ES2151084T3 - Polipropileno de mezcla de reactor y procedimiento para su preparacion. - Google Patents

Polipropileno de mezcla de reactor y procedimiento para su preparacion.

Info

Publication number
ES2151084T3
ES2151084T3 ES95942694T ES95942694T ES2151084T3 ES 2151084 T3 ES2151084 T3 ES 2151084T3 ES 95942694 T ES95942694 T ES 95942694T ES 95942694 T ES95942694 T ES 95942694T ES 2151084 T3 ES2151084 T3 ES 2151084T3
Authority
ES
Spain
Prior art keywords
preparation
fraction
mmmm
isotactic
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95942694T
Other languages
English (en)
Inventor
Luigi Resconi
Fabrizio Piemontesi
Lin-Chen Yu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from ITMI942566A external-priority patent/IT1271299B/it
Priority claimed from ITMI942567A external-priority patent/IT1271300B/it
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Application granted granted Critical
Publication of ES2151084T3 publication Critical patent/ES2151084T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465—Indenes; Completely or partially hydrogenated indenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61925—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SE REVELAN POLIPROPILENOS FRAGMENTABLES DE LA MEZCLA DE REACTIVOS QUE SE PUEDEN CONSEGUIR A PARTIR DE LA REACCION DE LA POLIMERIZACION DE PROPILENO, QUE TIENEN: (A) UN CONTENIDO DE PENTADAS ISOTACTICO (MMMM) COMPRENDIDO ENTRE EL 25 Y EL 85%, (B) UNA PROPORCION M{SUB,W}/M{SUB,N} < 5, QUE CONTIENEN DEL 10 AL 70% EN PESO DE UNA FRACCION SOLUBLE EN ETER DE DIETILO HIRVIENDO, DICHA FRACCION TIENE UN CONTENIDO DE PENTADAS ISOTACTICAS (MMMM) COMPRENDIDO ENTRE EL 5 Y EL 25%, Y DEL 30 AL 90% EN PESO DE UNA FRACCION DE N-HEPTANO INSOLUBLE HIRVIENDO, SOLUBLE EN XILENO A 135 C, DICHA FRACCION TIENE UN CONTENIDO DE PENTADAS ISOTACTICAS (MMMM) COMPRENDIDO ENTRE EL 50 Y EL 99%. ESTOS POLIMEROS SON ADECUADOS COMO MATERIALES TERMOPLASTICO-ELASTOMERICOS. TAMBIEN SE REVELA UN PROCESO PARA LA PREPARACION DE ESTOS POLIMEROS Y UN PROCESO PARA LA PREPARACION DE LIGANDOS DE METALOCENO DE INDENILO 2-ARIL-SUSTITUIDO.
ES95942694T 1994-12-20 1995-12-18 Polipropileno de mezcla de reactor y procedimiento para su preparacion. Expired - Lifetime ES2151084T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI942566A IT1271299B (it) 1994-12-20 1994-12-20 Composti metallocenici,loro leganti,procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione di olefine
ITMI942567A IT1271300B (it) 1994-12-20 1994-12-20 Polimero del propilene e procedimento per la sua preparazione

Publications (1)

Publication Number Publication Date
ES2151084T3 true ES2151084T3 (es) 2000-12-16

Family

ID=26331221

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95942694T Expired - Lifetime ES2151084T3 (es) 1994-12-20 1995-12-18 Polipropileno de mezcla de reactor y procedimiento para su preparacion.

