ES2170604A1 - Procedimiento para polimerizar polialquilpiperidinas insaturadas. - Google Patents

Procedimiento para polimerizar polialquilpiperidinas insaturadas.

Info

Publication number
ES2170604A1
ES2170604A1 ES009901358A ES9901358A ES2170604A1 ES 2170604 A1 ES2170604 A1 ES 2170604A1 ES 009901358 A ES009901358 A ES 009901358A ES 9901358 A ES9901358 A ES 9901358A ES 2170604 A1 ES2170604 A1 ES 2170604A1
Authority
ES
Spain
Prior art keywords
novel
polyalkylpiperidines
hals
polymerizing unsaturated
unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009901358A
Other languages
English (en)
Other versions
ES2170604B1 (es
Inventor
Carl-Eric-M Wilen
Jan Anders H Nasman
Alfred Steinmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2170604A1 publication Critical patent/ES2170604A1/es
Application granted granted Critical
Publication of ES2170604B1 publication Critical patent/ES2170604B1/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F26/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F26/06—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/10—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms
    • C07D211/12—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms with only hydrogen atoms attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
    • C07D211/10—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms
    • C07D211/14—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms with hydrocarbon or substituted hydrocarbon radicals attached to the ring nitrogen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40—Oxygen atoms
    • C07D211/44—Oxygen atoms attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/56—Nitrogen atoms
    • C07D211/58—Nitrogen atoms attached in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D211/70—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D211/74—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

Procedimiento para polimerizar polialquilpiperidinas insaturadas. Se describe un proceso de polimerización de aminas insaturadas e impedidas estéricamente del tipo de las polialquilpiperidinas (HALS) con intervención de un catalizador metaloceno, nuevos polímeros resultantes de dicho proceso y nuevas HALS insaturadas. Los nuevos compuestos monoméricos o copolímeros pueden emplearse con ventaja para la estabilización de materiales orgánicos contra el deterioro provocado por la luz, el oxígeno y/o el calor.
ES009901358A 1998-06-19 1999-06-18 Procedimiento para polimerizar polialquilpiperidinas insaturadas. Expired - Lifetime ES2170604B1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH132398 1998-06-19

Publications (2)

Publication Number Publication Date
ES2170604A1 true ES2170604A1 (es) 2002-08-01
ES2170604B1 ES2170604B1 (es) 2004-01-16

Family

ID=4207764

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009901358A Expired - Lifetime ES2170604B1 (es) 1998-06-19 1999-06-18 Procedimiento para polimerizar polialquilpiperidinas insaturadas.

Country Status (10)

Country Link
US (1) US20020128406A1 (es)
JP (1) JP2000143730A (es)
BE (1) BE1013051A3 (es)
CA (1) CA2275381A1 (es)
DE (1) DE19927492A1 (es)
ES (1) ES2170604B1 (es)
FR (1) FR2780064A1 (es)
GB (1) GB2338489B (es)
IT (1) IT1312353B1 (es)
NL (1) NL1012219C2 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1184442A1 (en) 2000-08-30 2002-03-06 Clariant International Ltd. Liquid crystal mixture
CZ2006196A3 (cs) * 2006-03-23 2008-04-23 Ústav makromolekulární chemie AV CR Kopolymerní stabilizátor obsahující derivát piperidinu a derivát fenolu, zpusob jeho výroby a použití
CN102241623A (zh) * 2010-05-13 2011-11-16 上海医药工业研究院 一类n-取代-4-卤代烷基哌啶醇类衍生物及其应用
CN102241622A (zh) * 2010-05-13 2011-11-16 上海医药工业研究院 一种制备盐酸替罗非班的方法
WO2014148136A1 (ja) * 2013-03-19 2014-09-25 岐阜市 抗アレルギー活性化合物及びその用途
JP6192566B2 (ja) * 2014-02-21 2017-09-06 日本ポリプロ株式会社 ポリオレフィン中に含まれるソルビトール系化合物を定量分析する方法
JP6310282B2 (ja) * 2014-03-11 2018-04-11 日本ポリエチレン株式会社 極性基含有オレフィン共重合体、その製造方法及び光安定化剤、並びにそれを用いた樹脂組成物、成形品及び農業用フィルム
CN112239458B (zh) * 2020-10-20 2022-10-14 天津利安隆新材料股份有限公司 受阻胺光稳定剂中间体及受阻胺光稳定剂的制备方法
CN115677565A (zh) * 2022-10-17 2023-02-03 南通大学 一种受阻胺类光稳定剂中间体的制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1502557A (en) * 1975-05-28 1978-03-01 Ciba Geigy Ag Stabilisation of light sensitive polymers
US4294949A (en) * 1977-07-19 1981-10-13 Ciba-Geigy Corporation Novel polymeric compounds
US4369274A (en) * 1981-07-20 1983-01-18 American Cyanamid Company Hindered amine light stabilizers for polymers
GB2105731A (en) * 1981-08-12 1983-03-30 Ciba Geigy Ag Copolymeric polyalkylpiperidines
EP0192987A2 (en) * 1985-01-30 1986-09-03 Himont Incorporated A process for preparing thermically stable olefinic polymers
EP0811638A2 (en) * 1996-06-06 1997-12-10 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling static in polymerizations utilizing metallocene catalysts
US5703149A (en) * 1995-06-29 1997-12-30 Ciba Specialty Chemicals Corporation Process for the preparation of stabilized olefin polymers

