ES2182333T3 - Acetales y cetales lineales como pro-fragancias. - Google Patents
Acetales y cetales lineales como pro-fragancias.Info
- Publication number
- ES2182333T3 ES2182333T3 ES98931620T ES98931620T ES2182333T3 ES 2182333 T3 ES2182333 T3 ES 2182333T3 ES 98931620 T ES98931620 T ES 98931620T ES 98931620 T ES98931620 T ES 98931620T ES 2182333 T3 ES2182333 T3 ES 2182333T3
- Authority
- ES
- Spain
- Prior art keywords
- perfume
- fabrics
- smell
- providing
- precursors
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/70—Fixation, conservation, or encapsulation of flavouring agents
- A23L27/75—Fixation, conservation, or encapsulation of flavouring agents the flavouring agents being bound to a host by chemical, electrical or like forces, e.g. use of precursors
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/30—Compounds having groups
- C07C43/303—Compounds having groups having acetal carbon atoms bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/30—Compounds having groups
- C07C43/305—Compounds having groups having acetal carbon atoms as rings members or bound to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
- C07C47/198—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/507—Compounds releasing perfumes by thermal or chemical activation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Nutrition Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
La invención se refiere a sistemas de suministro de perfume para empleo en composiciones detergentes de lavandería que incluyen composiciones para acondicionamiento de telas añadidos en el enjuagado y en el secado y que proporcionan a las telas un olor de "frescor" y de "limpieza" duradera. Las composiciones descritas en la presente invención suministran precursores de perfumes de acetal y/o cetales lineales muy eficaces en tejidos durante el lavado en el que los precursores de perfumes liberan las materias primas de fragancia que duran un periodo de hasta dos semanas. La presente invención también se refiere al procedimiento para suministrara un olor agradable a las telas que tiene un olor de frescor duradero poniendo en contacto la tela con una composición detergente de lavandería que incluye precursores de perfume difusores perfumes.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5110497P | 1997-06-27 | 1997-06-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2182333T3 true ES2182333T3 (es) | 2003-03-01 |
Family
ID=21969370
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98931620T Expired - Lifetime ES2182333T3 (es) | 1997-06-27 | 1998-06-26 | Acetales y cetales lineales como pro-fragancias. |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US6316397B1 (es) |
| EP (1) | EP0991615B1 (es) |
| JP (1) | JP2002510323A (es) |
| CN (1) | CN1268107A (es) |
| AR (1) | AR016292A1 (es) |
| BR (1) | BR9810630B1 (es) |
| CA (1) | CA2295114A1 (es) |
| DE (1) | DE69807224T2 (es) |
| ES (1) | ES2182333T3 (es) |
| WO (1) | WO1999000347A1 (es) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6551987B1 (en) * | 1999-04-20 | 2003-04-22 | The Procter & Gamble Company | Pro-fragrances |
| US7353229B2 (en) * | 2000-05-26 | 2008-04-01 | Vilcauskas Jr Andrew J | Post-session internet advertising system |
| US7503127B2 (en) * | 2002-04-22 | 2009-03-17 | The Procter And Gamble Company | Electrically charged volatile material delivery method |
| US7066412B2 (en) * | 2002-05-28 | 2006-06-27 | Johnsondiversey, Inc. | Apparatus, methods, and compositions for adding fragrance to laundry |
| US7109157B2 (en) * | 2003-02-27 | 2006-09-19 | Lawnie Taylor | Methods and equipment for removing stains from fabrics using a composition comprising hydroxide and hypochlorite |
| US8592361B2 (en) | 2002-11-25 | 2013-11-26 | Colgate-Palmolive Company | Functional fragrance precursor |
