ES2166553T3 - Procedimiento mejorado para halogenar copolimeros de isomonoolefinas. - Google Patents
Procedimiento mejorado para halogenar copolimeros de isomonoolefinas.Info
- Publication number
- ES2166553T3 ES2166553T3 ES97933558T ES97933558T ES2166553T3 ES 2166553 T3 ES2166553 T3 ES 2166553T3 ES 97933558 T ES97933558 T ES 97933558T ES 97933558 T ES97933558 T ES 97933558T ES 2166553 T3 ES2166553 T3 ES 2166553T3
- Authority
- ES
- Spain
- Prior art keywords
- find
- improved procedure
- reaction
- isomonoolefin
- isomonoolefin copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 230000026030 halogenation Effects 0.000 abstract 1
- 238000005658 halogenation reaction Methods 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
SE DESCRIBE UN PROCEDIMIENTO PARA HALOGENAR UN COPOLIMERO DE UNA ISOMONOOLEFINA DE C 4 A C 7 , POR EJEMPLO, ISOBUTILENO, Y UNA MULTIOLEFINA, POR EJEMPLO, ISOPRENO O UN PARA - ALQUILESTIRENO, POR EJEMPLO, PARA - METILESTIRENO. EL AUMENTO DE LA EFICIENCIA DE LA HALOGENACION Y LA DISMINUCION DEL TIEMPO DE REACCION SE CONSIGUEN DESARROLLANDOSE LA REACCION EN PRESENCIA DE UNA FUENTE DE HALOGENO Y DE UNA EMULSION ACUOSA QUE CONTIENE UN AGENTE OXIDANTE SOLUBLE EN AGUA, POR EJEMPLO, PEROXIDO DE HIDROGENO, QUE OXIDA EL HALURO DE HIDROGENO GENERADO IN SITU EN LA REACCION, CONVIRTIENDOLO DE NUEVO EN HALOGENO LIBRE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/685,403 US5681901A (en) | 1996-07-24 | 1996-07-24 | Process for halogenating isomonoolefin copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2166553T3 true ES2166553T3 (es) | 2002-04-16 |
Family
ID=24752063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97933558T Expired - Lifetime ES2166553T3 (es) | 1996-07-24 | 1997-07-18 | Procedimiento mejorado para halogenar copolimeros de isomonoolefinas. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5681901A (es) |
| EP (1) | EP0914356B1 (es) |
| JP (1) | JP4689770B2 (es) |
| KR (1) | KR100488327B1 (es) |
| CN (1) | CN1225649A (es) |
| AT (1) | AT406581B (es) |
| BR (1) | BR9710539A (es) |
| CA (1) | CA2257812C (es) |
| DE (1) | DE69709648T2 (es) |
| EA (1) | EA199900111A1 (es) |
| ES (1) | ES2166553T3 (es) |
| HU (1) | HUP9904331A3 (es) |
| PL (1) | PL330990A1 (es) |
| WO (1) | WO1998003562A1 (es) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5670582A (en) * | 1996-07-24 | 1997-09-23 | Exxon Chemical Patents Inc. | Process for halogenation of isomonoolefin/para-alkylstyrene copolymers |
| CA2282900C (en) * | 1999-09-20 | 2011-02-01 | Bayer Inc. | Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer |
| US20060167184A1 (en) * | 2000-10-18 | 2006-07-27 | Waddell Walter H | Innerliners for use in tires |
| TWI229089B (en) * | 2000-12-12 | 2005-03-11 | Bayer Ag | Halogenated, high molecular weight, gel-free isobutene copolymers with elevated double bond contents |
| RU2186789C1 (ru) * | 2001-01-12 | 2002-08-10 | Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" | Способ получения галоидированного бутилкаучука |
| AU2002353093A1 (en) * | 2001-12-10 | 2003-07-09 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
| CN100402558C (zh) * | 2002-12-20 | 2008-07-16 | 埃克森美孚化学专利公司 | 聚合方法 |
| EP1905581A1 (en) | 2003-10-27 | 2008-04-02 | ExxonMobil Chemical Patents Inc. | Microlayered composites and processes for making the same |
| ATE451253T1 (de) * | 2005-07-01 | 2009-12-15 | Pirelli | Verfahren zur herstellung von reifen |
| US7501460B1 (en) * | 2005-07-18 | 2009-03-10 | Exxonmobile Chemical Patents Inc. | Split-stream process for making nanocomposites |
| US7514491B2 (en) | 2005-07-18 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Functionalized isobutylene polymer-inorganic clay nanocomposites and organic-aqueous emulsion process |
| EP2502742B1 (en) | 2005-10-27 | 2017-06-21 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer for pneumatic tire |
