ES2536678T3 - Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados - Google Patents

Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados Download PDF

Info

Publication number
ES2536678T3
ES2536678T3 ES10011677.1T ES10011677T ES2536678T3 ES 2536678 T3 ES2536678 T3 ES 2536678T3 ES 10011677 T ES10011677 T ES 10011677T ES 2536678 T3 ES2536678 T3 ES 2536678T3
Authority
ES
Spain
Prior art keywords
carbohydrates
selective oxidation
supported gold
gold catalysts
carbohydrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES10011677.1T
Other languages
English (en)
Inventor
Jörg Kowalczyk
Alireza Haji Begli
Ulf PRÜSSE
Heinz Berndt
Irene Pitsch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suedzucker AG
Original Assignee
Suedzucker AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suedzucker AG filed Critical Suedzucker AG
Application granted granted Critical
Publication of ES2536678T3 publication Critical patent/ES2536678T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)

Abstract

Método de oxidación selectiva de al menos un oligosacárido, de una mezcla de ellos o de una composición que lo(s) contiene, haciendo reaccionar con oxígeno una solución acuosa del oligosacárido, de la mezcla o de la composición en presencia de un catalizador de oro formado por partículas de oro nanodispersas distribuidas sobre un soporte de carbono, de modo que un grupo aldehído existente en el átomo de carbono C1 del o de los hidratos de carbono se oxida selectivamente a un grupo carboxilo o bien un grupo aldehído introducido en el átomo de carbono C1 de una 2-cetosa se oxida selectivamente a grupo carboxilo.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
imagen9
imagen10
imagen11

Claims (1)

  1. imagen1
ES10011677.1T 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados Expired - Lifetime ES2536678T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10319917A DE10319917B4 (de) 2003-05-05 2003-05-05 Verfahren zur selektiven Kohlenhydrat-Oxidation unter Verwendung geträgerter Gold-Katalysatoren
DE10319917 2003-05-05

Publications (1)

Publication Number Publication Date
ES2536678T3 true ES2536678T3 (es) 2015-05-27

Family

ID=33426669

Family Applications (2)

Application Number Title Priority Date Filing Date
ES10011677.1T Expired - Lifetime ES2536678T3 (es) 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados
ES04730988T Expired - Lifetime ES2373441T3 (es) 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES04730988T Expired - Lifetime ES2373441T3 (es) 2003-05-05 2004-05-04 Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados.

Country Status (13)

