ES2136737T3 - Composicion marcadora y metodo de marcado por laser. - Google Patents
Composicion marcadora y metodo de marcado por laser.Info
- Publication number
- ES2136737T3 ES2136737T3 ES94919867T ES94919867T ES2136737T3 ES 2136737 T3 ES2136737 T3 ES 2136737T3 ES 94919867 T ES94919867 T ES 94919867T ES 94919867 T ES94919867 T ES 94919867T ES 2136737 T3 ES2136737 T3 ES 2136737T3
- Authority
- ES
- Spain
- Prior art keywords
- laser marking
- marking method
- marker composition
- composition
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000003550 marker Substances 0.000 title 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- YXFVVABEGXRONW-CNRUNOGKSA-N tritiomethylbenzene Chemical compound [3H]CC1=CC=CC=C1 YXFVVABEGXRONW-CNRUNOGKSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/333—Colour developing components therefor, e.g. acidic compounds
- B41M5/3333—Non-macromolecular compounds
- B41M5/3335—Compounds containing phenolic or carboxylic acid groups or metal salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/435—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of radiation to a printing material or impression-transfer material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/435—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of radiation to a printing material or impression-transfer material
- B41J2/447—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of radiation to a printing material or impression-transfer material using arrays of radiation sources
- B41J2/455—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of radiation to a printing material or impression-transfer material using arrays of radiation sources using laser arrays, the laser array being smaller than the medium to be recorded
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
- B41M5/327—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
- B41M5/3275—Fluoran compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/333—Colour developing components therefor, e.g. acidic compounds
- B41M5/3331—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/333—Colour developing components therefor, e.g. acidic compounds
- B41M5/3333—Non-macromolecular compounds
- B41M5/3335—Compounds containing phenolic or carboxylic acid groups or metal salts thereof
- B41M5/3336—Sulfur compounds, e.g. sulfones, sulfides, sulfonamides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
UNA COMPOSICION MARCADORA QUE CONTIENE UNA RESINA DE CURACION CON RAYOS DE ENERGIA, UN COLORANTE LEUCO Y UN REVELADOR DEL COLOR EN DONDE LOS DOS SON BAJOS EN SOLUBILIDAD EN TOLUENO, CUYA COMPOSICION PUEDE FORMAR UN COLOR NEGRO INTENSO AL RADIARLO CON HACES LASERICOS, Y UN METODO PARA MARCAR CON UN LASER PARA FORMAR UNA MARCA DE COLOR NEGRO DE CORTE CLARO MEDIANTE LA UTILIZACION DE LA COMPOSICION ANTEDICHA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6164809A JPH082106A (ja) | 1994-06-24 | 1994-06-24 | マーキング用組成物及びレーザーマーキング方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2136737T3 true ES2136737T3 (es) | 1999-12-01 |
Family
ID=15800333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94919867T Expired - Lifetime ES2136737T3 (es) | 1994-06-24 | 1994-07-07 | Composicion marcadora y metodo de marcado por laser. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5824715A (es) |
| EP (1) | EP0716135B1 (es) |
| JP (1) | JPH082106A (es) |
| KR (1) | KR960703993A (es) |
| CN (1) | CN1063470C (es) |
| DE (1) | DE69420971T2 (es) |
| ES (1) | ES2136737T3 (es) |
| WO (1) | WO1996000262A1 (es) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19522397A1 (de) * | 1995-06-23 | 1997-01-02 | Merck Patent Gmbh | Lasermarkierbare Kunststoffe |