| JP2007528195A (ja) | 2003-10-09 | 2007-10-11 | デウン カンパニー,リミテッド | 高シアル酸含量のヒトトロンボポエチンを精製する方法 |
| US7977303B2 (en) * | 2004-02-27 | 2011-07-12 | The Procter & Gamble Company | Multiple use fabric conditioning block with indentations |
| US7723285B2 (en) * | 2004-07-20 | 2010-05-25 | Michigan Molecular Institute | Beneficial agent delivery systems |
| US7569529B2 (en) * | 2005-09-07 | 2009-08-04 | The Procter & Gamble Company | Method of using fabric care compositions to achieve a synergistic odor benefit |
| DE102005058339A1 (de) * | 2005-12-06 | 2007-06-28 | Henkel Kgaa | Stabilitätsverbesserung flüssiger hypochlorithaltiger Wasch- und Reinigungsmittel |
| DE102005058642B3 (de) * | 2005-12-07 | 2007-07-26 | Henkel Kgaa | Erhöhung der Stabilität flüssiger hypochlorithaltiger Wasch- und Reinigungsmittel |
| DE102005062008B3 (de) * | 2005-12-22 | 2007-08-30 | Henkel Kgaa | Geruchsreduktion hypochlorithaltiger Mittel |
| DE102005063065A1 (de) * | 2005-12-29 | 2007-07-12 | Henkel Kgaa | Korrosionsinhibierung flüssiger hypochlorithaltiger Reinigungsmittel |
| DE102005063177A1 (de) | 2005-12-30 | 2007-07-05 | Henkel Kgaa | Erhöhung der Stabilität hypochlorihaltiger Waschmittel |
| EP1857436A1 (en) * | 2006-05-19 | 2007-11-21 | Kao Corporation, S.A. | Fragrance precursor |
| US20070275866A1 (en) * | 2006-05-23 | 2007-11-29 | Robert Richard Dykstra | Perfume delivery systems for consumer goods |
| ATE549391T1 (de) * | 2007-04-27 | 2012-03-15 | Dial Corp | Verfahren zur behandlung eines stoffs in einem trockner |
| EP1992606A1 (de) * | 2007-05-15 | 2008-11-19 | Symrise GmbH & Co. KG | Alkenacetale und ihre Verwendung als Riechstoffe |
| US20090312224A1 (en) * | 2008-06-13 | 2009-12-17 | Conopco, Inc., D/B/A Unilever | Method of Reducing Viscosity of Concentrated Liquid Cleansers by Selection of Perfume Components |
| US20090312223A1 (en) * | 2008-06-13 | 2009-12-17 | Conopco, Inc., D/B/A Unilever | Method of Controlling Structure and Rheology of Low Active Liquid Cleansers by Selecting Perfume Components |
| EP2318100B1 (en) * | 2008-08-22 | 2011-12-21 | Firmenich S.A. | Equilibrated dynamic mixtures containing stabilized hemiacetals for the controlled release of active alcohols |
| BRPI0922770A2 (pt) | 2008-12-01 | 2019-09-24 | Procter & Gamble | sistemas de perfume |
| US8754028B2 (en) * | 2008-12-16 | 2014-06-17 | The Procter & Gamble Company | Perfume systems |
| EP2270124A1 (en) * | 2009-06-30 | 2011-01-05 | The Procter & Gamble Company | Bleaching compositions comprising a perfume delivery system |
| EP3434764B1 (en) | 2009-12-09 | 2026-04-08 | The Procter & Gamble Company | Fabric and home care products |
| WO2011084463A1 (en) | 2009-12-17 | 2011-07-14 | The Procter & Gamble Company | Freshening compositions comprising malodor binding polymers and malodor control components |
| CN104546520B (zh) | 2010-06-22 | 2018-05-08 | 宝洁公司 | 香料体系 |
| WO2011163325A1 (en) | 2010-06-22 | 2011-12-29 | The Procter & Gamble Company | Perfume systems |
| WO2012003300A2 (en) | 2010-07-02 | 2012-01-05 | The Procter & Gamble Company | Filaments comprising a non-perfume active agent nonwoven webs and methods for making same |
| JP5859526B2 (ja) | 2010-07-02 | 2016-02-10 | ザ プロクター アンド ギャンブルカンパニー | 活性剤不織布ウェブを含むフィラメント及びその製造方法 |
| EP3533908B1 (en) | 2010-07-02 | 2026-07-01 | The Procter & Gamble Company | NONWOVEN FABRIC COMPRISING ONE OR MORE ACTIVE AGENTS |
| AR086558A1 (es) | 2011-06-23 | 2014-01-08 | Procter & Gamble | Sistema de perfume |
| US20140141126A1 (en) | 2011-06-29 | 2014-05-22 | Solae Llc | Baked food compositions comprising soy whey proteins that have been isolated from processing streams |
| RU2650884C1 (ru) | 2012-01-04 | 2018-04-18 | Дзе Проктер Энд Гэмбл Компани | Содержащие активные агенты волокнистые структуры с множеством областей |
