ES2404895T3 - Procedimiento para la descontaminación de superficies - Google Patents

Procedimiento para la descontaminación de superficies Download PDF

Info

Publication number: ES2404895T3
Authority: ES; Spain
Prior art keywords: stage; decontamination; acid; component; treated
Prior art date: 2009-12-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES10795259T

Other languages

English (en)

Spanish (es)

Inventor

Rainer Gassen

Bertram Zeiler

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Areva GmbH

Original Assignee

Areva NP GmbH

Areva GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2009-12-04

Filing date

2010-12-01

Publication date

2013-05-29

2010-12-01 Application filed by Areva NP GmbH, Areva GmbH filed Critical Areva NP GmbH

2013-05-29 Application granted granted Critical

2013-05-29 Publication of ES2404895T3 publication Critical patent/ES2404895T3/es

Status Active legal-status Critical Current

2030-12-01 Anticipated expiration legal-status Critical

Links

238000005202 decontamination Methods 0.000 title claims abstract description 76
238000000034 method Methods 0.000 title claims abstract description 64
230000003588 decontaminative effect Effects 0.000 title claims abstract description 40
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 60
239000000243 solution Substances 0.000 claims abstract description 42
239000002253 acid Substances 0.000 claims abstract description 40
230000003647 oxidation Effects 0.000 claims abstract description 28
238000007254 oxidation reaction Methods 0.000 claims abstract description 28
239000007800 oxidant agent Substances 0.000 claims abstract description 21
229910021645 metal ion Inorganic materials 0.000 claims abstract description 20
150000002500 ions Chemical class 0.000 claims abstract description 17
235000006408 oxalic acid Nutrition 0.000 claims abstract description 17
238000001556 precipitation Methods 0.000 claims abstract description 16
230000001590 oxidative effect Effects 0.000 claims abstract description 14
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
239000003638 chemical reducing agent Substances 0.000 claims abstract description 10
239000007864 aqueous solution Substances 0.000 claims abstract description 9
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 7
229910052804 chromium Inorganic materials 0.000 claims abstract description 7
239000011651 chromium Substances 0.000 claims abstract description 7
239000010953 base metal Substances 0.000 claims abstract description 3
JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims abstract description 3
238000009390 chemical decontamination Methods 0.000 claims abstract 2
HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 claims description 20
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 20
238000004140 cleaning Methods 0.000 claims description 17
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 10
235000019253 formic acid Nutrition 0.000 claims description 10
150000007524 organic acids Chemical class 0.000 claims description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
239000001301 oxygen Substances 0.000 claims description 3
229910052760 oxygen Inorganic materials 0.000 claims description 3
229910052751 metal Inorganic materials 0.000 abstract description 2
239000002184 metal Substances 0.000 abstract description 2
238000004090 dissolution Methods 0.000 description 18
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
150000007513 acids Chemical class 0.000 description 13
238000001816 cooling Methods 0.000 description 10
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
229910002092 carbon dioxide Inorganic materials 0.000 description 7
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
239000001569 carbon dioxide Substances 0.000 description 6
238000011946 reduction process Methods 0.000 description 6
238000012360 testing method Methods 0.000 description 6
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 5
VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 5
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000000203 mixture Substances 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
229910017604 nitric acid Inorganic materials 0.000 description 4
230000005855 radiation Effects 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
229910045601 alloy Inorganic materials 0.000 description 3
239000000956 alloy Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
150000007522 mineralic acids Chemical class 0.000 description 3
230000002285 radioactive effect Effects 0.000 description 3
239000003507 refrigerant Substances 0.000 description 3
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
229910000831 Steel Inorganic materials 0.000 description 2
ROBFUDYVXSDBQM-UHFFFAOYSA-N hydroxymalonic acid Chemical compound OC(=O)C(O)C(O)=O ROBFUDYVXSDBQM-UHFFFAOYSA-N 0.000 description 2
230000000977 initiatory effect Effects 0.000 description 2
235000013980 iron oxide Nutrition 0.000 description 2
DOLZKNFSRCEOFV-UHFFFAOYSA-L nickel(2+);oxalate Chemical compound [Ni+2].[O-]C(=O)C([O-])=O DOLZKNFSRCEOFV-UHFFFAOYSA-L 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000012286 potassium permanganate Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000010959 steel Substances 0.000 description 2
GOCCREQJUBABAL-UHFFFAOYSA-N 2,2-dihydroxyacetic acid Chemical compound OC(O)C(O)=O GOCCREQJUBABAL-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
239000004471 Glycine Substances 0.000 description 1
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
229910004039 HBF4 Inorganic materials 0.000 description 1
-1 HNO3 Chemical class 0.000 description 1
229910000990 Ni alloy Inorganic materials 0.000 description 1
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
229960005070 ascorbic acid Drugs 0.000 description 1
235000010323 ascorbic acid Nutrition 0.000 description 1
239000011668 ascorbic acid Substances 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
238000000975 co-precipitation Methods 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000011161 development Methods 0.000 description 1
239000002552 dosage form Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
229940093915 gynecological organic acid Drugs 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
239000000463 material Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
239000003758 nuclear fuel Substances 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
230000033116 oxidation-reduction process Effects 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-N peroxydisulfuric acid Chemical compound OS(=O)(=O)OOS(O)(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-N 0.000 description 1
238000005375 photometry Methods 0.000 description 1
230000002265 prevention Effects 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
238000005057 refrigeration Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
235000011149 sulphuric acid Nutrition 0.000 description 1
239000002699 waste material Substances 0.000 description 1