| TW340860B (en) * | 1996-02-28 | 1998-09-21 | Nippon Chemicals Pharmaceutical Co Ltd | Liquid composition |
| US5788754A (en) * | 1997-03-03 | 1998-08-04 | Hewlett-Packard Company | Ink-jet inks for improved image quality |
| US5858075A (en) * | 1997-03-03 | 1999-01-12 | Hewlett-Packard Company | Dye set for improved ink-jet image quality |
| US6075223A (en) * | 1997-09-08 | 2000-06-13 | Thermark, Llc | High contrast surface marking |
| US6852948B1 (en) | 1997-09-08 | 2005-02-08 | Thermark, Llc | High contrast surface marking using irradiation of electrostatically applied marking materials |
| US6124377A (en) * | 1998-07-01 | 2000-09-26 | Binney & Smith Inc. | Marking system |
| WO2001068776A1 (en) * | 2000-03-14 | 2001-09-20 | Dsm N.V. | Fully identifiable optical fiber assemblies |
| US6835457B2 (en) | 2001-05-15 | 2004-12-28 | Markem Corporation | Marking substrates |
| DE10146820B4 (de) * | 2001-09-19 | 2005-02-24 | Tampoprint Gmbh | Dekoriervorrichtung und Verfahren zum Dekorieren von Oberflächen |
| US7060654B2 (en) * | 2003-10-28 | 2006-06-13 | Hewlett-Packard Development Company | Imaging media and materials used therein |
| EP1456810B1 (en) | 2001-12-18 | 2011-05-11 | L-1 Secure Credentialing, Inc. | Multiple image security features for identification documents and methods of making same |
| CA2470600C (en) | 2001-12-24 | 2009-12-22 | Digimarc Id Systems, Llc | Systems, compositions, and methods for full color laser engraving of id documents |
| AU2002364036A1 (en) | 2001-12-24 | 2003-07-15 | Digimarc Id Systems, Llc | Laser etched security features for identification documents and methods of making same |
| US7728048B2 (en) | 2002-12-20 | 2010-06-01 | L-1 Secure Credentialing, Inc. | Increasing thermal conductivity of host polymer used with laser engraving methods and compositions |
| ATE552120T1 (de) | 2001-12-24 | 2012-04-15 | L 1 Secure Credentialing Inc | Verdeckte variableninformationen auf id- dokumenten und verfahren zu ihrer herstellung |
| US20030234286A1 (en) | 2001-12-24 | 2003-12-25 | Brian Labrec | Laser engraving methods and compositions, and articles having laser engraving thereon |
| US7694887B2 (en) | 2001-12-24 | 2010-04-13 | L-1 Secure Credentialing, Inc. | Optically variable personalized indicia for identification documents |
| US6799187B2 (en) * | 2001-12-26 | 2004-09-28 | The Boeing Company | Opportunistic parts marking management system |
| AU2003217642A1 (en) * | 2002-02-19 | 2003-09-09 | Digmarc Corporation | Security methods employing drivers licenses and other documents |
| WO2003088144A2 (en) | 2002-04-09 | 2003-10-23 | Digimarc Id Systems, Llc | Image processing techniques for printing identification cards and documents |
| US20040014859A1 (en) * | 2002-04-22 | 2004-01-22 | Ezbiansky Karin Ann | Coating formulations for limited play data storage media |
| US7824029B2 (en) | 2002-05-10 | 2010-11-02 | L-1 Secure Credentialing, Inc. | Identification card printer-assembler for over the counter card issuing |
| US7238396B2 (en) | 2002-08-02 | 2007-07-03 | Rieck Albert S | Methods for vitrescent marking |
| AU2003298731A1 (en) | 2002-11-26 | 2004-06-18 | Digimarc Id Systems | Systems and methods for managing and detecting fraud in image databases used with identification documents |
| GB0228647D0 (en) | 2002-12-09 | 2003-01-15 | Ciba Sc Holding Ag | Polyeric material containing a latent acid |
| US6974661B2 (en) | 2003-01-24 | 2005-12-13 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US7700258B2 (en) * | 2003-01-24 | 2010-04-20 | Hewlett-Packard Development Company, L.P. | Color forming compositions with improved marking sensitivity and image contrast and associated methods |
