ES2282278T3 - Recubrimiento anticorrosivo negro sobre una aleacion de zinc y procedimiento de preparacion del mismo. - Google Patents

Recubrimiento anticorrosivo negro sobre una aleacion de zinc y procedimiento de preparacion del mismo. Download PDF

Info

Publication number: ES2282278T3
Authority: ES; Spain
Prior art keywords: acid; solution; zinc alloy; stage; layer
Prior art date: 2000-07-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES01958148T

Other languages

English (en)

Spanish (es)

Inventor

Jean-Jacques Duprat

Lionel Thiery

Nicolas Pommier

Anne Charpentier

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Coventya SAS

Original Assignee

Coventya SAS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-07-25

Filing date

2001-07-20

Publication date

2007-10-16

2001-07-20 Application filed by Coventya SAS filed Critical Coventya SAS

2007-10-16 Application granted granted Critical

2007-10-16 Publication of ES2282278T3 publication Critical patent/ES2282278T3/es

2021-07-20 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 38
229910001297 Zn alloy Inorganic materials 0.000 title claims abstract description 33
239000011248 coating agent Substances 0.000 title claims abstract description 12
238000000576 coating method Methods 0.000 title claims abstract description 12
238000002360 preparation method Methods 0.000 title description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
239000007900 aqueous suspension Substances 0.000 claims abstract description 16
239000002253 acid Substances 0.000 claims abstract description 11
229920000620 organic polymer Polymers 0.000 claims abstract description 10
239000000049 pigment Substances 0.000 claims abstract description 10
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 9
150000004706 metal oxides Chemical class 0.000 claims abstract description 9
239000008139 complexing agent Substances 0.000 claims abstract description 7
239000000377 silicon dioxide Substances 0.000 claims abstract description 7
235000012239 silicon dioxide Nutrition 0.000 claims abstract description 7
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 6
239000007864 aqueous solution Substances 0.000 claims abstract description 5
229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 3
BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 3
239000004408 titanium dioxide Substances 0.000 claims abstract description 3
238000000151 deposition Methods 0.000 claims abstract 4
239000000243 solution Substances 0.000 claims description 62
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
-1 polyethylene Polymers 0.000 claims description 11
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
229910019142 PO4 Inorganic materials 0.000 claims description 9
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 8
239000000725 suspension Substances 0.000 claims description 8
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 4
239000004698 Polyethylene Substances 0.000 claims description 4
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
229920001577 copolymer Polymers 0.000 claims description 4
150000002500 ions Chemical class 0.000 claims description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 4
238000007654 immersion Methods 0.000 claims description 3
229910052742 iron Inorganic materials 0.000 claims description 3
235000006408 oxalic acid Nutrition 0.000 claims description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
229920000573 polyethylene Polymers 0.000 claims description 3
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
235000011054 acetic acid Nutrition 0.000 claims description 2
239000004202 carbamide Substances 0.000 claims description 2
235000015165 citric acid Nutrition 0.000 claims description 2
235000019253 formic acid Nutrition 0.000 claims description 2
229960002449 glycine Drugs 0.000 claims description 2
235000013905 glycine and its sodium salt Nutrition 0.000 claims description 2
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 claims description 2
239000004310 lactic acid Substances 0.000 claims description 2
235000014655 lactic acid Nutrition 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000002105 nanoparticle Substances 0.000 claims description 2
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
239000010452 phosphate Substances 0.000 claims description 2
229920005989 resin Polymers 0.000 claims description 2
239000011347 resin Substances 0.000 claims description 2
235000002906 tartaric acid Nutrition 0.000 claims description 2
239000011975 tartaric acid Substances 0.000 claims description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
229920002554 vinyl polymer Polymers 0.000 claims description 2
229910021193 La 2 O 3 Inorganic materials 0.000 claims 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
239000011976 maleic acid Substances 0.000 claims 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
239000003795 chemical substances by application Substances 0.000 abstract description 4
229910001404 rare earth metal oxide Inorganic materials 0.000 abstract description 2
229910002637 Pr6O11 Inorganic materials 0.000 abstract 1
YKHVDXDYDSMFJY-UHFFFAOYSA-N carbon dioxide zirconium Chemical compound [Zr].C(=O)=O YKHVDXDYDSMFJY-UHFFFAOYSA-N 0.000 abstract 1
MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 abstract 1
KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 abstract 1
RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 abstract 1
239000011651 chromium Substances 0.000 description 37
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 19
229910000831 Steel Inorganic materials 0.000 description 16
239000010959 steel Substances 0.000 description 16
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 13
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 12
238000005260 corrosion Methods 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
239000011701 zinc Substances 0.000 description 12
229910052804 chromium Inorganic materials 0.000 description 11
150000003839 salts Chemical class 0.000 description 10
230000007797 corrosion Effects 0.000 description 9
235000021317 phosphate Nutrition 0.000 description 8
229910000640 Fe alloy Inorganic materials 0.000 description 7
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
150000003013 phosphoric acid derivatives Chemical class 0.000 description 7
230000035939 shock Effects 0.000 description 7
239000007921 spray Substances 0.000 description 7
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 5
GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 5
229910017604 nitric acid Inorganic materials 0.000 description 5
238000002161 passivation Methods 0.000 description 5
239000001993 wax Substances 0.000 description 5
KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 4
229920006243 acrylic copolymer Polymers 0.000 description 4
239000006185 dispersion Substances 0.000 description 4
235000011007 phosphoric acid Nutrition 0.000 description 4
229910001379 sodium hypophosphite Inorganic materials 0.000 description 4
229910000990 Ni alloy Inorganic materials 0.000 description 3
229910000147 aluminium phosphate Inorganic materials 0.000 description 3
239000006229 carbon black Substances 0.000 description 3
VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
235000010755 mineral Nutrition 0.000 description 3
239000011707 mineral Substances 0.000 description 3
239000011734 sodium Substances 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 2
238000001246 colloidal dispersion Methods 0.000 description 2
238000001816 cooling Methods 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
229910052710 silicon Inorganic materials 0.000 description 2
239000010703 silicon Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
229910021205 NaH2PO2 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
229910007567 Zn-Ni Inorganic materials 0.000 description 1
229910007564 Zn—Co Inorganic materials 0.000 description 1
229910007614 Zn—Ni Inorganic materials 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000000654 additive Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
238000003556 assay Methods 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
150000001844 chromium Chemical class 0.000 description 1
BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 1
WYYQVWLEPYFFLP-UHFFFAOYSA-K chromium(3+);triacetate Chemical compound [Cr+3].CC([O-])=O.CC([O-])=O.CC([O-])=O WYYQVWLEPYFFLP-UHFFFAOYSA-K 0.000 description 1
229910000356 chromium(III) sulfate Inorganic materials 0.000 description 1
239000011696 chromium(III) sulphate Substances 0.000 description 1
235000015217 chromium(III) sulphate Nutrition 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
229940044175 cobalt sulfate Drugs 0.000 description 1
229910000361 cobalt sulfate Inorganic materials 0.000 description 1
230000002950 deficient Effects 0.000 description 1
230000001934 delay Effects 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
125000005397 methacrylic acid ester group Chemical group 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000003973 paint Substances 0.000 description 1
238000010422 painting Methods 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
239000011148 porous material Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/53—Treatment of zinc or alloys based thereon
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/51—One specific pretreatment, e.g. phosphatation, chromatation, in combination with one specific coating
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/08—Orthophosphates
- C23C22/10—Orthophosphates containing oxidants
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Metallurgy (AREA)
Chemical Kinetics & Catalysis (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Wood Science & Technology (AREA)
Chemical Treatment Of Metals (AREA)
Paints Or Removers (AREA)
Pigments, Carbon Blacks, Or Wood Stains (AREA)