Classifications

- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/001—Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof
- G21F9/002—Decontamination of the surface of objects with chemical or electrochemical processes
- G21F9/004—Decontamination of the surface of objects with chemical or electrochemical processes of metallic surfaces
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/12—Processing by absorption; by adsorption; by ion-exchange
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/28—Treating solids
- G21F9/30—Processing

Landscapes

Engineering & Computer Science (AREA)
Physics & Mathematics (AREA)
General Engineering & Computer Science (AREA)
High Energy & Nuclear Physics (AREA)
Electrochemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Food Science & Technology (AREA)
Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Cleaning By Liquid Or Steam (AREA)
Treatment Of Water By Oxidation Or Reduction (AREA)
Apparatus For Disinfection Or Sterilisation (AREA)

ES10795259T 2009-12-04 2010-12-01 Procedimiento para la descontaminación de superficies Active ES2404895T3 (es)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE102009047524A DE102009047524A1 (de)	2009-12-04	2009-12-04	Verfahren zur Oberflächen-Dekontamination
DE102009047524		2009-12-04
PCT/EP2010/068602 WO2011067271A1 (de)	2009-12-04	2010-12-01	Verfahren zur oberflächen-dekontamination

Publications (1)

Publication Number	Publication Date
ES2404895T3 true ES2404895T3 (es)	2013-05-29

Family

ID=43867196

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES10795259T Active ES2404895T3 (es)	2009-12-04	2010-12-01	Procedimiento para la descontaminación de superficies

Country Status (11)

Country	Link
US (1)	US20120138086A1 (de)
EP (1)	EP2417606B1 (de)
JP (1)	JP5602241B2 (de)
KR (1)	KR101309609B1 (de)
CN (1)	CN102405500A (de)
CA (1)	CA2755288A1 (de)
DE (1)	DE102009047524A1 (de)
ES (1)	ES2404895T3 (de)
TW (1)	TW201131581A (de)
WO (1)	WO2011067271A1 (de)
ZA (1)	ZA201106436B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9498802B2 (en) *	2012-07-26	2016-11-22	Dominion Engineering, Inc.	Methods of reusing a cleaning solution
JP2014041100A (ja) *	2012-08-23	2014-03-06	Shimizu Corp	コンクリート構造体の表層除染方法
DE102013100933B3 (de) *	2013-01-30	2014-03-27	Areva Gmbh	Verfahren zur Oberflächen-Dekontamination von Bauteilen des Kühlmittelkreislaufs eines Kernreaktors
TWI489489B (zh) *	2013-04-08	2015-06-21	Yi Hsing Huang	放射性廢料除污劑及其製造處理方法
KR101523763B1 (ko) *	2013-06-19	2015-06-01	한국원자력연구원	금속 표면 고착성 방사능 오염 산화막 제거를 위한 산화 제염제 및 이를 이용한 산화 제염방법
DE102015120722B4 (de) *	2015-11-30	2017-07-27	Areva Gmbh	Kernkraftwerk und Verfahren zum Betreiben eines Kernkraftwerks
DE102016104846B3 (de) *	2016-03-16	2017-08-24	Areva Gmbh	Verfahren zur Behandlung von Abwasser aus der Dekontamination einer Metalloberfläche, Abwasserbehandlungsvorrichtung und Verwendung der Abwasserbehandlungsvorrichtung
DE102017107584A1 (de) *	2017-04-07	2018-10-11	Rwe Power Aktiengesellschaft	Zinkdosierung zur Dekontamination von Leichtwasserreaktoren
CN107170503B (zh) *	2017-06-02	2019-04-02	苏州热工研究院有限公司	一种降低在役压水堆核电厂集体剂量的化学清洗方法
CN107240429B (zh) *	2017-06-28	2019-09-06	洛阳市琦安科技有限公司	一种放射性核污染物扩散迁移的压制材料及压制方法
DE102017115122B4 (de) *	2017-07-06	2019-03-07	Framatome Gmbh	Verfahren zum Dekontaminieren einer Metalloberfläche in einem Kernkraftwerk
CN108242273A (zh) *	2017-12-28	2018-07-03	中核四0四有限公司	一种用于放射性混凝土构筑物浅层剥离的装置
JP7475171B2 (ja) *	2020-03-17	2024-04-26	日立Ｇｅニュークリア・エナジー株式会社	化学除染方法および化学除染装置
CN112700900A (zh) *	2020-12-10	2021-04-23	中国辐射防护研究院	一种注锌反应堆部件放射性沉积氧化物的清洗方法
CN113105955A (zh) *	2021-03-31	2021-07-13	山东核电有限公司	一种用于ap1000反应堆一回路部件放射性污染沉积氧化物的去污配方和去污方法