Country Status (8)

Country Link
US (2) US5747621A (es)
EP (1) EP0745099B1 (es)
JP (1) JP3824325B2 (es)
CN (1) CN1147822A (es)
CA (1) CA2183419A1 (es)
DE (1) DE69518830T2 (es)
ES (1) ES2151084T3 (es)
WO (1) WO1996020225A2 (es)

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US5594080A (en) * 1994-03-24 1997-01-14 Leland Stanford, Jr. University Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US5705579A (en) * 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
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IT1292138B1 (it) * 1997-06-12 1999-01-25 Montell Technology Company Bv Film multistrato estensibili
WO1998057996A1 (en) * 1997-06-14 1998-12-23 The Board Of Trustees Of The Leland Stanford, Jr. University ETHYLENE ENHANCEMENT OF PROCESSES FOR SYNTHESIS OF HIGH MELTING THERMOPLASTIC ELASTOMERIC α-OLEFIN POLYMERS (PRE/EPE EFFECTS)
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7026404B2 (en) * 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US7232871B2 (en) 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6479685B2 (en) * 1998-01-09 2002-11-12 The Board Of Trustees Of The Leland Standard Junior University Metallocene catalysts for synthesis of high-melting polyolefin copolymer elastomers
US6518378B2 (en) * 1998-01-09 2003-02-11 The Board Of Trustees Of The Leland Stanford Junior University High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis
US6169151B1 (en) * 1998-01-09 2001-01-02 The Board Of Trustees Of The Leland Stanford Junior University High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis
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US6485664B1 (en) 1999-01-20 2002-11-26 Bp Corporation North America Inc. Extrusion crystallization of an olefin polymer
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CA2334743C (en) * 1999-04-15 2010-01-12 Basell Technology Company B.V. Components and catalysts for the polymerization of olefins
JP4438138B2 (ja) 1999-09-17 2010-03-24 住友化学株式会社 熱可塑性樹脂組成物
WO2001027169A1 (en) * 1999-10-08 2001-04-19 The Procter & Gamble Company Bodies of polymeric material comprising linear, isotactic polymers
US6863989B1 (en) 1999-10-08 2005-03-08 The Procter & Gamble Company Adhesives comprising linear isotactic polymers
US6727003B1 (en) 1999-10-08 2004-04-27 The Procter & Gamble Company Coating material comprising linear isotactic polymers
EP1237956A1 (en) * 1999-10-08 2002-09-11 The Procter & Gamble Company Coating material comprising linear, isotactic polymers
US6746780B1 (en) 1999-10-08 2004-06-08 The Procter & Gamble Company Bodies of polymeric material comprising linear, isotactic polymers
US6861143B2 (en) * 1999-11-17 2005-03-01 Pirelli Cavi E Sistemi S.P.A. Cable with recyclable covering
CN1222550C (zh) 1999-12-21 2005-10-12 巴塞尔聚烯烃有限公司 用于制备双轴拉伸聚丙烯膜的半结晶丙烯聚合物组合物
DE19962130A1 (de) 1999-12-21 2001-07-05 Basell Polypropylen Gmbh Teilkristalline Propylenpolymerisat-Zusammensetzungen mit guter Eignung zur Herstellung von biaxial orientierten Folien
EP1136525A1 (en) * 2000-03-23 2001-09-26 The Procter & Gamble Company A compatibilizer and modifier for polymeric compositions comprising polyolefins
US6770713B2 (en) 2000-03-23 2004-08-03 The Procter & Gamble Company Compatbilizer and modifier for polymeric compositions comprising polyolefins
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AU2002243244A1 (en) * 2000-11-30 2002-07-24 The Procter And Gamble Company High molecular weight polyolefin and catalyst and process for polymerising said polyolefin
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EP3148937B1 (en) * 2014-05-30 2019-09-18 Bridgestone Corporation Metallic complex catalyst and polymerization methods employing same
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Also Published As

Publication number Publication date
CN1147822A (zh) 1997-04-16
JPH09509982A (ja) 1997-10-07
JP3824325B2 (ja) 2006-09-20
EP0745099B1 (en) 2000-09-13
DE69518830D1 (de) 2000-10-19
US5747621A (en) 1998-05-05
CA2183419A1 (en) 1996-07-04
US6107431A (en) 2000-08-22
DE69518830T2 (de) 2001-03-22
EP0745099A1 (en) 1996-12-04
WO1996020225A3 (en) 1996-09-06
WO1996020225A2 (en) 1996-07-04

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