| US7585914B2 (en) | 2005-11-09 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions and methods for making the same |
| CN101351481B (zh) * | 2005-12-28 | 2013-06-05 | 埃克森美孚化学专利公司 | 卤化方法 |
| CN101389494B (zh) * | 2006-02-23 | 2010-06-09 | 横滨橡胶株式会社 | 叠层体和使用该叠层体的充气轮胎 |
| US7498381B1 (en) | 2006-08-02 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Low permeability elastomeric-metal phosphate nanocomposites |
| WO2008140875A1 (en) * | 2007-05-16 | 2008-11-20 | Exxonmobil Chemical Patents Inc. | Catalyst system for olefin polymerization and polymers produced therefrom |
| RU2401844C2 (ru) * | 2008-10-13 | 2010-10-20 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Способ получения бромбутилкаучука |
| BRPI0823164B1 (pt) | 2008-10-16 | 2020-03-24 | Pirelli Tyre S.P.A. | Pneu, e, conjunto |
| CN102781976B (zh) * | 2010-01-20 | 2015-12-02 | 朗盛国际股份公司 | 用于生产卤化丁基离聚物的方法 |
| KR101709022B1 (ko) * | 2010-01-20 | 2017-02-21 | 아란세오 도이치란드 게엠베하 | 고분자량 할로겐화 고무를 제조하기 위한 공통 용매 방법 |
| RU2559326C9 (ru) * | 2010-01-20 | 2016-04-27 | Ланксесс Интернасьональ Са | Способ производства полимерных нанокомпозитов |
| RU2584424C2 (ru) * | 2010-01-20 | 2016-05-20 | Ланксесс Интернасьональ Са | Способ получения высокомолекулярного бромированного каучука с использованием общего растворителя |
| WO2013011017A1 (en) * | 2011-07-20 | 2013-01-24 | Lanxess International Sa | Process for producing brominated butyl rubber |
| IN2015DN02472A (es) | 2012-09-06 | 2015-09-04 | Exxonmobil Chem Patents Inc | |
| RU2658039C2 (ru) * | 2014-02-28 | 2018-06-19 | Эксонмобил Кемикэл Пейтентс Инк. | Бромированные эластомеры, обладающие стабильной вязкостью по муни |
| CN105330776B (zh) * | 2014-06-16 | 2017-11-17 | 中国石油化工股份有限公司 | 制备卤化丁基橡胶的方法 |
| WO2016053594A1 (en) | 2014-09-30 | 2016-04-07 | Exxonmobil Chemical Patents Inc. | Process for preparing a brominated elastomer with improved mooney viscosity stability |
| CN105820281B (zh) * | 2015-01-09 | 2018-03-02 | 中国石油化工股份有限公司 | 一种卤化聚合物的制备方法 |
| CN105111347B (zh) * | 2015-09-15 | 2017-08-29 | 黄河三角洲京博化工研究院有限公司 | 一种溴化丁基橡胶的生产方法 |
| EP3356469B1 (en) * | 2015-09-30 | 2020-04-29 | ExxonMobil Chemical Patents Inc. | Polycyclic aromatic hydrocarbon functionalized isobutylene copolymers for dispersing graphene and graphite |
| WO2018217294A1 (en) | 2017-05-22 | 2018-11-29 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with mooney viscosity stability and method for preparing same |
| US10889704B2 (en) | 2017-05-22 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with Mooney viscosity stability and method for preparing same |
| WO2019036085A1 (en) | 2017-08-18 | 2019-02-21 | Exxonmobil Chemical Patents Inc | HYDROCARBON RESINS FOR BUTYL BASED COMPOSITIONS AND PROCESSES FOR PREPARING THE SAME |
| EP3774959B1 (en) | 2018-04-03 | 2025-02-12 | ExxonMobil Chemical Patents Inc. | Isobutylene-based polymers with olefinic side chain substituents and curable compositions containing the same |
| US12006393B2 (en) | 2018-04-03 | 2024-06-11 | ExxonMobil Engineering & Technology Company | Thioacetate functionalized isobutylene-based polymers and curable compositions containing the same |
| EP3774936B1 (en) | 2018-04-03 | 2024-09-04 | ExxonMobil Chemical Patents Inc. | Solvent-free process for functionalizing isobutylene-based polymers |
| SG11202105927SA (en) | 2018-12-17 | 2021-07-29 | Arlanxeo Singapore Pte Ltd | Process for the production of isoolefin polymers using a tertiary ether |
| CA3122592A1 (en) * | 2018-12-21 | 2020-06-25 | Arlanxeo Singapore Pte. Ltd. | Halogen recovery in a wet process for halogenating unsaturated isoolefin copolymer |
| US11919977B2 (en) | 2018-12-27 | 2024-03-05 | Arlanxeo Singapore Pte. Ltd. | Process for producing chlorinated butyl rubber |
| US20220267649A1 (en) | 2019-07-17 | 2022-08-25 | Exxonmobil Chemical Patents Inc. | Pressure Sensitive Adhesives Comprising Propylene-Ethylene(-Diene) Copolymers |
| WO2021262838A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom |
