ES2254973T3 - Procedimiento de preparacion de una cera microcristalina y de un combustible de destilado medio. - Google Patents
Procedimiento de preparacion de una cera microcristalina y de un combustible de destilado medio.Info
- Publication number
- ES2254973T3 ES2254973T3 ES03765027T ES03765027T ES2254973T3 ES 2254973 T3 ES2254973 T3 ES 2254973T3 ES 03765027 T ES03765027 T ES 03765027T ES 03765027 T ES03765027 T ES 03765027T ES 2254973 T3 ES2254973 T3 ES 2254973T3
- Authority
- ES
- Spain
- Prior art keywords
- weight
- fischer
- product
- tropsch
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 44
- 239000000446 fuel Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title description 5
- 239000013081 microcrystal Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 15
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 15
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 12
- 238000009835 boiling Methods 0.000 claims abstract description 10
- 238000000926 separation method Methods 0.000 claims abstract description 5
- 239000001993 wax Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000005345 coagulation Methods 0.000 claims description 6
- 230000015271 coagulation Effects 0.000 claims description 6
- 238000005238 degreasing Methods 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000047 product Substances 0.000 description 44
- 239000003054 catalyst Substances 0.000 description 14
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 239000002199 base oil Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 238000005292 vacuum distillation Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- DTBDAFLSBDGPEA-UHFFFAOYSA-N 3-Methylquinoline Natural products C1=CC=CC2=CC(C)=CN=C21 DTBDAFLSBDGPEA-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010053567 Coagulopathies Diseases 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000035602 clotting Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 210000000540 fraction c Anatomy 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/42—Refining of petroleum waxes
- C10G73/44—Refining of petroleum waxes in the presence of hydrogen or hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1022—Fischer-Tropsch products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/30—Physical properties of feedstocks or products
- C10G2300/301—Boiling range
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S208/00—Mineral oils: processes and products
- Y10S208/95—Processing of "fischer-tropsch" crude
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Steroid Compounds (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02077921 | 2002-07-18 | ||
| EP02077921 | 2002-07-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2254973T3 true ES2254973T3 (es) | 2006-06-16 |
Family
ID=30470285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES03765027T Expired - Lifetime ES2254973T3 (es) | 2002-07-18 | 2003-07-17 | Procedimiento de preparacion de una cera microcristalina y de un combustible de destilado medio. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7300565B2 (de) |
| EP (1) | EP1534802B1 (de) |
| JP (1) | JP4629435B2 (de) |
| AT (1) | ATE310066T1 (de) |
| AU (1) | AU2003255058A1 (de) |
| BR (1) | BR0312667B1 (de) |
| DE (1) | DE60302366T2 (de) |
| ES (1) | ES2254973T3 (de) |
| WO (1) | WO2004009739A2 (de) |
| ZA (1) | ZA200500155B (de) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20031361A1 (it) * | 2003-07-03 | 2005-01-04 | Enitecnologie Spa | Processo per la preparazione di distillati medi e basi lube a partire da cariche idrocarburiche sintetiche. |