Country Link
US (1) US7982031B2 (es)
EP (2) EP2332900B1 (es)
JP (3) JP4838115B2 (es)
CN (1) CN1816516B (es)
AT (1) ATE525343T1 (es)
AU (2) AU2004235932B2 (es)
BR (1) BRPI0410059B1 (es)
DE (2) DE10362249B4 (es)
ES (2) ES2536678T3 (es)
NZ (2) NZ585754A (es)
PL (1) PL1631537T3 (es)
RU (1) RU2345059C2 (es)
WO (1) WO2004099114A1 (es)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10362249B4 (de) * 2003-05-05 2014-05-15 Südzucker AG Mannheim/Ochsenfurt C1-selektive Oxidation von Oligosacchariden und die Verwendung eines Kohlenstoff geträgerten Gold-Katalysators für diese Oxidation
WO2005070534A1 (en) 2004-01-22 2005-08-04 Indian Institute Of Technology Adsorbent composition, a device and a method for decontaminating water containing pesticides
DE102005036890A1 (de) * 2005-08-05 2007-02-08 Südzucker AG Mannheim/Ochsenfurt Geträgerter Goldkatalysator
DE102007005528A1 (de) * 2007-02-03 2008-08-07 Südzucker AG Mannheim/Ochsenfurt Kohlenstoff-geträgerter Goldkatalysator
WO2008100228A1 (en) * 2007-02-13 2008-08-21 Agency For Science, Technology And Research Process for removing organic contaminants from aqueous media
DE102007017179A1 (de) * 2007-04-12 2008-10-23 Clariant International Ltd. Verfahren zur Herstellung von Alkylpolyglykolcarbonsäuren und Polyglykoldicarbonsäuren mittels Direktoxidation
KR20100019476A (ko) * 2007-06-05 2010-02-18 디에스엠 아이피 어셋츠 비.브이. 금 촉매를 사용한 신규 반응
JP5136017B2 (ja) * 2007-11-21 2013-02-06 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
DE102008053607A1 (de) * 2008-10-20 2010-04-22 Südzucker AG Mannheim/Ochsenfurt Solubilisierungsmittel für Metallionen
EP2204098A1 (en) 2008-12-19 2010-07-07 Südzucker Aktiengesellschaft Mannheim/Ochsenfurt Flavour enhancer
RU2423344C2 (ru) * 2009-06-09 2011-07-10 Государственное образовательное учреждение высшего профессионального образования "Тверской государственный технический университет" Способ селективного окисления d-глюкозы
CN101591233B (zh) * 2009-06-19 2012-06-27 厦门大学 葡萄糖酸的制备方法
US9770705B2 (en) * 2010-06-11 2017-09-26 Rennovia Inc. Oxidation catalysts
RU2439050C1 (ru) * 2010-08-19 2012-01-10 Государственное образовательное учреждение высшего профессионального образования "Тверской государственный технический университет" Способ получения лактобионовой кислоты
RU2468861C1 (ru) * 2011-05-04 2012-12-10 Государственное образовательное учреждение высшего профессионального образования "Юго-Западный государственный университет" (ЮЗГУ) Способ получения катализатора на пористом металлооксидном носителе для окисления углеводов
JP6086530B2 (ja) * 2012-02-17 2017-03-01 国立大学法人北陸先端科学技術大学院大学 Ｄ−グルコサミン酸又はその類縁体の製造方法、並びにそのための触媒組成物
US9079844B2 (en) 2012-04-04 2015-07-14 Stichting Dienst Landbouwkundig Onderzoek Catalytic oxidation of uronic acids to aldaric acids
EP2692843A1 (en) 2012-08-03 2014-02-05 Tiense Suikerraffinaderij N.V. Use of C1-oxidised starch hydrolysates
CN102875612A (zh) * 2012-10-12 2013-01-16 兰溪市苏格生物技术有限公司 催化氧化制备乳糖酸及乳糖酸盐的方法
FR3012347B1 (fr) 2013-10-30 2015-12-11 Commissariat Energie Atomique Complexes organo-metalliques a base d'iridium a titre de catalyseurs d'oxydation
KR101679914B1 (ko) * 2014-08-18 2016-11-25 현대자동차주식회사 글루카릭산 제조법
JP6789736B2 (ja) * 2016-09-07 2020-11-25 サンエイ糖化株式会社 ニッケル触媒を用いた糖カルボン酸の製造方法
US11123711B2 (en) 2017-12-28 2021-09-21 University Of Kentucky Research Foundation System and method for alcohol oxidation reaction of lignins
CN109382098A (zh) * 2018-10-31 2019-02-26 华南理工大学 一种Au@介孔氧化铝类蛋黄壳结构催化剂及其制备与应用
EP3976626A4 (en) * 2019-05-28 2023-07-05 Dfi Usa, Llc PROCESS FOR THE PREPARATION OF CALCIUM, MAGNESIUM AND ZINC SALTS OF SUGAR ACIDS
US20220306563A1 (en) * 2019-06-27 2022-09-29 Rhodia Operations Method for preparing glycolic acid
PL3822248T4 (pl) * 2019-11-18 2024-06-03 Archer Daniels Midland Company Sposób wytwarzania kwasów aldarowych, aldonowych i uronowych
ES2923504T3 (es) * 2019-11-18 2022-09-28 Archer Daniels Midland Co Procedimientos para preparar ácidos aldáricos, aldónicos y urónicos
CN115397977A (zh) * 2020-03-06 2022-11-25 索鲁根公司 用于生产葡萄糖氧化产物的组合物和方法
CN112110961A (zh) * 2020-09-27 2020-12-22 山东齐都药业有限公司 葡萄糖酸钙中杂质的制备方法
CN114425444B (zh) * 2020-10-14 2024-01-26 中国石油化工股份有限公司 乙烯法合成醋酸乙烯催化剂及其制备方法
CN115806537B (zh) * 2021-09-13 2024-09-24 中国石油化工股份有限公司 一种制备糠酸的方法
EP4223882A1 (en) 2022-02-02 2023-08-09 Vilnius University Process for producing aldonic acids
CN115990485B (zh) * 2023-03-23 2023-07-14 农业农村部环境保护科研监测所 一种糖酸合成用双金属复合生物炭催化剂及糖酸合成方法和应用

