ES2162007T3 - Estabilizacion de composiciones liquidas endurecibles por radiaciones, contra una indeseable prematura polimerizacion. - Google Patents

Estabilizacion de composiciones liquidas endurecibles por radiaciones, contra una indeseable prematura polimerizacion.

Info

Publication number
ES2162007T3
ES2162007T3 ES96810123T ES96810123T ES2162007T3 ES 2162007 T3 ES2162007 T3 ES 2162007T3 ES 96810123 T ES96810123 T ES 96810123T ES 96810123 T ES96810123 T ES 96810123T ES 2162007 T3 ES2162007 T3 ES 2162007T3
Authority
ES
Spain
Prior art keywords
polymerization
enduritible
stabilization
radiations
indeseable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES96810123T
Other languages
English (en)
Inventor
Adrian Schulthess
Bettina Steinmann
Manfred Hofmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Advanced Materials Switzerland GmbH
Original Assignee
Vantico GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vantico GmbH filed Critical Vantico GmbH
Application granted granted Critical
Publication of ES2162007T3 publication Critical patent/ES2162007T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0037Production of three-dimensional images
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/0045Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/029Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/038Macromolecular compounds which are rendered insoluble or differentially wettable

Landscapes

  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Epoxy Resins (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO PARA ESTABILIZAR UNA COMPOSICION LIQUIDA ENDURECIBLE POR RADIACION, CONTENIENDO UN COMPUESTO CATIONICAMENTE POLIMERIZABLE, Y UN FOTOINICIADOR PARA LA POLIMERIZACION CATIONICA, CONTRA UN INICIO TEMPRANO DE LA POLIMERIZACION, HACIENDO ENTRAR EN CONTACTO UN INTERCAMBIADOR BASICO DE IONES CON LA COMPOSICION AL MENOS TEMPORALMENTE. PREFERIBLEMENT EL INTERCAMBIADOR DE IONES NO DEBE ESTAR EN CONTACTO POR LO MENOS CON LA PARTE DE LA COMPOSICION QUE SEA SENSIBLE A LAS RADIACIONES ANTES DEL COMIENZO DEL ENDURECIMIENTO POR RADIACION. EL PROCEDIMIENTO ESTA ESPECIALMENTE INDICADO PARA LA ESTABILIZACION DE BAÑOS DE ESTEREOLITOGRAFIA QUE HAN SIDO MUY UTILIZADOS, PARA EVITAR UN AUMENTO NO DESEADO DE LA VISCOSIDAD.
ES96810123T 1995-03-13 1996-03-05 Estabilizacion de composiciones liquidas endurecibles por radiaciones, contra una indeseable prematura polimerizacion. Expired - Lifetime ES2162007T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH71795 1995-03-13
US08/611,914 US5783358A (en) 1995-03-13 1996-03-06 Stabilization of liquid radiation-curable compositions against undesired premature polymerization

Publications (1)

Publication Number Publication Date
ES2162007T3 true ES2162007T3 (es) 2001-12-16

Family

ID=25685464

Family Applications (1)

Application Number Title Priority Date Filing Date
ES96810123T Expired - Lifetime ES2162007T3 (es) 1995-03-13 1996-03-05 Estabilizacion de composiciones liquidas endurecibles por radiaciones, contra una indeseable prematura polimerizacion.

Country Status (10)

