ES2231849T5 - Acristalamiento que comprende un sustrato provisto de un apilamiento de capas delgadas para la protección solar y/o el aislamiento térmico - Google Patents

Acristalamiento que comprende un sustrato provisto de un apilamiento de capas delgadas para la protección solar y/o el aislamiento térmico Download PDF

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Publication number
ES2231849T5
ES2231849T5 ES97403006.6T ES97403006T ES2231849T5 ES 2231849 T5 ES2231849 T5 ES 2231849T5 ES 97403006 T ES97403006 T ES 97403006T ES 2231849 T5 ES2231849 T5 ES 2231849T5
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Spain
Prior art keywords
glazing
layer
stack
thin film
substrate
Prior art date
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Expired - Lifetime
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ES97403006.6T
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English (en)
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ES2231849T3 (es
Inventor
Philippe Boire
Fabrice Didier
Jean-Michel Grimal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Original Assignee
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
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Application filed by Saint Gobain Glass France SAS, Compagnie de Saint Gobain SA filed Critical Saint Gobain Glass France SAS
Publication of ES2231849T3 publication Critical patent/ES2231849T3/es
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3634—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing carbon, a carbide or oxycarbide
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3639—Multilayers containing at least two functional metal layers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366—Low-emissivity or solar control coatings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y10T428/24975—No layer or component greater than 5 mils thick
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
    • Y10T428/31601—Quartz or glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Surface Treatment Of Glass (AREA)
  • Optical Filters (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Photovoltaic Devices (AREA)

Description

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E97403006
28-07-2014
El acristalamiento según la invención comprende al menos el sustrato portador del apilamiento, eventualmente asociado a al menos otro sustrato. Pueden ser todos claros, o coloreados, principalmente al menos uno de los sustratos puede ser en vidrio coloreado en masa. La elección del tipo de coloración va a depender del nivel de transmisión luminosa y/o del aspecto colorimétrico buscados por el acristalamiento una vez terminada su fabricación. 5 Así para acristalamientos destinados a equipar vehículos, las normas imponen que el parabrisa tenga una transmisión luminosa TL de aproximadamente 75%, no exigiéndose un nivel tal de transmisión para los acristalamientos laterales o el techo del auto, por ejemplo. Los cristales tintados que se pueden retener son por ejemplo los que, para un espesor de 4 nm, presentan una TL de 65% a 95%, una transmisión energética TE de 40% a 80%, una longitud de onda dominante de 470 nm a 525 nm asociada a una pureza de transmisión de 0,4% a 6%
10 según el Iluminante D65, lo que se puede “traducir” en el sistema colorimétrico (L, a*, b*) por valores de a* y b* de transmisión comprendidos respectivamente entre -9 y 0 y entre -8 y +2.
Se puede tratar de vidrios comercializados bajo el nombre de PARSOL por SAINT-GOBAIN VITRAGE, principalmente aquellos de tinte verde de gris. Se puede tratar de vidrios de la gama dicha “TSA” igualmente comercializados por SAINT-GOBAIN VITRAGE, y de vidrios cuya composición y propiedades están descritas
15 principalmente en las patentes EP-0 616 883, EP-0 644 164, EP-0 722 427 y WO-96/00394.
El acristalamiento según la invención puede presentar una estructura laminar, asociando principalmente al menos dos sustancias rígidas del tipo vidrio por al menos una hoja de polímero termoplástico, con el fin de presentar una estructura de tipo vidrio/apilamiento de capas delgadas/hoja(s)/vidrio. El polímero puede ser principalmente a base de poli(butiral de vinilo) PVB, etileno-acetato vinílico EVA, poli(tereftalato de etileno) PET, poli(cloruro de vinilo) PVC.
20 El acristalamiento puede presentar también una estructura de acristalamiento laminar dicha asimétrica, al asociar a un sustrato rígido de tipo vidrio al menos una hoja de polímero de tipo poliuretano con propiedades de absorbente de energía, eventualmente asociada a otra capa de polímeros con propiedades “auto-cicatrizantes”. Para más detalles sobre este tipo de acristalamiento, puede referirse principalmente a las patentes EP-0 132 198, EP-0 131 523, EP-0 389 354. El acristalamiento puede presentar entonces una estructura de tipo vidrio/apilamiento de capas
25 delgadas/hoja(s) de polímero.
Los acristalamientos según la invención son aptos para sufrir un tratamiento térmico sin daño para el apilamiento de capas delgadas. Se curvan por lo tanto eventualmente y/o se templan. En el caso en el que se curven, principalmente con vistas a constituir acristalamientos para vehículos, el apilamiento de capas delgadas se encuentra preferentemente sobre una cara al menos parcialmente no plana. En una estructura laminar, está
30 preferentemente en contacto con la hoja de polímero.
El acristalamiento puede curvarse y/o templarse también al estar constituido por un solo sustrato, aquel dotado del apilamiento. Se habla entonces de acristalamiento “monolítico”. El acristalamiento puede ser también un acristalamiento múltiple, principalmente un doble-acristalamiento, estando curvado y/o templado al menos el sustrato portador del apilamiento. Es preferible en una configuración de acristalamiento múltiple que el apilamiento esté
35 dispuesto de manera a estar vuelto del lado de la lámina de gas intercalar.
Cuando el acristalamiento es monolítico o en acristalamiento múltiple del tipo doble-acristalamiento, al menos el sustrato portador del apilamiento puede ser de vidrio templado.
Los acristalamientos de la invención, de manera general, se conciben preferiblemente de manera a presentar un valor de transmisión luminosa de 50 a 85%, principalmente de 60 a 80%, con valores de reflexión RL inferiores a
40 20%, principalmente inferiores a 13% y valores de a* y b* negativos de reflexión exterior: se puede así “barrer” principalmente toda la gama de TL encontrada en los acristalamientos para vehículos, con coloración exterior un tinte más bien hacia los azules-verdes que se considera bastante estética actualmente.
La invención se refiere igualmente al procedimiento de fabricación de los acristalamientos, que consiste en depositar el apilamiento de capas delgadas sobre un sustrato de vidrio por una técnica a vacío del tipo pulverización catódica
45 eventualmente asistida por campo magnético, luego a efectuar sobre el sustrato revestido un tratamiento térmico de curvado/templado o recocido sin degradación de su calidad óptica.
No se excluye sin embargo que la primera o las primeras capas puedan depositarse por otra técnica de descomposición térmica de tipo pirólisis.
Los detalles y características ventajosas de la invención salen de los ejemplos no limitativos siguientes, ilustrados 50 con ayuda de la figura 1 para los ejemplos 1 a 3.
La figura 1 representa un apilamiento según la invención, y no respeta las proporciones entre los espesores de diferentes materiales con el fin de que se facilite su lectura.
En los ejemplos 1 a 3 que siguen, el apilamiento se deposita sobre el sustrato 1, que es un sustrato de vidrio silicosódico-cálcico claro de 2 nm de espesor. El apilamiento se descompone en dos capas funcionales de plata 3, 6 de 55 espesores idénticos, o diferentes con la primera capa 3 de espesor inferior a la de la segunda capa 6
6
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Claims (1)