| CA2860659C (en) | 2012-01-04 | 2017-08-29 | The Procter & Gamble Company | Fibrous structures comprising particles and methods for making same |
| EP2800802B1 (en) | 2012-01-04 | 2018-02-28 | The Procter and Gamble Company | Active containing fibrous structures with multiple regions having differing densities |
| EP3572572B1 (en) | 2013-12-09 | 2021-01-20 | The Procter & Gamble Company | Method for printing a graphic on a fibrous structure |
| EP3094615A4 (en) | 2014-01-13 | 2017-11-08 | P2 Science, Inc. | Terpene-derived acids and esters and methods for preparing and using same |
| US20150238394A1 (en) * | 2014-02-27 | 2015-08-27 | Kimberly-Clark Worldwide, Inc. | Triggerable Compositions For Two-Stage, Controlled Release of Proactive Chemistry Using Aldehydes |
| WO2015191706A1 (en) * | 2014-06-10 | 2015-12-17 | P2 Science, Inc. | Terpene-derived compounds and methods for preparing and using same |
| US10071944B2 (en) | 2014-06-20 | 2018-09-11 | P2 Science, Inc. | Film ozonolysis in a tubular or multitubular reactor |
| MX2018005529A (es) * | 2015-11-25 | 2018-08-15 | Kimberly Clark Co | Sistema de monomero funcional y polimero para liberacion de fragancia activada por agua o acido. |
| CN108697591B (zh) | 2016-02-18 | 2022-06-17 | 国际香料和香精公司 | 聚脲胶囊组合物 |
| CA3026192A1 (en) | 2016-06-21 | 2017-12-28 | P2 Science, Inc. | Flow-through reactors for the continuous quenching of peroxide mixtures and methods comprising the same |
| EP4209264A1 (en) | 2016-09-16 | 2023-07-12 | International Flavors & Fragrances Inc. | Microcapsule compositions stabilized with viscosity control agents |
| WO2018053289A1 (en) | 2016-09-16 | 2018-03-22 | P2 Science, Inc. | Uses of vanadium to oxidize aldehydes and ozonides |
| US11697904B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| EP4197598B1 (en) | 2017-01-27 | 2025-10-22 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| US11697906B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles and product-shipping assemblies for containing the same |
| US11697905B2 (en) | 2017-01-27 | 2023-07-11 | The Procter & Gamble Company | Active agent-containing articles that exhibit consumer acceptable article in-use properties |
| CN107325273B (zh) * | 2017-06-22 | 2019-09-20 | 温州大学 | 高分子聚合物及其制备方法和在酸敏感型两亲性纳米胶束的应用 |
| CA3114469A1 (en) | 2018-10-19 | 2020-04-23 | P2 Science, Inc. | New methods for disproportionation quenching of ozonides |
| EP4069810A1 (en) | 2019-12-05 | 2022-10-12 | The Procter & Gamble Company | Cleaning composition |
| EP4069811A1 (en) | 2019-12-05 | 2022-10-12 | The Procter & Gamble Company | Method of making a cleaning composition |
| IT202200003008A1 (it) | 2022-02-17 | 2023-08-17 | Andrea Macchia | Sistema pulente per la pulitura delle superfici dipinte di arte pubblica vandalizzate |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2206883A (en) * | 1936-03-07 | 1940-07-09 | Ig Farbenindustrie Ag | Aromatic-aliphatic acetals |
| GB1365062A (en) | 1970-07-01 | 1974-08-29 | Bush Boake Allen Ltd | Compounded perfumery compositions containing organic titanates or zirconates |
| DE2132898A1 (de) * | 1971-07-02 | 1973-01-18 | Henkel & Cie Gmbh | Schwachschaeumendes wasch-, reinigungsund enthaertungsmittel |
| CH628516A5 (en) * | 1977-07-25 | 1982-03-15 | Bush Boake Allen Ltd | Perfumery compositions |
| US4424146A (en) * | 1981-10-07 | 1984-01-03 | Fritzsche Dodge & Olcott Inc. | Acetaldehyde ethyl 6-dihydrolinalyl acetal perfume compositions |
| JPS58208211A (ja) | 1982-05-28 | 1983-12-03 | Chisso Corp | 徐分解性香料を使用した芳香剤 |
| JPH0644927B2 (ja) | 1987-03-14 | 1994-06-15 | 日本油脂株式会社 | 徐放性活性成分放出剤 |
| GB8816209D0 (en) | 1988-07-07 | 1988-08-10 | Bush Boake Allen Ltd | Perfumery compositions |
