ES2570353T3 - Método para la producción de espumas duras de poliuretano - Google Patents
Método para la producción de espumas duras de poliuretanoInfo
- Publication number
- ES2570353T3 ES2570353T3 ES12809181T ES12809181T ES2570353T3 ES 2570353 T3 ES2570353 T3 ES 2570353T3 ES 12809181 T ES12809181 T ES 12809181T ES 12809181 T ES12809181 T ES 12809181T ES 2570353 T3 ES2570353 T3 ES 2570353T3
- Authority
- ES
- Spain
- Prior art keywords
- molar
- dicarboxylic acids
- mol
- derivatives
- referred
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title abstract 2
- 229920005830 Polyurethane Foam Polymers 0.000 title 1
- 239000011496 polyurethane foam Substances 0.000 title 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 3
- -1 aromatic dicarboxylic acids Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 229920000570 polyether Polymers 0.000 abstract 3
- 229920005862 polyol Polymers 0.000 abstract 3
- 150000003077 polyols Chemical class 0.000 abstract 3
- 150000001991 dicarboxylic acids Chemical group 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 239000006260 foam Substances 0.000 abstract 2
- 229920005906 polyester polyol Polymers 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 239000012757 flame retardant agent Substances 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 229920000582 polyisocyanurate Polymers 0.000 abstract 1
- 239000011495 polyisocyanurate Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000003380 propellant Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
- C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4887—Polyethers containing carboxylic ester groups derived from carboxylic acids other than acids of higher fatty oils or other than resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Método para la producción de espumas duras de poliuretano o espumas duras de poliisocianurato que comprende la reacción de A) por lo menos un poliisocianato, B) por lo menos un poliol de polieteréster, obtenible mediante esterificación de b1) 10 a 70 % molar de una composición de ácidos dicarboxílicos, que contiene b11) 50 a 100 % molar, referido a la composición de ácidos dicarboxílicos, de uno o varios ácidos dicarboxílicos aromáticos o derivados de los mismos, b12) 0 a 50 % molar, referido a la composición de ácidos dicarboxílicos b1), de uno o varios ácidos dicarboxílicos alifáticos o derivados de los mismos, b2) 2 a 30 % molar de uno o varios ácidos grasos o derivados de ácidos grasos, b3) 10 a 70 % molar de uno o varios dioles alifáticos o cicloalifáticos con 2 a 18 átomos de C o alcoxilatos de los mismos, b4) 2 a 50 % molar de un poliol de poliéter con una funcionalidad mayor o igual a 2, producido mediante introducción de grupo alcoxilo en un poliol con una funcionalidad mayor a 2, referidos en cada caso la cantidad total de los componentes b1) a b4), en el que los componentes b1) a b4) suman 100 % molar, C) dado el caso otros polioles de poliéster, que se diferencian de los del componente B), D) polioles de poliéter, E) dado el caso agentes ignífugos, F) uno o varios agentes propelentes, G) catalizadores, y H) dado el caso otras sustancias auxiliares o aditivos, en la que la relación en masa de la suma de los componentes B) y dado el caso C) al componente D) es inferior a 1,6.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12151577 | 2012-01-18 | ||
