ES2178908A1 - Alcoxiaminas heterociclicas como reguladores en procedimiento de polimerizacion radicalica controlada. - Google Patents

Alcoxiaminas heterociclicas como reguladores en procedimiento de polimerizacion radicalica controlada.

Info

Publication number
ES2178908A1
ES2178908A1 ES009902254A ES9902254A ES2178908A1 ES 2178908 A1 ES2178908 A1 ES 2178908A1 ES 009902254 A ES009902254 A ES 009902254A ES 9902254 A ES9902254 A ES 9902254A ES 2178908 A1 ES2178908 A1 ES 2178908A1
Authority
ES
Spain
Prior art keywords
regulators
radical polymerization
polymerization processes
controlled radical
heterocyclic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
ES009902254A
Other languages
English (en)
Other versions
ES2178908B1 (es
Inventor
Peter Nesvadba
Andreas Kramer
Marie-Odile Zink
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of ES2178908A1 publication Critical patent/ES2178908A1/es
Application granted granted Critical
Publication of ES2178908B1 publication Critical patent/ES2178908B1/es
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
    • C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
    • C07D241/06—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having one or two double bonds between ring members or between ring members and non-ring members
    • C07D241/08—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having one or two double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C07D233/36—One oxygen atom with hydrocarbon radicals, substituted by nitrogen atoms, attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D243/00—Heterocyclic compounds containing seven-membered rings having two nitrogen atoms as the only ring hetero atoms
    • C07D243/06—Heterocyclic compounds containing seven-membered rings having two nitrogen atoms as the only ring hetero atoms having the nitrogen atoms in positions 1 and 4
    • C07D243/08—Heterocyclic compounds containing seven-membered rings having two nitrogen atoms as the only ring hetero atoms having the nitrogen atoms in positions 1 and 4 not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D265/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
    • C07D265/28—1,4-Oxazines; Hydrogenated 1,4-oxazines
    • C07D265/30—1,4-Oxazines; Hydrogenated 1,4-oxazines not condensed with other rings
    • C07D265/32—1,4-Oxazines; Hydrogenated 1,4-oxazines not condensed with other rings with oxygen atoms directly attached to ring carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerization Catalysts (AREA)
  • Hydrogenated Pyridines (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

Alcoxiaminas heterocíclicas como reguladores en procedimientos de polimerización radicálica controlada. Se trata de composiciones polimerizables que comprenden: a) por lo menos un monómero u oligómero etilénicamente insaturado, y b) un compuesto de la fórmula (Ia) o (Ib) en donde R{sub,1}, R{sub,2}, R{sub,3}, R{sub,4}, R{sub,5}, R{sub,6} , R{sub,7}, X y Z{sub,1} tienen el significado expresado en la descripción y en las reivindicaciones. Constituyen también objeto de la invención un procedimiento para la polimerización de monómeros etilénicamente insaturados, el empleo de compuestos de alcoxiamina heterocíclicos para polimerización controlada, los derivados de N-oxilo intermedios, una composición de estos derivados con monómeros etilénicamente insaturados y un iniciador de radical libre, así como un procedimiento para la polimerización. Los compuestos de fórmula (Ia) o (Ib) se emplean para la polimerización de monómeros u oligómeros etilénicamente insaturados.
ES009902254A 1998-10-16 1999-10-14 Alcoxiaminas heterociclicas como reguladores en procedimiento de polimerizacion radicalica controlada. Expired - Fee Related ES2178908B1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP98811030.0 1998-10-16
EP98811030 1998-10-16

Publications (2)

Publication Number Publication Date
ES2178908A1 true ES2178908A1 (es) 2003-01-01
ES2178908B1 ES2178908B1 (es) 2004-04-01

Family

ID=8236385

Family Applications (1)

Application Number Title Priority Date Filing Date
ES009902254A Expired - Fee Related ES2178908B1 (es) 1998-10-16 1999-10-14 Alcoxiaminas heterociclicas como reguladores en procedimiento de polimerizacion radicalica controlada.

Country Status (17)

Country Link
US (2) US6479608B1 (es)
JP (1) JP4895416B2 (es)
KR (1) KR100597892B1 (es)
CN (1) CN100343285C (es)
AU (1) AU769061B2 (es)
BE (1) BE1012727A5 (es)
BR (1) BR9904685A (es)
CA (1) CA2286375A1 (es)
DE (1) DE19949352B4 (es)
DK (1) DK199901463A (es)
ES (1) ES2178908B1 (es)
FR (1) FR2784684B1 (es)
GB (1) GB2342649B (es)
IT (1) IT1313663B1 (es)
NL (1) NL1013259C2 (es)
SE (1) SE522619C2 (es)
TW (1) TWI225483B (es)

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Also Published As

Publication number Publication date
US6479608B1 (en) 2002-11-12
FR2784684A1 (fr) 2000-04-21
DE19949352A1 (de) 2000-04-20
SE522619C2 (sv) 2004-02-24
GB2342649A (en) 2000-04-19
ITMI992125A0 (it) 1999-10-12
KR100597892B1 (ko) 2006-07-06
SE9903593L (sv) 2000-04-17
KR20000029079A (ko) 2000-05-25
US6664353B2 (en) 2003-12-16
CA2286375A1 (en) 2000-04-16
JP4895416B2 (ja) 2012-03-14
GB2342649B (en) 2001-07-18
DK199901463A (da) 2000-04-17
NL1013259A1 (nl) 2000-04-18
TWI225483B (en) 2004-12-21
SE9903593D0 (sv) 1999-10-06
GB9923579D0 (en) 1999-12-08
BR9904685A (pt) 2000-11-28
JP2000128869A (ja) 2000-05-09
US20030125494A1 (en) 2003-07-03
AU5361799A (en) 2000-04-20
CN100343285C (zh) 2007-10-17
ES2178908B1 (es) 2004-04-01
NL1013259C2 (nl) 2000-11-21
CN1253954A (zh) 2000-05-24
ITMI992125A1 (it) 2001-04-12
FR2784684B1 (fr) 2001-01-26
BE1012727A5 (fr) 2001-02-06
IT1313663B1 (it) 2002-09-09
AU769061B2 (en) 2004-01-15
DE19949352B4 (de) 2015-05-28

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