ES2060915T3 - Procedimiento de alquilacion. - Google Patents
Procedimiento de alquilacion.Info
- Publication number
- ES2060915T3 ES2060915T3 ES90124478T ES90124478T ES2060915T3 ES 2060915 T3 ES2060915 T3 ES 2060915T3 ES 90124478 T ES90124478 T ES 90124478T ES 90124478 T ES90124478 T ES 90124478T ES 2060915 T3 ES2060915 T3 ES 2060915T3
- Authority
- ES
- Spain
- Prior art keywords
- rent
- rental
- hydrocarbon substrate
- renting
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
- B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/56—Addition to acyclic hydrocarbons
- C07C2/58—Catalytic processes
- C07C2/62—Catalytic processes with acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
- C07C2527/03—Acids of sulfur other than sulfhydric acid or sulfuric acid, e.g. halosulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/025—Sulfonic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
UN PROCESO DE ALQUILACION EN FASE LIQUIDA DE UN SUBSTRATO DE HIDROCARBONO CON UN AGENTE DE ALQUILACION OLEFINICO COMPRENDE LOS PASOS DE PASAR UNA CORRIENTE DE PROCESO DEL SUBSTRATO DE HIDROCARBONO Y AGENTE DE ALQUILACION EN CONDICIONES DE ALQUILACION A TRAVES DE UN REACTOR FIJO DE LECHO DE ALQUILACION DE UN MATERIAL DE CONTACTO DE POLO DE PARTICULAS EN LA PRESENCIA DE UN CATALIZADOR ACIDO SULFONICO FLUORADO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK643989A DK643989A (da) | 1989-12-18 | 1989-12-18 | Alkylation process |
| DK140290A DK168520B1 (da) | 1989-12-18 | 1990-06-08 | Fremgangsmåde til væskefase-alkylering af et carbonhydrid med et olefinalkyleringsmiddel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2060915T3 true ES2060915T3 (es) | 1994-12-01 |
Family
ID=26065707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90124478T Expired - Lifetime ES2060915T3 (es) | 1989-12-18 | 1990-12-17 | Procedimiento de alquilacion. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5220095A (es) |
| EP (1) | EP0433954B1 (es) |
| JP (1) | JPH0688914B2 (es) |
| AR (1) | AR246501A1 (es) |
| AT (1) | ATE109445T1 (es) |
| AU (1) | AU641713B2 (es) |
| DE (1) | DE69011300T2 (es) |
| DK (1) | DK168520B1 (es) |
| ES (1) | ES2060915T3 (es) |
| NO (1) | NO180746C (es) |
| RU (1) | RU2009111C1 (es) |
| UA (1) | UA26063A1 (es) |
Families Citing this family (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK131092A (da) * | 1992-10-27 | 1994-04-28 | Haldor Topsoe As | Fremgangsmåde til genvinding af syrekatalysatorer fra syrekatalyserede processer |
| US5233119A (en) * | 1992-11-09 | 1993-08-03 | Phillips Petroleum Company | Alkylation process and catalyst therefor |
| FR2699429B1 (fr) * | 1992-12-22 | 1995-01-27 | Inst Francais Du Petrole | Catalyseur d'alkylation de paraffines. |
| DK170019B1 (da) * | 1993-03-12 | 1995-05-01 | Topsoe Haldor As | Fremgangsmåde til genvinding af brugt fluoreret sulfonsyrekatalysator fra en alkyleringsproces |
| DK170396B1 (da) * | 1993-04-20 | 1995-08-21 | Topsoe Haldor As | Fremgangsmåde til genvinding af brugt fluoreret sulfonsyrekatalysator fra en alkyleringsproces |
| FR2704161B1 (fr) * | 1993-04-20 | 1995-06-02 | Inst Francais Du Petrole | Catalyseur d'alkylation de paraffines. |
| US5349116A (en) * | 1993-06-25 | 1994-09-20 | Phillips Petroleum Company | Alkane alkylation and catalyst therefor |