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862005A (en) 1969-05-20 1975-01-21 Hayashibara Co Process for producing aldonic acids and starch sugars containing aldonic acids
IT1023006B (it) 1969-07-31 1978-05-10 Hayashibara Co Procedimento per la produzione di lattulosio da lattosio e prodotto relativo
JPS5520679A (en) 1978-08-03 1980-02-14 Saburo Miyazaki Coating device
DE3535720A1 (de) * 1985-10-07 1987-04-09 Hoechst Ag Saccharose-tricarbonsaeure, verfahren zu ihrer herstellung und ihre verwendung
FR2597473B1 (fr) * 1986-01-30 1988-08-12 Roquette Freres Procede d'oxydation de di-, tri-, oligo- et polysaccharides en acides polyhydroxycarboxyliques, catalyseur mis en oeuvre et produits ainsi obtenus.
DE3823301C1 (es) * 1988-07-09 1989-11-02 Degussa Ag, 6000 Frankfurt, De
FR2688780B1 (fr) * 1992-03-23 1995-05-12 Atochem Elf Sa Procede d'oxydation selective d'un saccharide.
JPH067184A (ja) 1992-06-26 1994-01-18 Nippon Shinyaku Co Ltd マルトビオン酸の製法
DE4307388A1 (de) 1993-03-10 1994-09-15 Zuckerindustrie Verein Verfahren und Vorrichtung zur Herstellung von monooxydierten Produkten aus Kohlenhydraten, Kohlenhydratderivaten und primären Alkoholen
JP2000506868A (ja) * 1996-03-21 2000-06-06 アクゾ ノーベル ナムローゼ フェンノートシャップ ジ、トリ、オリゴおよびポリサッカライドをポリヒドロキシカルボン酸へと酸化する方法
DE19804709A1 (de) 1998-02-06 1999-08-12 Bayer Ag Verfahren zur katalytischen Direktoxidation ungesättigter Kohlenwasserstoffe in der Gasphase
DE60021071T2 (de) 1999-04-08 2006-05-18 Dow Global Technologies, Inc., Midland Verfahren zur herstellung eines gold und titanium beinhaltenden katalysators
IT1313696B1 (it) * 1999-12-16 2002-09-09 Lonza Spa Procedimento per la produzione di acidi aldonici particolarmenteidonei come additivi alimentari.
DE10362249B4 (de) * 2003-05-05 2014-05-15 Südzucker AG Mannheim/Ochsenfurt C1-selektive Oxidation von Oligosacchariden und die Verwendung eines Kohlenstoff geträgerten Gold-Katalysators für diese Oxidation