ES01958148T 2000-07-25 2001-07-20 Recubrimiento anticorrosivo negro sobre una aleacion de zinc y procedimiento de preparacion del mismo. Expired - Lifetime ES2282278T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR0009716		2000-07-25
FR0009716A FR2812307B1 (fr)	2000-07-25	2000-07-25	Couche noire anticorrosive sur un alliage de zinc et son procede de preparation

Publications (1)

Publication Number	Publication Date
ES2282278T3 true ES2282278T3 (es)	2007-10-16

Family

ID=8852874

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES01958148T Expired - Lifetime ES2282278T3 (es)	2000-07-25	2001-07-20	Recubrimiento anticorrosivo negro sobre una aleacion de zinc y procedimiento de preparacion del mismo.

Country Status (5)

Country	Link
EP (1)	EP1409157B1 (fr)
DE (1)	DE60127870T2 (fr)
ES (1)	ES2282278T3 (fr)
FR (1)	FR2812307B1 (fr)
WO (1)	WO2002007902A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES2556680A1 (es) *	2014-07-18	2016-01-19	Moreda - Riviere Trefilerías, S.A.	Alambre recubierto, procedimiento de obtención del mismo y malla que lo comprende
ES2646237A1 (es) *	2017-09-28	2017-12-12	Avanzare Innovacion Tecnologica S.L.	Formulación para el mordentado de materiales poliméricos previo al recubrimiento de los mismos