| US7763179B2 (en) | 2003-03-21 | 2010-07-27 | Digimarc Corporation | Color laser engraving and digital watermarking |
| US7225991B2 (en) | 2003-04-16 | 2007-06-05 | Digimarc Corporation | Three dimensional data storage |
| US7083904B2 (en) | 2003-09-05 | 2006-08-01 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| PT1664172E (pt) * | 2003-09-17 | 2007-03-30 | Clariant Finance Bvi Ltd | Composições poliméricas que podem ser marcadas a laser |
| DE10343704A1 (de) * | 2003-09-18 | 2005-04-14 | Mankiewicz Gebr. & Co (Gmbh & Co Kg) | Pigment für lasergravierfähige Lacke |
| US7169542B2 (en) | 2003-10-28 | 2007-01-30 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US7993807B2 (en) | 2004-04-28 | 2011-08-09 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US7513682B2 (en) | 2004-05-11 | 2009-04-07 | Hewlett-Packard Development Company, L.P. | Temperature monitoring system |
| US7270943B2 (en) * | 2004-07-08 | 2007-09-18 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US20060078832A1 (en) * | 2004-10-07 | 2006-04-13 | Gore Makarand P | Compositions for multi-color, light activated imaging |
| US7377617B2 (en) | 2004-10-12 | 2008-05-27 | Clarke Leo C | Printing apparatus and method |
| US20060093958A1 (en) * | 2004-10-28 | 2006-05-04 | Vladek Kasperchik | Color forming compositions and associated methods |
| US20060096960A1 (en) * | 2004-11-09 | 2006-05-11 | Mobile Tool Management, Inc. | Method of marking and tracking objects |
| US7198834B2 (en) | 2005-03-22 | 2007-04-03 | Hewlett-Packard Development Company, L.P. | Imaging media including interference layer for generating human-readable marking on optical media |
| US7270944B2 (en) | 2005-03-29 | 2007-09-18 | Hewlett-Packard Development Company, L.P. | Compositions, systems, and methods for imaging |
| US7514198B2 (en) | 2005-08-15 | 2009-04-07 | Hewlett-Packard Development Company, L.P. | Color forming composition containing a plurality of antenna dyes |
| US8257906B2 (en) | 2006-03-29 | 2012-09-04 | Hewlett-Packard Development Company, L.P. | Multi-layered radiation imageable coating |
| US20070243354A1 (en) * | 2006-04-18 | 2007-10-18 | Hewlett-Packard Development Company, L.P. | Image-recording medium with thermally insulating layer |
| US8283100B2 (en) * | 2006-05-16 | 2012-10-09 | Hewlett-Packard Development Company, L.P. | Color forming compositions and associated methods |
| US7892619B2 (en) * | 2006-12-16 | 2011-02-22 | Hewlett-Packard Development Company, L.P. | Coating for optical recording |
| US20080145940A1 (en) * | 2006-12-18 | 2008-06-19 | 3M Innovative Properties Company | Chemical indicator test strip |
| US20080145948A1 (en) * | 2006-12-18 | 2008-06-19 | 3M Innovative Properties Company | Chemical indicator test strip |
| US20080248950A1 (en) * | 2007-04-04 | 2008-10-09 | Ibrahim Katampe | Ink and Developer System |
| US7582408B2 (en) | 2007-04-27 | 2009-09-01 | Hewlett-Packard Development Company, L.P. | Color forming compositions with a fluoran leuco dye having a latent developer |
| US9884342B2 (en) * | 2009-05-19 | 2018-02-06 | Apple Inc. | Techniques for marking product housings |
| JP5963229B2 (ja) * | 2010-04-26 | 2016-08-03 | Dic株式会社 | 活性エネルギー線硬化性コーティング用組成物 |
| JP5841740B2 (ja) * | 2011-04-21 | 2016-01-13 | 株式会社東芝 | 消去可能インクジェットインク |
| US8786650B1 (en) * | 2012-03-07 | 2014-07-22 | Express Scripts, Inc. | Systems and methods for pharmacy messaging |
| EP2639074B1 (en) | 2012-03-16 | 2015-03-04 | Agfa-Gevaert | Colour laser markable laminates and documents |
| GB2520633B (en) | 2013-11-25 | 2021-06-02 | Crayola Llc | Marking system |