Also Published As

Publication number Publication date
DE10362249B4 (de) 2014-05-15
JP2011236215A (ja) 2011-11-24
BRPI0410059B1 (pt) 2014-10-29
EP1631537A1 (de) 2006-03-08
RU2005137687A (ru) 2006-04-27
AU2004235932B2 (en) 2010-08-19
CN1816516A (zh) 2006-08-09
PL1631537T3 (pl) 2012-02-29
JP2010159280A (ja) 2010-07-22
JP5444054B2 (ja) 2014-03-19
EP2332900A1 (de) 2011-06-15
WO2004099114A1 (de) 2004-11-18
RU2345059C2 (ru) 2009-01-27
DE10319917A1 (de) 2004-12-09
AU2010202821B2 (en) 2012-03-15
DE10362249A1 (de) 2008-04-30
WO2004099114A8 (de) 2005-02-24
ES2373441T3 (es) 2012-02-03
JP4838115B2 (ja) 2011-12-14
EP2332900B1 (de) 2015-02-25
JP2006525272A (ja) 2006-11-09
CN1816516B (zh) 2010-05-12
BRPI0410059A (pt) 2006-05-23
US7982031B2 (en) 2011-07-19
EP1631537B1 (de) 2011-09-21
NZ585754A (en) 2011-12-22
AU2010202821A1 (en) 2010-07-22
US20070112186A1 (en) 2007-05-17
DE10319917B4 (de) 2009-01-02
ATE525343T1 (de) 2011-10-15
AU2004235932A1 (en) 2004-11-18
NZ543384A (en) 2010-08-27

Similar Documents

Publication Publication Date Title
ES2536678T3 (es) Método de oxidación selectiva de hidratos de carbono mediante el uso de catalizadores de oro soportados
BR0314971A (pt) Composição fotorreativa e artigo
IT1318550B1 (it) Catalizzatore e processo per la sintesi diretta di acqua ossigenata.
AU2001240085A1 (en) Multi-zoned catalytic trap and methods of making and using the same
AU4701200A (en) A method of detecting an analyte using semiconductor nanocrystals
AR020370A1 (es) PROCESO AUTOTÉRMICO DE OXIDACIoN PARA PREPARAR UNA OLEFINA , COMPOSICIoN DE CATALIZADOR PARA DICHO PROCESO Y PROCESO PARA SINTETIZAR O REGENERAR EN LINEA DICHO CATALIZADOR.
BR0104336A (pt) Métodos para produzir um ácido carboxìlico insaturado e para produzir uma nitrila insaturada
YU49231B (sh) Katalizator za proizvodnju vinil acetata koji sadrži metalni paladijum, zlato, bakar i ma koji od izvesnih četvrtih metala i postupak za proizvodnju vinil acetata primenom tog katalizatora
ES2161531T3 (es) Catalizador que comprende paladio y oro depositados sobre un vehiculo que contiene cobre para la produccion de acetato de vinilo.
YU48098A (sh) Katalizator vinil acetata koji sadrži paladijum, zlato i bilo koji od izvesnih trećih metala
MY131625A (en) " catalyst "
ATE327513T1 (de) Speichelvorbehandlungsmethode und -kit für die bestimmung von mutans streptococci im speichel mittels immunchromatographie
BR9813104A (pt) Catalisador de acetato de vinila compreendendo paládio metálico e ouro, e acetato cúprico
ATE342732T1 (de) Anti-allergische pharmazeutische zusammensetzung
ATE474613T1 (de) Genpistole mit niederdruckgasbeschleunigung
IL161998A (en) Gas production device, device manufacturing method, gas production method, piston moving method and fluid delivery method
AR015201A1 (es) Proceso para preparar acetato de vinilo.
ATE74109T1 (de) Katalysatoren zum abtrennen von sauerstoff aus luft durch absorption.
AU2003247802A8 (en) Method for chemiluminescent detection
ATE400362T1 (de) Hydrogenolysekatalysator
SE8302769L (sv) Katalysator baserad pa y-aluminiumoxid och forfarande for framstellning derav
ES2124563T3 (es) Catalizador de oxidacion.
SE8901938D0 (sv) Katalysator
DE60136310D1 (de) Matrizenhalteranordnung mit Anti-Drehbewegungsmitteln in Gesenkformvorrichtungen
ES2183714A1 (es) Un procedimiento para la fabricacion de oxalato de (1r,2r-ciclohexanodiamina)-platino (ii).