ES2128371T3 - Procedimiento para la obtencion de poliolefinas. - Google Patents

Procedimiento para la obtencion de poliolefinas.

Info

Publication number
ES2128371T3
ES2128371T3 ES93112580T ES93112580T ES2128371T3 ES 2128371 T3 ES2128371 T3 ES 2128371T3 ES 93112580 T ES93112580 T ES 93112580T ES 93112580 T ES93112580 T ES 93112580T ES 2128371 T3 ES2128371 T3 ES 2128371T3
Authority
ES
Spain
Prior art keywords
formula
meso
different
procedure
metalochene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93112580T
Other languages
English (en)
Inventor
Andreas Dr Winter
Martin Dr Antberg
Bernd Dr Bachmann
Volker Dr Dolle
Frank Dr Kuber
Jurgen Dr Rohrmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Targor GmbH
Original Assignee
Targor GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6465634&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2128371(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Targor GmbH filed Critical Targor GmbH
Application granted granted Critical
Publication of ES2128371T3 publication Critical patent/ES2128371T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Emergency Protection Circuit Devices (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)
  • Diaphragms And Bellows (AREA)

Abstract

PROCEDIMIENTO PARA LA FABRICACION DE UN POLIMERO DE OLEFINAS POR POLIMERIZACION O COPOLIMERIZACION DE UNA OLEFINA CON FORMULA RACH=CHRB, EN LA QUE RA Y RB SON IGUALES O DISTINTOS Y SIGNIFICAN UN ATOMO DE HIDROGENO O UN RESTO DE HIDROCARBURO CON 1 A 14 ATOMOS DE CARBONO O EN LA QUE RA Y RB PUEDEN FORMAR CON LOS ATOMOS QUE LOS UNEN UN ANILLO, A UN TEMPERATURA DE -60 A 200 GRADOS C, CON UNA PRESION DE 0,5 A 100 BARES, EN SOLUCION, EN SUSPENSION O EN LA FASE GASEOSA, EN PRESENCIA DE UN CATALIZADOR, QUE SE FORMA A PARTIR DE UN METALOCENO EN FORMA MESO O A PARTIR DE UNA MEZCLA MESO:RAC CON MESO:RAC < 1:99, COMO COMPUESTO METALICO DE TRANSICION Y DE UN COCATALIZADOR, CARACTERIZADO POR EL HECHO DE QUE EL METALOCENO ES UN COMPUESTO CON FORMULA I EN LA QUE M1 ES ZR O HF, R1 Y R2 SON IGUALES O DISTINTOS, SIENDO METILO O CLORO, R3 Y R6 SON IGUALES O DISTINTOS, SIENDO METILO, ISOPROPILO, FENILO, ETILO O TRIFLUORMETILO, R4 Y R5 SON HIDROGENO Y POSEEN EL SIGNIFICADO INDICADO PARA R3 Y R6, R4 CON R6 PUEDENFORMAR UN ANILLO ALIFATICO O AROMATICO Y R7 ES UN RESTO (FORMULA) O (FORMULA) CON M+N CERO O 1.
ES93112580T 1992-08-15 1993-08-05 Procedimiento para la obtencion de poliolefinas. Expired - Lifetime ES2128371T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4227049 1992-08-15

Publications (1)

Publication Number Publication Date
ES2128371T3 true ES2128371T3 (es) 1999-05-16

Family

ID=6465634

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93112580T Expired - Lifetime ES2128371T3 (es) 1992-08-15 1993-08-05 Procedimiento para la obtencion de poliolefinas.

Country Status (12)

Country Link
US (4) US5672668A (es)
EP (2) EP0882731A3 (es)
JP (1) JP3548755B2 (es)
KR (2) KR100283825B1 (es)
AT (1) ATE177436T1 (es)
AU (1) AU666565B2 (es)
CA (1) CA2104036A1 (es)
DE (1) DE59309424D1 (es)
ES (1) ES2128371T3 (es)
FI (1) FI110103B (es)
TW (1) TW309524B (es)
ZA (1) ZA935924B (es)

Families Citing this family (102)

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EP0882731A3 (de) 2000-05-31
US5672668A (en) 1997-09-30
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KR100301337B1 (ko) 2001-09-22
ATE177436T1 (de) 1999-03-15
JPH06157662A (ja) 1994-06-07
FI933573A7 (fi) 1994-02-16
EP0584609B1 (de) 1999-03-10
EP0584609A2 (de) 1994-03-02
KR100283825B1 (ko) 2001-03-02
KR940003974A (ko) 1994-03-14
ZA935924B (en) 1994-02-11
EP0882731A2 (de) 1998-12-09
AU666565B2 (en) 1996-02-15
US6028152A (en) 2000-02-22
US6359095B1 (en) 2002-03-19
DE59309424D1 (de) 1999-04-15
JP3548755B2 (ja) 2004-07-28
CA2104036A1 (en) 1994-02-16
TW309524B (es) 1997-07-01
US5693836A (en) 1997-12-02
AU4459193A (en) 1994-02-17

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