ES2215782T3 - Composiciones de detergente. - Google Patents

Composiciones de detergente.

Info

Publication number: ES2215782T3
Authority: ES; Spain
Prior art keywords: weight; detergent; sodium; particles; sodium tripolyphosphate
Prior art date: 1999-11-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES00988761T

Other languages

English (en)

Spanish (es)

Inventor

Peter Willem Unilever Research Vlaardingen APPEL

Erik C. Unilever Research Vlaardingen BERDEN

Jelles V. Unilever Research Vlaardingen BOSKAMP

Henning Unilever Research Vlaardingen WAGNER

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever NV

Original Assignee

Unilever NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-11-26

Filing date

2000-11-24

Publication date

2004-10-16

2000-11-24 Application filed by Unilever NV filed Critical Unilever NV

2004-10-16 Application granted granted Critical

2004-10-16 Publication of ES2215782T3 publication Critical patent/ES2215782T3/es

2020-11-24 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title claims abstract description 67
239000000203 mixture Substances 0.000 title claims abstract description 58
235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 79
239000002245 particle Substances 0.000 claims abstract description 78
150000003839 salts Chemical class 0.000 claims abstract description 51
150000001875 compounds Chemical class 0.000 claims abstract description 32
239000004615 ingredient Substances 0.000 claims abstract description 10
239000000463 material Substances 0.000 claims description 57
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
239000011734 sodium Substances 0.000 claims description 33
229910052708 sodium Inorganic materials 0.000 claims description 29
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 28
230000036571 hydration Effects 0.000 claims description 25
238000006703 hydration reaction Methods 0.000 claims description 25
239000002671 adjuvant Substances 0.000 claims description 23
239000007884 disintegrant Substances 0.000 claims description 21
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 20
-1 perborate Chemical compound 0.000 claims description 19
230000008961 swelling Effects 0.000 claims description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 56
239000006187 pill Substances 0.000 description 36
239000002253 acid Substances 0.000 description 28
239000000377 silicon dioxide Substances 0.000 description 26
239000007844 bleaching agent Substances 0.000 description 21
238000005406 washing Methods 0.000 description 18
239000004753 textile Substances 0.000 description 15
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
239000002736 nonionic surfactant Substances 0.000 description 12
150000007513 acids Chemical class 0.000 description 11
239000003945 anionic surfactant Substances 0.000 description 11
239000011230 binding agent Substances 0.000 description 11
239000000243 solution Substances 0.000 description 11
238000000034 method Methods 0.000 description 10
238000004061 bleaching Methods 0.000 description 9
239000003795 chemical substances by application Substances 0.000 description 9
229910052783 alkali metal Inorganic materials 0.000 description 8
229920002678 cellulose Polymers 0.000 description 8
235000010980 cellulose Nutrition 0.000 description 8
229920005646 polycarboxylate Polymers 0.000 description 8
229920000642 polymer Polymers 0.000 description 8
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
239000012190 activator Substances 0.000 description 7
125000000217 alkyl group Chemical group 0.000 description 7
239000001913 cellulose Substances 0.000 description 7
238000005056 compaction Methods 0.000 description 7
239000000843 powder Substances 0.000 description 7
239000000344 soap Substances 0.000 description 7
239000004094 surface-active agent Substances 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
108090000790 Enzymes Proteins 0.000 description 6
102000004190 Enzymes Human genes 0.000 description 6
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
229910052910 alkali metal silicate Inorganic materials 0.000 description 6
239000002518 antifoaming agent Substances 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 6
150000004649 carbonic acid derivatives Chemical class 0.000 description 6
239000002738 chelating agent Substances 0.000 description 6
239000000460 chlorine Substances 0.000 description 6
229910052801 chlorine Inorganic materials 0.000 description 6
229920001577 copolymer Polymers 0.000 description 6
229910052906 cristobalite Inorganic materials 0.000 description 6