| DK171701B1 (da) * | 1993-07-06 | 1997-04-01 | Topsoe Haldor As | Fremgangsmåde til genvinding af brugt syrekatalysator fra alkylering af carbonhydrider |
| DK171639B1 (da) * | 1993-08-05 | 1997-03-03 | Topsoe Haldor As | Fremgangsmåde til alkylering af alifatiske carbonhydrider |
| IT1265051B1 (it) * | 1993-08-06 | 1996-10-28 | Eniricerche Spa | Processo per l'alchilazione di idrocarburi alifatici con olefine |
| DK93193D0 (da) * | 1993-08-13 | 1993-08-13 | Haldor Topsoe As | Alkylering |
| EP0645184B1 (fr) * | 1993-09-10 | 1997-07-30 | Institut Francais Du Petrole | Catalyseur d'alkylation d'isoparaffine C4-C5 par au moins une oléfine C3-C6 |
| US5364976A (en) * | 1993-10-29 | 1994-11-15 | Phillips Petroleum Company | Alkylation/etherification process |
| EP0663377A1 (en) * | 1994-01-13 | 1995-07-19 | Haldor Topsoe A/S | Alkylation process |
| DK171409B1 (da) * | 1994-03-10 | 1996-10-21 | Topsoe Haldor As | Fremgangsmåde til genvinding af alkyleringskatalysatorer |
| US5731256A (en) * | 1994-05-04 | 1998-03-24 | Institut Francais Du Petrole | Alkylation catalyst for C4 -C5 isoparaffins using at least one C2 -C6 olefin |
| FR2719503B1 (fr) * | 1994-05-04 | 1996-06-21 | Inst Francais Du Petrole | Catalyseur d'alkylation d'isoparaffine C4-C5 par au moins une oléfine C2-C6. |
| FR2719504B1 (fr) * | 1994-05-04 | 1996-06-21 | Inst Francais Du Petrole | Catalyseur d'alkylation d'isoparaffine C4-C5 par au moins une oléfine C2-C6. |
| DK173114B1 (da) * | 1994-06-02 | 2000-01-31 | Topsoe Haldor As | Fremgangsmåde til genvinding af brugt sulfonsyrekatalysator samt anvendelse af fremgangsmåden |
| DE69501483T2 (de) | 1994-06-13 | 1998-04-30 | Topsoe Haldor As | Verfahren zur Rückgewinnung eines starken Säures aus einer wässrigen Lösung |
| US5603812A (en) * | 1994-06-17 | 1997-02-18 | Haldor Tops.o slashed.e A/S | Process for the recovery of a strong acid from an aqueous solution |
| US5759357A (en) * | 1994-06-14 | 1998-06-02 | Haldor Topsoe A/S | Process for the recovery of a strong acid from an aqueous solution |
| DK171932B1 (da) * | 1994-12-02 | 1997-08-18 | Topsoe Haldor As | Fremgangsmåde til alkylering af alifatiske carbonhydrider |
| US5574201A (en) * | 1995-05-12 | 1996-11-12 | Phillips Petroleum Company | Alkylation process |
| EP0748784A1 (en) * | 1995-06-13 | 1996-12-18 | Haldor Topsoe A/S | Process for the preparation of alkylated aromatic compounds |
| DK172596B1 (da) | 1996-02-15 | 1999-02-15 | Topsoe Haldor As | Fremgangsmåde til fremstilling af et alkyleret carbonhydridprodukt ved trinvis væskefasealkylering af et carbonhydridsubstr |
| US5817908A (en) * | 1996-05-20 | 1998-10-06 | Amoco Corporation | Staged alkylation process |
| DK172906B1 (da) * | 1996-06-17 | 1999-09-27 | Topsoe Haldor As | Fremgangsmåde til fjernelse af korrosive bestanddele fra en fluidastrøm |
| US5968868A (en) * | 1996-07-04 | 1999-10-19 | Nippon Oil Co., Ltd. | Catalyst for use in the alkylation of isoalkanes |
| US6127309A (en) * | 1996-09-19 | 2000-10-03 | Nippon Oil Co., Ltd. | Catalyst for use in the alkylation of isoalkanes |
| DK123796A (da) * | 1996-11-05 | 1998-05-06 | Haldor Topsoe As | Fremgangsmåde til fremstilling af carbonhydrid produkt med et højt indhold af middeldistilleret produktfraktionering |
