ES2701529T3 - Derivados de difosfito de 3-fenil-benzofuran-2-ona como estabilizadores - Google Patents

Derivados de difosfito de 3-fenil-benzofuran-2-ona como estabilizadores Download PDF

Info

Publication number: ES2701529T3
Authority: ES; Spain
Prior art keywords: alkyl; component; compound; formula; hydrogen
Prior art date: 2014-08-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

ES15744942T

Other languages

English (en)

Spanish (es)

Inventor

Werner Hoelzl

Bruno Rotzinger

Kai-Uwe Schoening

Iii Rick King

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2014-08-05

Filing date

2015-08-03

Publication date

2019-02-22

2015-08-03 Application filed by BASF SE filed Critical BASF SE

2019-02-22 Application granted granted Critical

2019-02-22 Publication of ES2701529T3 publication Critical patent/ES2701529T3/es

Status Active legal-status Critical Current

2035-08-03 Anticipated expiration legal-status Critical

Links

239000003381 stabilizer Substances 0.000 title description 20
YMFIUXNOXADSQY-UHFFFAOYSA-N OP(O)OP(O)O.C1(=CC=CC=C1)C1C(OC2=C1C=CC=C2)=O Chemical class OP(O)OP(O)O.C1(=CC=CC=C1)C1C(OC2=C1C=CC=C2)=O YMFIUXNOXADSQY-UHFFFAOYSA-N 0.000 title description 2
150000001875 compounds Chemical class 0.000 claims abstract description 177
239000000203 mixture Substances 0.000 claims abstract description 120
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 119
239000001257 hydrogen Substances 0.000 claims abstract description 118
-1 RO2 Chemical compound 0.000 claims abstract description 113
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 106
125000000217 alkyl group Chemical group 0.000 claims abstract description 78
239000011368 organic material Substances 0.000 claims abstract description 49
230000015556 catabolic process Effects 0.000 claims abstract description 43
238000006731 degradation reaction Methods 0.000 claims abstract description 43
230000001590 oxidative effect Effects 0.000 claims abstract description 41
239000000654 additive Substances 0.000 claims description 86
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230000000996 additive effect Effects 0.000 claims description 82
229910052698 phosphorus Inorganic materials 0.000 claims description 75
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239000002530 phenolic antioxidant Substances 0.000 claims description 45
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 25
238000000034 method Methods 0.000 claims description 22
230000008569 process Effects 0.000 claims description 20
150000001412 amines Chemical class 0.000 claims description 19
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OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 4
150000002118 epoxides Chemical class 0.000 claims 1
QRBIFAKBTSNLCS-ZTFBILFISA-N (3s,4as,8as)-n-tert-butyl-2-[(2r,3s)-2-hydroxy-3-[[(2r)-3-methyl-3-methylsulfonyl-2-[(2-pyridin-3-yloxyacetyl)amino]butanoyl]amino]-4-phenylbutyl]-3,4,4a,5,6,7,8,8a-octahydro-1h-isoquinoline-3-carboxamide Chemical compound C([C@@H]([C@H](O)CN1C[C@H]2CCCC[C@H]2C[C@H]1C(=O)NC(C)(C)C)NC(=O)[C@@H](NC(=O)COC=1C=NC=CC=1)C(C)(C)S(C)(=O)=O)C1=CC=CC=C1 QRBIFAKBTSNLCS-ZTFBILFISA-N 0.000 abstract description 14
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125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 3
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238000000465 moulding Methods 0.000 description 13
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239000004698 Polyethylene Substances 0.000 description 8
239000000010 aprotic solvent Substances 0.000 description 8
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238000010128 melt processing Methods 0.000 description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
YXFVVABEGXRONW-JGUCLWPXSA-N toluene-d8 Chemical compound [2H]C1=C([2H])C([2H])=C(C([2H])([2H])[2H])C([2H])=C1[2H] YXFVVABEGXRONW-JGUCLWPXSA-N 0.000 description 8
JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 7
150000001252 acrylic acid derivatives Chemical class 0.000 description 7
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125000003118 aryl group Chemical group 0.000 description 7
150000001993 dienes Chemical class 0.000 description 7
125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
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229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 7
239000000126 substance Substances 0.000 description 7
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
239000004594 Masterbatch (MB) Substances 0.000 description 6
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
239000003054 catalyst Substances 0.000 description 6
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239000001301 oxygen Substances 0.000 description 6
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PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
238000005481 NMR spectroscopy Methods 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 5
239000006096 absorbing agent Substances 0.000 description 5
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239000012964 benzotriazole Substances 0.000 description 5
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XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 5
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125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 5
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239000011701 zinc Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1
GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/527—Cyclic esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/529—Esters containing heterocyclic rings not representing cyclic esters of phosphoric or phosphorous acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/32—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal
- C09K15/322—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal containing only phosphorus
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
- C07F9/65517—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring condensed with carbocyclic rings or carbocyclic ring systems

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Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Biochemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Compositions Of Macromolecular Compounds (AREA)
Anti-Oxidant Or Stabilizer Compositions (AREA)

