ES2141833T3 - Catalizadores de polimerizacion, su produccion y uso. - Google Patents

Catalizadores de polimerizacion, su produccion y uso.

Info

Publication number
ES2141833T3
ES2141833T3 ES94925205T ES94925205T ES2141833T3 ES 2141833 T3 ES2141833 T3 ES 2141833T3 ES 94925205 T ES94925205 T ES 94925205T ES 94925205 T ES94925205 T ES 94925205T ES 2141833 T3 ES2141833 T3 ES 2141833T3
Authority
ES
Spain
Prior art keywords
rings
catalyst
component
substitutes
same
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94925205T
Other languages
English (en)
Inventor
Moses Olukayode Jejelowo
Robert Lee Bamberger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2141833T3 publication Critical patent/ES2141833T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

LA INVENCION SE DIRIGE A LA POLIMERIZACION DE OLEFINAS, OPCIONALMENTE CON UN COMONOMERO EN LA PRESENCIA DE UN CATALIZADOR DE METALOCENO PARA PRODUCIR UN PRODUCTO DE POLIMERO QUE TIENE UNA DISTRIBUCION CONTROLADA DE PESO MOLECULAR, QUE OSCILA ENTRE ESTRECHA Y ANCHA, UN PESO MOLECULAR ALTO Y UNA DISTRIBUCION DE COMPOSICION ESTRECHA. LOS CATALIZADORES DE LA INVENCION SUMINISTRAN POLIETILENOS LINEALES Y COPOLIMEROS DE ETILENO{AL}OLEFINA CON UNA RESISTENCIA A LA FUSION SUBSTANCIALMENTE MAYOR QUE LOS POLIETILENOS PRODUCIDOS POR UN CATALIZADOR ZIEGLERNATTA O UN CATALIZADOR DE METALOCENO TIPICO. LA INVENCION SUMINISTRA UN CATALIZADOR PARA LA POLIMERIZACION DE OLEFINAS QUE COMPRENDE UN PRIMER COMPONENTE QUE COMPRENDE AL MENOS UN METAL DE TRANSICION DEL GRUPO IV, V O VI Y QUE ESTA UNIDO A AL MENOS DOS ANILLO QUE CONTIENE CICLOPENTADIENILO, LOS ANILLOS TIENEN CADA UNO AL MENOS DOS SUSTITUYENTES UNIDOS A CADA UNO DE LOS ANILLOS EN LA MISMA POSICION; UN SEGUNDO COMPONENTE QUE COMPRENDE EL METAL DE TRANSICION Y DICHOS ANILLOS QUE CONTIENE CICLOPENTADIENILO, LOS ANILLOS TIENEN CADA UNO AL MENOS DOS SUSTITUYENTES UNIDOS A CADA UNO DE LOS ANILLOS EN LA MISMA O DIFERENTE POSICION QUE LOS SUSTITUYENTES DEL PRIMER COMPONENTE; LOS SUSTITUYENTES DEL PRIMER Y SEGUNDO COMPONENTE PUEDEN SER IGUALES O DIFERENTES, CON LA CONDICION DE QUE CUANDO LOS SUSTITUYENTES DEL PRIMER Y SEGUNDO COMPONENTES SEAN IGUALES, LOS SUSTITUYENTES DE LOS COMPONENTES ESTEN UNIDOS A LOS ANILLOS EN DIFERENTES POSICIONES; Y UN TERCER COMPONENTE QUE COMPRENDE EL METAL DE TRANSICION UNIDO A LOS ANILLOS QUE CONTIENEN CICLOPENTADIENILO EN DONDE UNO DE LOS ANILLOS ESTA SUSTITUIDO DE FORMA IDENTICA QUE EL PRIMER COMPONENTE Y OTRO DE LOS ANILLOS ESTA SUSTITUIDO DE FORMA IDENTICA AL SEGUNDO COMPONENTE. LA INVENCION SUMINISTRA ADEMAS SISTEMAS CATALIZADORES QUE COMPRENDEN EL COMPONENTE CATALIZADOR ANTERIOR EN COMBINACION CON UN COCATALIZADOR Y/O ACTIVADOR PARA EL CATALIZADOR. EL COCATALIZADOR O ACTIVADOR PUEDE SER BIEN ALUMOXANO O BIEN UN ACTIVADOR IONICO.
ES94925205T 1993-08-06 1994-08-03 Catalizadores de polimerizacion, su produccion y uso. Expired - Lifetime ES2141833T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10350593A 1993-08-06 1993-08-06

Publications (1)

Publication Number Publication Date
ES2141833T3 true ES2141833T3 (es) 2000-04-01

Family

ID=22295556

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94925205T Expired - Lifetime ES2141833T3 (es) 1993-08-06 1994-08-03 Catalizadores de polimerizacion, su produccion y uso.

Country Status (9)

Country Link
US (2) US5470811A (es)
EP (1) EP0719287B1 (es)
JP (1) JPH09501707A (es)
CN (1) CN1131953A (es)
AU (1) AU7521794A (es)
CA (1) CA2168883C (es)
DE (1) DE69422410T2 (es)
ES (1) ES2141833T3 (es)
WO (1) WO1995004761A1 (es)

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EP0719287A1 (en) 1996-07-03
CA2168883C (en) 2000-07-04
DE69422410T2 (de) 2000-07-06
CN1131953A (zh) 1996-09-25
WO1995004761A1 (en) 1995-02-16
US5536796A (en) 1996-07-16
AU7521794A (en) 1995-02-28
US5470811A (en) 1995-11-28
EP0719287B1 (en) 1999-12-29
CA2168883A1 (en) 1995-02-16
JPH09501707A (ja) 1997-02-18
DE69422410D1 (de) 2000-02-03

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