ES2217345T3 - Mezclas de sales de acidos carboxilicos y de esteres de acidos carboxilicos y su empleo. - Google Patents

Mezclas de sales de acidos carboxilicos y de esteres de acidos carboxilicos y su empleo.

Info

Publication number: ES2217345T3
Authority: ES; Spain
Prior art keywords: drying; mixtures; products; esters; carboxyl acids
Prior art date: 1996-04-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES97105741T

Other languages

English (en)

Spanish (es)

Inventor

Dirk Dr. Edelmann

Alain Pattou

Gunter Link

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

OMG Borchers GmbH

Original Assignee

Borchers GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-04-19

Filing date

1997-04-08

Publication date

2004-11-01

1996-05-31 Priority claimed from DE19621866A external-priority patent/DE19621866A1/de

1997-04-08 Application filed by Borchers GmbH filed Critical Borchers GmbH

2004-11-01 Application granted granted Critical

2004-11-01 Publication of ES2217345T3 publication Critical patent/ES2217345T3/es

2017-04-08 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 31
-1 CARBOXYL ACIDS Chemical class 0.000 title claims abstract description 7
239000002253 acid Substances 0.000 title abstract description 7
150000002148 esters Chemical class 0.000 claims description 12
229910052751 metal Inorganic materials 0.000 claims description 12
239000002184 metal Substances 0.000 claims description 12
150000001735 carboxylic acids Chemical class 0.000 claims description 11
229910052748 manganese Inorganic materials 0.000 claims description 6
229910052725 zinc Inorganic materials 0.000 claims description 6
125000001931 aliphatic group Chemical group 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
150000003839 salts Chemical class 0.000 claims description 4
229910052791 calcium Inorganic materials 0.000 claims description 3
229920006395 saturated elastomer Polymers 0.000 claims description 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
229910052787 antimony Inorganic materials 0.000 claims description 2
125000004429 atom Chemical group 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
229910052799 carbon Inorganic materials 0.000 claims description 2
229910052804 chromium Inorganic materials 0.000 claims description 2
229910052802 copper Inorganic materials 0.000 claims description 2
229910052759 nickel Inorganic materials 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
229910052712 strontium Inorganic materials 0.000 claims description 2
229910052718 tin Inorganic materials 0.000 claims description 2
238000001035 drying Methods 0.000 abstract description 49
238000000034 method Methods 0.000 abstract description 6
150000001734 carboxylic acid salts Chemical class 0.000 abstract 1
230000001590 oxidative effect Effects 0.000 abstract 1
238000002360 preparation method Methods 0.000 abstract 1
239000000047 product Substances 0.000 description 29
239000003973 paint Substances 0.000 description 22
150000004702 methyl esters Chemical class 0.000 description 16
239000003921 oil Substances 0.000 description 11
235000019198 oils Nutrition 0.000 description 11
230000003647 oxidation Effects 0.000 description 11
238000007254 oxidation reaction Methods 0.000 description 11
230000000052 comparative effect Effects 0.000 description 10
239000011230 binding agent Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
229910052726 zirconium Inorganic materials 0.000 description 9
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
239000011572 manganese Substances 0.000 description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
239000011701 zinc Substances 0.000 description 8
239000003960 organic solvent Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
238000012360 testing method Methods 0.000 description 7
MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000003549 soybean oil Substances 0.000 description 6
235000012424 soybean oil Nutrition 0.000 description 6
235000010469 Glycine max Nutrition 0.000 description 5
239000007787 solid Substances 0.000 description 5
150000001768 cations Chemical class 0.000 description 4
229910017052 cobalt Inorganic materials 0.000 description 4
239000010941 cobalt Substances 0.000 description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 3
229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 3
235000019484 Rapeseed oil Nutrition 0.000 description 3
229920000180 alkyd Polymers 0.000 description 3
OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 3
238000003556 assay Methods 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
239000002274 desiccant Substances 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
238000004821 distillation Methods 0.000 description 3
UKRVECBFDMVBPU-UHFFFAOYSA-N ethyl 3-oxoheptanoate Chemical compound CCCCC(=O)CC(=O)OCC UKRVECBFDMVBPU-UHFFFAOYSA-N 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
238000001914 filtration Methods 0.000 description 3
239000002966 varnish Substances 0.000 description 3
CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 3
OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
PKSIZOUDEUREFF-UHFFFAOYSA-N cobalt;dihydrate Chemical compound O.O.[Co] PKSIZOUDEUREFF-UHFFFAOYSA-N 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
238000009472 formulation Methods 0.000 description 2
239000000944 linseed oil Substances 0.000 description 2
235000021388 linseed oil Nutrition 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
125000005474 octanoate group Chemical group 0.000 description 2
238000010422 painting Methods 0.000 description 2
239000000344 soap Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
239000001149 (9Z,12Z)-octadeca-9,12-dienoate Substances 0.000 description 1
WTTJVINHCBCLGX-UHFFFAOYSA-N (9trans,12cis)-methyl linoleate Natural products CCCCCC=CCC=CCCCCCCCC(=O)OC WTTJVINHCBCLGX-UHFFFAOYSA-N 0.000 description 1
LNJCGNRKWOHFFV-UHFFFAOYSA-N 3-(2-hydroxyethylsulfanyl)propanenitrile Chemical compound OCCSCCC#N LNJCGNRKWOHFFV-UHFFFAOYSA-N 0.000 description 1
HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 description 1
239000004971 Cross linker Substances 0.000 description 1
101150045022 Epdr1 gene Proteins 0.000 description 1
244000068988 Glycine max Species 0.000 description 1
244000020551 Helianthus annuus Species 0.000 description 1
235000003222 Helianthus annuus Nutrition 0.000 description 1
101001012021 Homo sapiens Mammalian ependymin-related protein 1 Proteins 0.000 description 1
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
240000006240 Linum usitatissimum Species 0.000 description 1
235000004431 Linum usitatissimum Nutrition 0.000 description 1
102100030031 Mammalian ependymin-related protein 1 Human genes 0.000 description 1
PKIXXJPMNDDDOS-UHFFFAOYSA-N Methyl linoleate Natural products CCCCC=CCCC=CCCCCCCCC(=O)OC PKIXXJPMNDDDOS-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
235000019486 Sunflower oil Nutrition 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
239000000706 filtrate Substances 0.000 description 1
235000004426 flaxseed Nutrition 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000003292 glue Substances 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
229940073769 methyl oleate Drugs 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
239000003507 refrigerant Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 1
229940066675 ricinoleate Drugs 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
235000020354 squash Nutrition 0.000 description 1
239000002600 sunflower oil Substances 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
230000007704 transition Effects 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Paints Or Removers (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