Country Link
US (1) US5783358A (es)
EP (1) EP0732625B1 (es)
JP (1) JPH08259614A (es)
KR (1) KR960034239A (es)
AT (1) ATE205607T1 (es)
AU (1) AU704046B2 (es)
CA (1) CA2171504A1 (es)
DE (1) DE59607650D1 (es)
ES (1) ES2162007T3 (es)
TW (1) TW418215B (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW311923B (es) * 1992-01-27 1997-08-01 Ciba Sc Holding Ag
ATE208703T1 (de) * 1995-12-22 2001-11-15 Vantico Ag Verfahren zur stereolithografischen herstellung von dreidimensionalen gegenständen durch gebrauch eines strahlungshärtenden harzes mit füllstoff
CN1195356A (zh) * 1996-06-12 1998-10-07 日本化药株式会社 光聚合引发剂和包含它的可能量射线固化的组合物
US5902441A (en) 1996-09-04 1999-05-11 Z Corporation Method of three dimensional printing
US7332537B2 (en) 1996-09-04 2008-02-19 Z Corporation Three dimensional printing material system and method
JP3955333B2 (ja) 1996-11-08 2007-08-08 デーエスエム アイピー アセッツ ベー.ヴェー. 放射線硬化性の光ガラスファイバー被覆用組成物、被覆光ガラスファイバー、及び光ガラスファイバーアセンブリー
JP3765896B2 (ja) 1996-12-13 2006-04-12 Jsr株式会社 光学的立体造形用光硬化性樹脂組成物
FR2757530A1 (fr) * 1996-12-24 1998-06-26 Rhodia Chimie Sa Utilisation pour la stereophotolithographie - d'une composition liquide photoreticulable par voie cationique comprenant un photoamorceur du type sels d'onium ou de complexes organometalliques
JPH1171363A (ja) * 1997-06-25 1999-03-16 Wako Pure Chem Ind Ltd レジスト組成物及びこれを用いたパターン形成方法並びにレジスト剤用架橋剤
WO1999005572A2 (en) * 1997-07-21 1999-02-04 Ciba Specialty Chemicals Holding Inc. Viscosity stabilization of radiation-curable compositions
US6110593A (en) 1998-05-21 2000-08-29 Dsm N.V. Radiation-curable optical fiber primary coating system
WO2001034371A2 (en) * 1999-11-05 2001-05-17 Z Corporation Material systems and methods of three-dimensional printing
US20010050031A1 (en) 2000-04-14 2001-12-13 Z Corporation Compositions for three-dimensional printing of solid objects
US6811937B2 (en) 2001-06-21 2004-11-02 Dsm Desotech, Inc. Radiation-curable resin composition and rapid prototyping process using the same
JP3797348B2 (ja) * 2003-02-24 2006-07-19 コニカミノルタホールディングス株式会社 活性エネルギー線硬化組成物
CA2526100A1 (en) 2003-05-21 2004-12-29 Z Corporation Thermoplastic powder material system for appearance models from 3d printing systems
DE112004001165T5 (de) * 2003-06-25 2006-05-04 Cmet Inc., Yokohama Durch aktinische Strahlung härtbare stereolithographische Harzzusammensetzung mit verbesserter Stabilität
US20060247401A1 (en) * 2003-06-25 2006-11-02 Masashi Date Process for production of monosulfonium salts, cationic polymerization initiators, curable compositions, and products of curing
US7192991B2 (en) * 2003-11-26 2007-03-20 3M Innovative Properties Company Cationically curable composition
US7261542B2 (en) 2004-03-18 2007-08-28 Desktop Factory, Inc. Apparatus for three dimensional printing using image layers
JP4750381B2 (ja) * 2004-05-31 2011-08-17 Jsr株式会社 光学的立体造形用放射線硬化性液状樹脂組成物及びそれを光硬化させて得られる光造形物
WO2007148822A1 (en) 2006-06-23 2007-12-27 Canon Kabushiki Kaisha Polyfunctional epoxy compound, epoxy resin, cationic photopolymerizable epoxy resin composition, micro structured member, producing method therefor and liquid discharge head
CN101568422B (zh) 2006-12-08 2013-02-13 3D系统公司 使用过氧化物固化的三维印刷材料体系和方法
WO2008086033A1 (en) 2007-01-10 2008-07-17 Z Corporation Three-dimensional printing material system with improved color, article performance, and ease of use
US7968626B2 (en) 2007-02-22 2011-06-28 Z Corporation Three dimensional printing material system and method using plasticizer-assisted sintering
EP2778782B1 (en) 2013-03-13 2015-12-30 Kodak Graphic Communications GmbH Negative working radiation-sensitive elements
CN112074395A (zh) * 2018-03-02 2020-12-11 福姆实验室公司 潜伏性固化树脂及相关方法
CN112654490B (zh) * 2020-11-29 2022-06-21 苏州铼赛智能科技有限公司 底面曝光的3d打印设备、控制方法及控制系统

