ES2154111A1 - Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo). - Google Patents

Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo).

Info

Publication number
ES2154111A1
ES2154111A1 ES009701978A ES9701978A ES2154111A1 ES 2154111 A1 ES2154111 A1 ES 2154111A1 ES 009701978 A ES009701978 A ES 009701978A ES 9701978 A ES9701978 A ES 9701978A ES 2154111 A1 ES2154111 A1 ES 2154111A1
Authority
ES
Spain
Prior art keywords
sub
formula
stabilizers
vinyl chloride
oligomeros
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009701978A
Other languages
English (en)
Other versions
ES2154111B1 (es
Inventor
Horst Zinke
Karl Josef Kuhn
Wolfgang Wehner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Galata Chemicals GmbH
Original Assignee
Witco Vinyl Additives GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Witco Vinyl Additives GmbH filed Critical Witco Vinyl Additives GmbH
Publication of ES2154111A1 publication Critical patent/ES2154111A1/es
Application granted granted Critical
Publication of ES2154111B1 publication Critical patent/ES2154111B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/1411—Esters of phosphorous acids with hydroxyalkyl compounds with further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/144—Esters of phosphorous acids with cycloaliphatic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6561—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom containing systems of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring or ring system, with or without other non-condensed hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65742—Esters of oxyacids of phosphorus non-condensed with carbocyclic rings or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)

Abstract

"Bisfosfitosmonómeros y oligómeros como estabilizadores del poli (cloruro de vinilo). Se describen composiciones que contienen (i) un material polimérico halogenado y (ii) por lo menos un fosfito de la fórmula I **FORMULA 1** en la que n es un número de 1 a 6, R es un eslabón bivalente de las fórmulas **FORMULA 2** **FORMULA 3** m es un número de 1 a 5, R{Sub,1}, R{sub,2}, R{sub,3} y R{sub,4}, con independencia entre sí, significan alquilo C{sub,4}-C{sub,22}, fenilalquilo C{sub,7}-C{sub,9}, cicloalquilo C{sub,5}-C{sub,8} o (alquil C{sub,1}-C{sub,4})- cicloalquilo C{sub,5}-C{sub,8} o bien R{sub,1} y R{sub,2} y/o R{sub,3} y R{sub,4}, juntos, significan alquileno C{sub,2}- C{sub,9} o un grupo de la fórmula **FORMULA 4** así como nuevos compuestos de la fórmula I y su utilización como estabilizadores.
ES009701978A 1996-09-25 1997-09-22 Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo). Expired - Fee Related ES2154111B1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH234396 1996-09-25

Publications (2)

Publication Number Publication Date
ES2154111A1 true ES2154111A1 (es) 2001-03-16
ES2154111B1 ES2154111B1 (es) 2001-10-16

Family

ID=4231591

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009701978A Expired - Fee Related ES2154111B1 (es) 1996-09-25 1997-09-22 Bisfosfitos monomeros y oligomeros como estabilizadores del poli(cloruro de vinilo).

Country Status (7)

Country Link
KR (1) KR100509258B1 (es)
BE (1) BE1012645A5 (es)
DK (1) DK110297A (es)
ES (1) ES2154111B1 (es)
NL (1) NL1007102C2 (es)
TW (1) TW402619B (es)
ZA (1) ZA978530B (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102011678B1 (ko) * 2012-06-22 2019-08-19 도버 케미칼 코포레이션 사이클로알리파틱 폴리포스파이트 폴리머 안정화제

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3283037A (en) * 1963-09-12 1966-11-01 Eastman Kodak Co Bis(cyclic 2, 2-dimethyltrimethylene) 1, 4-cyclohexanedimethylene phosphite
US4088709A (en) * 1977-07-01 1978-05-09 Eastman Kodak Company Phosphorus stabilized-polyester-polycarbonate molding compositions
DD229995A1 (de) * 1984-12-13 1985-11-20 Greiz Doelau Chemie Fluessiges cadmiumfreies stabilisatorsystem fuer formmassen des polyvinylchlorids
EP0437886A2 (en) * 1990-01-19 1991-07-24 EUROPEAN VINYLS CORPORATION (ITALIA) S.p.A. Stabilizer composition for polymers of vinyl chloride and polymeric compositions containing such compositions
EP0635512A1 (en) * 1993-07-22 1995-01-25 General Electric Company Cyclic phosphites as polymer stabilizers

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1236184B (de) * 1961-08-07 1967-03-09 Pure Chem Ltd Verfahren zur Herstellung von gegebenenfalls verschaeumten Polyurethanen
US3714116A (en) * 1970-04-08 1973-01-30 Raychem Corp Polyimide compositions
BE766399A (fr) * 1970-04-29 1971-10-28 Union Carbide Corp Polymeres ethyleniques thermostables
US3886114A (en) * 1973-08-24 1975-05-27 Vanderbilt Co R T Synergistic antioxidant combination

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3283037A (en) * 1963-09-12 1966-11-01 Eastman Kodak Co Bis(cyclic 2, 2-dimethyltrimethylene) 1, 4-cyclohexanedimethylene phosphite
US4088709A (en) * 1977-07-01 1978-05-09 Eastman Kodak Company Phosphorus stabilized-polyester-polycarbonate molding compositions
DD229995A1 (de) * 1984-12-13 1985-11-20 Greiz Doelau Chemie Fluessiges cadmiumfreies stabilisatorsystem fuer formmassen des polyvinylchlorids
EP0437886A2 (en) * 1990-01-19 1991-07-24 EUROPEAN VINYLS CORPORATION (ITALIA) S.p.A. Stabilizer composition for polymers of vinyl chloride and polymeric compositions containing such compositions
EP0635512A1 (en) * 1993-07-22 1995-01-25 General Electric Company Cyclic phosphites as polymer stabilizers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
National Polychemicals, Inc. Neth. Appl. 6410226, 11.03.1965. Columbus, OH (EE.UU) Chemical Abstracts, Vol. 63, 1965, resumen no 5850e, resumen. *
TCHERKERZOFF, N. New organic phosphorus compounds. Rev. Ins. Franc. Petrole Ann. Combust. liquides. 1963, 18 (3) 438-70. Columbus, OH (EE.UU): Chemical Abstracts, Vol. 59, resumen No 12800g, resumen. *

Also Published As

Publication number Publication date
NL1007102C2 (nl) 2000-11-14
DK110297A (da) 1998-03-26
KR19980024936A (ko) 1998-07-06
ES2154111B1 (es) 2001-10-16
KR100509258B1 (ko) 2005-12-14
NL1007102A1 (nl) 1998-03-26
TW402619B (en) 2000-08-21
MX9707315A (es) 1998-08-30
ZA978530B (en) 1998-03-25
BE1012645A5 (fr) 2001-02-06

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