- 1993-05-04 JP JP51970093A patent/JP3510885B2/ja not_active Expired - Fee Related
- 1993-05-04 NZ NZ252649A patent/NZ252649A/en not_active IP Right Cessation
- 1993-05-04 KR KR1019940704139A patent/KR100271405B1/ko not_active Expired - Fee Related
- 1993-05-04 AU AU42560/93A patent/AU659021B2/en not_active Expired
- 1993-05-04 ES ES93911683T patent/ES2134261T3/es not_active Expired - Lifetime
- 1993-05-04 CA CA 2136080 patent/CA2136080C/en not_active Expired - Lifetime
- 1993-05-04 HU HU9403298A patent/HU214090B/hu unknown
- 1993-05-04 PL PL93311308A patent/PL181832B1/pl unknown
- 1993-05-04 EP EP19930911683 patent/EP0641366B1/en not_active Expired - Lifetime
- 1993-05-04 AT AT93911683T patent/ATE182578T1/de active
- 1993-05-04 DE DE69325803T patent/DE69325803T2/de not_active Expired - Lifetime
- 1993-05-04 BR BR9306379A patent/BR9306379A/pt not_active IP Right Cessation
- 1993-05-04 SG SG1995002318A patent/SG74541A1/en unknown
- 1993-05-04 UA UA94129109A patent/UA27907C2/uk unknown
- 1993-05-04 WO PCT/AU1993/000198 patent/WO1993023465A1/en not_active Ceased
- 1993-05-11 MY MYPI93000870A patent/MY110079A/en unknown
- 1993-05-14 TW TW82103797A patent/TW242150B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR950701661A (ko) | 1995-04-28 |
| JPH08502079A (ja) | 1996-03-05 |
| TW242150B (es) | 1995-03-01 |
| EP0641366B1 (en) | 1999-07-28 |
| BR9306379A (pt) | 1998-09-01 |
| HUT68173A (en) | 1995-04-03 |
| CA2136080C (en) | 2000-04-18 |
| AU4256093A (en) | 1993-12-13 |
| WO1993023465A1 (en) | 1993-11-25 |
| EP0641366A1 (en) | 1995-03-08 |
| HU9403298D0 (en) | 1995-01-30 |
| SG74541A1 (en) | 2000-08-22 |
| PL311308A1 (en) | 1996-02-05 |
| KR100271405B1 (ko) | 2000-11-15 |
| MY110079A (en) | 1997-12-31 |
| ATE182578T1 (de) | 1999-08-15 |
| DE69325803T2 (de) | 1999-12-09 |
| NZ252649A (en) | 1996-03-26 |
| HU214090B (en) | 1997-12-29 |
| JP3510885B2 (ja) | 2004-03-29 |
| CA2136080A1 (en) | 1993-11-25 |
| EP0641366A4 (en) | 1995-05-31 |
| AU659021B2 (en) | 1995-05-04 |
| PL181832B1 (pl) | 2001-09-28 |
| DE69325803D1 (de) | 1999-09-02 |
| UA27907C2 (uk) | 2000-10-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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