ES2564558T3 - Procedimiento para la retirada de oxígeno, óxidos de nitrógeno, acetilenos y/o dienos de mezclas de gases que contienen olefinas ricas en hidrógeno - Google Patents
Procedimiento para la retirada de oxígeno, óxidos de nitrógeno, acetilenos y/o dienos de mezclas de gases que contienen olefinas ricas en hidrógenoInfo
- Publication number
- ES2564558T3 ES2564558T3 ES07802844.6T ES07802844T ES2564558T3 ES 2564558 T3 ES2564558 T3 ES 2564558T3 ES 07802844 T ES07802844 T ES 07802844T ES 2564558 T3 ES2564558 T3 ES 2564558T3
- Authority
- ES
- Spain
- Prior art keywords
- dienes
- oxygen
- nitrogen oxides
- removal
- acetylenes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title abstract 9
- 150000001993 dienes Chemical class 0.000 title abstract 4
- 239000007789 gas Substances 0.000 title abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 3
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000001301 oxygen Substances 0.000 title abstract 3
- 229910052760 oxygen Inorganic materials 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- AQMRBJNRFUQADD-UHFFFAOYSA-N copper(I) sulfide Chemical compound [S-2].[Cu+].[Cu+] AQMRBJNRFUQADD-UHFFFAOYSA-N 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
- C10G70/02—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by hydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/104—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7022—Aliphatic hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Procedimiento para la retirada de acetileno y dado el caso uno o varios de los componentes seleccionados del grupo que consiste en oxígeno, óxidos de nitrógeno y dienos de una mezcla de gases que contiene acetileno y dado el caso uno o varios de los componentes seleccionados del grupo que consiste en oxígeno, óxidos de nitrógeno y dienos, y además hidrógeno, una o varias olefinas que no son dienos y dado el caso otros componentes de gas, en el que la mezcla de gases se pone en contacto con un catalizador en una zona de reacción, caracterizado porque el catalizador contiene sulfuro de cobre (I).
Description
Claims (1)
-
imagen1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84002606P | 2006-08-25 | 2006-08-25 | |
| US840026P | 2006-08-25 | ||
| PCT/EP2007/058792 WO2008023051A1 (de) | 2006-08-25 | 2007-08-24 | Verfahren zur entfernung von sauerstoff, stickstoffoxiden, acetylenen und/oder dienen aus wasserstoffreichen olefinhaltigen gasgemischen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2564558T3 true ES2564558T3 (es) | 2016-03-23 |
Family
ID=38608730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES07802844.6T Active ES2564558T3 (es) | 2006-08-25 | 2007-08-24 | Procedimiento para la retirada de oxígeno, óxidos de nitrógeno, acetilenos y/o dienos de mezclas de gases que contienen olefinas ricas en hidrógeno |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8586815B2 (es) |
| EP (1) | EP2056962B1 (es) |
| JP (1) | JP5591537B2 (es) |
| KR (1) | KR101452529B1 (es) |
| CN (1) | CN101505866B (es) |
| BR (1) | BRPI0715798B1 (es) |
| CA (1) | CA2660334C (es) |
| ES (1) | ES2564558T3 (es) |
| HU (1) | HUE029626T2 (es) |
| TW (1) | TWI414516B (es) |
| WO (1) | WO2008023051A1 (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR067902A1 (es) * | 2007-08-17 | 2009-10-28 | Shell Int Research | Un proceso para remover azufre de una corriente de gas combustible que adicionalmente contiene diolefinas y oxigeno |
| WO2010061212A1 (en) | 2008-11-25 | 2010-06-03 | Johnson Matthey Plc | Reduced copper sulphide sorbent for removing heavy metals |
| GB0905896D0 (en) * | 2009-04-06 | 2009-05-20 | Univ Belfast | Process for removing metals from hydrocarbons |
| US8927745B2 (en) | 2009-05-12 | 2015-01-06 | Basf Se | Process for producing propylene oxide |
| JP5300643B2 (ja) * | 2009-07-28 | 2013-09-25 | Jx日鉱日石エネルギー株式会社 | 気体状の炭化水素中の窒素酸化物の測定方法 |