ES15744942T 2014-08-05 2015-08-03 Derivados de difosfito de 3-fenil-benzofuran-2-ona como estabilizadores Active ES2701529T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP14179922		2014-08-05
PCT/EP2015/067808 WO2016020322A1 (en)	2014-08-05	2015-08-03	3-phenyl-benzofuran-2-one diphosphite derivatives as stabilizers

Publications (1)

Publication Number	Publication Date
ES2701529T3 true ES2701529T3 (es)	2019-02-22

Family

ID=51300556

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES15744942T Active ES2701529T3 (es)	2014-08-05	2015-08-03	Derivados de difosfito de 3-fenil-benzofuran-2-ona como estabilizadores

Country Status (15)

Country	Link
US (1)	US10072136B2 (pl)
EP (1)	EP3177681B1 (pl)
JP (1)	JP6559224B2 (pl)
KR (1)	KR102377818B1 (pl)
CN (1)	CN106574090B (pl)
AU (1)	AU2015299175B2 (pl)
BR (1)	BR112017002203B1 (pl)
CA (1)	CA2955260C (pl)
ES (1)	ES2701529T3 (pl)
MX (1)	MX375961B (pl)
PL (1)	PL3177681T3 (pl)
RU (1)	RU2700027C2 (pl)
SA (1)	SA517380827B1 (pl)
TW (1)	TWI659992B (pl)
WO (1)	WO2016020322A1 (pl)

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2015
- 2015-08-03 CA CA2955260A patent/CA2955260C/en active Active
- 2015-08-03 PL PL15744942T patent/PL3177681T3/pl unknown
- 2015-08-03 BR BR112017002203-6A patent/BR112017002203B1/pt not_active IP Right Cessation
- 2015-08-03 EP EP15744942.2A patent/EP3177681B1/en active Active
- 2015-08-03 JP JP2017506341A patent/JP6559224B2/ja active Active
- 2015-08-03 ES ES15744942T patent/ES2701529T3/es active Active
- 2015-08-03 RU RU2017107097A patent/RU2700027C2/ru active
- 2015-08-03 MX MX2017001645A patent/MX375961B/es active IP Right Grant
- 2015-08-03 US US15/501,655 patent/US10072136B2/en active Active
- 2015-08-03 AU AU2015299175A patent/AU2015299175B2/en not_active Ceased
- 2015-08-03 KR KR1020177002790A patent/KR102377818B1/ko active Active
- 2015-08-03 WO PCT/EP2015/067808 patent/WO2016020322A1/en not_active Ceased
- 2015-08-03 CN CN201580041057.9A patent/CN106574090B/zh active Active
- 2015-08-05 TW TW104125460A patent/TWI659992B/zh not_active IP Right Cessation
2017
- 2017-02-01 SA SA517380827A patent/SA517380827B1/ar unknown

Also Published As

Publication number	Publication date
BR112017002203B1 (pt)	2021-10-26
WO2016020322A1 (en)	2016-02-11
EP3177681B1 (en)	2018-09-12
TWI659992B (zh)	2019-05-21
EP3177681A1 (en)	2017-06-14
JP6559224B2 (ja)	2019-08-14
RU2017107097A (ru)	2018-09-06
CN106574090A (zh)	2017-04-19
JP2017531701A (ja)	2017-10-26
SA517380827B1 (ar)	2020-06-04
MX375961B (es)	2025-03-07
AU2015299175B2 (en)	2018-12-20
MX2017001645A (es)	2017-05-09
CA2955260A1 (en)	2016-02-11
RU2700027C2 (ru)	2019-09-12
KR102377818B1 (ko)	2022-03-24
AU2015299175A1 (en)	2017-02-16
TW201612223A (en)	2016-04-01
BR112017002203A2 (pt)	2018-01-16
CA2955260C (en)	2022-06-28
CN106574090B (zh)	2019-11-19
KR20170039165A (ko)	2017-04-10
US10072136B2 (en)	2018-09-11
RU2017107097A3 (pl)	2019-02-19
PL3177681T3 (pl)	2019-02-28
US20170226323A1 (en)	2017-08-10

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ES2860806T3 (es)	2021-10-05	Derivados de 3-fenil-benzofuran-2-ona que contienen fósforo como estabilizantes
ES2814128T3 (es)	2021-03-26	Derivados de 3-fenil-benzofuran-2-ona que contienen fósforo como estabilizadores
AU2015299175B2 (en)	2018-12-20	3-phenyl-benzofuran-2-one diphosphite derivatives as stabilizers
ES2715646T3 (es)	2019-06-05	Estabilizantes contra la luz, de amina impedida a base de triazina, piperidina y pirrolidina
JP7443260B2 (ja)	2024-03-05	安定剤としての３－フェニル－ベンゾフラン－２－オンジホスフェート誘導体
EP2872496B1 (en)	2018-02-28	Polyglycol bis-[3-(7-tert-butyl-2-oxo-3-phenyl-3h-benzofuran-5-yl-)propanoyl]derivatives as stabilizers of organic material
KR102074740B1 (ko)	2020-02-10	유기 물질의 안정화를 위한 이소인돌로[2,1-a]퀴나졸린 유도체
KR20140027356A (ko)	2014-03-06	유기 물질의 안정화를 위한 5h-푸란-2-온 유도체