ES2168105T3 - Componente catalitico solido, que contiene circonio y agrupamientos ciclo-alcadienilo, su procedimiento de obtencion y procedimiento para la polimerizacion de olefinas en su presencia. - Google Patents

Componente catalitico solido, que contiene circonio y agrupamientos ciclo-alcadienilo, su procedimiento de obtencion y procedimiento para la polimerizacion de olefinas en su presencia.

Info

Publication number
ES2168105T3
ES2168105T3 ES95402085T ES95402085T ES2168105T3 ES 2168105 T3 ES2168105 T3 ES 2168105T3 ES 95402085 T ES95402085 T ES 95402085T ES 95402085 T ES95402085 T ES 95402085T ES 2168105 T3 ES2168105 T3 ES 2168105T3
Authority
ES
Spain
Prior art keywords
procedure
olefins
polymerization
catalytic component
circony
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95402085T
Other languages
English (en)
Inventor
Roger Spitz
Veronique Pasquet
Jerome Dupuy
Jean Malinge
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atofina SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina SA filed Critical Atofina SA
Application granted granted Critical
Publication of ES2168105T3 publication Critical patent/ES2168105T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

LA COMPONENTE CATALITICA SEGUN LA INVENCION SE OBTIENE POR A) TRATAMIENTO DE UN SOPORTE DE COMPONENTE CATALITICA POR ZRCL4 O HFCL4 EN FASE GASEOSA, SEGUIDO POR B) TRATAMIENTO POR UNA SOLUCION O SUSPENSION DE UN COMPUESTO CAPAZ DE INJERTAR UN GRUPO AL ESQUELETO CICLOALCADIENILO AL ZR O HF CONTENIDO EN EL SOPORTE. LA POLIMERIZACION DE LAS OLEFINAS EN PRESENCIA DE TAL COMPONENTE CATALITICA LLEVA POLIMEROS EN BAJAS POLIMOLECULARIDADES CON PRODUCTIVIDADES ELEVADAS.
ES95402085T 1994-10-21 1995-09-15 Componente catalitico solido, que contiene circonio y agrupamientos ciclo-alcadienilo, su procedimiento de obtencion y procedimiento para la polimerizacion de olefinas en su presencia. Expired - Lifetime ES2168105T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9412604A FR2725993B1 (fr) 1994-10-21 1994-10-21 Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence

Publications (1)

Publication Number Publication Date
ES2168105T3 true ES2168105T3 (es) 2002-06-01

Family

ID=9468083

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95402085T Expired - Lifetime ES2168105T3 (es) 1994-10-21 1995-09-15 Componente catalitico solido, que contiene circonio y agrupamientos ciclo-alcadienilo, su procedimiento de obtencion y procedimiento para la polimerizacion de olefinas en su presencia.

Country Status (12)

Country Link
US (1) US5739226A (es)
EP (1) EP0708116B1 (es)
JP (1) JP3819957B2 (es)
KR (1) KR100397862B1 (es)
CN (2) CN1069907C (es)
AT (1) ATE210686T1 (es)
CA (1) CA2161061C (es)
DE (1) DE69524532T2 (es)
ES (1) ES2168105T3 (es)
FI (1) FI955017A7 (es)
FR (1) FR2725993B1 (es)
NO (1) NO315052B1 (es)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996026227A2 (de) * 1995-02-24 1996-08-29 Basf Aktiengesellschaft Verfahren zur herstellung von polymerisaten von vinylaromatischen verbindungen unter verwendung von polymere enthaltenden katalysatorsystemen
ES2182946T3 (es) * 1995-03-29 2003-03-16 Univation Tech Llc Polimeros de etileno que tiene una polidispersividad estrecha y procedimiento de preparacion.
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
EP0878483B1 (en) * 1997-03-27 2008-03-12 Council of Scientific and Industrial Research A process for polymerization and copolymerization of olefins
EP0878485B1 (en) * 1997-05-14 2006-04-26 Council of Scientific and Industrial Research A process for polymerization of olefins
FR2765225B1 (fr) * 1997-06-30 2000-01-14 Atochem Elf Sa Composante catalytique solide pour la polymerisation des olefines
CA2460316A1 (en) * 2001-09-11 2003-03-20 Exxonmobil Chemical Patents Inc. Method for preparing polyolefins
EP1293589A3 (en) * 2001-09-17 2004-10-13 Nissan Motor Company, Limited Apparatus for pretreatment prior to painting
US8080699B2 (en) * 2009-08-28 2011-12-20 Chemtura Corporation Two-stage process and system for forming high viscosity polyalphaolefins
US8193288B2 (en) 2007-10-16 2012-06-05 Sinopec Yangzi Petro-Chemical Ltd. Supported nonmetallocene catalyst and preparation thereof
EP2202246B1 (en) 2007-10-16 2016-06-15 Sinopec Yangzi Petrochemical Company Ltd. Non-metallocene catalyst supported on magnesium compound and its preparation method
EP2251362A1 (en) * 2009-05-07 2010-11-17 Total Petrochemicals Research Feluy Activating supports with controlled distribution of OH groups
JP5670465B2 (ja) 2009-11-13 2015-02-18 中國石油化工股▲分▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
JP5670466B2 (ja) 2009-11-13 2015-02-18 中国石油化工股▲ふん▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
BR112015011215B1 (pt) 2012-11-26 2018-11-21 Braskem S.A. Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metalocenosuportado e polímero de etileno com distribuição de massa molar ampla ou bimodal
WO2014171775A1 (ko) * 2013-04-19 2014-10-23 (주) 엘지화학 왁스 함량이 조절된 폴리에틸렌, 이의 염소화 폴리에틸렌 및 이로부터 제조된 성형품
KR101597421B1 (ko) 2013-04-19 2016-02-24 주식회사 엘지화학 왁스 함량이 조절된 폴리에틸렌, 이의 염소화 폴리에틸렌 및 이로부터 제조된 성형품

