ES2338519T1 - Espuma de aislamiento termico que comprende hfo-1233zd como agente de soplado. - Google Patents
Espuma de aislamiento termico que comprende hfo-1233zd como agente de soplado. Download PDFInfo
- Publication number
- ES2338519T1 ES2338519T1 ES09173778T ES09173778T ES2338519T1 ES 2338519 T1 ES2338519 T1 ES 2338519T1 ES 09173778 T ES09173778 T ES 09173778T ES 09173778 T ES09173778 T ES 09173778T ES 2338519 T1 ES2338519 T1 ES 2338519T1
- Authority
- ES
- Spain
- Prior art keywords
- foam
- hfco
- blowing agent
- thermal insulation
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004604 Blowing Agent Substances 0.000 title claims abstract 11
- 239000002937 thermal insulation foam Substances 0.000 title claims abstract 5
- 239000000203 mixture Substances 0.000 claims abstract 9
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 claims abstract 6
- 229920000642 polymer Polymers 0.000 claims abstract 2
- 239000006260 foam Substances 0.000 claims 23
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 238000009413 insulation Methods 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229920001187 thermosetting polymer Polymers 0.000 claims 2
- 229920005830 Polyurethane Foam Polymers 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 229920000582 polyisocyanurate Polymers 0.000 claims 1
- 239000011495 polyisocyanurate Substances 0.000 claims 1
- 239000011496 polyurethane foam Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/20—Ternary blends of expanding agents
- C08J2203/202—Ternary blends of expanding agents of physical blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Molding Of Porous Articles (AREA)
Abstract
Una espuma de aislamiento térmico que comprende una pluralidad de celdillas de polímero y una composición contenida en al menos una de dichas celdillas, comprendiendo dicha composición al menos un agente de soplado que comprende HFCO-1233zd (1-cloro-3,3,3-trifluoro-propeno).
Claims (14)
1. Una espuma de aislamiento térmico que
comprende una pluralidad de celdillas de polímero y una composición
contenida en al menos una de dichas celdillas, comprendiendo dicha
composición al menos un agente de soplado que comprende
HFCO-1233zd
(1-cloro-3,3,3-trifluoro-propeno).
2. La espuma de aislamiento térmico de acuerdo
con la reivindicación 1, en donde la espuma es una espuma de
celdillas cerradas.
3. La espuma de la reivindicación 1, que tiene
un factor k (BTU in/hr ft^{2}ºF) a 40ºF (4,4ºC) no mayor que
aproximadamente 0,14 (0,0202 W/m.K), preferiblemente no mayor que
0,135 (0,0194 W/m.K), preferiblemente no mayor que 0,13 (0,0187
W/m.K).
4. La espuma de la reivindicación 1, que tiene
un factor k (BTU in/hr ft^{2}ºF) a 75ºF (23,9ºC) no mayor que
aproximadamente 0,16 (0,0230 W/m.K), preferiblemente no mayor que
0,15 (0,0216 W/m.K), preferiblemente no mayor que 0,145 (0,0209
W/m.K).
5. La espuma de la reivindicación 1, en donde la
espuma es una espuma de poliuretano, una espuma de poliisocianurato
o una espuma fenólica.
6. La espuma de la reivindicación 1, en donde el
agente de soplado consiste en HFCO-1233zd.
7. La espuma de la reivindicación 1, en donde el
HFCO-1233zd está presente en el agente de soplado en
cantidades de aproximadamente 5% en peso a aproximadamente 95% en
peso del agente de soplado.
8. La espuma de la reivindicación 1, en donde el
HFCO-1233zd es
cis-HFCO-1233zd.
9. La espuma de la reivindicación 1, en donde el
HFCO-1233zd es
trans-HFCO-1233zd.
10. La espuma de la reivindicación 1, en donde
la composición comprende adicionalmente al menos un agente de
cosoplado.
11. La espuma de la reivindicación 1, en donde
el al menos un agente de cosoplado se selecciona del grupo
constituido por agua, CO_{2}, CFCs, HCCs, HCFCs, alcoholes
C1-C5, aldehídos C1-C4, cetonas
C1-C4, éteres C1-C4, y
combinaciones de dos o más de estos.