| WO2011081836A2 (en) * | 2009-12-15 | 2011-07-07 | Uop Llc | Mercury removal from cracked gas |
| CN103261128A (zh) * | 2010-12-20 | 2013-08-21 | 环球油品公司 | 利用粘土从烃料流移除不饱和脂族烃的方法 |
| US9670115B2 (en) | 2012-02-15 | 2017-06-06 | Clariant Corporation | Method and system for purifying an ethylene-containing gas stream |
| KR20150036137A (ko) * | 2012-06-29 | 2015-04-07 | 할도르 토프쉐 에이/에스 | 수소화에 의한 처리 가스의 정제 |
| US8609048B1 (en) * | 2012-11-02 | 2013-12-17 | Uop Llc | Process for reducing corrosion, fouling, solvent degradation, or zeolite degradation in a process unit |
| SG10201703786YA (en) * | 2012-11-15 | 2017-06-29 | Exxonmobil Chemical Patents Inc | Nox removal method |
| CN108697976A (zh) * | 2015-11-10 | 2018-10-23 | 环球油品公司 | 用于炔转化器防护床的铜吸附剂 |
| WO2017083116A1 (en) | 2015-11-10 | 2017-05-18 | Uop Llc | Copper adsorbent for gas purification |
| SG11202007617UA (en) | 2018-02-12 | 2020-09-29 | Lanzatech Inc | Integrated process for filtering constituents from a gas stream |
| CN116806254B (zh) | 2021-01-08 | 2026-01-13 | 埃克森美孚化学专利公司 | 提质烃的方法和系统 |
| RU2760125C1 (ru) * | 2021-04-30 | 2021-11-22 | Общество с ограниченной ответственностью "Юнайтед Кэталист Текнолоджис" | Способ очистки углеводородных газов от N2O |
| RU2760126C1 (ru) * | 2021-05-12 | 2021-11-22 | Общество с ограниченной ответственностью "Юнайтед Кэталист Текнолоджис" | Способ очистки потоков насыщенных углеводородов от примесей |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3456029A (en) * | 1966-07-20 | 1969-07-15 | Yawata Chem Ind Co Ltd | Process for the purification of lower olefin gases |
| JPS5062856A (es) * | 1973-09-13 | 1975-05-29 | ||
| GB8529245D0 (en) * | 1985-11-27 | 1986-01-02 | British Petroleum Co Plc | Chemical process |
| US4744973A (en) * | 1985-11-29 | 1988-05-17 | Westinghouse Electric Corp. | Inorganic polymeric cationic ion exchange matrix |
| FR2668465B1 (fr) * | 1990-10-30 | 1993-04-16 | Inst Francais Du Petrole | Procede d'elimination de mercure ou d'arsenic dans un fluide en presence d'une masse de captation de mercure et/ou d'arsenic. |
| US5689032A (en) * | 1994-11-22 | 1997-11-18 | Krause/Pasadyn, A Partnership | Method and apparatus for recovery of H2 and C2 and heavier components |
| GB9607066D0 (en) * | 1996-04-03 | 1996-06-05 | Ici Plc | Purification process |
| GB0223300D0 (en) * | 2002-10-08 | 2002-11-13 | Bp Chem Int Ltd | Process |
-
2007
- 2007-08-16 TW TW096130340A patent/TWI414516B/zh active
- 2007-08-24 KR KR1020097004078A patent/KR101452529B1/ko active Active
- 2007-08-24 CN CN2007800317378A patent/CN101505866B/zh active Active
- 2007-08-24 US US12/438,436 patent/US8586815B2/en active Active
- 2007-08-24 EP EP07802844.6A patent/EP2056962B1/de active Active
- 2007-08-24 HU HUE07802844A patent/HUE029626T2/en unknown
- 2007-08-24 JP JP2009525074A patent/JP5591537B2/ja not_active Expired - Fee Related
- 2007-08-24 CA CA2660334A patent/CA2660334C/en not_active Expired - Fee Related
- 2007-08-24 WO PCT/EP2007/058792 patent/WO2008023051A1/de not_active Ceased
- 2007-08-24 ES ES07802844.6T patent/ES2564558T3/es active Active
- 2007-08-24 BR BRPI0715798A patent/BRPI0715798B1/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP2056962B1 (de) | 2016-01-27 |
| BRPI0715798B1 (pt) | 2016-12-06 |
| JP2010501529A (ja) | 2010-01-21 |
| JP5591537B2 (ja) | 2014-09-17 |
| HUE029626T2 (en) | 2017-03-28 |
| TW200815340A (en) | 2008-04-01 |
| WO2008023051A1 (de) | 2008-02-28 |
| US20100000911A1 (en) | 2010-01-07 |
| CA2660334A1 (en) | 2008-02-28 |
| KR101452529B1 (ko) | 2014-10-21 |
| US8586815B2 (en) | 2013-11-19 |
| CA2660334C (en) | 2014-07-15 |
| TWI414516B (zh) | 2013-11-11 |
| CN101505866A (zh) | 2009-08-12 |
| KR20090053799A (ko) | 2009-05-27 |
| EP2056962A1 (de) | 2009-05-13 |
| CN101505866B (zh) | 2013-05-15 |
| BRPI0715798A2 (pt) | 2013-07-16 |
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