| WO2021262842A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM |
| JP7439303B2 (ja) | 2020-09-18 | 2024-02-27 | エルジー・ケム・リミテッド | イソブテン－イソプレン共重合体のハロゲン化方法 |
| KR20230117594A (ko) * | 2020-12-11 | 2023-08-08 | 아란세오 싱가포르 프라이빗 리미티드 | 불포화 이소올레핀 공중합체의 할로겐화 방법에서의k+-함유 산화제에 의한 할로겐 회수 |
| CN115215980B (zh) * | 2021-04-15 | 2024-06-11 | 李长荣化学工业股份有限公司 | 苯乙烯-异戊二烯/丁二烯二嵌段共聚物、氢化嵌段共聚物、组合物及其用途及形成方法 |
| KR20240115831A (ko) * | 2021-12-13 | 2024-07-26 | 아란세오 싱가포르 프라이빗 리미티드 | 불포화 이소올레핀 공중합체를 할로겐화하는 공정에서의 산화제 및 상 전이 촉매를 이용한 할로겐 회수 |
| CN116355155A (zh) * | 2021-12-28 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种溴化接枝剂及其制备方法和应用 |
| WO2025106223A1 (en) * | 2023-11-14 | 2025-05-22 | ExxonMobil Technology and Engineering Company | In-situ bromine regeneration processes for the production of bromobutyl elastomers |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3018275A (en) * | 1958-12-30 | 1962-01-23 | Exxon Research Engineering Co | Halogenation of low unsaturation rubbery polymers in the presence of oxidizing agen |
| DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
| US4129699A (en) * | 1977-08-25 | 1978-12-12 | The Firestone Tire & Rubber Company | Process for the hydrohalogenation of buta-diene-containing polymers |
| FR2427343A1 (fr) * | 1978-05-31 | 1979-12-28 | Dia Prosim | Procede de bromation de resines a base de copolymeres vinylaromatiques reticules |
| US5162445A (en) * | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
| BR8907906A (pt) * | 1989-10-03 | 1992-07-21 | Exxon Chemical Patents Inc | Copolimero de enxerto,processo para a compatibilizacao de uma mistura de polimeros,e mistura de polimeros |
| US5077345A (en) * | 1990-03-01 | 1991-12-31 | Exxon Chemical Patents Inc. | Halogenation of polymers with improved neutralization |
| DE4213164A1 (de) * | 1992-04-22 | 1993-10-28 | Bayer Ag | Verfahren zur Herstellung von bromiertem chlorsubstituiertem Poly-1,3-butadien |
| DE4437931A1 (de) * | 1994-10-24 | 1996-04-25 | Bayer Ag | Verfahren zur Bromierung von Alkylkautschuken |
-
1996
- 1996-07-24 US US08/685,403 patent/US5681901A/en not_active Expired - Lifetime
-
1997
- 1997-07-18 BR BR9710539A patent/BR9710539A/pt not_active Application Discontinuation
- 1997-07-18 EA EA199900111A patent/EA199900111A1/ru unknown
- 1997-07-18 EP EP97933558A patent/EP0914356B1/en not_active Expired - Lifetime
- 1997-07-18 PL PL97330990A patent/PL330990A1/xx unknown
- 1997-07-18 DE DE69709648T patent/DE69709648T2/de not_active Expired - Lifetime
- 1997-07-18 WO PCT/US1997/012638 patent/WO1998003562A1/en not_active Ceased
- 1997-07-18 AT AT0907597A patent/AT406581B/de not_active IP Right Cessation
- 1997-07-18 JP JP50711998A patent/JP4689770B2/ja not_active Expired - Lifetime
- 1997-07-18 KR KR10-1999-7000418A patent/KR100488327B1/ko not_active Expired - Fee Related
- 1997-07-18 HU HU9904331A patent/HUP9904331A3/hu unknown
- 1997-07-18 CA CA002257812A patent/CA2257812C/en not_active Expired - Lifetime
- 1997-07-18 CN CN97196597A patent/CN1225649A/zh active Pending
- 1997-07-18 ES ES97933558T patent/ES2166553T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2257812A1 (en) | 1998-01-29 |
| HUP9904331A2 (hu) | 2000-05-28 |
| HUP9904331A3 (en) | 2000-07-28 |
| AT406581B (de) | 2000-06-26 |
| JP2000515192A (ja) | 2000-11-14 |
| EA199900111A1 (ru) | 1999-08-26 |
| JP4689770B2 (ja) | 2011-05-25 |
| KR100488327B1 (ko) | 2005-05-11 |
| CA2257812C (en) | 2003-01-07 |
| CN1225649A (zh) | 1999-08-11 |
| EP0914356B1 (en) | 2002-01-16 |
| US5681901A (en) | 1997-10-28 |
| DE69709648T2 (de) | 2002-08-22 |
| ATA907597A (de) | 1999-11-15 |
| BR9710539A (pt) | 1999-08-17 |
| PL330990A1 (en) | 1999-06-21 |
| KR20000067939A (ko) | 2000-11-25 |
| EP0914356A1 (en) | 1999-05-12 |
| WO1998003562A1 (en) | 1998-01-29 |
| DE69709648D1 (de) | 2002-02-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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