| PCT/EP2012/075350 WO2013107573A1 (de) | 2012-01-18 | 2012-12-13 | Verfahren zur herstellung von polyurethan-hartschäumen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2570353T3 true ES2570353T3 (es) | 2016-05-18 |
Family
ID=47471745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES12809181T Active ES2570353T3 (es) | 2012-01-18 | 2012-12-13 | Método para la producción de espumas duras de poliuretano |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP2804886B1 (es) |
| JP (2) | JP6577189B2 (es) |
| KR (1) | KR102023224B1 (es) |
| CN (1) | CN104080827B (es) |
| AU (1) | AU2012366814B2 (es) |
| BR (1) | BR112014017049A8 (es) |
| CA (1) | CA2861351A1 (es) |
| ES (1) | ES2570353T3 (es) |
| MX (1) | MX339680B (es) |
| MY (1) | MY165909A (es) |
| PL (1) | PL2804886T3 (es) |
| RS (1) | RS54819B1 (es) |
| WO (1) | WO2013107573A1 (es) |
| ZA (1) | ZA201405897B (es) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2800769B1 (de) * | 2012-01-02 | 2015-12-09 | Basf Se | Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen |
| KR102023224B1 (ko) * | 2012-01-18 | 2019-09-19 | 바스프 에스이 | 경질 폴리우레탄 폼의 제조 방법 |
| US9475220B2 (en) | 2013-02-13 | 2016-10-25 | Basf Se | Process for producing composite elements |
| WO2017021439A1 (de) * | 2015-08-04 | 2017-02-09 | Covestro Deutschland Ag | Verfahren zur herstellung polyesterurethanweichschaumstoffen mit erhöhter stauchhärte |
| RU2018119341A (ru) * | 2015-10-28 | 2019-11-28 | Басф Се | Простые/сложные полиэфиры и их применение для получения жестких пенополиуретнов |
| EP3269748A1 (en) * | 2016-07-13 | 2018-01-17 | Basf Se | Process for producing rigid polymer foam |
| US10808070B2 (en) * | 2016-07-21 | 2020-10-20 | Covestro Deutschland Ag | High temperature-resistant polyisocyanurate foams |
| KR102791623B1 (ko) * | 2018-01-23 | 2025-04-03 | 스테판 컴파니 | 저 voc 폴리우레탄 용도의 폴리올 |
| KR102867102B1 (ko) * | 2018-08-16 | 2025-10-01 | 바스프 에스이 | 환경 친화적으로 유도된 폴리우레탄 분무 폼 시스템 |
| CN110218293B (zh) * | 2019-06-26 | 2021-07-23 | 山东宏鑫源钢板有限公司 | 铝镁锰聚氨酯屋面板及其制备工艺 |
| CN114072450B (zh) | 2019-06-28 | 2023-12-01 | 巴斯夫欧洲公司 | 多元醇组分及其用于制备硬质聚氨酯泡沫的用途 |
| CA3188780A1 (en) | 2020-06-25 | 2021-12-30 | Basf Se | Polyisocyanurate resin foam having high compressive strength, low thermal conductivity, and high surface quality |
| CN111808264A (zh) * | 2020-07-23 | 2020-10-23 | 长虹美菱股份有限公司 | 一种聚氨酯发泡原料 |
| CN112831040A (zh) * | 2020-12-31 | 2021-05-25 | 烟台市顺达聚氨酯有限责任公司 | 一种合成聚酯醚多元醇的方法 |
| PT4419574T (pt) | 2021-10-18 | 2025-10-24 | Basf Se | Processo para a produção de espumas rígidas de poliisocianurato melhoradas à base de poliois poliéster aromáticos e poliois poliéter à base de óxido de etileno |
| WO2023085797A1 (ko) | 2021-11-10 | 2023-05-19 | 이대수 | 알데히드 화합물 및 알데히드 화합물의 딜스-알더 반응물을 이용한 환경 친화적인 폴리우레탄 폼과 그 제조 방법 |
| KR20240107933A (ko) | 2022-12-30 | 2024-07-09 | 주식회사 씨엔에스파트너 | 폴리우레탄 스크랩 해중합물의 시프 염기를 이용한 반응성 폴리우레탄 발포제와 그 제조 방법 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1097671B (de) * | 1959-05-23 | 1961-01-19 | Bayer Ag | Verfahren zur Herstellung von Urethangruppen enthaltenden harten Schaumstoffen |
