ES2144090T3 - Procedimiento de alquilacion. - Google Patents
Procedimiento de alquilacion.Info
- Publication number
- ES2144090T3 ES2144090T3 ES95118007T ES95118007T ES2144090T3 ES 2144090 T3 ES2144090 T3 ES 2144090T3 ES 95118007 T ES95118007 T ES 95118007T ES 95118007 T ES95118007 T ES 95118007T ES 2144090 T3 ES2144090 T3 ES 2144090T3
- Authority
- ES
- Spain
- Prior art keywords
- reactor
- catalyst
- solutions
- acid catalyst
- hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000003377 acid catalyst Substances 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 150000002430 hydrocarbons Chemical class 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- 238000010521 absorption reaction Methods 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- -1 HYDROCARBONS C {SUB Chemical class 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- VJYFKVYYMZPMAB-UHFFFAOYSA-N ethoprophos Chemical compound CCCSP(=O)(OCC)SCCC VJYFKVYYMZPMAB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 239000006104 solid solution Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/025—Sulfonic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
SE PRESENTA UN PROCESO MEJORADO PARA LA ALQUILACION DE FASE LIQUIDA, SOPORTADA DE UN SUMINISTRO DE HIDROCARBONOS ALIFATICOS EN LA PRESENCIA DE UN CATALIZADOR DE ACIDO SULFONICO FLUORADO CON UN AGENTE ALQUILANTE OLEFINICO EN UN REACTOR QUE CONTIENE UN LECHO FIJO DE UN MATERIAL DE CONTACTO, POLAR, PARTICULAR, EN DONDE UNA ZONA DE REACCION CON EL CATALIZADOR DE ACIDO SULFONICO FLUORADO SE ESTABLECE DE FORMA MOVIL MEDIANTE LA ABSORCION DEL CATALIZADOR DE ACIDO DENTRO DE UN AREA CONFINADA DE MATERIAL DE CONTACTO Y HACIENDO PASAR UNA CORRIENTE DE PROCESAMIENTO DE SUMINISTRO DE HIDROCARBONOS ALIFATICOS Y EL AGENTE ALQUILANTE, OLEFINICO A TRAVES DEL REACTOR Y DE LA ZONA DE REACCION, Y EXTRAYENDO UNA CORRIENTE DE PRODUCTO ALQUILADO DEL REACTOR, EN DONDE LA MEJORA COMPRENDE LA INTRODUCCION DEL CATALIZADOR DE ALQUILACION DE ACIDO SULFONICO FLUORADO EN EL INTERIOR DEL REACTOR DISUELTO EN UN SOLVENTE DE HIDROCARBONO QUE COMPRENDE HIDROCARBONOS C{SUB,3-9} Y LA ABSORCION DEL CATALIZADOR EN LA SOLUCION DELSOLVENTE DE HIDROCARBONOS SOBRE EL MATERIAL DE CONTACTO EN EL EXTREMO DE ENTRADA DEL REACTOR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK138094A DK171932B1 (da) | 1994-12-02 | 1994-12-02 | Fremgangsmåde til alkylering af alifatiske carbonhydrider |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2144090T3 true ES2144090T3 (es) | 2000-06-01 |
Family
ID=8104237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95118007T Expired - Lifetime ES2144090T3 (es) | 1994-12-02 | 1995-11-15 | Procedimiento de alquilacion. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5675053A (es) |
| EP (1) | EP0714871B1 (es) |
| JP (1) | JPH08268923A (es) |
| DE (1) | DE69515106T2 (es) |
| DK (1) | DK171932B1 (es) |
| ES (1) | ES2144090T3 (es) |
| RU (1) | RU2163588C2 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK172596B1 (da) * | 1996-02-15 | 1999-02-15 | Topsoe Haldor As | Fremgangsmåde til fremstilling af et alkyleret carbonhydridprodukt ved trinvis væskefasealkylering af et carbonhydridsubstr |
| US5817908A (en) * | 1996-05-20 | 1998-10-06 | Amoco Corporation | Staged alkylation process |
