ES2164855T3 - Catalizador de hidrogenacion selectiva y procedimiento que utiliza este catalizador. - Google Patents
Catalizador de hidrogenacion selectiva y procedimiento que utiliza este catalizador.Info
- Publication number
- ES2164855T3 ES2164855T3 ES96402687T ES96402687T ES2164855T3 ES 2164855 T3 ES2164855 T3 ES 2164855T3 ES 96402687 T ES96402687 T ES 96402687T ES 96402687 T ES96402687 T ES 96402687T ES 2164855 T3 ES2164855 T3 ES 2164855T3
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- sub
- selective hydrogenation
- paladio
- catalyzer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
- C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/48—Silver or gold
- C07C2523/50—Silver
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/58—Platinum group metals with alkali- or alkaline earth metals or beryllium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
SE DESCRIBE UN CATALIZADOR PARA LA HIDROGENACION SELECTIVA EN FASE GASEOSA DE COMPUESTOS ACETILENICOS DE 2 O 3 ATOMOS DE CARBONO EN LOS COMPUESTOS ETILENICOS CORRESPONDIENTES, COMPRENDIENDO DICHO CATALIZADOR, EN FORMA DE BOLAS O DE EXTRUSIONADOS, PALADIO,AL MENOS UN METAL DEL GRUPO IB Y EVENTUALMENTE AL MENOS UN METAL ALCALINO O ALCALINOTERREO Y ALUMINIO, EN EL QUE AL MENOS 80% DEL PALADIO Y AL MENOS 80% DE ELEMENTO DEL GRUPO IB ESTAN PRESENTES EN UN VOLUMEN EN LA PERIFERIA DEL CATALIZADOR DEFINIDO ENTRE UNA SUPERFICIE ESFERIA O CILINDRICA DE RADIO R{SUB,1} QUE CORRESPONDE AL RADIO MEDIO DE LAS BOLAS O EXTRUSIONADOS DE CATALIZADOR Y UNA SUPERFICIE ESFERICA O CILINDRICA DE RADIO R{SUB,2} AL MENOS IGUAL A 0,8 R{SUB,1}, ESTE CATALIZADOR PRESENTA UNA RELACION PONDERAL DE METAL DEL GRUPO IB/PALADIO DE 0,4 A 3. ADEMAS, PARA ESTE CATALIZADOR, ES VENTAJOSO QUE AL MENOS 30 DE LAS PARTICULAS METALICAS CONTENGAN A LA VEZ PALADIO Y PLATA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9515340A FR2742679B1 (fr) | 1995-12-22 | 1995-12-22 | Catalyseur d'hydrogenation selective et procede utilisant ce catalyseur |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2164855T3 true ES2164855T3 (es) | 2002-03-01 |
Family
ID=9485848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES96402687T Expired - Lifetime ES2164855T3 (es) | 1995-12-22 | 1996-12-10 | Catalizador de hidrogenacion selectiva y procedimiento que utiliza este catalizador. |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0780155B1 (es) |
| JP (1) | JPH09173843A (es) |
| KR (1) | KR100449965B1 (es) |
| DE (1) | DE69615514T2 (es) |
| ES (1) | ES2164855T3 (es) |
| FR (1) | FR2742679B1 (es) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6096933A (en) * | 1996-02-01 | 2000-08-01 | Phillips Petroleum Company | Hydrocarbon hydrogenation and catalyst therefor |
| DE19839459A1 (de) * | 1998-08-29 | 2000-03-02 | Basf Ag | Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen |
| DE19840373A1 (de) * | 1998-09-04 | 2000-03-09 | Basf Ag | Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen |
| DE19959064A1 (de) | 1999-12-08 | 2001-06-13 | Basf Ag | Trägerkatalysator zur Selektivhydrierung von Alkinen und Dienen |
| DE10048219A1 (de) * | 2000-02-10 | 2002-04-11 | Sued Chemie Ag | Katalysator für die Hydrierung von ungesättigten Kohlenwasserstoffen |
| DE102004059282A1 (de) | 2004-10-13 | 2006-04-27 | Basf Ag | Selektivhydrierkatalysator |
| JP5222278B2 (ja) * | 2006-03-21 | 2013-06-26 | ビーエーエスエフ ソシエタス・ヨーロピア | アミンの製造法 |
| DE102007025315A1 (de) | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung |
| DE102007025442B4 (de) * | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| DE102009018109A1 (de) | 2009-04-20 | 2010-11-18 | Süd-Chemie AG | Verfahren zur Herstellung eines geträgerten Ag/Pd-Katalysators |
| DE102009018110A1 (de) | 2009-04-20 | 2010-10-21 | Süd-Chemie AG | Silber-Palladium-Mischoxid, Verfahren zu seiner Herstellung sowie Verwendung |
| US8481451B2 (en) | 2009-06-08 | 2013-07-09 | Lg Chem, Ltd. | Catalyst for hydrocarbon steam cracking, method of preparing the same and method of preparing olefin by using the same |
| KR101072177B1 (ko) | 2009-06-08 | 2011-10-10 | 주식회사 엘지화학 | 탄화수소 수증기 열분해용 촉매, 그의 제조방법 및 이를 이용한 올레핀의 제조방법 |
| DE102009051462B4 (de) | 2009-10-30 | 2015-02-05 | Clariant International Ag | Verfahren zur Herstellung eines Kompositmaterials, Kompositmaterial und dessen Verwendung |
| DE102010030990A1 (de) | 2010-07-06 | 2012-01-12 | Evonik Oxeno Gmbh | Verfahren zur selektiven Hydrierung von mehrfach ungesättigten Kohlenwasserstoffen in olefinhaltigen Kohlenwasserstoffgemischen |
