ES2564558T3 - Procedimiento para la retirada de oxígeno, óxidos de nitrógeno, acetilenos y/o dienos de mezclas de gases que contienen olefinas ricas en hidrógeno - Google Patents

Procedimiento para la retirada de oxígeno, óxidos de nitrógeno, acetilenos y/o dienos de mezclas de gases que contienen olefinas ricas en hidrógeno

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Publication number
ES2564558T3
ES2564558T3 ES07802844.6T ES07802844T ES2564558T3 ES 2564558 T3 ES2564558 T3 ES 2564558T3 ES 07802844 T ES07802844 T ES 07802844T ES 2564558 T3 ES2564558 T3 ES 2564558T3
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ES
Spain
Prior art keywords
dienes
oxygen
nitrogen oxides
removal
acetylenes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES07802844.6T
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English (en)
Inventor
Peter Rudolf
Michael Bender
Michael Koch
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BASF SE
Original Assignee
BASF SE
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Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2564558T3 publication Critical patent/ES2564558T3/es
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04Sulfides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8665Removing heavy metals or compounds thereof, e.g. mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8668Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/86Chromium
    • B01J23/868Chromium copper and chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20Sulfiding
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/02Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by hydrogenation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/104Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/60Heavy metals or heavy metal compounds
    • B01D2257/602Mercury or mercury compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7022Aliphatic hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

Procedimiento para la retirada de acetileno y dado el caso uno o varios de los componentes seleccionados del grupo que consiste en oxígeno, óxidos de nitrógeno y dienos de una mezcla de gases que contiene acetileno y dado el caso uno o varios de los componentes seleccionados del grupo que consiste en oxígeno, óxidos de nitrógeno y dienos, y además hidrógeno, una o varias olefinas que no son dienos y dado el caso otros componentes de gas, en el que la mezcla de gases se pone en contacto con un catalizador en una zona de reacción, caracterizado porque el catalizador contiene sulfuro de cobre (I).

Description

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Claims (1)

  1. imagen1
ES07802844.6T 2006-08-25 2007-08-24 Procedimiento para la retirada de oxígeno, óxidos de nitrógeno, acetilenos y/o dienos de mezclas de gases que contienen olefinas ricas en hidrógeno Active ES2564558T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US84002606P 2006-08-25 2006-08-25
US840026P 2006-08-25
PCT/EP2007/058792 WO2008023051A1 (de) 2006-08-25 2007-08-24 Verfahren zur entfernung von sauerstoff, stickstoffoxiden, acetylenen und/oder dienen aus wasserstoffreichen olefinhaltigen gasgemischen

Publications (1)

Publication Number Publication Date
ES2564558T3 true ES2564558T3 (es) 2016-03-23

Family

ID=38608730

Family Applications (1)

Application Number Title Priority Date Filing Date
ES07802844.6T Active ES2564558T3 (es) 2006-08-25 2007-08-24 Procedimiento para la retirada de oxígeno, óxidos de nitrógeno, acetilenos y/o dienos de mezclas de gases que contienen olefinas ricas en hidrógeno

Country Status (11)

Country Link
US (1) US8586815B2 (es)
EP (1) EP2056962B1 (es)
JP (1) JP5591537B2 (es)
KR (1) KR101452529B1 (es)
CN (1) CN101505866B (es)
BR (1) BRPI0715798B1 (es)
CA (1) CA2660334C (es)
ES (1) ES2564558T3 (es)
HU (1) HUE029626T2 (es)
TW (1) TWI414516B (es)
WO (1) WO2008023051A1 (es)

