ES2560785T3 - Suspensión acuosa de carbonato de calcio tratado mediante reacción en superficie, productos resultantes y usos de los mismos - Google Patents
Suspensión acuosa de carbonato de calcio tratado mediante reacción en superficie, productos resultantes y usos de los mismos Download PDFInfo
- Publication number
- ES2560785T3 ES2560785T3 ES10730227.5T ES10730227T ES2560785T3 ES 2560785 T3 ES2560785 T3 ES 2560785T3 ES 10730227 T ES10730227 T ES 10730227T ES 2560785 T3 ES2560785 T3 ES 2560785T3
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- Spain
- Prior art keywords
- calcium carbonate
- aqueous suspension
- surface reaction
- resulting products
- carbonate treated
- Prior art date
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Links
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title abstract 6
- 229910000019 calcium carbonate Inorganic materials 0.000 title abstract 3
- 239000007900 aqueous suspension Substances 0.000 title abstract 2
- 238000006557 surface reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/90—Carbides
- C01B32/914—Carbides of single elements
- C01B32/942—Calcium carbide
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
- C09C1/022—Treatment with inorganic compounds
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Paper (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Removal Of Specific Substances (AREA)
- Materials For Medical Uses (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Suspensión acuosa de carbonato de calcio tratado mediante reacción en superficie que puede obtenerse mediante un procedimiento para preparar un carbonato de calcio tratado mediante reacción en superficie en un entorno acuoso, comprendiendo el procedimiento las siguientes etapas: a) proporcionar al menos un carbonato de calcio natural triturado (GNCC); b) proporcionar al menos un ácido soluble en agua; c) proporcionar CO2 gaseoso; d) poner en contacto dicho GNCC de la etapa a) con dicho ácido de la etapa b) y con dicho CO2 de la etapa c); caracterizada porque: (i) dicho(s) ácido(s) de la etapa b) tiene(n) cada uno un pKa de más de 2,5 y menos de o igual a 7, cuando se mide a 20ºC, asociado con la ionización de su primer hidrógeno disponible, y un anión correspondiente formado con la pérdida de este primer hidrógeno disponible que puede formar sales de calcio solubles en agua y en la que dicho(s) ácido(s) soluble(s) en agua se selecciona(n) del grupo que consiste en ácido acético, ácido fórmico, ácido propanoico y mezclas de los mismos; (ii) tras poner en contacto dicho(s) ácido(s) con dicho GNCC, se proporciona adicionalmente al menos una sal soluble en agua, que en el caso de una sal que contiene hidrógeno tiene un pKa de más de 7, cuando se mide a 20ºC, asociado con la ionización del primer hidrógeno disponible, y cuyo anión de sal puede formar sales de calcio insolubles en agua; (iii) dicho(s) ácido(s) soluble(s) en agua se dosifica(n) en una cantidad total correspondiente a desde 3 x 10-4 hasta 10 x 10-4 mol de átomos de hidrógeno en el ácido/m2 de GNCC proporcionado en la etapa a).
Description
Claims (1)
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imagen1 imagen2 imagen3
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09162727 | 2009-06-15 | ||
| EP20090162727 EP2264108B1 (en) | 2009-06-15 | 2009-06-15 | Process to prepare a surface-reacted calcium carbonate implementing a weak acid |
| US26924309P | 2009-06-22 | 2009-06-22 | |
| US269243P | 2009-06-22 | ||
| PCT/IB2010/052666 WO2010146530A1 (en) | 2009-06-15 | 2010-06-15 | Process to prepare a surface-reacted calcium carbonate implementing a weak acid, resulting products and uses thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2560785T3 true ES2560785T3 (es) | 2016-02-22 |
Family
ID=40907322
