ES2180967T3 - Procedimiento para la preparacion de copolimeros en bloques de polipropileno resistente al deslizamiento. - Google Patents

Procedimiento para la preparacion de copolimeros en bloques de polipropileno resistente al deslizamiento.

Info

Publication number
ES2180967T3
ES2180967T3 ES97917322T ES97917322T ES2180967T3 ES 2180967 T3 ES2180967 T3 ES 2180967T3 ES 97917322 T ES97917322 T ES 97917322T ES 97917322 T ES97917322 T ES 97917322T ES 2180967 T3 ES2180967 T3 ES 2180967T3
Authority
ES
Spain
Prior art keywords
polypropylene
ethylene
weight
value
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES97917322T
Other languages
English (en)
Other versions
ES2180967T5 (es
Inventor
Mika Harkonen
Bo Malm
Anders Nymark
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Technology Oy
Original Assignee
Borealis Technology Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8545883&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2180967(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Borealis Technology Oy filed Critical Borealis Technology Oy
Application granted granted Critical
Publication of ES2180967T3 publication Critical patent/ES2180967T3/es
Publication of ES2180967T5 publication Critical patent/ES2180967T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/12Rigid pipes of plastics with or without reinforcement
    • F16L9/133Rigid pipes of plastics with or without reinforcement the walls consisting of two layers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L57/00Protection of pipes or objects of similar shape against external or internal damage or wear
    • F16L57/02Protection of pipes or objects of similar shape against external or internal damage or wear against cracking or buckling

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA LA PREPARACION DE UN POLIPROPILENO PARA, POR EJEMPLO, APLICACIONES EN TUBERIAS, QUE CONTIENE DE 1,0 A 10,0 % EN PESO DE ETILENO O UNIDADES REPETITIVAS DE C4-C10 - AL - OLEFINA Y QUE TIENEN UN VALOR MFR 2 ENTRE 0,05 Y 0,04 G/10 MIN, POLIMERIZA NDO PROPILENO Y ETILENO EN PRESENCIA DE UN SISTEMA DE CATALISIS. LA RESISTENCIA AL RESQUEBRAJAMIENTO DEL POLIPROPILENO SE MEJORA REALIZANDO EL PROCESO POR MEDIO DE LOS SIGUIENTES PASOS: (A) COPOLIMERIZANDO EL PROPILENO Y EL ETILENO EN UN COPOLIMERO AL AZAR A UNOS 40 A 110º C UTILIZANDO: UNA PORCION DE ETILENO DE C4-C10 - AL OLEFINA LLEVANDOLO A UN 1,0 A 10,0% EN PESO DE UNIDADES REPETITIVAS DE ETILENO EN DICHO COPOLIMERO AL AZAR, Y SIN NINGUNA O CON UNA MINIMA CANTIDAD DE HIDROGENO QUE SE LLEVA A UN VALOR MFR 10 DE ENTRE 0,01 Y 5,0 G/10 MIN PARA DICHO COPOLIMERO AL AZAR, SI ESTE PASO SE REALIZA PRIMERO, O A UN VALOR MFR2 PARA DICHO POLIPROPILENO DE ENTRE 0,05 A 0,40 G/10 MIN, SI ESTE PASO SE REALIZA DESPUES DELPASO (B); SIENDO LA PROPORCION DEL COPOLIMERO AL AZAR DE ESTE PASO DE 20 A 80% EN PESO DE DICHO POLIPROPILENO, (B) POLIMERIZANDO EL PROPILENO CON UNOS 40 A 110º C UTILIZANDO; NINGUNA O UNA MINIMA PORCION DE ETILENO QUE SE LLEVA DE 0,0 A 1,0% EN PESO DE UNIDADES REPETITIVAS DE ETILENO EN EL POLIMERO RESULTANTE DE ESTE PASO; Y UNA CANTIDAD DE HIDROGENO LLEGANDO A UN VALOR MFR2 DE DICHO POLIPROPILENO DE ENTRE 0,05 Y 0,40 G/10 MIN, SI ESTE PASO SE REALIZA DESPUES DEL PASO (A); SIENDO LA PROPORCION DE POLIMERO DE ESTE PASO DE 80 A 20% EN PESO DE DICHO POLIPROPILENO. EL POLIPROPILENO PUEDE SER MODIFICADO POR ELASTOMEROS.
ES97917322T 1996-04-19 1997-04-18 Procedimiento para la preparacion de copolimeros en bloques de polipropileno resistente al deslizamiento. Expired - Lifetime ES2180967T5 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI961722 1996-04-19
FI961722A FI104828B (fi) 1996-04-19 1996-04-19 Uusi putkilaatuinen polypropyleenikoostumus

