ES2190932T3 - Procedimiento para la preparacion catalitica de aldehidos a partir de olefinas, utilizando mezclas de ligandos. - Google Patents
Procedimiento para la preparacion catalitica de aldehidos a partir de olefinas, utilizando mezclas de ligandos.Info
- Publication number
- ES2190932T3 ES2190932T3 ES00121488T ES00121488T ES2190932T3 ES 2190932 T3 ES2190932 T3 ES 2190932T3 ES 00121488 T ES00121488 T ES 00121488T ES 00121488 T ES00121488 T ES 00121488T ES 2190932 T3 ES2190932 T3 ES 2190932T3
- Authority
- ES
- Spain
- Prior art keywords
- formula
- olefins
- aldehids
- legand
- blends
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 238000007037 hydroformylation reaction Methods 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 229910052714 tellurium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Procedimiento para elaborar aldehidos de 4 a 25 átomos de carbono mediante la hidroformilación catalítica de las olefinas correspondientes, caracterizado porque como catalizador se utiliza un metal del 8° grupo secundario del sistema periódico, en presencia de un ligando A de fórmula I **(Fórmula)** con X = As, Sb o P y R1, R2, R3 significa un resto de hidrocarburo alifático, cicloalifático o aromático, sustituido o no sustituido, de 1 a 50 átomos de carbono, donde dos de los restos R1, R2, R3 pueden presentar un enlace covalente, con la condición de que por lo menos uno de los restos de hidrocarburo R1, R2, R3 contenga un heteroátomo del grupo de O, S, N, F, Cl, Br, I, Se y Te, y un ligando B de fórmula II **(Fórmula)** con R4, R5, R6: que significan un resto de hidrocarburo sustituido o no sustituido, alifático o aromático de 1 a 50 átomos de carbono, donde respectivamente dos de los restos R4, R5, R6 pueden presentar un enlace covalente.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19954510A DE19954510A1 (de) | 1999-11-12 | 1999-11-12 | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2190932T3 true ES2190932T3 (es) | 2003-09-01 |
Family
ID=7928840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES00121488T Expired - Lifetime ES2190932T3 (es) | 1999-11-12 | 2000-09-29 | Procedimiento para la preparacion catalitica de aldehidos a partir de olefinas, utilizando mezclas de ligandos. |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6403837B1 (es) |
| EP (1) | EP1099678B1 (es) |
| JP (1) | JP2001187759A (es) |
| KR (1) | KR20010051634A (es) |
| CN (1) | CN1295997A (es) |
| AR (1) | AR026425A1 (es) |
| AT (1) | ATE234801T1 (es) |
| BR (1) | BR0005333A (es) |
| CA (1) | CA2325676A1 (es) |
| CZ (1) | CZ20004142A3 (es) |
| DE (2) | DE19954510A1 (es) |
| ES (1) | ES2190932T3 (es) |
| ID (1) | ID28360A (es) |
| MX (1) | MXPA00011028A (es) |
| MY (1) | MY135998A (es) |
| PL (1) | PL343792A1 (es) |
| SG (1) | SG88797A1 (es) |
| TR (1) | TR200003273A2 (es) |
| TW (1) | TW538030B (es) |
| ZA (1) | ZA200006514B (es) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10058383A1 (de) | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | Neue Phosphininverbindungen und deren Metallkomplexe |
| DE60304034T2 (de) | 2002-03-11 | 2006-10-12 | Union Carbide Chemicals & Plastics Technology Corp., Danbury | Bisphosphit-ligande für carbonylierungsverfahren |
| DE10210918B4 (de) | 2002-03-13 | 2004-06-03 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Bisphosphiten |
| DE10220801A1 (de) | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