| US7727378B2 (en) * | 2003-07-04 | 2010-06-01 | Shell Oil Company | Process to prepare a Fischer-Tropsch product |
| BRPI0618644A2 (pt) * | 2005-11-10 | 2016-11-22 | Shell Int Research | composição de betume, composição de asfalto, uso do asfalto, e, processo para abaixar o ponto de fraass de uma composição de betume |
| MY146631A (en) * | 2006-03-30 | 2012-09-14 | Nippon Oil Corp | Light oil composition |
| EP2087079A1 (de) * | 2006-11-10 | 2009-08-12 | Shell Internationale Research Maatschappij B.V. | Schwefelarme, sulfataschearme, phosphorarme und hochparaffinische schmiermittelzusammensetzung |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| CN101678925A (zh) | 2007-05-10 | 2010-03-24 | 国际壳牌研究有限公司 | 石蜡组合物 |
| CA2617614C (en) | 2007-08-10 | 2012-03-27 | Indian Oil Corporation Limited | Novel synthetic fuel and method of preparation thereof |
| BR112012010793B1 (pt) * | 2009-11-09 | 2021-07-27 | Jx Nippon Oil & Energy Corporation | Processo para produção de óleo hidrocarbonado |
| WO2013064539A1 (en) | 2011-11-01 | 2013-05-10 | Shell Internationale Research Maatschappij B.V. | Paraffin wax |
| EP3040402A1 (de) | 2014-12-31 | 2016-07-06 | Shell Internationale Research Maatschappij B.V. | Verfahren zur Herstellung eines Paraffinwachs |
| SG10201907001WA (en) | 2014-12-31 | 2019-09-27 | Shell Int Research | Process to prepare paraffin wax |
| EP3240874A1 (de) | 2014-12-31 | 2017-11-08 | Shell Internationale Research Maatschappij B.V. | Verfahren zur herstellung eines schweren paraffinwachses |
| EP3040403A1 (de) | 2014-12-31 | 2016-07-06 | Shell Internationale Research Maatschappij B.V. | Verfahren zur Herstellung eines Paraffinwachs |
| EP3344729B1 (de) * | 2015-09-04 | 2019-12-11 | Shell International Research Maatschappij B.V. | Verfahren zur herstellung von paraffinen und wachsen |
| WO2018083140A1 (en) | 2016-11-07 | 2018-05-11 | Shell Internationale Research Maatschappij B.V. | Normal paraffin composition |
| EP3538610A1 (de) | 2016-11-11 | 2019-09-18 | Shell Internationale Research Maatschappij B.V. | Polyvinylchloridzusammensetzungen mit einem fischer-tropsch-wachs |
| AU2017358979A1 (en) | 2016-11-11 | 2019-05-02 | Shell Internationale Research Maatschappij B.V. | Process to prepare a solid cement composition |
| WO2019025358A1 (en) | 2017-08-01 | 2019-02-07 | Shell Internationale Research Maatschappij B.V. | DRILLING FLUID |
| EP4010451A1 (de) | 2019-08-08 | 2022-06-15 | Shell Internationale Research Maatschappij B.V. | Mikrokristallines wachs |
| CN115678602A (zh) * | 2022-11-15 | 2023-02-03 | 国家能源集团宁夏煤业有限责任公司 | 费托蜡的处理方法 |
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| JPS5624493A (en) | 1979-08-06 | 1981-03-09 | Nippon Oil Co Ltd | Central system fluid composition for automobile |
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| GB2133035A (en) | 1982-12-31 | 1984-07-18 | Exxon Research Engineering Co | An oil composition |
| JPS6044593A (ja) | 1983-08-23 | 1985-03-09 | Idemitsu Kosan Co Ltd | 汎用グリ−ス組成物 |
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| US6165949A (en) | 1998-09-04 | 2000-12-26 | Exxon Research And Engineering Company | Premium wear resistant lubricant |
| US6179994B1 (en) | 1998-09-04 | 2001-01-30 | Exxon Research And Engineering Company | Isoparaffinic base stocks by dewaxing fischer-tropsch wax hydroisomerate over Pt/H-mordenite |
| US6103099A (en) | 1998-09-04 | 2000-08-15 | Exxon Research And Engineering Company | Production of synthetic lubricant and lubricant base stock without dewaxing |