| US5849965A (en) * | 1997-05-22 | 1998-12-15 | Amoco Corporation | Multistage alkylation process |
| EP0889015B1 (en) * | 1997-07-04 | 2001-11-07 | Haldor Topsoe A/S | Process for the removal of acid compounds from a hydrocarbon stream |
| DK26298A (da) * | 1998-02-27 | 1999-08-28 | Haldor Topsoe As | Fremgangsmåde til genvinding af sulfonsyreester ud fra carbonhydridstrøm |
| CN1057989C (zh) | 1998-04-22 | 2000-11-01 | 中国石油化工总公司 | 异构烷烃与烯烃的烷基化方法 |
| EP0957086A3 (en) * | 1998-05-14 | 2003-02-12 | Haldor Topsoe A/S | Process for the removal of metal compounds from an aqueous acid solution |
| EP0976451A1 (en) | 1998-07-31 | 2000-02-02 | Haldor Topsoe A/S | Process for the recovery of perfluorinated sulphonic acids from spent acid |
| EP0987237B1 (en) * | 1998-09-14 | 2003-11-26 | Haldor Topsoe A/S | Process for the catalytic alkylation of a hydrocarbon feed |
| US6228797B1 (en) | 1998-12-11 | 2001-05-08 | Phillips Petroleum Company | Oligomerization catalyst system and method of making and method of using such catalyst system in the oligomerization of olefins |
| CN1100028C (zh) | 1999-07-22 | 2003-01-29 | 中国石油化工集团公司 | 一种异构烷烃与烯烃的烷基化方法 |
| US6395673B1 (en) * | 2000-06-29 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Catalyst of mixed fluorosulfonic acids |
| US6858770B2 (en) | 2001-08-21 | 2005-02-22 | Catalytic Distillation Technologies | Paraffin alkylation |
| US20040052703A1 (en) | 2001-08-21 | 2004-03-18 | Catalytic Distillation Technologies | Contact structures |
| US6852902B2 (en) * | 2002-03-15 | 2005-02-08 | Catalytic Distillation Technologies | Method of removing entrained sulfuric acid from alkylate |
| US7087803B2 (en) * | 2002-10-25 | 2006-08-08 | Haldor Topsoe A/S | Method for the recovery of perfluorinated sulphonic acid |
| CN1291954C (zh) * | 2004-01-19 | 2006-12-27 | 中国石油化工股份有限公司 | 一种固体酸催化异构烷烃与烯烃的烷基化反应方法 |
| US7119244B2 (en) * | 2005-01-13 | 2006-10-10 | Catalytic Distillation Technologies | Method of removing organic sulfur compounds from alkylate |
| US7344692B2 (en) | 2005-05-05 | 2008-03-18 | Catalytic Distillation Technologies | Process for regenerating spent sulfuric acid |
| US20060278568A1 (en) * | 2005-06-08 | 2006-12-14 | Catalytic Distillation Technologies | Method of removing oxygenated sulfur compounds from hydrocarbons |
| US7495290B2 (en) * | 2005-12-14 | 2009-02-24 | Infineon Technologies Ag | Semiconductor devices and methods of manufacture thereof |
| US20080063593A1 (en) * | 2006-09-08 | 2008-03-13 | Catalytic Distillation Technologies | Low temperature process for regenerating spent sulfuric acid |
| US8227366B2 (en) | 2009-06-01 | 2012-07-24 | Uop Llc | Alkylation system including a catalyst regeneration zone, and a process relating thereto |
| CN104587925B (zh) * | 2013-10-31 | 2017-01-25 | 中国石油化工股份有限公司 | 一种微丝接触反应器和一种烷基化反应方法 |
| WO2016210006A2 (en) | 2015-06-22 | 2016-12-29 | Exelus, Inc. | Improved catalyzed alkylation, alkylation catalysts, and methods of making alkylation catalysts |
| US11851386B2 (en) | 2021-10-15 | 2023-12-26 | Exelus, Inc. | Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2313103A (en) * | 1939-03-25 | 1943-03-09 | Universal Oil Prod Co | Alkylation of paraffin hydrocarbons |