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ES97403006.6T 1996-12-12 1997-12-11 Acristalamiento que comprende un sustrato provisto de un apilamiento de capas delgadas para la protección solar y/o el aislamiento térmico Expired - Lifetime ES2231849T5 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9615265 1996-12-12
FR9615265A FR2757151B1 (fr) 1996-12-12 1996-12-12 Vitrage comprenant un substrat muni d'un empilement de couches minces pour la protection solaire et/ou l'isolation thermique

Publications (2)

Publication Number Publication Date
ES2231849T3 ES2231849T3 (es) 2005-05-16
ES2231849T5 true ES2231849T5 (es) 2014-08-18

Family

ID=9498588

Family Applications (1)

Application Number Title Priority Date Filing Date
ES97403006.6T Expired - Lifetime ES2231849T5 (es) 1996-12-12 1997-12-11 Acristalamiento que comprende un sustrato provisto de un apilamiento de capas delgadas para la protección solar y/o el aislamiento térmico

Country Status (8)

Country Link
US (3) US6045896A (es)
EP (1) EP0847965B2 (es)
JP (1) JP4633872B2 (es)
AT (1) ATE280140T1 (es)
DE (1) DE69731268T3 (es)
ES (1) ES2231849T5 (es)
FR (1) FR2757151B1 (es)
PT (1) PT847965E (es)