| DE10223593A1 (de) * | 2002-05-27 | 2003-12-11 | Degussa | Hydroxydiphosphine und deren Verwendung in der Katalyse |
| CN1290814C (zh) | 2002-08-31 | 2006-12-20 | 奥克森诺奥勒芬化学股份有限公司 | 通过烯属不饱和化合物的加氢甲酰基化制备醛的方法，该方法在环状碳酸酯存在的条件下由未改性的金属配合物催化 |
| RU2337090C2 (ru) | 2002-08-31 | 2008-10-27 | Оксено Олефинхеми Гмбх | Способ гидроформилирования олефиновых соединений в присутствии циклических эфиров угольной кислоты |
| DE60319725T2 (de) | 2002-10-15 | 2009-01-29 | Dow Technology Investments LLC, Midland | Bischelatligand und seine verwendung in carbonylierungs-verfahren |
| GB0322247D0 (en) | 2003-09-23 | 2003-10-22 | Exxonmobil Chem Patents Inc | Improvement in or relating to an isobutylene containing stream |
| DE10360771A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen |
| DE10360772A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Organoacylphosphiten |
| DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
| DE102005014055A1 (de) * | 2005-03-23 | 2006-09-28 | Degussa Ag | Unsymmetrisch substituierte Phospholankatalysatoren |
| DE102005042464A1 (de) * | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen |
| CA2647396C (en) | 2006-03-17 | 2014-01-07 | University Of Kansas | Tuning product selectivity in catalytic hydroformylation reactions with carbon dioxide expanded liquids |
| DE102006034442A1 (de) * | 2006-07-26 | 2008-01-31 | Oxeno Olefinchemie Gmbh | Katalysatorvorstufe für einen Rh-Komplexkatalysator |
| DE102006058682A1 (de) * | 2006-12-13 | 2008-06-19 | Evonik Oxeno Gmbh | Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung |
| KR100964098B1 (ko) * | 2007-04-09 | 2010-06-16 | 주식회사 엘지화학 | 포스파이트 리간드를 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법 |
| DE102007023514A1 (de) * | 2007-05-18 | 2008-11-20 | Evonik Oxeno Gmbh | Stabile Katalysatorvorstufe von Rh-Komplexkatalysatoren |
| RU2354642C2 (ru) * | 2007-06-26 | 2009-05-10 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Способ получения альдегидов c3-c21 |
| DE102008002188A1 (de) * | 2008-06-03 | 2009-12-10 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung |
| JP5670909B2 (ja) | 2008-11-14 | 2015-02-18 | ユニバーシティ・オブ・カンザス | ポリマーに担持された遷移金属触媒錯体、及びその使用方法 |
| CA2784943C (en) † | 2009-12-22 | 2016-09-06 | Dow Technology Investments Llc | Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure |
| DE102014209536A1 (de) * | 2014-05-20 | 2015-11-26 | Evonik Degussa Gmbh | Herstellung qualitativ hochwertiger Oxo-Alkohole aus unsteten Rohstoffquellen |
| DE102015202722A1 (de) | 2014-05-20 | 2015-11-26 | Evonik Degussa Gmbh | Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Monophosphit-Gemischen |
| DE102014209533A1 (de) | 2014-05-20 | 2015-12-17 | Evonik Degussa Gmbh | Gemische von Monophosphitligand und deren Verwendung zur Katalyse einer Hydroformylierungsreaktion |
| CN115066429A (zh) | 2020-02-11 | 2022-09-16 | 巴斯夫欧洲公司 | 二异丁烯的低压醛化 |
| JP7278506B2 (ja) * | 2020-12-04 | 2023-05-19 | Ｋｈネオケム株式会社 | アルデヒドの製造方法 |
| CN114644652A (zh) * | 2022-04-22 | 2022-06-21 | 广东欧凯新材料有限公司 | 一种大位阻双苯酚化合物及其双膦配体的制备方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4668651A (en) | 1985-09-05 | 1987-05-26 | Union Carbide Corporation | Transition metal complex catalyzed processes |
| US4885401A (en) | 1985-09-05 | 1989-12-05 | Union Carbide Corporation | Bis-phosphite compounds |
| US4748261A (en) | 1985-09-05 | 1988-05-31 | Union Carbide Corporation | Bis-phosphite compounds |
| US4774361A (en) | 1986-05-20 | 1988-09-27 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| US5113022A (en) | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