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3166542A (en) * 1960-01-18 1965-01-19 Cabot Corp Surface treated inorganic solid polymerization catalyst and method of polymerization therewith
US3243421A (en) * 1963-07-31 1966-03-29 Cabot Corp Catalysts for polymerization
GB1400453A (en) * 1971-07-21 1975-07-16 Ici Ltd Copolymerisation of olefins
IT951956B (it) * 1971-12-27 1973-07-10 Sir Soc Italiana Resine Spa Procedimento per la polimerizzazio ne di olefine
US4043941A (en) * 1975-11-26 1977-08-23 Emery Industries, Inc. Supported transition metal catalysts and process for their preparation
SU589209A1 (ru) * 1976-04-05 1978-01-25 Институт Физической Химии Им. Л.В.Писаржевского Ан Украинской Сср Способ получени высокодисперсных окислов металлов
JPS5846838A (ja) * 1981-09-14 1983-03-18 株式会社東芝 直流高電圧発生装置
US4459372A (en) * 1982-08-25 1984-07-10 Uop Inc. Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides
JPS59174557A (ja) * 1983-03-18 1984-10-03 三井造船株式会社 多孔質セラミツクスの製造方法
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
DE3718888A1 (de) * 1987-06-05 1988-12-22 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
EP0426643B1 (en) * 1989-10-30 1995-12-27 Fina Research S.A. Process for the preparation of metallocenes
US5117020A (en) * 1989-10-30 1992-05-26 Fina Research, S.A. Process for the preparation of metallocenes
US5075394A (en) * 1990-06-07 1991-12-24 Phillips Petroleum Company Olefin polymerization using supported pentadienyl derivative-transition metal complexes
JP2957242B2 (ja) * 1990-07-26 1999-10-04 三菱化学株式会社 オレフィン重合用触媒およびその製造法ならびにオレフィン重合体の製造法
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
EP0585512B1 (en) * 1992-08-31 1999-01-13 Fina Research S.A. Process for the preparation of an olefin polymerization catalyst component
CA2105889A1 (en) * 1992-09-10 1994-03-11 Yoshio Tajima Catalyst component for the polymerization of olefins and process for preparing olefin polymers using same
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96611C (fi) * 1993-09-10 1996-07-25 Neste Oy Heterogeeninen polymerointikatalyytti ja menetelmä sen valmistamiseksi

Also Published As

Publication number Publication date
KR100397862B1 (ko) 2003-12-11
CN1148387C (zh) 2004-05-05
NO315052B1 (no) 2003-06-30
CA2161061A1 (fr) 1996-04-22
CA2161061C (fr) 2007-01-09
KR960014170A (ko) 1996-05-22
FR2725993A1 (fr) 1996-04-26
CN1069907C (zh) 2001-08-22
FI955017L (fi) 1996-04-22
NO954148D0 (no) 1995-10-18
FI955017A7 (fi) 1996-04-22
JPH08301918A (ja) 1996-11-19
NO954148L (no) 1996-04-22
US5739226A (en) 1998-04-14
DE69524532D1 (de) 2002-01-24
FI955017A0 (fi) 1995-10-20
FR2725993B1 (fr) 1996-11-29
ATE210686T1 (de) 2001-12-15
EP0708116A1 (fr) 1996-04-24
CN1131676A (zh) 1996-09-25
DE69524532T2 (de) 2002-07-04
JP3819957B2 (ja) 2006-09-13
EP0708116B1 (fr) 2001-12-12
CN1309139A (zh) 2001-08-22

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