| US9744559B2 (en) | 2014-05-27 | 2017-08-29 | Paul W Harrison | High contrast surface marking using nanoparticle materials |
| CN107604752B (zh) * | 2017-09-18 | 2020-04-03 | 广西工业职业技术学院 | 一种显色抗菌蔗糖包装纸的制备方法 |
| CN111902520B (zh) * | 2018-04-05 | 2022-11-22 | 陶氏环球技术有限责任公司 | 作为燃料标记物的呫吨 |
| EP3805004A1 (en) * | 2019-10-11 | 2021-04-14 | Agfa Nv | Laser markable articles |
| PL242889B1 (pl) | 2020-09-12 | 2023-05-08 | Wysokinski Karol | Metoda modyfikowania metali za pomocą lasera |
| CN118007469A (zh) * | 2023-12-29 | 2024-05-10 | 浙江越宏新材料有限公司 | 一种抗油耐高温热敏纸及其制备方法 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4343885A (en) * | 1978-05-09 | 1982-08-10 | Dynachem Corporation | Phototropic photosensitive compositions containing fluoran colorformer |
| JPS5672991A (en) * | 1979-11-19 | 1981-06-17 | Mita Ind Co Ltd | Color former for coloring substance of leucoline and recording material made by use thereof |
| US4500354A (en) * | 1982-09-27 | 1985-02-19 | Graphic Controls Corp. | Heat sensitive recording papers |
| JPS5991438A (ja) * | 1982-11-17 | 1984-05-26 | Fuji Photo Film Co Ltd | 感光感熱記録材料 |
| JPS59165687A (ja) * | 1983-03-10 | 1984-09-18 | Ricoh Co Ltd | 感熱記録材料 |
| JPS61174276A (ja) * | 1985-01-29 | 1986-08-05 | Toyobo Co Ltd | 紫外線硬化型インキ組成物 |
| US4663642A (en) * | 1985-02-23 | 1987-05-05 | Ricoh Company, Ltd. | Thermosensitive recording material |
| JPH0714656B2 (ja) * | 1985-04-20 | 1995-02-22 | 株式会社リコー | 多色発色感熱記録材料 |
| DE3639266A1 (de) * | 1985-12-27 | 1987-07-02 | Fsk K K | Haftfolie |
| JPS63317571A (ja) * | 1987-06-19 | 1988-12-26 | Asahi Glass Co Ltd | マ−キングインキ組成物 |
| JP2901625B2 (ja) * | 1988-12-28 | 1999-06-07 | 株式会社リコー | 感熱記録材料 |
| JP2728214B2 (ja) * | 1989-01-20 | 1998-03-18 | 共同印刷株式会社 | 感熱記録媒体 |
| JPH0745265B2 (ja) * | 1989-04-07 | 1995-05-17 | 日本製紙株式会社 | 感熱記録紙 |
| JPH0741744B2 (ja) * | 1989-07-26 | 1995-05-10 | 日本製紙株式会社 | 感熱記録体 |
| EP0442823B1 (en) * | 1990-02-16 | 1995-01-18 | Tomoegawa Paper Co. Ltd. | Thermal printing medium and label incorporating the same |
| JPH0491172A (ja) * | 1990-08-07 | 1992-03-24 | Dainichiseika Color & Chem Mfg Co Ltd | 放射線硬化性感熱発色インキ及びそのインキを塗布した感熱発色プラスチックカード |
| US5434119A (en) * | 1991-06-24 | 1995-07-18 | Jujo Paper Co., Ltd. | Transparent recording medium |
| JP2762319B2 (ja) * | 1991-07-01 | 1998-06-04 | 大日本インキ化学工業株式会社 | レーザーマーキング方法および印刷インキ |
| DE4129284A1 (de) * | 1991-09-03 | 1993-03-04 | Agfa Gevaert Ag | Bilderzeugungselement mit einem fotopolymerisierbaren monomer |
| US5646088A (en) * | 1995-02-16 | 1997-07-08 | Ricoh Co., Ltd. | Thermosensitive recording material and production process thereof |
-
1994
- 1994-06-24 JP JP6164809A patent/JPH082106A/ja active Pending
- 1994-07-07 CN CN94193084A patent/CN1063470C/zh not_active Expired - Fee Related
- 1994-07-07 ES ES94919867T patent/ES2136737T3/es not_active Expired - Lifetime
- 1994-07-07 EP EP94919867A patent/EP0716135B1/en not_active Expired - Lifetime
- 1994-07-07 WO PCT/JP1994/001108 patent/WO1996000262A1/ja not_active Ceased
- 1994-07-07 KR KR1019960700890A patent/KR960703993A/ko not_active Ceased
- 1994-07-07 US US08/592,424 patent/US5824715A/en not_active Expired - Fee Related
- 1994-07-07 DE DE69420971T patent/DE69420971T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0716135B1 (en) | 1999-09-29 |
| CN1129458A (zh) | 1996-08-21 |
| WO1996000262A1 (en) | 1996-01-04 |
| JPH082106A (ja) | 1996-01-09 |
| EP0716135A1 (en) | 1996-06-12 |
| EP0716135A4 (en) | 1997-01-02 |
| US5824715A (en) | 1998-10-20 |
| KR960703993A (ko) | 1996-08-31 |
| DE69420971D1 (de) | 1999-11-04 |
| DE69420971T2 (de) | 2000-04-06 |
| CN1063470C (zh) | 2001-03-21 |
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