ES2157273T3 - Procedimiento para producir atmosferas de tratamiento termico. - Google Patents

Procedimiento para producir atmosferas de tratamiento termico.

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Publication number
ES2157273T3
ES2157273T3 ES95108626T ES95108626T ES2157273T3 ES 2157273 T3 ES2157273 T3 ES 2157273T3 ES 95108626 T ES95108626 T ES 95108626T ES 95108626 T ES95108626 T ES 95108626T ES 2157273 T3 ES2157273 T3 ES 2157273T3
Authority
ES
Spain
Prior art keywords
endogenerator
sub
reactor
oxygen
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95108626T
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English (en)
Inventor
Den Sype Jaak Stefaan Van
Alan Russell Barlow
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Praxair Technology Inc
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Praxair Technology Inc
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22965619&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2157273(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Praxair Technology Inc filed Critical Praxair Technology Inc
Application granted granted Critical
Publication of ES2157273T3 publication Critical patent/ES2157273T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386Catalytic partial combustion
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material
    • C21D1/76Adjusting the composition of the atmosphere
    • C21D1/763Adjusting the composition of the atmosphere using a catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00654Controlling the process by measures relating to the particulate material
    • B01J2208/0069Attrition
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0816Heating by flames
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/085Methods of heating the process for making hydrogen or synthesis gas by electric heating
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0866Methods of heating the process for making hydrogen or synthesis gas by combination of different heating methods
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0877Methods of cooling by direct injection of fluid
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1011Packed bed of catalytic structures, e.g. particles, packing elements
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1029Catalysts in the form of a foam
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • C01B2203/107Platinum catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1082Composition of support materials
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1604Starting up the process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1642Controlling the product
    • C01B2203/1671Controlling the composition of the product
    • C01B2203/1676Measuring the composition of the product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

SE PROPORCIONA UN ENDOGENERADOR EN EL QUE SE GENERAN CO Y H{SUB,2} COMO PRODUCTOS PRIMARIOS DE OXIDACION DE HIDROCARBONO. CATALIZADORES DE METAL NOBLE COMO PLATINO (PT) Y PARTICULARMENTE RODIO (RH), SON CARGADOS A UN SOPORTE DE CERAMICA POROSA, POR EJEMPLO, UN PORTADOR DE ALUMINA. EN EL REACTOR DEL ENDOGENERADOR SE PRODUCE POCO O NADA DE CO Y H{SUB,2} MEDIANTE LAS REACCIONES DE REFORMA LENTA Y DE ENERGIA INTENSIVA Y ESTO PERMITE QUE UN REACTOR COMPACTO FUNCIONE AUTOTERMICAMENTE SIN ELEMENTOS DE CALENTAMIENTO AUXILIARES, Y CON VELOCIDADES ESPACIALES ALTAS EN DONDE LA VELOCIDAD ESPACIAL SE DEFINE COMO EL NUMERO DE PIES CUBICOS ESTANDAR POR HORA DE GAS DE SALIDA POR PIE CUBICO DEL PORTADOR CATALIZADOR. HIDROCARBONOS PREFERIDOS SON METANO O PROPANO, OXIDANTES PREFERIDOS SON MEZCLAS DE NITROGENO/OXIGENO CON DESDE EL 5% DE OXIGENO HASTA EL 100% DE OXIGENO. EL ENDOGENERADOR DE LA PRESENTE INVENCION PROPORCIONA UN PROCESO Y APARATO QUE GENERA EL CO Y H{SUB,2} DE GASES DE REDUCCION REQUERIDOS PARA APLICACIONES DE TRATAMIENTO DE CALOR QUE REQUIERAN ATMOSFERAS MAS ESCASAS Y POTENCIALES DE CARBON INFERIORES. LA PRESENTE INVENCION PROPORCIONA UN REACTOR QUE FUNCIONA AUTOTERMICAMENTE Y EN EL QUE TIENEN LUGAR VELOCIDADES ESPACIALES MUY ALTAS. LOS REACTORES DE LA PRESENTE INVENCION TAMBIEN PROPORCIONAN LA REDUCCION BARATA DE ELEMENTOS REQUERIDOS PARA OBTENER ATMOSFERAS SEPARADAS EN HORNOS DE TRATAMIENTO DE CALOR Y PERMITEN DE ESTE MODO LA INTRODUCCION DE NITROGENO BARATO PRODUCIDO POR MEMBRANAS O PSA EN TALES HORNOS.
ES95108626T 1994-06-06 1995-06-05 Procedimiento para producir atmosferas de tratamiento termico. Expired - Lifetime ES2157273T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/254,796 US5441581A (en) 1994-06-06 1994-06-06 Process and apparatus for producing heat treatment atmospheres

