ES2287408T3 - Composiciones detergentes. - Google Patents

Composiciones detergentes. Download PDF

Info

Publication number: ES2287408T3
Authority: ES; Spain
Prior art keywords: weight; semi; solid; fluid; tablet
Prior art date: 2002-10-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES03077852T

Other languages

English (en)

Spanish (es)

Inventor

Felix Marco Van Der Kooij

Lammert Nauta

Johannes Cornelis Van De Pas

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever NV

Original Assignee

Unilever NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-10-01

Filing date

2003-09-11

Publication date

2007-12-16

2003-09-11 Application filed by Unilever NV filed Critical Unilever NV

2007-12-16 Application granted granted Critical

2007-12-16 Publication of ES2287408T3 publication Critical patent/ES2287408T3/es

2023-09-11 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title description 52
239000003599 detergent Substances 0.000 title description 21
239000004094 surface-active agent Substances 0.000 claims abstract description 36
239000000463 material Substances 0.000 claims abstract description 28
238000004140 cleaning Methods 0.000 claims abstract description 24
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
239000000344 soap Substances 0.000 claims abstract description 21
239000007790 solid phase Substances 0.000 claims abstract description 15
125000000217 alkyl group Chemical group 0.000 claims abstract description 10
230000000087 stabilizing effect Effects 0.000 claims abstract description 7
150000001720 carbohydrates Chemical class 0.000 claims abstract description 5
235000014633 carbohydrates Nutrition 0.000 claims abstract description 5
239000007787 solid Substances 0.000 claims description 72
239000012530 fluid Substances 0.000 claims description 63
-1 polyoxyethylene Polymers 0.000 claims description 57
239000012071 phase Substances 0.000 claims description 44
238000006073 displacement reaction Methods 0.000 claims description 17
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 14
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 13
229920001214 Polysorbate 60 Polymers 0.000 claims description 12
150000002194 fatty esters Chemical class 0.000 claims description 11
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 10
229910019142 PO4 Inorganic materials 0.000 claims description 10
235000021317 phosphate Nutrition 0.000 claims description 10
239000000600 sorbitol Substances 0.000 claims description 10
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 8
239000011780 sodium chloride Substances 0.000 claims description 8
150000002148 esters Chemical class 0.000 claims description 6
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 5
239000003085 diluting agent Substances 0.000 claims description 5
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 5
150000007942 carboxylates Chemical class 0.000 claims description 4
SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical group OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
VULQAGPYFSUFCA-UHFFFAOYSA-N 16-methylheptadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CC(C)CCCCCCCCCCCCCCC(O)=O VULQAGPYFSUFCA-UHFFFAOYSA-N 0.000 claims 1
JNYAEWCLZODPBN-UHFFFAOYSA-N 2-(1,2-dihydroxyethyl)oxolane-3,4-diol Polymers OCC(O)C1OCC(O)C1O JNYAEWCLZODPBN-UHFFFAOYSA-N 0.000 claims 1
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239000005017 polysaccharide Substances 0.000 claims 1
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
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HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
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150000003839 salts Chemical class 0.000 description 3
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235000012217 sodium aluminium silicate Nutrition 0.000 description 3
239000000243 solution Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000007916 tablet composition Substances 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
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KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
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FGUZFFWTBWJBIL-XWVZOOPGSA-N [(1r)-1-[(2s,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)O[C@H](CO)[C@H]1OC[C@H](O)[C@H]1O FGUZFFWTBWJBIL-XWVZOOPGSA-N 0.000 description 2
NWGKJDSIEKMTRX-BFWOXRRGSA-N [(2r)-2-[(3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)C1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-BFWOXRRGSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
125000005599 alkyl carboxylate group Chemical group 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
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150000004649 carbonic acid derivatives Chemical class 0.000 description 2
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PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 2
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239000001257 hydrogen Substances 0.000 description 2
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ASKIVFGGGGIGKH-UHFFFAOYSA-N isostearic acid monoglyceride Natural products CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
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BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
238000005057 refrigeration Methods 0.000 description 2
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NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
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CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
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ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
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239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical group O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
238000007873 sieving Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
239000000429 sodium aluminium silicate Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
NASFKTWZWDYFER-UHFFFAOYSA-N sodium;hydrate Chemical compound O.[Na] NASFKTWZWDYFER-UHFFFAOYSA-N 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
MOFJBYOBLBVDJZ-UHFFFAOYSA-N sodium;stilbene Chemical compound C=1C=CC=CC=1C([Na])C([Na])C1=CC=CC=C1 MOFJBYOBLBVDJZ-UHFFFAOYSA-N 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000002600 sunflower oil Substances 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
230000007704 transition Effects 0.000 description 1
SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
229940099259 vaseline Drugs 0.000 description 1
239000003981 vehicle Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0086—Laundry tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Molecular Biology (AREA)
Detergent Compositions (AREA)
Woven Fabrics (AREA)

ES03077852T 2002-10-01 2003-09-11 Composiciones detergentes. Expired - Lifetime ES2287408T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP02256832		2002-10-01
EP02256832		2002-10-01

Publications (1)

Publication Number	Publication Date
ES2287408T3 true ES2287408T3 (es)	2007-12-16

Family

ID=38220035

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES03077852T Expired - Lifetime ES2287408T3 (es)	2002-10-01	2003-09-11	Composiciones detergentes.