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3708296A (en) 1968-08-20 1973-01-02 American Can Co Photopolymerization of epoxy monomers
US4339567A (en) 1980-03-07 1982-07-13 Ciba-Geigy Corporation Photopolymerization by means of sulphoxonium salts
US4383025A (en) * 1980-07-10 1983-05-10 Ciba-Geigy Corporation Photopolymerization by means of sulfoxonium salts
US4398014A (en) 1980-11-04 1983-08-09 Ciba-Geigy Corporation Sulfoxonium salts and their use as polymerization catalysts
EP0094915B1 (de) 1982-05-19 1987-01-21 Ciba-Geigy Ag Härtbare, Metallocenkomplexe enthaltende Zusammensetzungen, daraus erhältliche aktivierte Vorstufen und deren Verwendung
EP0094914B1 (de) 1982-05-19 1986-09-24 Ciba-Geigy Ag Photopolymerisation mittels organometallischer Salze
US5073476A (en) 1983-05-18 1991-12-17 Ciba-Geigy Corporation Curable composition and the use thereof
EP0153904B1 (de) 1984-02-10 1988-09-14 Ciba-Geigy Ag Verfahren zur Herstellung einer Schutzschicht oder einer Reliefabbildung
US4536604A (en) * 1984-03-15 1985-08-20 Texaco Inc. Butadiene reductive dimerization using a platinum catalyst and polymeric amine promoter
GB8414525D0 (en) 1984-06-07 1984-07-11 Ciba Geigy Ag Sulphoxonium salts
US4575330A (en) * 1984-08-08 1986-03-11 Uvp, Inc. Apparatus for production of three-dimensional objects by stereolithography
US4772541A (en) 1985-11-20 1988-09-20 The Mead Corporation Photohardenable compositions containing a dye borate complex and photosensitive materials employing the same
US4772530A (en) 1986-05-06 1988-09-20 The Mead Corporation Photosensitive materials containing ionic dye compounds as initiators
EP0223587B1 (en) 1985-11-20 1991-02-13 The Mead Corporation Photosensitive materials containing ionic dye compounds as initiators
US4751102A (en) 1987-07-27 1988-06-14 The Mead Corporation Radiation-curable ink and coating compositions containing ionic dye compounds as initiators
ATE161860T1 (de) 1988-02-19 1998-01-15 Asahi Denka Kogyo Kk Kunststoffzusammensetzung für optisches modellieren
JPH01228560A (ja) * 1988-03-08 1989-09-12 Hitachi Chem Co Ltd 不純金属成分の低減された溶液の製造法
US5378802A (en) * 1991-09-03 1995-01-03 Ocg Microelectronic Materials, Inc. Method for removing impurities from resist components and novolak resins
KR950000099B1 (ko) * 1991-11-12 1995-01-09 삼성전자 주식회사 바이너리 코딩(Bianry Coding)법을 이용한 반도체소자의 위치인식방법
KR100242920B1 (ko) * 1992-03-06 2000-03-02 잰대머 저수준의 금속이온을 갖는 포토레지스트(rhotoresists having a low level of metal ions)
TW269017B (es) 1992-12-21 1996-01-21 Ciba Geigy Ag
JP3282284B2 (ja) * 1993-03-31 2002-05-13 日本ゼオン株式会社 感光性組成物の処理方法
US5350714A (en) * 1993-11-08 1994-09-27 Shipley Company Inc. Point-of-use purification

Also Published As

Publication number Publication date
CA2171504A1 (en) 1996-09-14
TW418215B (en) 2001-01-11
ATE205607T1 (de) 2001-09-15
JPH08259614A (ja) 1996-10-08
AU4806096A (en) 1996-09-26
DE59607650D1 (de) 2001-10-18
KR960034239A (ko) 1996-10-22
EP0732625A3 (de) 1996-09-25
EP0732625B1 (de) 2001-09-12
EP0732625A2 (de) 1996-09-18
AU704046B2 (en) 1999-04-15
US5783358A (en) 1998-07-21

Similar Documents

Publication Publication Date Title
ES2162007T3 (es) Estabilizacion de composiciones liquidas endurecibles por radiaciones, contra una indeseable prematura polimerizacion.
AR038651A1 (es) Una composicion de un polimero superabsorbente de color estable; un articulo que la comprende; un metodo para fabricar dicha composicion y un metodo para prevenir la decoloracion de particulas de polimero superabsorbente
GB1103245A (en) Method of manufacturing soft, flexible contact lenses
MX9302872A (es) Procedimiento para mejorar la resistencia al blanqueado por el agua de adhesivos sensibles a la presion.
ES2083074T3 (es) Dispositivo de liberacion controlada.
ES2097782T3 (es) Metodo y composicion para la determinacion de iones sodio en fluidos.
ES2193384T3 (es) Dispositivo medico.
SV2002000250A (es) Formula de dosis de droga accionada por hidrogel ref. pc10818ajtb/bb
ES2069012T3 (es) Tinta y metodo para impresion por chorros.
BR9813802A (pt) Dispositivo eletroquìmico para controlar reversivelmente a propagação de radiação eletromagnética.
ES2123323T3 (es) Asociacion de un compuesto con actividad antimicrobiana (por ejemplo lipoaminoacido n,n-octanoilglicina) y de un monoalquileter de glicerol y su uso como agente antimicrobiano.
BR9916560A (pt) Estrutura absorvente composta, método para formar a mesma, e produto absorvente descartável
ES2184679T3 (es) Composicion de gel y su uso en composiciones cosmeticas y similares.
BR9811609A (pt) Sensor eletroquìmico com áreas de elétrodo equalizadas
DK566686A (da) Rensning og/eller desinfektion af kontaktlinser
BR0210314A (pt) Embalagem solúvel em água com uma composição de condicionamento de enxágue lìquida substancialmente não aquosa em seu interior
GB1078165A (en) Improvements in or relating to method for producing anodic films on beryllium
ES2039898T3 (es) Acondicionamiento para una composicion liquida lista para su uso realizada a partir de una composicion liquida concentrada y procedimiento de realizacion.
AR077053A2 (es) Formulacion liquida concentrada desinfectante.
ES2111547T3 (es) Comprimido de liberacion prolongada.
ES2191595T3 (es) Peliculas de eter de celulosa.
ES2029297T3 (es) Empleo de una composicion para el tratamiento de las superficies de los suelos.
ES459237A1 (es) Un procedimiento para la esterilizacion de las superficies de materiales de embalaje.
GB2006114A (en) Printing on soft contact lenses
AU2084383A (en) Agent for retarding polymerization of aziridine compounds

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 732625

Country of ref document: ES