| DE4110973A1 (de) | 1991-04-05 | 1992-10-08 | Haarmann & Reimer Gmbh | Mittel mit physiologischem kuehleffekt und fuer diese mittel geeignete wirksame verbindungen |
| US5232612A (en) | 1991-08-28 | 1993-08-03 | The Procter & Gamble Company | Solid, particulate fabric softener with protected, dryer-activated, cyclodextrin/perfume complex |
| JPH05230496A (ja) | 1992-02-24 | 1993-09-07 | Nippon Fine Chem Co Ltd | 調合香料及び該調合香料を含有する芳香性組成物 |
| US5378468A (en) | 1992-09-22 | 1995-01-03 | The Mennen Company | Composition containing body activated fragrance for contacting the skin and method of use |
| BR9405545A (pt) | 1993-08-09 | 1999-05-25 | Firmenich & Cie | Processo para perfumar e lavar texteis e para prolongar o efeito de difusão do odor caracteristico de um alcool e um aldeido odorante detergente ou amaciante textil composto e composição perfumante |
| US5739100A (en) | 1993-12-17 | 1998-04-14 | Nippon Zeon Co., Ltd. | Cis-3-hexenal-cis-3-hexenyl acetal compound, process for preparing same, and fragrance-or flavor-imparting or fragrance-or flavor-retaining agent and perfume composition containing same |
| US5506201A (en) | 1994-04-29 | 1996-04-09 | International Flavors & Fragrances Inc. | Formulation of a fat surfactant vehicle containing a fragrance |
| US5500138A (en) * | 1994-10-20 | 1996-03-19 | The Procter & Gamble Company | Fabric softener compositions with improved environmental impact |
| EP0786247B1 (en) | 1994-11-10 | 2005-08-17 | Kanebo Cosmetics Inc. | Sustained-release aromatic and method of detecting microorganism by using the same |
| CA2249588A1 (en) * | 1996-03-22 | 1997-09-25 | The Procter & Gamble Company | Detergent compositions containing fragrance precursors and the fragrance precursors themselves |
| US5968893A (en) * | 1996-05-03 | 1999-10-19 | The Procter & Gamble Company | Laundry detergent compositions and methods for providing soil release to cotton fabric |
| EP0918835B1 (en) * | 1996-08-12 | 2002-01-16 | The Procter & Gamble Company | Rinse added fabric softening compositions and method of use for the delivery of fragrance precursors |
| ZA9711272B (en) * | 1996-12-19 | 1998-06-23 | Procter & Gamble | Dryer-activated fabric conditioning and antistatic compositions with improved perfume longevity. |
-
1998
- 1998-06-26 ES ES98931620T patent/ES2182333T3/es not_active Expired - Lifetime
- 1998-06-26 EP EP98931620A patent/EP0991615B1/en not_active Expired - Lifetime
- 1998-06-26 US US09/445,325 patent/US6316397B1/en not_active Expired - Fee Related
- 1998-06-26 DE DE69807224T patent/DE69807224T2/de not_active Expired - Lifetime
- 1998-06-26 CA CA002295114A patent/CA2295114A1/en not_active Abandoned
- 1998-06-26 JP JP50787399A patent/JP2002510323A/ja not_active Ceased
- 1998-06-26 CN CN98808558A patent/CN1268107A/zh active Pending
- 1998-06-26 AR ARP980103108A patent/AR016292A1/es active IP Right Grant
- 1998-06-26 WO PCT/US1998/013281 patent/WO1999000347A1/en not_active Ceased
- 1998-06-26 BR BRPI9810630-9A patent/BR9810630B1/pt not_active IP Right Cessation
-
2001
- 2001-07-27 US US09/917,542 patent/US6395695B1/en not_active Expired - Fee Related
-
2002
- 2002-05-09 US US10/142,039 patent/US6677491B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69807224T2 (de) | 2003-04-17 |
| BR9810630B1 (pt) | 2010-10-05 |
| US6316397B1 (en) | 2001-11-13 |
| CN1268107A (zh) | 2000-09-27 |
| EP0991615A1 (en) | 2000-04-12 |
| CA2295114A1 (en) | 1999-01-07 |
| US20030032565A1 (en) | 2003-02-13 |
| BR9810630A (pt) | 2000-10-03 |
| DE69807224D1 (de) | 2002-09-19 |
| AR016292A1 (es) | 2001-07-04 |
| US6677491B2 (en) | 2004-01-13 |
| WO1999000347A1 (en) | 1999-01-07 |
| EP0991615B1 (en) | 2002-08-14 |
| US6395695B1 (en) | 2002-05-28 |
| JP2002510323A (ja) | 2002-04-02 |
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