Family Cites Families (15)

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Publication number	Priority date	Publication date	Assignee	Title
DD118956A1 (de) *	1975-03-11	1976-03-20
DE2847780C2 (de) *	1978-11-03	1984-08-30	Kraftwerk Union AG, 4330 Mülheim	Verfahren zur chemischen Dekontamination von metallischen Bauteilen von Kernreaktoranlagen
EP0071336B1 (de) *	1981-06-17	1986-03-26	Central Electricity Generating Board	Verfahren zur chemischen Zersetzung von Oxydniederschlägen
DE3413868A1 (de) *	1984-04-12	1985-10-17	Kraftwerk Union AG, 4330 Mülheim	Verfahren zur chemischen dekontamination von metallischen bauteilen von kernreaktoranlagen
CH673545A5 (de) *	1987-10-02	1990-03-15	Industrieorientierte Forsch
ES2045298T3 (es) *	1988-08-24	1994-01-16	Siemens Ag	Procedimiento para la descontaminacion quimica de la superficie de un componente metalico de una instalacion de reactor nuclear.
FR2699936B1 (fr) *	1992-12-24	1995-01-27	Electricite De France	Procédé de dissolution d'oxydes déposés sur un substrat métallique.
US5305360A (en) *	1993-02-16	1994-04-19	Westinghouse Electric Corp.	Process for decontaminating a nuclear reactor coolant system
JP3417296B2 (ja) *	1998-05-29	2003-06-16	栗田エンジニアリング株式会社	除染方法
FR2817492B1 (fr) *	2000-12-04	2003-07-18	Commissariat Energie Atomique	Procede de dissolution des solides formes dans une installation nucleaire
KR100724710B1 (ko)	2002-11-21	2007-06-04	가부시끼가이샤 도시바	방사화 부품의 화학적 오염제거 시스템 및 방법
JP4083607B2 (ja)	2003-03-19	2008-04-30	株式会社東芝	放射能の化学除染方法および装置
JP4551843B2 (ja) *	2005-08-29	2010-09-29	株式会社東芝	化学除染方法
EP1968075B1 (de) *	2005-11-29	2011-08-31	Areva NP GmbH	Verfahren zur Dekontamination einer eine Oxidschicht aufweisenden Oberfläche einer Komponente oder eines Systems einer kerntechnischen Anlage
CN103155047B (zh) *	2010-07-21	2016-08-03	加拿大原子能有限公司	反应堆去污方法和试剂

2009
- 2009-12-04 DE DE102009047524A patent/DE102009047524A1/de not_active Withdrawn
2010
- 2010-12-01 JP JP2012541479A patent/JP5602241B2/ja not_active Expired - Fee Related
- 2010-12-01 CN CN2010800170411A patent/CN102405500A/zh active Pending
- 2010-12-01 ES ES10795259T patent/ES2404895T3/es active Active
- 2010-12-01 WO PCT/EP2010/068602 patent/WO2011067271A1/de not_active Ceased
- 2010-12-01 CA CA2755288A patent/CA2755288A1/en not_active Abandoned
- 2010-12-01 KR KR1020117026921A patent/KR101309609B1/ko not_active Expired - Fee Related
- 2010-12-01 EP EP10795259A patent/EP2417606B1/de not_active Not-in-force
- 2010-12-02 TW TW099141882A patent/TW201131581A/zh unknown
2011
- 2011-09-02 ZA ZA2011/06436A patent/ZA201106436B/en unknown
2012
- 2012-02-13 US US13/371,891 patent/US20120138086A1/en not_active Abandoned

Also Published As

Publication number	Publication date
CA2755288A1 (en)	2011-06-09
JP5602241B2 (ja)	2014-10-08
EP2417606A1 (de)	2012-02-15
US20120138086A1 (en)	2012-06-07
CN102405500A (zh)	2012-04-04
WO2011067271A1 (de)	2011-06-09
JP2013513098A (ja)	2013-04-18
TW201131581A (en)	2011-09-16
DE102009047524A1 (de)	2011-06-09
EP2417606B1 (de)	2013-02-20
KR20120057568A (ko)	2012-06-05
ZA201106436B (en)	2012-08-29
KR101309609B1 (ko)	2013-09-17

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