12. Una espuma de aislamiento térmico de acuerdo
con cualquiera de las reivindicaciones anteriores, en donde la
espuma es una espuma termoendurecible que exhibe conductividad
térmica mejorada con relación a las espumas fabricadas utilizando
el mismo agente de soplado en la misma cantidad pero sin
HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno).
13. Un método de proporcionar una espuma de
aislamiento térmico de acuerdo con cualquiera de las
reivindicaciones anteriores, comprendiendo dicho método (a)
proporcionar una composición de agente de soplado que comprende al
menos un agente de soplado que comprende HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno);
(b) añadir la composición de agente de soplado a una composición
susceptible de transformarse en espuma; (c) hacer reaccionar la
composición susceptible de transformarse en espuma para formar una
espuma o estructura alveolar.
14. Uso de HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno)
para mejorar la conductividad térmica de una espuma
termoendurecible de aislamiento térmico con relación a las espumas
fabricadas utilizando el mismo agente de soplado en la misma
cantidad pero sin HFCO-1233zd
(1-cloro-3,3,3-trifluoropropeno).
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69385305P | 2005-06-24 | 2005-06-24 | |
| US693853P | 2005-06-24 | ||
| US78473106P | 2006-03-21 | 2006-03-21 | |
| US784731P | 2006-03-21 |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| ES2338519T1 true ES2338519T1 (es) | 2010-05-10 |
| ES2338519T3 ES2338519T3 (es) | 2013-04-29 |
| ES2338519T5 ES2338519T5 (es) | 2018-03-28 |
| ES2338519T7 ES2338519T7 (es) | 2020-08-21 |
Family
ID=37595995
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13166417.9T Pending ES2464528T1 (es) | 2005-06-24 | 2006-06-26 | Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación |
| ES13166420.3T Expired - Lifetime ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
| ES09173778T Active ES2338519T7 (es) | 2005-06-24 | 2006-06-26 | Espuma de aislamiento térmico que comprende HFO-1233zd como agente de soplado |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13166417.9T Pending ES2464528T1 (es) | 2005-06-24 | 2006-06-26 | Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación |
| ES13166420.3T Expired - Lifetime ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
Country Status (15)
| Country | Link |
|---|---|
| EP (3) | EP2706087A3 (es) |
| JP (12) | JP2008546892A (es) |
| KR (9) | KR20140119717A (es) |
| CN (1) | CN103497351B (es) |
| CA (1) | CA2613090C (es) |
| DE (3) | DE09173778T1 (es) |
| DK (2) | DK2154223T6 (es) |
| ES (3) | ES2464528T1 (es) |
| HK (1) | HK1243109A1 (es) |
| MX (4) | MX359510B (es) |
| MY (3) | MY158385A (es) |
| PL (1) | PL2154223T6 (es) |
| PT (1) | PT2154223E (es) |
| TW (5) | TW201533108A (es) |
| WO (1) | WO2007002703A2 (es) |
Families Citing this family (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2779979B2 (ja) | 1990-10-05 | 1998-07-23 | 内山工業株式会社 | 密封シールの製造方法 |
| US20090253820A1 (en) * | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
| US20110037016A1 (en) * | 2003-10-27 | 2011-02-17 | Honeywell International Inc. | Fluoropropene compounds and compositions and methods using same |
| US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
| US8008244B2 (en) | 2004-04-29 | 2011-08-30 | Honeywell International Inc. | Compositions of tetrafluoropropene and hydrocarbons |
| TWI482748B (zh) * | 2005-06-24 | 2015-05-01 | Honeywell Int Inc | 含有經氟取代之烯烴之組合物 |
| CA2840435A1 (en) * | 2005-11-01 | 2007-05-10 | E.I. Du Pont De Nemours And Company | Methods for making foams using blowing agents comprising unsaturated fluorocarbons |