Country Status (4)

Country	Link
EP (1)	EP1405901B1 (de)
AT (1)	ATE364680T1 (de)
DE (1)	DE60314348T2 (de)
ES (1)	ES2287408T3 (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1669438B1 (de)	2004-12-08	2007-10-17	Unilever N.V.	Wasch- und Reinigungsmitteltablette
ATE430796T1 (de)	2005-01-04	2009-05-15	Unilever Nv	Wasch- und reinigungsmittelformkörper
EP1705240A1 (de)	2005-03-23	2006-09-27	Unilever N.V.	Wasch- oder Reinigungsmitteltabletten
ATE404660T1 (de)	2005-03-23	2008-08-15	Unilever Nv	Körperförmige wasch- oder reinigungsmittelzusammensetzungen
GB0506850D0 (en) *	2005-04-05	2005-05-11	Unilever Plc	Dispensing device
EP1746151A1 (de)	2005-07-20	2007-01-24	Unilever N.V.	Wasch- und Reinigungsmitteltabletten
EP1746152A1 (de)	2005-07-20	2007-01-24	Unilever N.V.	Wasch- oder Reinigungsmittel
DE602006007142D1 (de) *	2006-09-19	2009-07-16	Unilever Nv	Waschmitteltablette
DE102010051226A1 (de)	2010-11-12	2012-05-31	Dental Care Innovation Gmbh	Ausspültablete mit abrasiven Bestandteilen
CN119950331A (zh)	2017-02-02	2025-05-09	洁碧有限公司	用于牙齿清洁的包括研磨剂的片剂

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2147674C (en) *	1994-05-16	1999-03-30	David Robert Zint	Shaped semi-solid or solid dishwashing detergent
BR9812955A (pt) *	1997-10-22	2000-08-08	Unilever Nv	Tablete de detergente de composição particulada comprimida, e, processo para obtenção do mesmo
EP1043390A1 (de) *	1999-04-09	2000-10-11	The Procter & Gamble Company	Wasch- und Reinigungsmittel in Tablettenform

2003
- 2003-09-11 AT AT03077852T patent/ATE364680T1/de not_active IP Right Cessation
- 2003-09-11 DE DE60314348T patent/DE60314348T2/de not_active Expired - Lifetime
- 2003-09-11 ES ES03077852T patent/ES2287408T3/es not_active Expired - Lifetime
- 2003-09-11 EP EP03077852A patent/EP1405901B1/de not_active Expired - Lifetime

Also Published As

Publication number	Publication date
ATE364680T1 (de)	2007-07-15
DE60314348T2 (de)	2008-02-21
EP1405901A1 (de)	2004-04-07
EP1405901B1 (de)	2007-06-13
DE60314348D1 (de)	2007-07-26

Publication	Publication Date	Title
ES2331788T3 (es)	2010-01-15	Pastillas de detergente.
ES2210789T3 (es)	2004-07-01	Composiciones detergentes.
ES2210775T3 (es)	2004-07-01	Composiciones de limpieza.
EP1705241B1 (de)	2008-08-13	Körperförmige Wasch- oder Reinigungsmittelzusammensetzungen
ES2269597T5 (es)	2011-02-14	Composiciones detergentes en forma de pastilla.
ES2287408T3 (es)	2007-12-16	Composiciones detergentes.
ES2249731T3 (es)	2006-04-01	Pastillas detergentes.
ES2301755T3 (es)	2008-07-01	Pastillas detergentes.
ES2222583T3 (es)	2005-02-01	Composiciones detergentes.
ES2254602T3 (es)	2006-06-16	Procedimiento de produccion de una pastilla de limpieza.
EP1405902A1 (de)	2004-04-07	Wasch- und Reinigungsmittel
ES2257511T3 (es)	2006-08-01	Composiciones detergentes.
ES2304489T3 (es)	2008-10-16	Pastillas de detergente.
ES2255995T3 (es)	2006-07-16	Cuerpos moldeados de agentes de lavado y limpieza mono- o polifasicos con activadores de blanqueo especiales.
EP1119608B1 (de)	2002-11-27	Wasserenthärtungs- und waschmittelzusammensetzungen
ES2265338T3 (es)	2007-02-16	Cuerpos moldeados de agentes de lavado y de limpieza con activadores de blanqueo especiales.
ES2375369T3 (es)	2012-02-29	Pastillas multi-fases de tratamiento de lavandería.
ES2289424T3 (es)	2008-02-01	Metodo para la preparacion de comprimidos limpiadores multi-fase que comprenden una fase suave.
ES2310225T3 (es)	2009-01-01	Composiciones detergentes.
ES2326983T3 (es)	2009-10-22	Pastillas detergentes.
ES2292051T3 (es)	2008-03-01	Pastilla de detergente.
EP1522575B1 (de)	2006-06-07	Waschmittelzusammensetzungen
EP1710297A1 (de)	2006-10-11	Waschmittelzusammensetzungen in Tablettenform
EP1466964A1 (de)	2004-10-13	Renigungsmittel
EP1746152A1 (de)	2007-01-24	Wasch- oder Reinigungsmittel