229940088598 enzyme Drugs 0.000 description 6
239000008187 granular material Substances 0.000 description 6
235000012239 silicon dioxide Nutrition 0.000 description 6
238000012360 testing method Methods 0.000 description 6
229910052905 tridymite Inorganic materials 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
150000001340 alkali metals Chemical class 0.000 description 5
238000004140 cleaning Methods 0.000 description 5
229910052681 coesite Inorganic materials 0.000 description 5
229910001385 heavy metal Inorganic materials 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
235000017281 sodium acetate Nutrition 0.000 description 5
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
239000007787 solid Substances 0.000 description 5
229910052682 stishovite Inorganic materials 0.000 description 5
239000007916 tablet composition Substances 0.000 description 5
239000010457 zeolite Substances 0.000 description 5
BDKLKNJTMLIAFE-UHFFFAOYSA-N 2-(3-fluorophenyl)-1,3-oxazole-4-carbaldehyde Chemical compound FC1=CC=CC(C=2OC=C(C=O)N=2)=C1 BDKLKNJTMLIAFE-UHFFFAOYSA-N 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
239000004115 Sodium Silicate Substances 0.000 description 4
229910021536 Zeolite Inorganic materials 0.000 description 4
239000002280 amphoteric surfactant Substances 0.000 description 4
125000004429 atom Chemical group 0.000 description 4
239000002585 base Substances 0.000 description 4
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
229910052794 bromium Inorganic materials 0.000 description 4
229910052799 carbon Inorganic materials 0.000 description 4
239000003638 chemical reducing agent Substances 0.000 description 4
229960004106 citric acid Drugs 0.000 description 4
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
238000004851 dishwashing Methods 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
239000011591 potassium Substances 0.000 description 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
150000004760 silicates Chemical class 0.000 description 4
229940087562 sodium acetate trihydrate Drugs 0.000 description 4
229960001922 sodium perborate Drugs 0.000 description 4
229910052911 sodium silicate Inorganic materials 0.000 description 4
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 4
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
239000002202 Polyethylene glycol Substances 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
239000000654 additive Substances 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000013078 crystal Substances 0.000 description 3
238000004090 dissolution Methods 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
239000000178 monomer Substances 0.000 description 3
150000004965 peroxy acids Chemical class 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
239000001267 polyvinylpyrrolidone Substances 0.000 description 3
229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
239000002243 precursor Substances 0.000 description 3
238000012545 processing Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
235000012217 sodium aluminium silicate Nutrition 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
239000001509 sodium citrate Substances 0.000 description 3
229960000999 sodium citrate dihydrate Drugs 0.000 description 3
239000012418 sodium perborate tetrahydrate Substances 0.000 description 3
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 3
230000007928 solubilization Effects 0.000 description 3
238000005063 solubilization Methods 0.000 description 3
239000002195 soluble material Substances 0.000 description 3
150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 2
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 2
239000004604 Blowing Agent Substances 0.000 description 2
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
240000000731 Fagus sylvatica Species 0.000 description 2
235000010099 Fagus sylvatica Nutrition 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
108091005804 Peptidases Proteins 0.000 description 2
102000035195 Peptidases Human genes 0.000 description 2
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
239000004365 Protease Substances 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
108010056079 Subtilisins Proteins 0.000 description 2
102000005158 Subtilisins Human genes 0.000 description 2
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
150000008052 alkyl sulfonates Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
150000001642 boronic acid derivatives Chemical class 0.000 description 2
239000001768 carboxy methyl cellulose Substances 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000000280 densification Methods 0.000 description 2
WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
235000021186 dishes Nutrition 0.000 description 2
PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000000975 dye Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000005538 encapsulation Methods 0.000 description 2
239000002979 fabric softener Substances 0.000 description 2
239000006260 foam Substances 0.000 description 2
238000005187 foaming Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
238000005469 granulation Methods 0.000 description 2
230000003179 granulation Effects 0.000 description 2
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 2
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
229910052943 magnesium sulfate Inorganic materials 0.000 description 2
235000019341 magnesium sulphate Nutrition 0.000 description 2
229920000609 methyl cellulose Polymers 0.000 description 2
239000001923 methylcellulose Substances 0.000 description 2
235000010981 methylcellulose Nutrition 0.000 description 2
125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
238000002156 mixing Methods 0.000 description 2
150000004682 monohydrates Chemical class 0.000 description 2
150000004967 organic peroxy acids Chemical class 0.000 description 2
150000004686 pentahydrates Chemical class 0.000 description 2
239000002304 perfume Substances 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
235000002949 phytic acid Nutrition 0.000 description 2
SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
235000011181 potassium carbonates Nutrition 0.000 description 2
238000003825 pressing Methods 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
230000008569 process Effects 0.000 description 2
238000000926 separation method Methods 0.000 description 2
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
239000007921 spray Substances 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
229920005613 synthetic organic polymer Polymers 0.000 description 2
150000004685 tetrahydrates Chemical group 0.000 description 2
229910052723 transition metal Inorganic materials 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 1
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
BPSYZMLXRKCSJY-UHFFFAOYSA-N 1,3,2-dioxaphosphepan-2-ium 2-oxide Chemical compound O=[P+]1OCCCCO1 BPSYZMLXRKCSJY-UHFFFAOYSA-N 0.000 description 1
SZHQPBJEOCHCKM-UHFFFAOYSA-N 2-phosphonobutane-1,2,4-tricarboxylic acid Chemical compound OC(=O)CCC(P(O)(O)=O)(C(O)=O)CC(O)=O SZHQPBJEOCHCKM-UHFFFAOYSA-N 0.000 description 1
TYKPJLVEPXWTFW-UHFFFAOYSA-N 3,7,9-trichloro-1-isocyanopurine-2,6,8-trione Chemical compound ClN1C(=O)N([N+]#[C-])C(=O)C2=C1N(Cl)C(=O)N2Cl TYKPJLVEPXWTFW-UHFFFAOYSA-N 0.000 description 1
YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
KNMZUYRTYPXGDH-UHFFFAOYSA-N BrC12NC(NC1(NC(N(C2=O)[N+]#[C-])=O)Br)=O Chemical compound BrC12NC(NC1(NC(N(C2=O)[N+]#[C-])=O)Br)=O KNMZUYRTYPXGDH-UHFFFAOYSA-N 0.000 description 1
LRRDOTYFRDWULQ-UHFFFAOYSA-N BrN1C(N(C=2N(C(N(C(C1=2)=O)[N+]#[C-])=O)Br)Br)=O Chemical compound BrN1C(N(C=2N(C(N(C(C1=2)=O)[N+]#[C-])=O)Br)Br)=O LRRDOTYFRDWULQ-UHFFFAOYSA-N 0.000 description 1
240000002791 Brassica napus Species 0.000 description 1
235000004977 Brassica sinapistrum Nutrition 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
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229920002545 silicone oil Polymers 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
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229920003109 sodium starch glycolate Polymers 0.000 description 1
239000008109 sodium starch glycolate Substances 0.000 description 1
229940079832 sodium starch glycolate Drugs 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
MOFJBYOBLBVDJZ-UHFFFAOYSA-N sodium;stilbene Chemical compound C=1C=CC=CC=1C([Na])C([Na])C1=CC=CC=C1 MOFJBYOBLBVDJZ-UHFFFAOYSA-N 0.000 description 1
QBIHEHITTANFEO-UHFFFAOYSA-N sodium;tetrahydrate Chemical compound O.O.O.O.[Na] QBIHEHITTANFEO-UHFFFAOYSA-N 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
229940032147 starch Drugs 0.000 description 1
239000008107 starch Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
229940117986 sulfobetaine Drugs 0.000 description 1
239000002600 sunflower oil Substances 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
VUYXVWGKCKTUMF-UHFFFAOYSA-N tetratriacontaethylene glycol monomethyl ether Chemical compound COCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO VUYXVWGKCKTUMF-UHFFFAOYSA-N 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
230000007704 transition Effects 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

