ES2175308T3 - Procedimiento de produccion de isobuteno de alta pureza combinando unadestilacion reactiva de hidroisomerizacion y una isomerizacion estructural. - Google Patents

Procedimiento de produccion de isobuteno de alta pureza combinando unadestilacion reactiva de hidroisomerizacion y una isomerizacion estructural.

Info

Publication number
ES2175308T3
ES2175308T3 ES97403048T ES97403048T ES2175308T3 ES 2175308 T3 ES2175308 T3 ES 2175308T3 ES 97403048 T ES97403048 T ES 97403048T ES 97403048 T ES97403048 T ES 97403048T ES 2175308 T3 ES2175308 T3 ES 2175308T3
Authority
ES
Spain
Prior art keywords
hydroisomerization
area
structural isomerization
unadestilation
high purity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97403048T
Other languages
English (en)
Inventor
Michel Dorbon
Jean-Alain Chodorge
Jean Cosyns
Jean-Charles Viltard
Blaise Didillon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of ES2175308T3 publication Critical patent/ES2175308T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2791—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/06—Reactor-distillation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN METODO DE PRODUCCION DE ISOBUTENO DE ELEVADA PUREZA A PARTIR DE UNA FRACCION DE HIDROCARBUROS FORMADA ESENCIALMENTE POR HIDROCARBUROS OLEFINICOS DE 4 ATOMOS DE CARBONO POR MOLECULA E ISOBUTENO, ADEMAS DE BUTENO - 1 Y BUTENOS - 2 EN RELACION EQUIVALENTE EN ESENCIA AL EQUILIBRIO TERMODINAMICO; DICHO METODO COMPRENDE EL PASO DE LA MENCIONADA FRACCION A UNA ZONA (1) DE DESTILACION ASOCIADA CON UNA ZONA DE REACCION DE HIDROISOMERIZACION; EL FONDO DE LA ZONA DE DESTILACION QUE CONTIENE LOS BUTENOS - 2 SE PASA A UNA ZONA DE ISOMERIZACION ESTRUCTURAL (2) DONDE LOS BUTENOS LINEALES SE ISOMERIZAN, AL MENOS PARCIALMENTE, EN ISOBUTENO; EL EFLUENTE PRINCIPAL DE LA ZONA DE ISOMERIZACION ESTRUCTURAL SE RECICLA AL MENOS EN PARTE HACIA LA ENTRADA A LA ZONA (1) DE DESTILACION REACTIVA.
ES97403048T 1996-12-23 1997-12-15 Procedimiento de produccion de isobuteno de alta pureza combinando unadestilacion reactiva de hidroisomerizacion y una isomerizacion estructural. Expired - Lifetime ES2175308T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9616023A FR2757506B1 (fr) 1996-12-23 1996-12-23 Procede de production d'isobutene de haute purete combinant une distillation reactive d'hydroisomerisation et une isomerisation squelettale

Publications (1)

Publication Number Publication Date
ES2175308T3 true ES2175308T3 (es) 2002-11-16

Family

ID=9499144

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97403048T Expired - Lifetime ES2175308T3 (es) 1996-12-23 1997-12-15 Procedimiento de produccion de isobuteno de alta pureza combinando unadestilacion reactiva de hidroisomerizacion y una isomerizacion estructural.

Country Status (7)

Country Link
US (1) US6137023A (es)
EP (1) EP0850903B1 (es)
JP (1) JP4235925B2 (es)
KR (1) KR100530713B1 (es)
DE (1) DE69711579T2 (es)
ES (1) ES2175308T3 (es)
FR (1) FR2757506B1 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6242661B1 (en) * 1999-07-16 2001-06-05 Catalytic Distillation Technologies Process for the separation of isobutene from normal butenes
FR2802921B1 (fr) * 1999-12-24 2002-08-23 Inst Francais Du Petrole Production d'isobutene de haute purete et de propylene a partir de coupes d'hydrocarbures a quatre atomes de carbone
US6875901B2 (en) * 2001-05-23 2005-04-05 Abb Lummus Global Inc. Olefin isomerization process
DE10233620A1 (de) * 2002-07-24 2004-02-12 Basf Ag Kontinuierliches Verfahren zur Auftrennung eines C4-Schnittes
US20040245210A1 (en) * 2003-06-09 2004-12-09 Peter Kukanskis Method for the manufacture of printed circuit boards with embedded resistors
RU2248342C1 (ru) * 2003-12-29 2005-03-20 Московская государственная академия тонкой химической технологии им. М.В. Ломоносова Способ получения высокооктановой добавки бензина
CN102070391B (zh) * 2011-01-12 2016-01-20 王伟跃 综合利用混合碳四制异丁烯的方法
CA2825115C (en) * 2011-01-19 2018-02-20 Limited Company "Reactive Rectification Technology" Naphtha isomerisation on three catalytic reaction zones inside a distillation column
RU2470905C1 (ru) * 2011-04-13 2012-12-27 Олег Станиславович Павлов Способ получения 1-бутена и изобутена или/и его производных
KR101658545B1 (ko) * 2014-08-22 2016-09-21 대림산업 주식회사 폴리부텐의 제조방법
CN106831294A (zh) * 2016-12-20 2017-06-13 惠州宇新化工有限责任公司 一种提高丁烯异构反应转化率的方法
AR120161A1 (es) * 2019-10-07 2022-02-02 Lummus Technology Inc Coproducción de isobutano y buteno-1 de alta pureza a partir de c₄ mixto

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3758604A (en) * 1971-03-19 1973-09-11 Exxon Research Engineering Co Isomerization-fractionation process
US4104321A (en) * 1977-03-18 1978-08-01 Uop Inc. Process for the separation of olefins
US4255605A (en) * 1980-01-02 1981-03-10 Philliphs Petroleum Company Diisopropyl from butenes
JPS5920232A (ja) * 1982-07-26 1984-02-01 Japan Synthetic Rubber Co Ltd ｎ−ブテンの製造方法
US4482775A (en) * 1982-09-22 1984-11-13 Chemical Research & Licensing Company Isomerization of C4 alkenes
JPS6118732A (ja) * 1984-07-06 1986-01-27 Mitsui Petrochem Ind Ltd Ｃ４炭化水素中のイソブチレンの濃縮方法
JPS6461434A (en) * 1987-08-31 1989-03-08 Tonen Sekiyukagaku Kk Method for isomerizing butene-1 contained in isobutylene to butene-2
US5087780A (en) * 1988-10-31 1992-02-11 Chemical Research & Licensing Company Hydroisomerization process
FR2708597B1 (fr) * 1993-07-30 1995-09-29 Inst Francais Du Petrole Procédé d'isomérisation d'oléfines sur des catalyseurs métalliques imprégnés de composés organiques soufrés avant chargement dans le réacteur.
GB9404368D0 (en) * 1994-03-07 1994-04-20 Bp Chem Int Ltd Production of polyisobutenes
KR0175697B1 (ko) * 1995-08-03 1999-05-15 서곤 n-부텐으로부터 이소부텐으로의 전환방법

Also Published As

Publication number Publication date
EP0850903B1 (fr) 2002-04-03
FR2757506B1 (fr) 1999-02-19
US6137023A (en) 2000-10-24
KR100530713B1 (ko) 2006-01-27
FR2757506A1 (fr) 1998-06-26
JP4235925B2 (ja) 2009-03-11
KR19980064503A (ko) 1998-10-07
JPH10231256A (ja) 1998-09-02
DE69711579D1 (de) 2002-05-08
DE69711579T2 (de) 2002-07-18
EP0850903A1 (fr) 1998-07-01

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