| TW201247315A (en) | 2011-05-16 | 2012-12-01 | Du Pont | Catalytic hydrogenation of fluoroolefins, alpha-alumina supported palladium compositions and their use as hydrogenation catalysts |
| US20130102819A1 (en) | 2011-10-19 | 2013-04-25 | Normen Szesni | Catalyst composition for selective hydrogenation with improved characteristics |
| EP2583751B1 (en) | 2011-10-19 | 2014-12-03 | Clariant Produkte (Deutschland) GmbH | Catalyst composition for selective hydrogenation with improved characteristics |
| FR2991197B1 (fr) * | 2012-05-31 | 2014-08-22 | IFP Energies Nouvelles | Catalyseur comprenant du palladium et de l'argent et son application en hydrogenation selective |
| DE102012212317A1 (de) | 2012-07-13 | 2014-01-16 | Evonik Industries Ag | Thioveretherung von Mercaptanen in C4-Kohlenwasserstoffgemischen |
| KR102937606B1 (ko) * | 2021-10-27 | 2026-03-10 | 에스케이이노베이션 주식회사 | 높은 아세틸렌 함량을 갖는 가스 혼합물의 선택적 수소화 공정 |
| FR3137848A1 (fr) * | 2022-07-18 | 2024-01-19 | IFP Energies Nouvelles | Procede de preparation d’un catalyseur comprenant un metal du groupe viii et un support sous la forme d’un monolithe ou d’une mousse enduit d’alumine alpha |
| FR3137849A1 (fr) * | 2022-07-18 | 2024-01-19 | IFP Energies Nouvelles | Procede de preparation d’un catalyseur comprenant un metal du groupe viii a partir d’une alumine alpha |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2802889A (en) | 1954-06-01 | 1957-08-13 | Dow Chemical Co | Selective hydrogenation of acetylene in ethylene and catalyst therefor |
| US3243387A (en) | 1963-04-25 | 1966-03-29 | Leuna Werke Veb | Palladium-silver-iron oxide on alphaalumina catalyst composition for the selective hydrogenation of acetylene |
| US3325556A (en) | 1964-05-18 | 1967-06-13 | Universal Oil Prod Co | Selective hydrogenation of acetylene in a mixture of acetylene and other unsaturated hydrocarbons |
| US3651167A (en) * | 1970-08-03 | 1972-03-21 | Universal Oil Prod Co | Selective hydrogenation of c4-acetylenic hydrocarbons |
| DE3064972D1 (en) | 1979-11-20 | 1983-10-27 | Ici Plc | Hydrogenation catalyst material, a precursor thereto, method of making the latter and use of the catalyst for selective hydrogenation |
| US4404124A (en) | 1981-05-06 | 1983-09-13 | Phillips Petroleum Company | Selective hydrogenation catalyst |
| FR2523149A1 (fr) | 1982-03-15 | 1983-09-16 | Catalyse Soc Prod Francais | Nouveau catalyseur supporte palladium-or, sa preparation et son utilisation dans les reactions d'hydrogenation selective d'hydrocarbures diolefiniques et/ou acetyleniques |
| FR2539647B1 (fr) | 1983-01-24 | 1985-06-07 | Inst Francais Du Petrole | Procede de preparation de catalyseurs bimetalliques ou plurimetalliques supportes a base d'un ou plusieurs metaux du groupe viii et d'au moins un metal du groupe iv catalyseurs obtenus et leurs utilisations |
| DE3312252A1 (de) | 1983-04-05 | 1984-10-11 | EC Erdölchemie GmbH, 5000 Köln | Hydrierkatalysator, verfahren zu seiner herstellung und seine verwendung |
| DD270442A3 (de) | 1986-04-10 | 1989-08-02 | Grotewohl Boehlen Veb | Rieselphasenverfahren zur selektiven hydrierung stark ungesaettigter kohlenwasserstoffe |
| US5004859A (en) * | 1989-11-13 | 1991-04-02 | Uop | Catalyst for the isomerization of alkanes |
| EP0686615B2 (fr) * | 1994-06-09 | 2007-06-27 | Institut Francais Du Petrole | Procédé d'hydrogénation catalytique et catalyseur utilisable dans ce procédé |
| FR2721018B1 (fr) | 1994-06-09 | 1996-08-09 | Inst Francais Du Petrole | Procédé d'hydrogénation catalytique et catalyseur utilisable dans ce procédé. |
-
1995
- 1995-12-22 FR FR9515340A patent/FR2742679B1/fr not_active Expired - Lifetime
-
1996
- 1996-12-10 EP EP96402687A patent/EP0780155B1/fr not_active Revoked
- 1996-12-10 ES ES96402687T patent/ES2164855T3/es not_active Expired - Lifetime
- 1996-12-10 DE DE69615514T patent/DE69615514T2/de not_active Revoked
- 1996-12-18 JP JP8337964A patent/JPH09173843A/ja active Pending
- 1996-12-20 KR KR1019960069060A patent/KR100449965B1/ko not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0780155B1 (fr) | 2001-09-26 |
| EP0780155A1 (fr) | 1997-06-25 |
| JPH09173843A (ja) | 1997-07-08 |
| FR2742679B1 (fr) | 1998-01-16 |
| FR2742679A1 (fr) | 1997-06-27 |
| KR970033027A (ko) | 1997-07-22 |
| KR100449965B1 (ko) | 2004-12-13 |
| DE69615514T2 (de) | 2002-04-25 |
| DE69615514D1 (de) | 2001-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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