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09162727T Active ES2382628T3 (es) | 2009-06-15 | 2009-06-15 | Proceso para la preparación de un carbonato cálcico que reacciona con la superficie aplicando un ácido débil |
| ES10730227.5T Active ES2560785T3 (es) | 2009-06-15 | 2010-06-15 | Suspensión acuosa de carbonato de calcio tratado mediante reacción en superficie, productos resultantes y usos de los mismos |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09162727T Active ES2382628T3 (es) | 2009-06-15 | 2009-06-15 | Proceso para la preparación de un carbonato cálcico que reacciona con la superficie aplicando un ácido débil |
Country Status (25)
| Country | Link |
|---|---|
| US (4) | US9096761B2 (es) |
| EP (2) | EP2264108B1 (es) |
| JP (1) | JP5584290B2 (es) |
| KR (1) | KR101399737B1 (es) |
| CN (1) | CN102459470B (es) |
| AT (1) | ATE545682T1 (es) |
| AU (1) | AU2010261441B2 (es) |
| BR (1) | BRPI1013114B1 (es) |
| CA (1) | CA2765343C (es) |
| CO (1) | CO6440525A2 (es) |
| DK (2) | DK2264108T3 (es) |
| ES (2) | ES2382628T3 (es) |
| HR (2) | HRP20160139T1 (es) |
| HU (1) | HUE028686T2 (es) |
| ME (1) | ME01441B (es) |
| MX (1) | MX2011013574A (es) |
| NZ (1) | NZ597478A (es) |
| PL (2) | PL2264108T3 (es) |
| PT (2) | PT2264108E (es) |
| RS (1) | RS52297B (es) |
| RU (1) | RU2520452C2 (es) |
| SI (2) | SI2264108T1 (es) |
| TW (1) | TWI429591B (es) |
| UY (1) | UY32708A (es) |
| WO (1) | WO2010146530A1 (es) |
Families Citing this family (154)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT2264108E (pt) | 2009-06-15 | 2012-05-23 | Omya Development Ag | Processo para preparar um carbonato de cálcio feito reagir em superfície utilizando um ácido fraco |
| PL2537883T3 (pl) * | 2011-06-20 | 2014-08-29 | Imerys Minerals Ltd | Sposoby i kompozycje związane z odpadami polimerowymi z recyklingu |
| EP2557129B1 (en) | 2011-08-09 | 2018-02-28 | Omya International AG | Surface-treated calcium carbonate for binding and bioremediating hydrocarbon-containing compositions |
| PL2565165T3 (pl) * | 2011-08-31 | 2017-04-28 | Omya International Ag | Remineralizacja odsolonej i słodkiej wody przez dozowanie roztworu węglanu wapnia w miękkiej wodzie |
| PT2589430E (pt) | 2011-11-04 | 2015-11-16 | Omya Int Ag | Carbonato de cálcio tratado na superfície e sua utilização na purificação de água e para a desidratação de lamas e sedimentos |
| EP3075376A1 (en) | 2011-11-10 | 2016-10-05 | Omya International AG | New coated controlled release active agent carriers |
| TWI625129B (zh) | 2011-11-10 | 2018-06-01 | 歐米亞國際公司 | 新穎的經塗布控釋活性劑載體 |
| PT2596702E (pt) | 2011-11-25 | 2015-09-21 | Omya Int Ag | Processo para estabilização do conteúdo bacteriano de preparações minerais aquosas que compreendem carbonato de cálcio natural triturado e/ou carbonato de cálcio precipitado e/ou dolomite e/ou carbonato de cálcio reagido superficialmente |
| CN103284929B (zh) * | 2012-02-23 | 2015-08-12 | 黄曦 | 一种护肤品及其制备方法 |
| ES2547808T3 (es) * | 2012-05-11 | 2015-10-08 | Omya International Ag | Tratamiento de materiales que contienen carbonato de calcio para carga de agente de relleno aumentada en papel |
| PL2679638T3 (pl) * | 2012-06-28 | 2016-02-29 | Omya Int Ag | Wodna zawiesina minerału i/lub wypełniacza i/lub pigmentu o dużej zawartości części stałych w środowisku o kwaśnym pH |
| ES2584628T3 (es) | 2012-07-13 | 2016-09-28 | Omya International Ag | Minerales que contienen carbonato de calcio de superficie modificada y su uso |
| DK2719373T3 (en) | 2012-10-12 | 2017-07-03 | Omya Int Ag | Fast dissolving solid dosage formulation comprising functionalized calcium carbonate and process for the preparation thereof |
| DK2719376T3 (en) | 2012-10-12 | 2015-06-15 | Omya Int Ag | Gastroretentiv drug formulation and delivery systems and their method of preparation by the use of functional calcium carbonate |