| US9695267B2 (en) * | 2009-08-11 | 2017-07-04 | Honeywell International Inc. | Foams and foamable compositions containing halogenated olefin blowing agents |
| US9000061B2 (en) | 2006-03-21 | 2015-04-07 | Honeywell International Inc. | Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) |
| GB2441006A (en) * | 2006-08-17 | 2008-02-20 | Ineos Fluor Holdings Ltd | Fluid Composition |
| JP5592249B2 (ja) * | 2007-03-27 | 2014-09-17 | ダウ グローバル テクノロジーズ エルエルシー | フッ素化アルケン発泡剤からの高品質ポリマー発泡体 |
| US9279039B2 (en) * | 2007-03-29 | 2016-03-08 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin |
| US9234070B2 (en) | 2007-03-29 | 2016-01-12 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
| WO2008121783A1 (en) * | 2007-03-29 | 2008-10-09 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
| JP5763338B2 (ja) * | 2007-03-29 | 2015-08-12 | アーケマ・インコーポレイテッド | ヒドロフルオロオレフィンとヒドロクロロフルオロオレフィンの発泡剤組成物 |
| US9206297B2 (en) | 2007-03-29 | 2015-12-08 | Arkema Inc. | Blowing agent compositions of hydrochlorofluoroolefins |
| US11208536B2 (en) | 2007-03-29 | 2021-12-28 | Arkema Inc. | Blowing agent compositions of hydrofluoroolefins and hydrochlorofluoroolefins |
| US11091602B2 (en) | 2007-03-29 | 2021-08-17 | Arkema Inc. | Blowing agent compositions of carbon dioxide and hydrochlorofluoroolefins |
| US8895635B2 (en) | 2007-03-29 | 2014-11-25 | Arkema Inc. | Blowing agent compositions of hydrochlorofluoroolefins |
| US9738768B2 (en) | 2007-03-29 | 2017-08-22 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
| US8114828B2 (en) * | 2007-04-16 | 2012-02-14 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and alcohols |
| KR20110133616A (ko) | 2007-09-13 | 2011-12-13 | 알케마 인코포레이티드 | 하이드로플루오로올레핀의 ｚ 및 ｅ 입체이성체의 조합물의 제조방법 |
| US20090099273A1 (en) * | 2007-10-12 | 2009-04-16 | Williams David J | Non-silicone surfactants for polyurethane or polyisocyanurate foam containing halogenated olefins as blowing agents |
| US9453115B2 (en) * | 2007-10-12 | 2016-09-27 | Honeywell International Inc. | Stabilization of polyurethane foam polyol premixes containing halogenated olefin blowing agents |
| US7479238B1 (en) | 2007-11-06 | 2009-01-20 | Arkema Inc. | Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and methyl formate |
| US20110001080A1 (en) | 2008-03-07 | 2011-01-06 | Arkema Inc. | Stable formulated systems with chloro-3,3,3-trifluoropropene |
| ES2727525T3 (es) * | 2008-03-07 | 2019-10-16 | Arkema Inc | Composiciones de transferencia térmica de alqueno halogenado con retorno de aceite mejorado |
| US7438826B1 (en) | 2008-03-07 | 2008-10-21 | Arkema Inc. | Azeotrope-like composition of 1,1,1-trifluoro-3-chloropropene and methyl acetate |
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| KR102010208B1 (ko) | 2008-05-07 | 2019-08-12 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | 2,3-다이클로로-1,1,1-트라이플루오로프로판, 2-클로로-1,1,1-트라이플루오로프로펜, 2-클로로-1,1,1,2-테트라플루오로프로판 또는 2,3,3,3-테트라플루오로프로펜을 포함하는 조성물 |
| KR20160040314A (ko) | 2008-06-20 | 2016-04-12 | 이 아이 듀폰 디 네모아 앤드 캄파니 | Ｚ-1,1,1,4,4,4-헥사플루오로-2-부텐의 공비 및 공비-유사 조성물 |
| CA2730917A1 (en) * | 2008-07-16 | 2010-01-21 | Honeywell International Inc. | Hfo-1234ze mixed isomers with hfc-245fa as a blowing agent, aerosol, and solvent |
| US8163196B2 (en) * | 2008-10-28 | 2012-04-24 | Honeywell International Inc. | Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene |
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| GB201002616D0 (en) * | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
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| FR2968009B1 (fr) | 2010-11-25 | 2012-11-16 | Arkema France | Fluides frigorigenes contenant du (e)-1,1,1,4,4,4-hexafluorobut-2-ene |
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