ES2195252T3 - Complejos de iridio (i)-fosfino y su utilizacion como catalizador en la hidroaminacion asimetrica de olefinas. - Google Patents
Complejos de iridio (i)-fosfino y su utilizacion como catalizador en la hidroaminacion asimetrica de olefinas.Info
- Publication number
- ES2195252T3 ES2195252T3 ES98119241T ES98119241T ES2195252T3 ES 2195252 T3 ES2195252 T3 ES 2195252T3 ES 98119241 T ES98119241 T ES 98119241T ES 98119241 T ES98119241 T ES 98119241T ES 2195252 T3 ES2195252 T3 ES 2195252T3
- Authority
- ES
- Spain
- Prior art keywords
- formula
- optionally substituted
- preparation
- alkyl
- optically active
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000005913 hydroamination reaction Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 title 1
- 150000001412 amines Chemical class 0.000 abstract 5
- VURFVHCLMJOLKN-UHFFFAOYSA-N Diphosphine Natural products PP VURFVHCLMJOLKN-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003387 indolinyl group Chemical class N1(CCC2=CC=CC=C12)* 0.000 abstract 2
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 abstract 1
- KSHARGNRPFMEHY-UHFFFAOYSA-N P.[Ir+] Chemical class P.[Ir+] KSHARGNRPFMEHY-UHFFFAOYSA-N 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000002619 bicyclic group Chemical group 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000004475 heteroaralkyl group Chemical group 0.000 abstract 1
- 125000001072 heteroaryl group Chemical group 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 238000007363 ring formation reaction Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0033—Iridium compounds
- C07F15/004—Iridium compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Indole Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH239297 | 1997-10-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2195252T3 true ES2195252T3 (es) | 2003-12-01 |
Family
ID=4232707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98119241T Expired - Lifetime ES2195252T3 (es) | 1997-10-14 | 1998-10-12 | Complejos de iridio (i)-fosfino y su utilizacion como catalizador en la hidroaminacion asimetrica de olefinas. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5929265A (de) |
| EP (1) | EP0909762B1 (de) |
| JP (1) | JP4218088B2 (de) |
| AT (1) | ATE236913T1 (de) |
| CA (1) | CA2249958C (de) |
| DE (1) | DE59807829D1 (de) |
| DK (1) | DK0909762T3 (de) |
| ES (1) | ES2195252T3 (de) |
| PT (1) | PT909762E (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19952348A1 (de) * | 1998-12-19 | 2000-06-21 | Degussa | Liganden und Komplexe zur enantioselektiven Hydrierung |
| US6384282B2 (en) | 2000-03-01 | 2002-05-07 | Yale University | Transition metal-catalyzed process for addition of amines to carbon-carbon double bonds |
| JP5185485B2 (ja) * | 2000-07-03 | 2013-04-17 | ソルヴィーアス アクチェンゲゼルシャフト | フェロセニルジホスフィンおよびその使用 |
| AU9619301A (en) | 2000-10-20 | 2002-04-29 | Biovitrum Ab | 2-, 3-, 4-, or 5-substituted-n1-(benzensulfonyl)indoles and their use in therapy |
| CN100395250C (zh) * | 2004-11-25 | 2008-06-18 | 友达光电股份有限公司 | 有机金属络合物以及包括该有机金属络合物的有机电致发光装置 |
| WO2006090688A1 (ja) * | 2005-02-25 | 2006-08-31 | Mitsui Chemicals, Inc. | 重合触媒組成物およびポリマーの製造方法 |
| US10396298B2 (en) * | 2017-01-25 | 2019-08-27 | National Tsing Hua University | Iridium complex and organic light-emitting diode using the same |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2408388A1 (fr) * | 1977-11-10 | 1979-06-08 | Ugine Kuhlmann | Complexe binucleaire du rhodium en tant que catalyseur d'hydroformylation et d'hydrogenation |
| US5011995A (en) * | 1987-07-28 | 1991-04-30 | Ciba-Geigy Corporation | Process for the preparation of optically active secondary amines |
| DE59009835D1 (de) * | 1989-09-18 | 1995-12-07 | Ciba Geigy Ag | Iridiumkomplexe, Verfahren zu deren Herstellung und deren Verwendung. |
| DE59309554D1 (de) * | 1992-04-02 | 1999-06-10 | Novartis Ag | Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
| DE59410267D1 (de) * | 1993-02-26 | 2003-05-15 | Syngenta Participations Ag | Ferrocenyldiphosphine als Liganden für homogene Katalysatoren |
| JP3338243B2 (ja) * | 1995-07-21 | 2002-10-28 | 高砂香料工業株式会社 | 光学活性非対称ジホスフィン化合物及びその製造方法 |
-
1998
- 1998-10-12 AT AT98119241T patent/ATE236913T1/de active
- 1998-10-12 JP JP28989398A patent/JP4218088B2/ja not_active Expired - Fee Related
- 1998-10-12 DE DE59807829T patent/DE59807829D1/de not_active Expired - Lifetime
- 1998-10-12 PT PT98119241T patent/PT909762E/pt unknown
- 1998-10-12 ES ES98119241T patent/ES2195252T3/es not_active Expired - Lifetime
- 1998-10-12 DK DK98119241T patent/DK0909762T3/da active
- 1998-10-12 EP EP98119241A patent/EP0909762B1/de not_active Expired - Lifetime
- 1998-10-13 CA CA002249958A patent/CA2249958C/en not_active Expired - Fee Related
- 1998-10-13 US US09/170,114 patent/US5929265A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2249958C (en) | 2008-12-09 |
| JP4218088B2 (ja) | 2009-02-04 |
| JPH11228589A (ja) | 1999-08-24 |
| ATE236913T1 (de) | 2003-04-15 |
| DE59807829D1 (de) | 2003-05-15 |
| DK0909762T3 (da) | 2003-08-18 |
| EP0909762B1 (de) | 2003-04-09 |
| PT909762E (pt) | 2003-08-29 |
| EP0909762A3 (de) | 1999-10-06 |
| CA2249958A1 (en) | 1999-04-14 |
| EP0909762A2 (de) | 1999-04-21 |
| US5929265A (en) | 1999-07-27 |
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