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4582881A (en) * 1981-06-10 1986-04-15 Ciba-Geigy Corporation 2-substituted 5-vinylpyrimidines, polymer obtainable therefrom and preparation thereof
DE58909021D1 (de) * 1988-06-30 1995-03-30 Ciba Geigy Ag Verfahren zur Herstellung von thermisch stabilen Olefinpolymeren.
US5616636A (en) * 1992-03-11 1997-04-01 Sandoz Ltd. Phosphonite-hals and phosphite-hals compounds as stabilizers
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
JP3293927B2 (ja) * 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
TW270131B (es) * 1993-07-13 1996-02-11 Ciba Geigy

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1502557A (en) * 1975-05-28 1978-03-01 Ciba Geigy Ag Stabilisation of light sensitive polymers
US4294949A (en) * 1977-07-19 1981-10-13 Ciba-Geigy Corporation Novel polymeric compounds
US4369274A (en) * 1981-07-20 1983-01-18 American Cyanamid Company Hindered amine light stabilizers for polymers
GB2105731A (en) * 1981-08-12 1983-03-30 Ciba Geigy Ag Copolymeric polyalkylpiperidines
EP0192987A2 (en) * 1985-01-30 1986-09-03 Himont Incorporated A process for preparing thermically stable olefinic polymers
US5703149A (en) * 1995-06-29 1997-12-30 Ciba Specialty Chemicals Corporation Process for the preparation of stabilized olefin polymers
EP0811638A2 (en) * 1996-06-06 1997-12-10 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling static in polymerizations utilizing metallocene catalysts

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
C.-E. WILEN et al. "Preparation of hindered piperidine and its copolymerization with propylene over a supported high activity Ziegler-Natta catalyst", J. Polym. Sci. Part A. Polym. Chem., 1992, Vol. 30, paginas 1163-1170. *

Also Published As

Publication number Publication date
IT1312353B1 (it) 2002-04-15
US20020128406A1 (en) 2002-09-12
ITMI991331A0 (it) 1999-06-15
BE1013051A3 (fr) 2001-08-07
NL1012219A1 (nl) 1999-12-21
GB9913587D0 (en) 1999-08-11
ITMI991331A1 (it) 2000-12-15
GB2338489B (en) 2000-09-13
ES2170604B1 (es) 2004-01-16
JP2000143730A (ja) 2000-05-26
GB2338489A (en) 1999-12-22
CA2275381A1 (en) 1999-12-19
FR2780064A1 (fr) 1999-12-24
NL1012219C2 (nl) 2000-04-13
DE19927492A1 (de) 1999-12-23

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