| SI2749679T1 (sl) | 2012-12-28 | 2017-07-31 | Omya International Ag | CaCO3 V POLIESTRU ZA NETKANINE IN VLAKNA |
| FI127761B (en) | 2013-02-28 | 2019-02-15 | Nordkalk Oy Ab | Preparation of salt particles from precipitated calcium carbonate |
| KR101466225B1 (ko) * | 2013-04-24 | 2014-12-10 | 한국지질자원연구원 | 방해석의 표면개질화 방법 |
| HUE031412T2 (en) | 2013-05-07 | 2017-07-28 | Omya Int Ag | Water purification and sludge dewatering employing surface-treated calcium carbonate and phyllosilicate, use of the combination of surface-treated calcium carbonate and phyllosilicate and composite material |
| ES2703729T3 (es) * | 2013-05-24 | 2019-03-12 | Omya Int Ag | Instalación para la preparación de una solución de hidrogenocarbonato de calcio adecuada para la remineralización del agua |
| EP2883573B2 (en) * | 2013-12-13 | 2020-10-28 | Omya International AG | Abrasive cleaning composition |
| EP2886291A1 (en) | 2013-12-23 | 2015-06-24 | Omya International AG | Polymer composition by continuous filler slurry extrusion |
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| EP2921173A1 (en) * | 2014-03-21 | 2015-09-23 | Omya International AG | Surface-reacted calcium carbonate for desensitizing teeth |
| ES2651325T3 (es) * | 2014-03-31 | 2018-01-25 | Omya International Ag | Carbonato de calcio tratado mediante reacción superficial para remineralización y blanqueamiento de dientes |
| ES2626081T3 (es) | 2014-05-26 | 2017-07-21 | Omya International Ag | Procedimiento para preparar un material de superficie modificada |
| TWI565763B (zh) | 2014-05-30 | 2017-01-11 | 歐米亞國際公司 | 製造包含表面經反應碳酸鈣之顆粒的方法 |
| EP2949708B1 (en) | 2014-05-30 | 2018-04-04 | Omya International AG | Method for the production of granules comprising surface-reacted calcium carbonate |
| EP2957603A1 (en) | 2014-06-20 | 2015-12-23 | Omya International AG | Method for the production of granules comprising surface-reacted calcium carbonate |
| RS56115B1 (sr) * | 2014-06-20 | 2017-10-31 | Omya Int Ag | Metod za kontrolu mirisa |
| TR201810896T4 (tr) | 2014-07-01 | 2018-08-27 | Omya Int Ag | Çok filamentli polyester elyaflar. |
| EP2975078A1 (en) | 2014-08-14 | 2016-01-20 | Omya International AG | Surface-treated fillers for breathable films |
| EP2997833B1 (en) | 2014-09-22 | 2018-01-31 | Omya International AG | Surface-reacted calcium carbonate for use as anti-caking agent |
| TR201808701T4 (tr) | 2014-11-07 | 2018-07-23 | Omya Int Ag | Yumaklaşmış dolgu maddesi parçacıklarının hazırlanması için bir işlem. |
| SI3018175T1 (sl) | 2014-11-07 | 2019-05-31 | Omya International Ag | Postopek za pripravo flokulirnih polnilnih delcev |
| ES2660425T3 (es) | 2014-12-02 | 2018-03-22 | Omya International Ag | Proceso para la producción de un material compactado, material así producido y uso del mismo |
| NO3033944T3 (es) | 2014-12-16 | 2018-07-14 | ||
| EP3034070A1 (en) | 2014-12-18 | 2016-06-22 | Omya International AG | Method for the production of a pharmaceutical delivery system |
| EP3045503A1 (en) | 2015-01-15 | 2016-07-20 | Omya International AG | Surface-treated calcium carbonate with improved stability in environments with a pH of 4.5 to 7 |
| ES2655290T3 (es) | 2015-03-13 | 2018-02-19 | Omya International Ag | Método de impresión por inyección de tinta |
| NO3067214T3 (es) | 2015-03-13 | 2018-05-19 | ||
| EP3070057A1 (en) * | 2015-03-16 | 2016-09-21 | Omya International AG | Process for the purification of water |
| EP3069713A1 (en) | 2015-03-20 | 2016-09-21 | Omya International AG | Dispersible dosage form |
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| EP3103844B1 (en) | 2015-06-10 | 2018-08-08 | Omya International AG | Use of surface-reacted calcium carbonate as anti-blocking agent |
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