| DE4026406A1 (de) | 1990-08-21 | 1992-02-27 | Basf Ag | Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden |
| US5179055A (en) | 1990-09-24 | 1993-01-12 | New York University | Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins |
| TW213465B (es) | 1991-06-11 | 1993-09-21 | Mitsubishi Chemicals Co Ltd | |
| DE4204808A1 (de) | 1992-02-18 | 1993-08-19 | Basf Ag | Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern |
| US5312996A (en) | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
| US5364950A (en) | 1992-09-29 | 1994-11-15 | Union Carbide Chimicals & Plastics Technology Corporation | Process for stabilizing phosphite ligands in hydroformylation reaction mixtures |
| US5763680A (en) * | 1995-12-06 | 1998-06-09 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed process |
| JPH09255610A (ja) | 1996-03-28 | 1997-09-30 | Mitsubishi Chem Corp | アルデヒド類の製造方法 |
| JPH09268152A (ja) | 1996-04-03 | 1997-10-14 | Mitsubishi Chem Corp | アルデヒド類の製造方法 |
| AU6518398A (en) * | 1997-03-27 | 1998-10-22 | Mitsubishi Chemical Corporation | Process for producing aldehydes |
-
1999
- 1999-11-12 DE DE19954510A patent/DE19954510A1/de not_active Withdrawn
-
2000
- 2000-09-29 EP EP00121488A patent/EP1099678B1/de not_active Expired - Lifetime
- 2000-09-29 AT AT00121488T patent/ATE234801T1/de not_active IP Right Cessation
- 2000-09-29 ES ES00121488T patent/ES2190932T3/es not_active Expired - Lifetime
- 2000-09-29 DE DE50001482T patent/DE50001482D1/de not_active Expired - Fee Related
- 2000-11-03 TW TW089123187A patent/TW538030B/zh not_active IP Right Cessation
- 2000-11-03 ID IDP20000949D patent/ID28360A/id unknown
- 2000-11-06 SG SG200006385A patent/SG88797A1/en unknown
- 2000-11-07 TR TR2000/03273A patent/TR200003273A2/xx unknown
- 2000-11-08 CZ CZ20004142A patent/CZ20004142A3/cs unknown
- 2000-11-09 US US09/708,624 patent/US6403837B1/en not_active Expired - Fee Related
- 2000-11-09 MX MXPA00011028A patent/MXPA00011028A/es unknown
- 2000-11-09 JP JP2000342074A patent/JP2001187759A/ja active Pending
- 2000-11-10 PL PL00343792A patent/PL343792A1/xx not_active IP Right Cessation
- 2000-11-10 MY MYPI20005297A patent/MY135998A/en unknown
- 2000-11-10 CA CA002325676A patent/CA2325676A1/en not_active Abandoned
- 2000-11-10 AR ARP000105933A patent/AR026425A1/es unknown
- 2000-11-10 BR BR0005333-3A patent/BR0005333A/pt not_active IP Right Cessation
- 2000-11-10 ZA ZA200006514A patent/ZA200006514B/xx unknown
- 2000-11-11 KR KR1020000066962A patent/KR20010051634A/ko not_active Ceased
- 2000-11-13 CN CN00132364A patent/CN1295997A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US6403837B1 (en) | 2002-06-11 |
| ATE234801T1 (de) | 2003-04-15 |
| TW538030B (en) | 2003-06-21 |
| PL343792A1 (en) | 2001-05-21 |
| MXPA00011028A (es) | 2002-05-23 |
| CN1295997A (zh) | 2001-05-23 |
| KR20010051634A (ko) | 2001-06-25 |
| TR200003273A2 (tr) | 2001-06-21 |
| BR0005333A (pt) | 2001-07-03 |
| SG88797A1 (en) | 2002-05-21 |
| EP1099678B1 (de) | 2003-03-19 |
| DE19954510A1 (de) | 2001-05-17 |
| DE50001482D1 (de) | 2003-04-24 |
| AR026425A1 (es) | 2003-02-12 |
| ZA200006514B (en) | 2001-05-29 |
| CZ20004142A3 (cs) | 2002-04-17 |
| MY135998A (en) | 2008-07-31 |
| CA2325676A1 (en) | 2001-05-12 |
| ID28360A (id) | 2001-05-17 |
| EP1099678A1 (de) | 2001-05-16 |
| JP2001187759A (ja) | 2001-07-10 |
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