ES2166553T3 - Procedimiento mejorado para halogenar copolimeros de isomonoolefinas. - Google Patents
Procedimiento mejorado para halogenar copolimeros de isomonoolefinas.Info
- Publication number
- ES2166553T3 ES2166553T3 ES97933558T ES97933558T ES2166553T3 ES 2166553 T3 ES2166553 T3 ES 2166553T3 ES 97933558 T ES97933558 T ES 97933558T ES 97933558 T ES97933558 T ES 97933558T ES 2166553 T3 ES2166553 T3 ES 2166553T3
- Authority
- ES
- Spain
- Prior art keywords
- find
- improved procedure
- reaction
- isomonoolefin
- isomonoolefin copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001577 copolymer Polymers 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 230000026030 halogenation Effects 0.000 abstract 1
- 238000005658 halogenation reaction Methods 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
- C08F8/22—Halogenation by reaction with free halogens
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
SE DESCRIBE UN PROCEDIMIENTO PARA HALOGENAR UN COPOLIMERO DE UNA ISOMONOOLEFINA DE C 4 A C 7 , POR EJEMPLO, ISOBUTILENO, Y UNA MULTIOLEFINA, POR EJEMPLO, ISOPRENO O UN PARA - ALQUILESTIRENO, POR EJEMPLO, PARA - METILESTIRENO. EL AUMENTO DE LA EFICIENCIA DE LA HALOGENACION Y LA DISMINUCION DEL TIEMPO DE REACCION SE CONSIGUEN DESARROLLANDOSE LA REACCION EN PRESENCIA DE UNA FUENTE DE HALOGENO Y DE UNA EMULSION ACUOSA QUE CONTIENE UN AGENTE OXIDANTE SOLUBLE EN AGUA, POR EJEMPLO, PEROXIDO DE HIDROGENO, QUE OXIDA EL HALURO DE HIDROGENO GENERADO IN SITU EN LA REACCION, CONVIRTIENDOLO DE NUEVO EN HALOGENO LIBRE.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/685,403 US5681901A (en) | 1996-07-24 | 1996-07-24 | Process for halogenating isomonoolefin copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2166553T3 true ES2166553T3 (es) | 2002-04-16 |
Family
ID=24752063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES97933558T Expired - Lifetime ES2166553T3 (es) | 1996-07-24 | 1997-07-18 | Procedimiento mejorado para halogenar copolimeros de isomonoolefinas. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5681901A (es) |
| EP (1) | EP0914356B1 (es) |
| JP (1) | JP4689770B2 (es) |
| KR (1) | KR100488327B1 (es) |
| CN (1) | CN1225649A (es) |
| AT (1) | AT406581B (es) |
| BR (1) | BR9710539A (es) |
| CA (1) | CA2257812C (es) |
| DE (1) | DE69709648T2 (es) |
| EA (1) | EA199900111A1 (es) |
| ES (1) | ES2166553T3 (es) |
| HU (1) | HUP9904331A3 (es) |
| PL (1) | PL330990A1 (es) |
| WO (1) | WO1998003562A1 (es) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5670582A (en) * | 1996-07-24 | 1997-09-23 | Exxon Chemical Patents Inc. | Process for halogenation of isomonoolefin/para-alkylstyrene copolymers |
| CA2282900C (en) | 1999-09-20 | 2011-02-01 | Bayer Inc. | Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer |
| US20060167184A1 (en) * | 2000-10-18 | 2006-07-27 | Waddell Walter H | Innerliners for use in tires |
| TWI229089B (en) * | 2000-12-12 | 2005-03-11 | Bayer Ag | Halogenated, high molecular weight, gel-free isobutene copolymers with elevated double bond contents |
| RU2186789C1 (ru) * | 2001-01-12 | 2002-08-10 | Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" | Способ получения галоидированного бутилкаучука |
| US7241831B2 (en) * | 2001-12-10 | 2007-07-10 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
| CN100569812C (zh) * | 2002-12-20 | 2009-12-16 | 埃克森美孚化学专利公司 | 具有新的序列分布的聚合物 |
| EP1905581A1 (en) | 2003-10-27 | 2008-04-02 | ExxonMobil Chemical Patents Inc. | Microlayered composites and processes for making the same |
| ATE451253T1 (de) * | 2005-07-01 | 2009-12-15 | Pirelli | Verfahren zur herstellung von reifen |
| US7514491B2 (en) | 2005-07-18 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Functionalized isobutylene polymer-inorganic clay nanocomposites and organic-aqueous emulsion process |
| US7501460B1 (en) | 2005-07-18 | 2009-03-10 | Exxonmobile Chemical Patents Inc. | Split-stream process for making nanocomposites |