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3774415B2 (ja) *	2002-03-14	2006-05-17	ディップソール株式会社	亜鉛及び亜鉛合金めっき上に黒色の六価クロムフリー化成皮膜を形成するための処理溶液及び亜鉛及び亜鉛合金めっき上に黒色の六価クロムフリー化成皮膜を形成する方法。
US20050109426A1 (en)	2002-03-14	2005-05-26	Dipsol Chemicals Co., Ltd.	Processing solution for forming hexavalent chromium free, black conversion film on zinc or zinc alloy plating layers, and method for forming hexavalent chromium free, black conversion film on zinc or zinc alloy plating layers
US20040156999A1 (en) *	2003-02-07	2004-08-12	Pavco, Inc.	Black trivalent chromium chromate conversion coating
WO2006014266A1 (fr) *	2004-07-02	2006-02-09	Henkel Kommanditgesellschaft Auf Aktien	Lubrifiant de film sec
US20070243397A1 (en) *	2006-04-17	2007-10-18	Ludwig Robert J	Chromium(VI)-free, aqueous acidic chromium(III) conversion solutions
EP2014793B1 (fr)	2007-06-14	2013-11-20	Atotech Deutschland GmbH	Traitement anti-corrosion pour couches de conversion
EP2281923A1 (fr)	2009-07-03	2011-02-09	ATOTECH Deutschland GmbH	Traitement de protection anticorrosion pour surfaces en zinc et alliages de zinc
DE102009045569A1 (de)	2009-10-12	2011-04-14	Dr.-Ing. Max Schlötter GmbH & Co KG	Schwarzpassivierung von Zink- und Zinkeisenschichten
JP2013249528A (ja) *	2012-06-04	2013-12-12	Dipsol Chemicals Co Ltd	アルミ変性コロイダルシリカを含有した３価クロム化成処理液
JP6283857B2 (ja) *	2013-08-28	2018-02-28	ディップソール株式会社	耐食性及び黒色外観に優れた車両用黒色締結部材
ES2747838T3 (es)	2014-04-16	2020-03-11	Doerken Ewald Ag	Procedimiento para producir un revestimiento protector contra la corrosión oscuro
EP3246429A1 (fr) *	2016-05-20	2017-11-22	ATOTECH Deutschland GmbH	Composition aqueuse pour la passivation de surfaces en zinc et procédé de passivation de surfaces en zinc
JP2017226925A (ja) *	2017-10-05	2017-12-28	ディップソール株式会社	アルミ変性コロイダルシリカを含有した３価クロム化成処理液
CA3131809A1 (fr)	2019-02-28	2020-09-03	Atotech Deutschland Gmbh	Composition aqueuse de post-traitement et procede de protection contre la corrosion
EP3771748A1 (fr) *	2019-07-30	2021-02-03	Dr.Ing. Max Schlötter GmbH & Co. KG	Passivation noire sans chrome (vi) et sans cobalt pour surfaces nickel-zinc

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3392008B2 (ja) *	1996-10-30	2003-03-31	日本表面化学株式会社	金属の保護皮膜形成処理剤と処理方法
US3900689A (en) *	1970-04-02	1975-08-19	Du Pont	Substrates treated with chromium(iii) complexes to increase the adhesion of organic polymers thereto
CA1228000A (fr) *	1981-04-16	1987-10-13	David E. Crotty	Solution et procede de passivation, donnant un aspect chrome
JP2844953B2 (ja) *	1991-03-29	1999-01-13	日本鋼管株式会社	溶接可能な着色鋼板
US5415702A (en) *	1993-09-02	1995-05-16	Mcgean-Rohco, Inc.	Black chromium-containing conversion coatings on zinc-nickel and zinc-iron alloys
EP0970757B1 (fr) *	1998-07-07	2002-10-30	Kabushiki Kaisha Nippankenkyusho	Revêtement protecteur contre la rouille et procédé pour sa fabrication
US6224657B1 (en) *	1998-10-13	2001-05-01	Sermatech International, Inc.	Hexavalent chromium-free phosphate-bonded coatings

2000
- 2000-07-25 FR FR0009716A patent/FR2812307B1/fr not_active Expired - Fee Related
2001
- 2001-07-20 ES ES01958148T patent/ES2282278T3/es not_active Expired - Lifetime
- 2001-07-20 WO PCT/FR2001/002376 patent/WO2002007902A2/fr not_active Ceased
- 2001-07-20 DE DE60127870T patent/DE60127870T2/de not_active Expired - Lifetime
- 2001-07-20 EP EP01958148A patent/EP1409157B1/fr not_active Expired - Lifetime