ES97105741T 1996-04-19 1997-04-08 Mezclas de sales de acidos carboxilicos y de esteres de acidos carboxilicos y su empleo. Expired - Lifetime ES2217345T3 (es)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
DE19615450		1996-04-19
DE19615450		1996-04-19
DE19621866		1996-05-31
DE19621866A DE19621866A1 (de)	1996-04-19	1996-05-31	Mischungen von Carbonsäuresalzen und Carbonsäureestern, Verfahren zu deren Herstellung und deren Verwendung

Publications (1)

Publication Number	Publication Date
ES2217345T3 true ES2217345T3 (es)	2004-11-01

Family

ID=26024887

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES97105741T Expired - Lifetime ES2217345T3 (es)	1996-04-19	1997-04-08	Mezclas de sales de acidos carboxilicos y de esteres de acidos carboxilicos y su empleo.

Country Status (6)

Country	Link
US (1)	US5759252A (2)
EP (1)	EP0802248B1 (2)
JP (1)	JP3936024B2 (2)
AT (1)	ATE260960T1 (2)
CA (1)	CA2202966C (2)
ES (1)	ES2217345T3 (2)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU2003230461A1 (en) *	2002-05-03	2003-11-17	Ato B.V.	Drier for air-drying coatings
PL1648851T3 (pl) *	2003-07-25	2007-09-28	Prometic Biosciences Inc	Wytwarzanie soli średniołańcuchowych kwasów tłuszczowych z metalami
CA2534021C (en) *	2003-08-08	2013-01-08	Imperial Chemical Industries Plc	Autoxidisable architectural coating compositions
US7682440B2 (en) *	2005-03-29	2010-03-23	Genesis Ii Of Nc, Llc	Drying enhancement additive and method of using same
CN101484544B (zh)	2006-07-07	2013-11-06	Omg英国技术有限公司	液体硬化
EP2364215A4 (en)	2008-11-12	2012-05-30	Lorama Inc	SICCATIVE STABILIZED FOR ALKYDE-BASED COMPOSITIONS
US9914848B1 (en)	2016-10-31	2018-03-13	Ppg Architectural Finishes, Inc.	Refinish coating composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2361027A (en) *		1944-10-24		Drying compositions
US3124475A (en) *	1960-10-04	1964-03-10		Metal salt drier compositions
US4689266A (en) *	1986-07-16	1987-08-25	International Minerals & Chemical Corp.	Air drying protective coatings
DE4236697A1 (de) *	1992-10-30	1994-05-05	Henkel Kgaa	Trockenstoffe für oxidativ trocknende Lacke