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AR067902A1 (es) * 2007-08-17 2009-10-28 Shell Int Research Un proceso para remover azufre de una corriente de gas combustible que adicionalmente contiene diolefinas y oxigeno
JP2012509758A (ja) 2008-11-25 2012-04-26 ジョンソン、マッセイ、パブリック、リミテッド、カンパニー 重金属除去用還元型硫化銅収着剤
GB0905896D0 (en) 2009-04-06 2009-05-20 Univ Belfast Process for removing metals from hydrocarbons
ES2436625T3 (es) 2009-05-12 2014-01-03 Basf Se Proceso para producir óxido de propileno
JP5300643B2 (ja) * 2009-07-28 2013-09-25 Jx日鉱日石エネルギー株式会社 気体状の炭化水素中の窒素酸化物の測定方法
WO2011081836A2 (en) * 2009-12-15 2011-07-07 Uop Llc Mercury removal from cracked gas
KR101621601B1 (ko) * 2010-12-20 2016-05-16 유오피 엘엘씨 점토를 사용하여 탄화수소 스트림으로부터 불포화 지방족 탄화수소를 제거하는 방법
US9670115B2 (en) 2012-02-15 2017-06-06 Clariant Corporation Method and system for purifying an ethylene-containing gas stream
CN104395269A (zh) * 2012-06-29 2015-03-04 赫多特普索化工设备公司 通过加氢净化原料气
US8609048B1 (en) * 2012-11-02 2013-12-17 Uop Llc Process for reducing corrosion, fouling, solvent degradation, or zeolite degradation in a process unit
CA2889683C (en) * 2012-11-15 2018-08-14 Exxonmobil Chemical Patents Inc. Nox removal method
WO2017083116A1 (en) 2015-11-10 2017-05-18 Uop Llc Copper adsorbent for gas purification
EP3374059A4 (en) * 2015-11-10 2019-05-22 Uop Llc COPPER ADSORBENT FOR ACETYLENE CONVERTER PROTECTION BED
SG11202007617UA (en) * 2018-02-12 2020-09-29 Lanzatech Inc Integrated process for filtering constituents from a gas stream
CN116806254B (zh) 2021-01-08 2026-01-13 埃克森美孚化学专利公司 提质烃的方法和系统
RU2760125C1 (ru) * 2021-04-30 2021-11-22 Общество с ограниченной ответственностью "Юнайтед Кэталист Текнолоджис" Способ очистки углеводородных газов от N2O
RU2760126C1 (ru) * 2021-05-12 2021-11-22 Общество с ограниченной ответственностью "Юнайтед Кэталист Текнолоджис" Способ очистки потоков насыщенных углеводородов от примесей

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US3456029A (en) * 1966-07-20 1969-07-15 Yawata Chem Ind Co Ltd Process for the purification of lower olefin gases
JPS5062856A (es) * 1973-09-13 1975-05-29
GB8529245D0 (en) * 1985-11-27 1986-01-02 British Petroleum Co Plc Chemical process
US4744973A (en) * 1985-11-29 1988-05-17 Westinghouse Electric Corp. Inorganic polymeric cationic ion exchange matrix
FR2668465B1 (fr) * 1990-10-30 1993-04-16 Inst Francais Du Petrole Procede d'elimination de mercure ou d'arsenic dans un fluide en presence d'une masse de captation de mercure et/ou d'arsenic.
US5689032A (en) * 1994-11-22 1997-11-18 Krause/Pasadyn, A Partnership Method and apparatus for recovery of H2 and C2 and heavier components
GB9607066D0 (en) * 1996-04-03 1996-06-05 Ici Plc Purification process
GB0223300D0 (en) * 2002-10-08 2002-11-13 Bp Chem Int Ltd Process

Also Published As

Publication number Publication date
BRPI0715798A2 (pt) 2013-07-16
KR101452529B1 (ko) 2014-10-21
JP2010501529A (ja) 2010-01-21
US20100000911A1 (en) 2010-01-07
JP5591537B2 (ja) 2014-09-17
BRPI0715798B1 (pt) 2016-12-06
CA2660334C (en) 2014-07-15
CA2660334A1 (en) 2008-02-28
CN101505866B (zh) 2013-05-15
TW200815340A (en) 2008-04-01
CN101505866A (zh) 2009-08-12
EP2056962B1 (de) 2016-01-27
TWI414516B (zh) 2013-11-11
EP2056962A1 (de) 2009-05-13
KR20090053799A (ko) 2009-05-27
WO2008023051A1 (de) 2008-02-28
HUE029626T2 (en) 2017-03-28
US8586815B2 (en) 2013-11-19

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