ES00988761T 1999-11-26 2000-11-24 Composiciones de detergente. Expired - Lifetime ES2215782T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GBGB9928078.6A GB9928078D0 (en)	1999-11-26	1999-11-26	Detergent compositions
GB9928078		1999-11-26

Publications (1)

Publication Number	Publication Date
ES2215782T3 true ES2215782T3 (es)	2004-10-16

Family

ID=10865275

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
ES00988761T Expired - Lifetime ES2215782T3 (es)	1999-11-26	2000-11-24	Composiciones de detergente.
ES00983174T Expired - Lifetime ES2225276T3 (es)	1999-11-26	2000-11-24	Composiciones detergentes.

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
ES00983174T Expired - Lifetime ES2225276T3 (es)	1999-11-26	2000-11-24	Composiciones detergentes.

Country Status (11)

Country	Link
EP (2)	EP1232241B1 (de)
CN (2)	CN1399672A (de)
AT (2)	ATE276351T1 (de)
AU (2)	AU2508801A (de)
BR (2)	BR0015904A (de)
CA (2)	CA2389975A1 (de)
DE (2)	DE60013889T2 (de)
ES (2)	ES2215782T3 (de)
GB (1)	GB9928078D0 (de)
TR (1)	TR200401112T4 (de)
WO (2)	WO2001038478A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1337615A2 (de) *	2000-11-21	2003-08-27	Unilever N.V.	Waschmittelzusammensetzungen
DE60139499D1 (de) *	2000-11-24	2009-09-17	Unilever Nv	Reinigungsmittelzusammensetzungen
FR2842426B1 (fr) *	2002-07-19	2005-03-18	Philippe Guichard	Composition nettoyante, detergente, desinfectante et decontaminante, a large spectre d'utilisation
JP4635223B2 (ja) *	2004-09-06	2011-02-23	株式会社古河テクノマテリアル	界面活性剤系組成物
EP3181676B1 (de)	2015-12-17	2019-03-13	The Procter and Gamble Company	Spülmittelzusammensetzung für automatisches geschirrspülen
EP3181671B1 (de) *	2015-12-17	2024-07-10	The Procter & Gamble Company	Spülmittelzusammensetzung für automatisches geschirrspülen
EP3181672A1 (de) *	2015-12-17	2017-06-21	The Procter and Gamble Company	Spülmittelzusammensetzung für automatisches geschirrspülen
EP3181675B2 (de)	2015-12-17	2022-12-07	The Procter & Gamble Company	Spülmittelzusammensetzung für automatisches geschirrspülen
EP3181679A1 (de) *	2015-12-17	2017-06-21	The Procter and Gamble Company	Verfahren zur herstellung eines automatischen geschirrspülprodukts
CN107177429A (zh) *	2016-03-11	2017-09-19	华北制药秦皇岛有限公司	一种便于携带、使用方便的洗衣片及其制备工艺
WO2020176821A1 (en)	2019-02-28	2020-09-03	Ecolab Usa Inc.	Hardness additives and block detergents containing hardness additives to improve edge hardening
WO2021161059A1 (en) *	2020-02-14	2021-08-19	Wash To Go, Unipessoal, Lda	Detergent composition in effervescent tablet form
WO2022268657A1 (en)	2021-06-24	2022-12-29	Unilever Ip Holdings B.V.	Unit dose cleaning composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB2324495A (en) *	1997-04-22	1998-10-28	Procter & Gamble	Multi-layer detergent tablet
GB9711829D0 (en) *	1997-06-06	1997-08-06	Unilever Plc	Detergent compositions
GB2331994A (en) *	1997-12-02	1999-06-09	Procter & Gamble	Detergent tablet
FR2778666B1 (fr) *	1998-05-14	2003-01-17	Chimiotechnic	Tablette detergente tricouches, et utilisation

1999
- 1999-11-26 GB GBGB9928078.6A patent/GB9928078D0/en not_active Ceased
2000
- 2000-11-24 WO PCT/EP2000/011815 patent/WO2001038478A1/en not_active Ceased
- 2000-11-24 AU AU25088/01A patent/AU2508801A/en not_active Abandoned
- 2000-11-24 ES ES00988761T patent/ES2215782T3/es not_active Expired - Lifetime
- 2000-11-24 AT AT00983174T patent/ATE276351T1/de not_active IP Right Cessation
- 2000-11-24 BR BR0015904-2A patent/BR0015904A/pt not_active Application Discontinuation
- 2000-11-24 CA CA002389975A patent/CA2389975A1/en not_active Abandoned
- 2000-11-24 AT AT00988761T patent/ATE264908T1/de not_active IP Right Cessation
- 2000-11-24 EP EP00988761A patent/EP1232241B1/de not_active Expired - Lifetime
- 2000-11-24 BR BR0015903-4A patent/BR0015903A/pt not_active Application Discontinuation
- 2000-11-24 ES ES00983174T patent/ES2225276T3/es not_active Expired - Lifetime
- 2000-11-24 DE DE60013889T patent/DE60013889T2/de not_active Expired - Fee Related
- 2000-11-24 EP EP00983174A patent/EP1232240B1/de not_active Expired - Lifetime
- 2000-11-24 WO PCT/EP2000/011816 patent/WO2001038479A1/en not_active Ceased
- 2000-11-24 DE DE60010117T patent/DE60010117T2/de not_active Expired - Fee Related
- 2000-11-24 CN CN00816261.1A patent/CN1399672A/zh active Pending
- 2000-11-24 AU AU20023/01A patent/AU2002301A/en not_active Abandoned
- 2000-11-24 CA CA002389984A patent/CA2389984A1/en not_active Abandoned
- 2000-11-24 TR TR2004/01112T patent/TR200401112T4/xx unknown
- 2000-11-24 CN CN00818656.1A patent/CN1425060A/zh active Pending