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FR2757151B1 (fr) 1996-12-12 1999-01-08 Saint Gobain Vitrage Vitrage comprenant un substrat muni d'un empilement de couches minces pour la protection solaire et/ou l'isolation thermique
US7096692B2 (en) * 1997-03-14 2006-08-29 Ppg Industries Ohio, Inc. Visible-light-responsive photoactive coating, coated article, and method of making same
US6027766A (en) * 1997-03-14 2000-02-22 Ppg Industries Ohio, Inc. Photocatalytically-activated self-cleaning article and method of making same
US20050096288A1 (en) * 1997-06-13 2005-05-05 Aragene, Inc. Lipoproteins as nucleic acid vectors
FR2766174B1 (fr) * 1997-07-21 1999-08-20 Saint Gobain Vitrage Substrat transparent revetu d'au moins une couche mince
EP0918044A1 (en) 1997-11-19 1999-05-26 Glaverbel Solar control glazing
US6592996B1 (en) 1998-02-06 2003-07-15 Nippon Sheet Glass Co., Ltd. Solar-shading light-transmissive panel and solar-shading multi-layer light-transmissive panel using same
JP2000302486A (ja) * 1999-04-15 2000-10-31 Nippon Sheet Glass Co Ltd 日射遮蔽性透光板およびこれを用いた日射遮蔽性複層透光板
DE19808795C2 (de) * 1998-03-03 2001-02-22 Sekurit Saint Gobain Deutsch Wärmestrahlen reflektierendes Schichtsystem für transparente Substrate
FR2784984B1 (fr) * 1998-10-22 2001-10-26 Saint Gobain Vitrage Substrat transparent muni d'un empilement de couches minces
FR2784985B1 (fr) * 1998-10-22 2001-09-21 Saint Gobain Vitrage Substrat transparent muni d'un empilement de couches minces
DE19850023A1 (de) * 1998-10-30 2000-05-04 Leybold Systems Gmbh Wärmedämmendes Schichtsystem
EP1010677A1 (fr) * 1998-12-17 2000-06-21 Saint-Gobain Vitrage Systeme de couches reflechissant la chaleur pour substrats transparents
US6610410B2 (en) * 1998-12-18 2003-08-26 Asahi Glass Company, Limited Glazing panel
EP1155816B1 (en) * 1998-12-28 2007-02-14 Asahi Glass Company Ltd. Layered product
DE19927683C1 (de) * 1999-06-17 2001-01-25 Sekurit Saint Gobain Deutsch Sonnen- und Wärmestrahlen reflektierende Verbundglasscheibe
US6838181B1 (en) * 1999-08-26 2005-01-04 Glaverbel Glazing
MXPA02004955A (es) * 1999-11-24 2002-09-18 Ppg Ind Ohio Inc Revestimientos de coeficiente de oscurecimiento bajo y de baja enmisividad y articulos revestidos.
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JP3477148B2 (ja) * 1999-12-02 2003-12-10 カーディナル・シージー・カンパニー 耐曇り性透明フィルム積層体
EP1754691B1 (en) * 1999-12-02 2009-02-11 Cardinal CG Company Haze-resistant transparent film stacks
US6495263B2 (en) 1999-12-06 2002-12-17 Guardian Industries Corp. Low-E matchable coated articles and methods of making same
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FR2809388B1 (fr) * 2000-05-23 2002-12-20 Saint Gobain Vitrage Vitrage comprenant au moins une couche a proprietes thermochromes
FR2810118B1 (fr) * 2000-06-07 2005-01-21 Saint Gobain Vitrage Substrat transparent comportant un revetement antireflet
US6576349B2 (en) 2000-07-10 2003-06-10 Guardian Industries Corp. Heat treatable low-E coated articles and methods of making same
US7879448B2 (en) 2000-07-11 2011-02-01 Guardian Industires Corp. Coated article with low-E coating including IR reflecting layer(s) and corresponding method
US6445503B1 (en) 2000-07-10 2002-09-03 Guardian Industries Corp. High durable, low-E, heat treatable layer coating system
US7267879B2 (en) * 2001-02-28 2007-09-11 Guardian Industries Corp. Coated article with silicon oxynitride adjacent glass
US6887575B2 (en) * 2001-10-17 2005-05-03 Guardian Industries Corp. Heat treatable coated article with zinc oxide inclusive contact layer(s)
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US7462397B2 (en) * 2000-07-10 2008-12-09 Guardian Industries Corp. Coated article with silicon nitride inclusive layer adjacent glass
US20030186064A1 (en) * 2000-09-29 2003-10-02 Kenji Murata Transparent laminate having low emissivity
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Publication number Publication date
FR2757151A1 (fr) 1998-06-19
ES2231849T3 (es) 2005-05-16
DE69731268T3 (de) 2014-09-25
DE69731268T2 (de) 2006-09-28
US6322881B1 (en) 2001-11-27
FR2757151B1 (fr) 1999-01-08
ATE280140T1 (de) 2004-11-15
JPH10217378A (ja) 1998-08-18
PT847965E (pt) 2005-03-31
DE69731268D1 (de) 2004-11-25
EP0847965B2 (fr) 2014-05-14
EP0847965B1 (fr) 2004-10-20
JP4633872B2 (ja) 2011-02-16
US6045896A (en) 2000-04-04
US20020045037A1 (en) 2002-04-18
EP0847965A1 (fr) 1998-06-17
US6582809B2 (en) 2003-06-24

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