Publications (2)

Publication Number Publication Date
ES2180967T3 true ES2180967T3 (es) 2003-02-16
ES2180967T5 ES2180967T5 (es) 2008-06-16

Family

ID=8545883

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97917322T Expired - Lifetime ES2180967T5 (es) 1996-04-19 1997-04-18 Procedimiento para la preparacion de copolimeros en bloques de polipropileno resistente al deslizamiento.

Country Status (12)

Country Link
US (1) US6221974B1 (es)
EP (1) EP0894103B2 (es)
CN (1) CN1128169C (es)
AR (1) AR006768A1 (es)
AU (1) AU2571097A (es)
DE (1) DE69714429T3 (es)
ES (1) ES2180967T5 (es)
FI (1) FI104828B (es)
MY (1) MY118766A (es)
TW (1) TW341577B (es)
WO (1) WO1997040080A1 (es)
ZA (1) ZA973300B (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69721504T2 (de) * 1996-03-04 2003-11-27 Borealis A/S, Lyngby Verfahren zur herstellung einer mehrschichtigen rohrleitung
GB2322376B (en) 1997-02-25 2000-11-29 Solvay Polypropylene block copolymers and containers made therefrom
FI973816A0 (fi) 1997-09-26 1997-09-26 Borealis As Polypropen med hoeg smaeltstyrka
IT1295925B1 (it) * 1997-10-28 1999-05-28 Montell North America Inc Composizioni polipropileniche ad elevato contenuto di cariche minerali pesanti, adatte al rivestimento di tubi metallici
US6750284B1 (en) 1999-05-13 2004-06-15 Exxonmobil Chemical Patents Inc. Thermoplastic filled membranes of propylene copolymers
BE1014226A3 (fr) * 2001-06-15 2003-06-03 Polypropylene Belgium Nv Procede de fabrication de tubes et de raccords comprenant une etape de recuit.
GB0324837D0 (en) * 2003-10-24 2003-11-26 Polypropylene Belgium Nv Polypropylene pipe
WO2006018813A1 (en) * 2004-08-18 2006-02-23 Basell Poliolefine Italia S.R.L. Stretch blow-molded containers from ziegler natta propylene polymer compositions
JP2008509862A (ja) * 2004-08-18 2008-04-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 改良された赤外線昇温速度を有する透明なポリプロピレン系延伸ブロー成形容器を製造する方法
SG160338A1 (en) 2005-01-31 2010-04-29 Exxonmobil Chem Patents Inc Polymer blends and pellets and methods of producing same
ATE435243T1 (de) * 2005-05-20 2009-07-15 Borealis Tech Oy Polymer mit hohem schmelzfluss und verbesserter beständigkeit für röhrenanwendungen
EP2042552A1 (en) * 2007-09-27 2009-04-01 Borealis Technology Oy Polyolefin compositions having improved optical and mechanical properties
EP2077286A1 (en) * 2008-01-07 2009-07-08 Total Petrochemicals Research Feluy Heterophasic propylene copolymer with improved creep behavior
ATE529476T1 (de) 2008-08-01 2011-11-15 Borealis Ag Polypropylenzusammensetzung mit geringem schrumpffaktor
RU2478668C2 (ru) * 2008-08-06 2013-04-10 Бореалис Аг Состав на основе полипропилена с эластомерами на основе стирола
US7851554B2 (en) * 2008-10-27 2010-12-14 Exxonmobil Chemical Patents Inc. Propylene impact copolymers with balanced impact strength and stiffness
EP2191955A1 (en) 2008-11-28 2010-06-02 Borealis AG Process for butt welding of polypropylene
US8217116B2 (en) * 2009-07-15 2012-07-10 Braskem America, Inc. Polypropylene composition for buried structures
EP2390279A1 (en) 2009-12-17 2011-11-30 ExxonMobil Chemical Patents Inc. Polypropylene composition with plasticiser for sterilisable films
EP2361950A1 (en) * 2010-02-26 2011-08-31 Borealis AG Random propylene copolymers for pipes
EP2495280A1 (en) 2011-03-03 2012-09-05 Borealis AG Polyolefin composition with low CLTE and reduced occurrence of flow marks
ES2525494T3 (es) 2011-11-29 2014-12-23 Borealis Ag Composición de poliolefinas con reducida aparición de marcas de flujo
CN103665204B (zh) * 2012-09-07 2016-04-27 中国石油化工股份有限公司 一种烯烃聚合用固体催化剂组分及催化剂
ES2632593T3 (es) 2013-04-22 2017-09-14 Borealis Ag Procedimiento de dos fases de producción de composiciones de polipropileno
EP2796473B1 (en) 2013-04-22 2017-05-31 Borealis AG Multistage process for producing low-temperature resistant polypropylene compositions
EP3235832B1 (en) 2013-04-22 2018-06-20 Borealis AG Polypropylene compositions
EP2853562A1 (en) 2013-09-27 2015-04-01 Borealis AG Two-stage process for producing polypropylene compositions
EP2933291A1 (en) * 2014-04-17 2015-10-21 Borealis AG Propylene copolymer composition for pipe applications
WO2016198601A1 (en) * 2015-06-12 2016-12-15 Borealis Ag Process for producing propylene polymer compositions
EP3707174A4 (en) * 2017-11-06 2021-11-03 ExxonMobil Chemical Patents Inc. PROPYLENE-BASED IMPACT-RESISTANT COPOLYMERS AND METHOD AND DEVICE FOR MANUFACTURING
CN113549291B (zh) * 2021-06-25 2022-08-16 宁波东拓塑业有限公司 一种耐蠕变聚丙烯及其制备方法以及塑料托盘