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ES2556680A1 (es) *	2014-07-18	2016-01-19	Moreda - Riviere Trefilerías, S.A.	Alambre recubierto, procedimiento de obtención del mismo y malla que lo comprende
ES2646237A1 (es) *	2017-09-28	2017-12-12	Avanzare Innovacion Tecnologica S.L.	Formulación para el mordentado de materiales poliméricos previo al recubrimiento de los mismos
WO2019063859A1 (fr) *	2017-09-28	2019-04-04	Avanzare Innovacion Tencologica S.L.	Formulation pour le mordançage de matériaux polymères avant le revêtement de ces derniers
US10501852B2 (en)	2017-09-28	2019-12-10	Avanzare Innovación Tecnológica, S,L.	Formulation for the etching of polymer materials prior to coating of the materials
CN111201091A (zh) *	2017-09-28	2020-05-26	阿万扎雷创新科技有限公司	用于在涂覆聚合物材料之前对其进行腐蚀的制剂
CN111201091B (zh) *	2017-09-28	2022-08-02	阿万扎雷创新科技有限公司	用于在涂覆聚合物材料之前对其进行腐蚀的制剂
US11761091B2 (en)	2017-09-28	2023-09-19	Srg Global Liria, S.L.	Surface activated polymers
US11898250B2 (en)	2017-09-28	2024-02-13	Avanzare Innovación Tecnológica, S.L.	Formulation for the etching of polymer materials prior to coating of the materials

Also Published As

Publication number	Publication date
EP1409157B1 (fr)	2007-04-11
DE60127870D1 (de)	2007-05-24
EP1409157A2 (fr)	2004-04-21
DE60127870T2 (de)	2008-01-17
FR2812307B1 (fr)	2003-02-14
WO2002007902A2 (fr)	2002-01-31
WO2002007902A3 (fr)	2002-06-20
FR2812307A1 (fr)	2002-02-01

Publication	Publication Date	Title
ES2282278T3 (es)	2007-10-16	Recubrimiento anticorrosivo negro sobre una aleacion de zinc y procedimiento de preparacion del mismo.
JP3774415B2 (ja)	2006-05-17	亜鉛及び亜鉛合金めっき上に黒色の六価クロムフリー化成皮膜を形成するための処理溶液及び亜鉛及び亜鉛合金めっき上に黒色の六価クロムフリー化成皮膜を形成する方法。
ES2205456T3 (es)	2004-05-01	Acondicionamiento de superficies metalicas antes del recubrimiento de conversion con fosfato.
JP2806531B2 (ja)	1998-09-30	鉄又は鉄合金材料の表面処理用リン酸亜鉛系水溶液及び処理方法
US4278477A (en)	1981-07-14	Metal treatment
US6090224A (en)	2000-07-18	Phosphating process with a copper-containing re-rinsing stage
JPH0953192A (ja)	1997-02-25	液体防錆皮膜組成物及び防錆皮膜形成方法
US9650521B1 (en)	2017-05-16	Friction modifier for top coating agent for trivalent chromium chemical conversion coating film or chromium-free chemical conversion coating film, and top coating agent including same
US6551417B1 (en)	2003-04-22	Tri-cation zinc phosphate conversion coating and process of making the same
JP2004346360A (ja)	2004-12-09	黒色化成皮膜形成用組成物
CN104334770A (zh)	2015-02-04	含有铝改性胶态氧化硅的3价铬转化处理液
CN108546941A (zh)	2018-09-18	一种环保型钛盐彩色钝化液
JPS61124582A (ja)	1986-06-12	活性化浴を使用する改良亜鉛リン酸処理法および活性化精製浴用の濃厚物
JP2007023353A (ja)	2007-02-01	亜鉛系めっき部材のノンクロム反応型化成処理
TW200406505A (en)	2004-05-01	Surface treatment composition, surface treatment liquid, surface treatment method and metallic article
JP5660751B2 (ja)	2015-01-28	亜鉛又は亜鉛合金めっき上にクロムフリー化成皮膜を形成するための化成処理水溶液及びそれより得られたクロムフリー化成皮膜
JP5593532B2 (ja)	2014-09-24	亜鉛又は亜鉛合金めっき上にクロムフリー化成皮膜を形成するための化成処理水溶液及びそれより得られたクロムフリー化成皮膜
CN107419256A (zh)	2017-12-01	一种钢瓶的陶化液及其钢瓶表面的陶化方法
ES2543789T5 (es)	2018-07-05	Proceso para la protección frente a la corrosión de materiales que contienen hierro
CN102575354A (zh)	2012-07-11	用于制备无铬和钴的黑色转化涂层的处理溶液
CN110144576A (zh)	2019-08-20	一种无铬镀锌金属表面处理剂
US4351675A (en)	1982-09-28	Conversion coatings for zinc and cadmium surfaces
CN103014690A (zh)	2013-04-03	一种提供镀锌表面使用的新型无污染黑色钝化液
JPS59501269A (ja)	1984-07-19	耐アルカリ性燐酸塩変換被覆と製造法
JP2004244647A (ja)	2004-09-02	耐食性亜鉛系めっき鋼板およびその製造方法