1997
- 1997-04-07 US US08/826,743 patent/US5759252A/en not_active Expired - Lifetime
- 1997-04-08 AT AT97105741T patent/ATE260960T1/de active
- 1997-04-08 ES ES97105741T patent/ES2217345T3/es not_active Expired - Lifetime
- 1997-04-08 EP EP97105741A patent/EP0802248B1/de not_active Expired - Lifetime
- 1997-04-17 JP JP11418297A patent/JP3936024B2/ja not_active Expired - Fee Related
- 1997-04-17 CA CA002202966A patent/CA2202966C/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
EP0802248A2 (de)	1997-10-22
CA2202966C (en)	2007-06-19
US5759252A (en)	1998-06-02
JPH1072570A (ja)	1998-03-17
ATE260960T1 (de)	2004-03-15
CA2202966A1 (en)	1997-10-19
EP0802248B1 (de)	2004-03-03
JP3936024B2 (ja)	2007-06-27
EP0802248A3 (de)	1998-01-14

Publication	Publication Date	Title
ES2261613T3 (es)	2006-11-16	Tratamiento de particulas metalicas con un derivado de acido fosfonico.
US2236296A (en)	1941-03-25	Westing and dispersing agent
US2409774A (en)	1946-10-22	Drier metal salt and process of making it
EP0052928B1 (en)	1984-04-11	Water-borne surface-coating compositions containing complexed cobalt driers
ES2252803T3 (es)	2006-05-16	Empleo de compuestos especiales de vanadio como secantes para barnices que secan por oxidacion.
DE3238864C2 (de)	1991-05-29	Wäßrige Harzmasse
DE2502282C2 (de)	1985-03-07	Überzugsmittel
US1936534A (en)	1933-11-21	Coating compositions
JPH1143631A5 (ja)	2005-09-15	酸化乾燥性ラッカー用乾燥剤としてのバナジウム化合物の使用
CA2202966C (en)	2007-06-19	Mixtures of carboxylic acid salts and carboxylic acid esters and their use as siccatives for oxidatively drying lacquers
US3876574A (en)	1975-04-08	Rust preventing paint consisting essentially of high molecular metal-combining reaction product
DE2917172C2 (2)	1989-01-05
US3705852A (en)	1972-12-12	Stable solutions of calcium salts
JPH1072570A5 (2)	2005-03-17
US3972825A (en)	1976-08-03	Loss-of-dry inhibitors for surface-coating compositions
DE767788C (de)	1953-06-22	Verfahren zur Herstellung von Farbstoffsalzen
DE4236697A1 (de)	1994-05-05	Trockenstoffe für oxidativ trocknende Lacke
US3562194A (en)	1971-02-09	Oil-modified alkyd resin thixotropic paint and process for the preparation thereof
JP3290857B2 (ja)	2002-06-10	防錆塗料組成物
NZ241053A (en)	1995-04-27	Paint/stain formulations containing up to 60% by vol of reclaimed engine oil, and preferably alkyd resin
JPS59108756A (ja)	1984-06-23	アルカリ土類金属酸化物をベ−スとする被覆組成物
ES2744562T3 (es)	2020-02-25	Agente de secado catalítico basado en cobalto para recubrimientos poliméricos
DE19621866A1 (de)	1997-10-23	Mischungen von Carbonsäuresalzen und Carbonsäureestern, Verfahren zu deren Herstellung und deren Verwendung
US766740A (en)	1904-08-02	Production of paints and paint vehicles.
CS239773B1 (sk)	1986-01-16	Pomocné sušidlo na bázi solí baria karboxylové kyseliny