| DK172906B1 (da) * | 1996-06-17 | 1999-09-27 | Topsoe Haldor As | Fremgangsmåde til fjernelse af korrosive bestanddele fra en fluidastrøm |
| DK123796A (da) * | 1996-11-05 | 1998-05-06 | Haldor Topsoe As | Fremgangsmåde til fremstilling af carbonhydrid produkt med et højt indhold af middeldistilleret produktfraktionering |
| CN1100028C (zh) | 1999-07-22 | 2003-01-29 | 中国石油化工集团公司 | 一种异构烷烃与烯烃的烷基化方法 |
| US6395673B1 (en) | 2000-06-29 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Catalyst of mixed fluorosulfonic acids |
| CN1291954C (zh) | 2004-01-19 | 2006-12-27 | 中国石油化工股份有限公司 | 一种固体酸催化异构烷烃与烯烃的烷基化反应方法 |
| WO2011135206A1 (fr) | 2010-04-28 | 2011-11-03 | IFP Energies Nouvelles | Procede d'oligomerisation des olefines utilisant au moins un catalyseur organique possedant une forte densite de sites acides |
| ES2816018T3 (es) | 2015-06-22 | 2021-03-31 | Exelus Inc | Alquilación catalizada mejorada, catalizadores de alquilación, y métodos de fabricación de catalizadores de alquilación |
| US11851386B2 (en) | 2021-10-15 | 2023-12-26 | Exelus, Inc. | Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4044069A (en) * | 1973-09-26 | 1977-08-23 | Societe Nationale Elf Aquitaine | Catalytic composition for the isomerization and alkylation of hydrocarbons |
| US4056578A (en) * | 1976-03-04 | 1977-11-01 | Shell Oil Company | Isoparaffin-olefin alkylation process using a supported perfluorinated polymer catalyst |
| US4783567A (en) * | 1987-11-23 | 1988-11-08 | Uop Inc. | HF alkylation process |
| DK168520B1 (da) | 1989-12-18 | 1994-04-11 | Topsoe Haldor As | Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel |
| US5245100A (en) | 1989-12-18 | 1993-09-14 | Haldor Topsoe, S.A. | Alkylation process |
| US5202518A (en) * | 1991-09-18 | 1993-04-13 | Mobil Oil Corporation | Liquid acid alkylation catalyst and isoparaffin:olefin alkylation process |
| FR2704161B1 (fr) * | 1993-04-20 | 1995-06-02 | Inst Francais Du Petrole | Catalyseur d'alkylation de paraffines. |
| WO1994024075A1 (en) * | 1993-04-22 | 1994-10-27 | Mobil Oil Corporation | Isoparaffin/olefin alkylation |
| DK93193D0 (da) * | 1993-08-13 | 1993-08-13 | Haldor Topsoe As | Alkylering |
-
1994
- 1994-12-02 DK DK138094A patent/DK171932B1/da not_active IP Right Cessation
-
1995
- 1995-11-15 EP EP95118007A patent/EP0714871B1/en not_active Expired - Lifetime
- 1995-11-15 DE DE69515106T patent/DE69515106T2/de not_active Expired - Fee Related
- 1995-11-15 ES ES95118007T patent/ES2144090T3/es not_active Expired - Lifetime
- 1995-12-01 US US08/566,186 patent/US5675053A/en not_active Expired - Fee Related
- 1995-12-01 RU RU95121081/04A patent/RU2163588C2/ru not_active IP Right Cessation
- 1995-12-01 JP JP7314377A patent/JPH08268923A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE69515106D1 (de) | 2000-03-23 |
| EP0714871B1 (en) | 2000-02-16 |
| DK138094A (da) | 1996-06-03 |
| RU2163588C2 (ru) | 2001-02-27 |
| JPH08268923A (ja) | 1996-10-15 |
| DE69515106T2 (de) | 2000-06-21 |
| US5675053A (en) | 1997-10-07 |
| EP0714871A1 (en) | 1996-06-05 |
| DK171932B1 (da) | 1997-08-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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