Publications (1)

Publication Number Publication Date
ES2157273T3 true ES2157273T3 (es) 2001-08-16

Family

ID=22965619

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95108626T Expired - Lifetime ES2157273T3 (es) 1994-06-06 1995-06-05 Procedimiento para producir atmosferas de tratamiento termico.

Country Status (9)

Country Link
US (2) US5441581A (es)
EP (1) EP0686701B1 (es)
JP (1) JP3410582B2 (es)
KR (1) KR100252709B1 (es)
CN (1) CN1047799C (es)
BR (1) BR9502662A (es)
CA (1) CA2150971C (es)
DE (1) DE69520910T2 (es)
ES (1) ES2157273T3 (es)

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US5441581A (en) * 1994-06-06 1995-08-15 Praxair Technology, Inc. Process and apparatus for producing heat treatment atmospheres
US5968457A (en) * 1994-06-06 1999-10-19 Praxair Technology, Inc. Apparatus for producing heat treatment atmospheres
NZ314334A (en) * 1996-04-19 1997-09-22 Boc Group Inc Method of heat treating a metal with nitrogen rich gas preheated and then having oxygen-reactive gas added
US6007763A (en) * 1996-04-23 1999-12-28 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process and installation for preparing a heat treatment atmosphere
DE19621036C2 (de) * 1996-05-24 2000-07-06 Westfalen Ag Vorrichtung zur Erzeugung von Endogas
US5735970A (en) * 1996-05-30 1998-04-07 Air Liquide America Corporation Apparatus and process for the production of a neutral atmosphere
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IT1291205B1 (it) * 1997-03-18 1998-12-29 Rivoira S P A Procedimento per la generazione di un'atmosfera protettiva a basso punto di rugiada ed esente da ossigeno, per l'effettuazione di
JP4013007B2 (ja) * 1998-08-28 2007-11-28 大阪瓦斯株式会社 水素−窒素混合ガスの製造方法およびその装置
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TWI568986B (zh) * 2011-04-22 2017-02-01 應用材料股份有限公司 改良的燈頭氛圍
RU2725983C2 (ru) * 2017-01-17 2020-07-08 Андрей Владиславович Курочкин Автотермический реактор
CN110079657B (zh) * 2019-05-17 2024-01-26 东台艺新金属材料有限公司 一种锯条回火炉中的气体混合供给装置

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Also Published As

Publication number Publication date
CN1126173A (zh) 1996-07-10
US5441581A (en) 1995-08-15
CA2150971A1 (en) 1995-12-07
DE69520910T2 (de) 2001-11-15
JP3410582B2 (ja) 2003-05-26
CN1047799C (zh) 1999-12-29
EP0686701B1 (en) 2001-05-16
JPH08169701A (ja) 1996-07-02
CA2150971C (en) 1999-05-11
KR100252709B1 (ko) 2000-04-15
KR960001143A (ko) 1996-01-25
EP0686701A1 (en) 1995-12-13
BR9502662A (pt) 1996-02-27
DE69520910D1 (de) 2001-06-21
US5785774A (en) 1998-07-28

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