| US3678120A (en) * | 1970-01-29 | 1972-07-18 | Universal Oil Prod Co | Hydrocarbon conversion catalyst and process |
| US3778489A (en) * | 1971-12-16 | 1973-12-11 | Exxon Research Engineering Co | Alkylation with separate olefin streams including isobutylene |
| US3976759A (en) * | 1974-12-30 | 1976-08-24 | Texaco Inc. | Process for removal of fluoride compounds from spent alkylation catalyst |
| US4073821A (en) * | 1977-02-28 | 1978-02-14 | Exxon Research & Engineering Co. | SO2 Stripping in fluorosulfuric acid catalyst regeneration |
| US4071576A (en) * | 1977-02-28 | 1978-01-31 | Exxon Research & Engineering Co. | Process for regenerating fluorosulfuric acid catalyst |
| JPS5524144A (en) * | 1978-08-10 | 1980-02-21 | Nippon Petrochem Co Ltd | Aralkylation process |
| IT1129809B (it) * | 1979-03-26 | 1986-06-11 | Ugine Kuhlmann | Composizione catalitica per la conversione di idrocarburi e procedimento per la disidratazione di acidi perfluoroalcansolfonici destinati a fare parte bella composizione |
| US4288646A (en) * | 1979-10-05 | 1981-09-08 | Pcuk Produits Chimiques Ugine Kuhlmann | Regioselective preparation of β-isopropylnaphthalene over superacidic solid or supported perfluorinated sulfonic acid catalysts |
| US4508618A (en) * | 1984-06-04 | 1985-04-02 | El Paso Products Company | Increasing the octane number of natural gasoline with trifluoromethanesulfonic acid |
| US4544794A (en) * | 1984-12-10 | 1985-10-01 | Atlantic Richfield Company | Alkylation aide for sulfuric acid catalyzed alkylation units |
| US4783567A (en) * | 1987-11-23 | 1988-11-08 | Uop Inc. | HF alkylation process |
-
1990
- 1990-06-08 DK DK140290A patent/DK168520B1/da not_active IP Right Cessation
- 1990-12-13 US US07/626,956 patent/US5220095A/en not_active Expired - Lifetime
- 1990-12-17 ES ES90124478T patent/ES2060915T3/es not_active Expired - Lifetime
- 1990-12-17 NO NO905436A patent/NO180746C/no unknown
- 1990-12-17 DE DE69011300T patent/DE69011300T2/de not_active Expired - Fee Related
- 1990-12-17 RU SU904831931A patent/RU2009111C1/ru not_active IP Right Cessation
- 1990-12-17 UA UA4831931A patent/UA26063A1/uk unknown
- 1990-12-17 EP EP90124478A patent/EP0433954B1/en not_active Expired - Lifetime
- 1990-12-17 AT AT90124478T patent/ATE109445T1/de not_active IP Right Cessation
- 1990-12-18 AU AU68143/90A patent/AU641713B2/en not_active Ceased
- 1990-12-18 AR AR90318652A patent/AR246501A1/es active
- 1990-12-18 JP JP2403190A patent/JPH0688914B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| NO180746C (no) | 1997-06-11 |
| DE69011300D1 (de) | 1994-09-08 |
| AR246501A1 (es) | 1994-08-31 |
| RU2009111C1 (ru) | 1994-03-15 |
| US5220095A (en) | 1993-06-15 |
| EP0433954A1 (en) | 1991-06-26 |
| AU6814390A (en) | 1991-06-20 |
| DK168520B1 (da) | 1994-04-11 |
| NO905436L (no) | 1991-06-19 |
| DK140290D0 (da) | 1990-06-08 |
| DK140290A (da) | 1991-06-19 |
| ATE109445T1 (de) | 1994-08-15 |
| JPH041141A (ja) | 1992-01-06 |
| AU641713B2 (en) | 1993-09-30 |
| UA26063A1 (uk) | 1999-04-30 |
| EP0433954B1 (en) | 1994-08-03 |
| NO180746B (no) | 1997-03-03 |
| NO905436D0 (no) | 1990-12-17 |
| JPH0688914B2 (ja) | 1994-11-09 |
| DE69011300T2 (de) | 1994-11-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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