Also Published As

Publication number	Publication date
EP1232241A1 (de)	2002-08-21
CN1399672A (zh)	2003-02-26
EP1232241B1 (de)	2004-04-21
DE60010117T2 (de)	2004-08-26
CN1425060A (zh)	2003-06-18
ES2225276T3 (es)	2005-03-16
ATE264908T1 (de)	2004-05-15
GB9928078D0 (en)	2000-01-26
DE60013889D1 (de)	2004-10-21
CA2389984A1 (en)	2001-05-31
WO2001038478A1 (en)	2001-05-31
CA2389975A1 (en)	2001-05-31
BR0015904A (pt)	2002-07-16
AU2002301A (en)	2001-06-04
DE60013889T2 (de)	2005-01-27
EP1232240A1 (de)	2002-08-21
ATE276351T1 (de)	2004-10-15
BR0015903A (pt)	2002-07-16
EP1232240B1 (de)	2004-09-15
AU2508801A (en)	2001-06-04
WO2001038479A1 (en)	2001-05-31
TR200401112T4 (tr)	2004-06-21
DE60010117D1 (de)	2004-05-27

Publication	Publication Date	Title
ES2241360T3 (es)	2005-10-16	Pastillas de determente.
ES2210789T3 (es)	2004-07-01	Composiciones detergentes.
ES2313539T3 (es)	2009-03-01	Composiciones de detergente en forma de pastillas.
ES2210775T5 (es)	2007-05-16	Composiciones de limpieza.
EP0838519B1 (de)	2000-03-08	Wasserenthärtende Zusammensetzungen und Waschmittelzusammensetzungen
ES2178273T5 (es)	2011-02-25	Composiciones detergentes en forma de comprimidos.
ES2215782T3 (es)	2004-10-16	Composiciones de detergente.
JPH04339899A (ja)	1992-11-26	洗剤組成物
ES2215416T3 (es)	2004-10-01	Composiciones de detergente.
JPH05186800A (ja)	1993-07-27	洗剤組成物
JPH04253800A (ja)	1992-09-09	洗剤組成物
EP0986634B1 (de)	2002-09-11	Reinigungsmittel in tablettenform
ES2331230T3 (es)	2009-12-28	Composiciones de limpieza.
SK164499A3 (en)	2000-07-11	Additive granules for moulded bodies having a detergent and cleaning action
ES2311301T3 (es)	2009-02-01	Composiciones detergentes y suavizantes de agua.
ES2246245T3 (es)	2006-02-16	Composiciones detergentes.
ES2213806T3 (es)	2004-09-01	Composicion detergente.
EP1239029A1 (de)	2002-09-11	Wasch- oder Reinigungsmittel
ES2257511T3 (es)	2006-08-01	Composiciones detergentes.
ES2250158T3 (es)	2006-04-16	Composiciones detergentes y ablandadoras del agua.
CZ20011248A3 (cs)	2002-04-17	Prací prostředek
WO2002042398A2 (en)	2002-05-30	Detergent compositions
ES2448841T3 (es)	2014-03-17	Pastillas de tratamiento para el lavado de ropa, de múltiples fases
ES2368134T3 (es)	2011-11-14	Composiciones de limpieza.
ES2184514T5 (es)	2007-03-16	Composiciones detergentes en forma de pastillas.