| EP2502742B1 (en) | 2005-10-27 | 2017-06-21 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer for pneumatic tire |
| US7585914B2 (en) | 2005-11-09 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions and methods for making the same |
| WO2007075164A1 (en) * | 2005-12-28 | 2007-07-05 | Exxonmobil Chemical Patents Inc. | Halogenation processes |
| JP4267061B2 (ja) * | 2006-02-23 | 2009-05-27 | 横浜ゴム株式会社 | 積層体及びそれを用いた空気入りタイヤ |
| US7498381B1 (en) | 2006-08-02 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Low permeability elastomeric-metal phosphate nanocomposites |
| EP2152764A1 (en) * | 2007-05-16 | 2010-02-17 | ExxonMobil Chemical Patents Inc. | Catalyst system for olefin polymerization and polymers produced therefrom |
| RU2401844C2 (ru) * | 2008-10-13 | 2010-10-20 | ОТКРЫТОЕ АКЦИОНЕРНОЕ ОБЩЕСТВО "СИБУР Холдинг" | Способ получения бромбутилкаучука |
| BRPI0823164B1 (pt) | 2008-10-16 | 2020-03-24 | Pirelli Tyre S.P.A. | Pneu, e, conjunto |
| EP2526127B1 (en) * | 2010-01-20 | 2014-01-01 | LANXESS International S.A. | Process for production of polymer nanocomposites |
| WO2011089091A1 (en) | 2010-01-20 | 2011-07-28 | Lanxess International Sa | Common solvent process for producing high molecular weight brominated rubber |
| WO2011089092A1 (en) * | 2010-01-20 | 2011-07-28 | Lanxess International Sa | Common solvent process for producing high molecular weight halogenated rubber |
| IN2012DN06385A (es) * | 2010-01-20 | 2015-10-02 | Lanxess Int Sa | |
| PL2734555T3 (pl) * | 2011-07-20 | 2020-11-16 | Arlanxeo Deutschland Gmbh | Sposób wytwarzania bromowanego kauczuku butylowego |
| JP6238990B2 (ja) | 2012-09-06 | 2017-11-29 | エクソンモービル ケミカル パテンツ，インコーポレイティド | タイ層を含む構造体 |
| RU2658039C2 (ru) * | 2014-02-28 | 2018-06-19 | Эксонмобил Кемикэл Пейтентс Инк. | Бромированные эластомеры, обладающие стабильной вязкостью по муни |
| CN105330776B (zh) * | 2014-06-16 | 2017-11-17 | 中国石油化工股份有限公司 | 制备卤化丁基橡胶的方法 |
| CN107075006B (zh) * | 2014-09-30 | 2020-11-03 | 埃克森美孚化学专利公司 | 用于制备具有改善的门尼粘度稳定性的卤化弹性体的方法 |
| CN105820281B (zh) * | 2015-01-09 | 2018-03-02 | 中国石油化工股份有限公司 | 一种卤化聚合物的制备方法 |
| CN105111347B (zh) * | 2015-09-15 | 2017-08-29 | 黄河三角洲京博化工研究院有限公司 | 一种溴化丁基橡胶的生产方法 |
| WO2017058393A1 (en) * | 2015-09-30 | 2017-04-06 | Exxomobil Chemical Patents Inc. | Polycyclic aromatic hydrocarbon functionalized isobutylene copolymers for dispersing graphene and graphite |
| WO2018217294A1 (en) | 2017-05-22 | 2018-11-29 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with mooney viscosity stability and method for preparing same |
| US10889704B2 (en) | 2017-05-22 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with Mooney viscosity stability and method for preparing same |
| WO2019036085A1 (en) | 2017-08-18 | 2019-02-21 | Exxonmobil Chemical Patents Inc | HYDROCARBON RESINS FOR BUTYL BASED COMPOSITIONS AND PROCESSES FOR PREPARING THE SAME |
| SG11202009641SA (en) | 2018-04-03 | 2020-10-29 | Exxonmobil Chemical Patents Inc | Thioacetate functionalized isobutylene-based polymers and curable compositions containing the same |
| CN117362503A (zh) | 2018-04-03 | 2024-01-09 | 埃克森美孚化学专利公司 | 官能化基于异丁烯的聚合物的无溶剂方法 |
| EP3774959B1 (en) | 2018-04-03 | 2025-02-12 | ExxonMobil Chemical Patents Inc. | Isobutylene-based polymers with olefinic side chain substituents and curable compositions containing the same |
| SG11202105927SA (en) | 2018-12-17 | 2021-07-29 | Arlanxeo Singapore Pte Ltd | Process for the production of isoolefin polymers using a tertiary ether |
| CN113366032B (zh) | 2018-12-21 | 2024-01-23 | 阿朗新科新加坡私人有限公司 | 用于卤化不饱和异烯烃共聚物的湿法中的卤素回收 |
| CA3122591A1 (en) | 2018-12-27 | 2020-07-02 | Arlanxeo Singapore Pte. Ltd. | Process for producing chlorinated butyl rubber |
| WO2021011906A1 (en) | 2019-07-17 | 2021-01-21 | Exxonmobil Chemical Patents Inc. | TIRES COMPRISING RUBBER COMPOUNDS THAT COMPRISE PROPYLENE-α-OLEFIN-DIENE POLYMERS |
| WO2021262838A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom |
| WO2021262842A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM |
| US12344699B2 (en) | 2020-09-18 | 2025-07-01 | Lg Chem, Ltd. | Method for halogenating isobutene-isoprene copolymer |
| CN116601182B (zh) * | 2020-12-11 | 2026-02-27 | 阿朗新科新加坡私人有限公司 | 在用于卤化不饱和异烯烃共聚物的方法中使用含k+氧化剂的卤素回收 |
| CN115215980B (zh) * | 2021-04-15 | 2024-06-11 | 李长荣化学工业股份有限公司 | 苯乙烯-异戊二烯/丁二烯二嵌段共聚物、氢化嵌段共聚物、组合物及其用途及形成方法 |
| WO2023108259A1 (en) * | 2021-12-13 | 2023-06-22 | Arlanxeo Singapore Pte. Ltd. | Halogen recovery with oxidant and phase transfer catalyst in a process for halogenating unsaturated isoolefin copolymer |
| CN116355155A (zh) * | 2021-12-28 | 2023-06-30 | 中国石油天然气股份有限公司 | 一种溴化接枝剂及其制备方法和应用 |
| CN122138983A (zh) * | 2023-11-14 | 2026-06-02 | 埃克森美孚技术与工程公司 | 用于生产溴化丁基弹性体的原位溴再生方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3018275A (en) * | 1958-12-30 | 1962-01-23 | Exxon Research Engineering Co | Halogenation of low unsaturation rubbery polymers in the presence of oxidizing agen |
| DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
| US4129699A (en) * | 1977-08-25 | 1978-12-12 | The Firestone Tire & Rubber Company | Process for the hydrohalogenation of buta-diene-containing polymers |
| FR2427343A1 (fr) * | 1978-05-31 | 1979-12-28 | Dia Prosim | Procede de bromation de resines a base de copolymeres vinylaromatiques reticules |
| US5162445A (en) * | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US4975496A (en) * | 1989-08-10 | 1990-12-04 | The Dow Chemical Company | Process for brominating aromatic resins |
| BR8907906A (pt) * | 1989-10-03 | 1992-07-21 | Exxon Chemical Patents Inc | Copolimero de enxerto,processo para a compatibilizacao de uma mistura de polimeros,e mistura de polimeros |
| US5077345A (en) * | 1990-03-01 | 1991-12-31 | Exxon Chemical Patents Inc. | Halogenation of polymers with improved neutralization |
| DE4213164A1 (de) * | 1992-04-22 | 1993-10-28 | Bayer Ag | Verfahren zur Herstellung von bromiertem chlorsubstituiertem Poly-1,3-butadien |
| DE4437931A1 (de) * | 1994-10-24 | 1996-04-25 | Bayer Ag | Verfahren zur Bromierung von Alkylkautschuken |
-
1996
- 1996-07-24 US US08/685,403 patent/US5681901A/en not_active Expired - Lifetime
-
1997
- 1997-07-18 HU HU9904331A patent/HUP9904331A3/hu unknown
- 1997-07-18 AT AT0907597A patent/AT406581B/de not_active IP Right Cessation
- 1997-07-18 EA EA199900111A patent/EA199900111A1/ru unknown
- 1997-07-18 JP JP50711998A patent/JP4689770B2/ja not_active Expired - Lifetime
- 1997-07-18 DE DE69709648T patent/DE69709648T2/de not_active Expired - Lifetime
- 1997-07-18 ES ES97933558T patent/ES2166553T3/es not_active Expired - Lifetime
- 1997-07-18 KR KR10-1999-7000418A patent/KR100488327B1/ko not_active Expired - Fee Related
- 1997-07-18 BR BR9710539A patent/BR9710539A/pt not_active Application Discontinuation
- 1997-07-18 WO PCT/US1997/012638 patent/WO1998003562A1/en not_active Ceased
- 1997-07-18 CN CN97196597A patent/CN1225649A/zh active Pending
- 1997-07-18 EP EP97933558A patent/EP0914356B1/en not_active Expired - Lifetime
- 1997-07-18 PL PL97330990A patent/PL330990A1/xx unknown
- 1997-07-18 CA CA002257812A patent/CA2257812C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BR9710539A (pt) | 1999-08-17 |
| AT406581B (de) | 2000-06-26 |
| DE69709648D1 (de) | 2002-02-21 |
| KR20000067939A (ko) | 2000-11-25 |
| CN1225649A (zh) | 1999-08-11 |
| EA199900111A1 (ru) | 1999-08-26 |
| JP4689770B2 (ja) | 2011-05-25 |
| PL330990A1 (en) | 1999-06-21 |
| EP0914356B1 (en) | 2002-01-16 |
| EP0914356A1 (en) | 1999-05-12 |
| ATA907597A (de) | 1999-11-15 |
| WO1998003562A1 (en) | 1998-01-29 |
| HUP9904331A3 (en) | 2000-07-28 |
| JP2000515192A (ja) | 2000-11-14 |
| HUP9904331A2 (hu) | 2000-05-28 |
| KR100488327B1 (ko) | 2005-05-11 |
| DE69709648T2 (de) | 2002-08-22 |
| US5681901A (en) | 1997-10-28 |
| CA2257812A1 (en) | 1998-01-29 |
| CA2257812C (en) | 2003-01-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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