| US3399154A (en) * | 1965-10-22 | 1968-08-27 | Witco Chemical Corp | Rigid polyurethane foams and polyesters for use therein |
| DE4129285A1 (de) * | 1991-09-03 | 1993-03-04 | Bayer Ag | Verfahren zur herstellung von flammgeschuetzten, urethangruppen aufweisenden hartschaumstoffen |
| US9284401B2 (en) | 2006-11-13 | 2016-03-15 | Bayer Materialscience Llc | Process for the preparation of polyether-ester polyols |
| JP2010510339A (ja) * | 2006-11-17 | 2010-04-02 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリフェニレンポリメチレンポリイソシアネート及びポリウレタンフォームを製造するための、その使用方法 |
| ITMI20081480A1 (it) | 2008-08-06 | 2010-02-06 | Dow Global Technologies Inc | Poliesteri aromatici, miscele palioliche che li comprendono e prodotti risultanti |
| SI2340269T1 (sl) * | 2008-10-15 | 2013-01-31 | Basf Se | Poliesterski polioli na bazi terefthalične kisline |
| KR101699098B1 (ko) | 2009-04-09 | 2017-02-01 | 코베스트로 도이칠란드 아게 | 테레프탈산 및 올리고알킬 옥시드로부터의 폴리에스테르 폴리올 |
| EP2800769B1 (de) * | 2012-01-02 | 2015-12-09 | Basf Se | Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen |
| KR102023224B1 (ko) * | 2012-01-18 | 2019-09-19 | 바스프 에스이 | 경질 폴리우레탄 폼의 제조 방법 |
-
2012
- 2012-12-13 KR KR1020147022744A patent/KR102023224B1/ko active Active
- 2012-12-13 EP EP12809181.6A patent/EP2804886B1/de active Active
- 2012-12-13 MX MX2014008362A patent/MX339680B/es active IP Right Grant
- 2012-12-13 CN CN201280067337.3A patent/CN104080827B/zh active Active
- 2012-12-13 AU AU2012366814A patent/AU2012366814B2/en not_active Ceased
- 2012-12-13 CA CA2861351A patent/CA2861351A1/en not_active Abandoned
- 2012-12-13 BR BR112014017049A patent/BR112014017049A8/pt active Search and Examination
- 2012-12-13 MY MYPI2014002107A patent/MY165909A/en unknown
- 2012-12-13 RS RS20160376A patent/RS54819B1/sr unknown
- 2012-12-13 WO PCT/EP2012/075350 patent/WO2013107573A1/de not_active Ceased
- 2012-12-13 ES ES12809181T patent/ES2570353T3/es active Active
- 2012-12-13 JP JP2014552542A patent/JP6577189B2/ja not_active Expired - Fee Related
- 2012-12-13 PL PL12809181.6T patent/PL2804886T3/pl unknown
-
2014
- 2014-08-13 ZA ZA2014/05897A patent/ZA201405897B/en unknown
-
2017
- 2017-11-02 JP JP2017212668A patent/JP2018059111A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| MX2014008362A (es) | 2014-10-06 |
| CN104080827A (zh) | 2014-10-01 |
| PL2804886T3 (pl) | 2016-09-30 |
| BR112014017049A2 (pt) | 2017-06-13 |
| BR112014017049A8 (pt) | 2017-07-04 |
| KR102023224B1 (ko) | 2019-09-19 |
| JP2015505336A (ja) | 2015-02-19 |
| WO2013107573A1 (de) | 2013-07-25 |
| EP2804886B1 (de) | 2016-03-16 |
| CN104080827B (zh) | 2016-04-27 |
| MX339680B (es) | 2016-06-03 |
| JP2018059111A (ja) | 2018-04-12 |
| EP2804886A1 (de) | 2014-11-26 |
| AU2012366814B2 (en) | 2016-03-10 |
| AU2012366814A1 (en) | 2014-08-07 |
| JP6577189B2 (ja) | 2019-09-18 |
| CA2861351A1 (en) | 2013-07-25 |
| ZA201405897B (en) | 2017-04-26 |
| KR20140119120A (ko) | 2014-10-08 |
| RS54819B1 (sr) | 2016-10-31 |
| MY165909A (en) | 2018-05-18 |
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