| US6332974B1 (en) | 1998-09-11 | 2001-12-25 | Exxon Research And Engineering Co. | Wide-cut synthetic isoparaffinic lubricating oils |
| ES2251249T3 (es) | 1998-11-16 | 2006-04-16 | Shell Internationale Research Maatschappij B.V. | Procedimiento de desparafinado catalitico. |
| US6485794B1 (en) | 1999-07-09 | 2002-11-26 | Ecolab Inc. | Beverage container and beverage conveyor lubricated with a coating that is thermally or radiation cured |
| ITFO990015A1 (it) | 1999-07-23 | 2001-01-23 | Verdini Antonio | "dendrimeri polipeptidici quali trasportatori unimolecolari di farmaci e sostanze biologicamente attive". |
| WO2001007538A1 (en) | 1999-07-26 | 2001-02-01 | Shell Internationale Research Maatschappij B.V. | Process for preparing a lubricating base oil |
| FR2798136B1 (fr) | 1999-09-08 | 2001-11-16 | Total Raffinage Distribution | Nouvelle huile de base hydrocarbonee pour lubrifiants a indice de viscosite tres eleve |
| US6642189B2 (en) | 1999-12-22 | 2003-11-04 | Nippon Mitsubishi Oil Corporation | Engine oil compositions |
| US7067049B1 (en) | 2000-02-04 | 2006-06-27 | Exxonmobil Oil Corporation | Formulated lubricant oils containing high-performance base oils derived from highly paraffinic hydrocarbons |
| US6776898B1 (en) * | 2000-04-04 | 2004-08-17 | Exxonmobil Research And Engineering Company | Process for softening fischer-tropsch wax with mild hydrotreating |
| AU2002249198B2 (en) | 2001-02-13 | 2006-10-12 | Shell Internationale Research Maatschappij B.V. | Lubricant composition |
| AR032932A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Procedimiento para preparar un aceite de base lubricante y un gas oil |
| AR032930A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Procedimiento para preparar un aceite de base lubricante y gas oil |
| DE10126516A1 (de) | 2001-05-30 | 2002-12-05 | Schuemann Sasol Gmbh | Verfahren zur Herstellung von mikrokristallinen Paraffinen |
| US6627779B2 (en) | 2001-10-19 | 2003-09-30 | Chevron U.S.A. Inc. | Lube base oils with improved yield |
-
2003
- 2003-07-17 AU AU2003255058A patent/AU2003255058A1/en not_active Abandoned
- 2003-07-17 ES ES03765027T patent/ES2254973T3/es not_active Expired - Lifetime
- 2003-07-17 DE DE60302366T patent/DE60302366T2/de not_active Expired - Lifetime
- 2003-07-17 US US10/521,668 patent/US7300565B2/en not_active Expired - Fee Related
- 2003-07-17 JP JP2004522491A patent/JP4629435B2/ja not_active Expired - Fee Related
- 2003-07-17 AT AT03765027T patent/ATE310066T1/de not_active IP Right Cessation
- 2003-07-17 EP EP03765027A patent/EP1534802B1/de not_active Expired - Lifetime
- 2003-07-17 WO PCT/EP2003/007785 patent/WO2004009739A2/de not_active Ceased
- 2003-07-17 BR BRPI0312667-6A patent/BR0312667B1/pt not_active IP Right Cessation
-
2005
- 2005-01-07 ZA ZA200500155A patent/ZA200500155B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2003255058A1 (en) | 2004-02-09 |
| US20050247601A1 (en) | 2005-11-10 |
| WO2004009739A3 (de) | 2004-03-25 |
| WO2004009739A2 (de) | 2004-01-29 |
| ZA200500155B (en) | 2006-07-26 |
| EP1534802A2 (de) | 2005-06-01 |
| BR0312667B1 (pt) | 2012-11-27 |
| DE60302366T2 (de) | 2006-08-03 |
| JP4629435B2 (ja) | 2011-02-09 |
| ATE310066T1 (de) | 2005-12-15 |
| EP1534802B1 (de) | 2005-11-16 |
| DE60302366D1 (de) | 2005-12-22 |
| BR0312667A (pt) | 2005-04-26 |
| JP2005537344A (ja) | 2005-12-08 |
| US7300565B2 (en) | 2007-11-27 |
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