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5650909A (en) * 1979-10-04 1981-05-08 Mitsubishi Chem Ind Ltd Manufacture of propylene-ethylene block copolymer
JPS5661415A (en) * 1979-10-24 1981-05-26 Mitsubishi Chem Ind Ltd Preparation of propylene-ethylene block copolymer
NO834504L (no) * 1983-01-20 1984-07-23 El Paso Polyolefins Propylenkopolymerer med forbedret slagfasthet
NL8304440A (nl) * 1983-12-24 1985-07-16 Stamicarbon Werkwijze voor de bereiding van een slagvast etheen-propeen-blokcopolymeer.
CN1006071B (zh) * 1985-04-01 1989-12-13 中国石油化工总公司 用于烯烃聚合和共聚合的催化剂体系
JPS61264043A (ja) * 1985-05-16 1986-11-21 Mitsubishi Petrochem Co Ltd 架橋されたオレフイン系ブロツク共重合体
US4736002A (en) * 1986-06-30 1988-04-05 El Paso Products Company Novel propylene polymerization process
US4950720A (en) * 1988-04-29 1990-08-21 Exxon Chemical Patents Inc. Modified polypropylene, process for making and article made from the same
JPH0348214A (ja) * 1989-07-17 1991-03-01 Hitachi Ltd 光路切換スイッチ
US5234879A (en) * 1990-12-19 1993-08-10 Neste Oy Method for the modification of catalysts intended for the polymerization of olefins
GB9408767D0 (en) * 1994-05-04 1994-06-22 Hepworth Building Prod Piping
FI944761A0 (fi) 1994-10-11 1994-10-11 Borealis Holding As Ny polypropylenkomposition med vid molekylvikt distribution

Also Published As

Publication number Publication date
FI961722A0 (fi) 1996-04-19
TW341577B (en) 1998-10-01
ES2180967T5 (es) 2008-06-16
AU2571097A (en) 1997-11-12
US6221974B1 (en) 2001-04-24
WO1997040080A1 (en) 1997-10-30
EP0894103B1 (en) 2002-07-31
EP0894103B2 (en) 2008-02-27
DE69714429T3 (de) 2008-09-25
EP0894103A1 (en) 1999-02-03
AR006768A1 (es) 1999-09-29
CN1128169C (zh) 2003-11-19
FI961722A7 (fi) 1997-10-20
CN1219180A (zh) 1999-06-09
ZA973300B (en) 1998-01-28
DE69714429T2 (de) 2003-03-20
FI104828B (fi) 2000-04-14
MY118766A (en) 2005-01-31
DE69714429D1 (de) 2002-09-05

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