ES473535A1 - Procedimiento para deshalogenar aminas aromaticas halogena- das. - Google Patents
Procedimiento para deshalogenar aminas aromaticas halogena- das.Info
- Publication number
- ES473535A1 ES473535A1 ES473535A ES473535A ES473535A1 ES 473535 A1 ES473535 A1 ES 473535A1 ES 473535 A ES473535 A ES 473535A ES 473535 A ES473535 A ES 473535A ES 473535 A1 ES473535 A1 ES 473535A1
- Authority
- ES
- Spain
- Prior art keywords
- dehalogenation
- catalyst
- aromatic compounds
- halogenated aromatic
- action
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005695 dehalogenation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000001491 aromatic compounds Chemical class 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000004982 aromatic amines Chemical class 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8926—Copper and noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Procedimiento para deshalogenar aminas aromáticas halogenadas que conduce a la obtención preferente de derivados que llevan menor número de átomos de halógeno, al menos uno de los cuales está situado en posición meta respecto a la agrupación amino, en fase vapor, por acción de hidrógeno en presencia de un catalizador de hidrogenación de acción acondicionada, a una temperatura comprendidas entre 280 y 420ºC, caracterizado porque la fase activa del catalizador contiene, además del metal catalizador principal, una cantidad secundaria de un catalizador auxiliar de hidrogenación constituido por otro metal diferente del primero.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7729399A FR2403990A1 (fr) | 1977-09-22 | 1977-09-22 | Procede de deshalogenation d'amines aromatiques halogenees |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES473535A1 true ES473535A1 (es) | 1979-05-16 |
Family
ID=9195931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES473535A Expired ES473535A1 (es) | 1977-09-22 | 1978-09-21 | Procedimiento para deshalogenar aminas aromaticas halogena- das. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4206147A (es) |
| EP (1) | EP0001372B1 (es) |
| JP (1) | JPS5846499B2 (es) |
| AT (1) | AT360504B (es) |
| BR (1) | BR7806120A (es) |
| CA (1) | CA1130775A (es) |
| DD (1) | DD138974A5 (es) |
| DE (1) | DE2860202D1 (es) |
| DK (1) | DK419378A (es) |
| ES (1) | ES473535A1 (es) |
| FR (1) | FR2403990A1 (es) |
| GB (1) | GB2007668A (es) |
| HU (1) | HU178079B (es) |
| IE (1) | IE47477B1 (es) |
| IL (1) | IL55618A (es) |
| IT (1) | IT1099500B (es) |
| SU (1) | SU942583A3 (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2449077A2 (fr) * | 1979-02-15 | 1980-09-12 | Rhone Poulenc Agrochimie | Procede de preparation d'anilines metachlorees |
| FR2487824A1 (fr) * | 1980-08-01 | 1982-02-05 | Rhone Poulenc Agrochimie | Procede de preparation selective d'anilines metachlorees |
| DE3104643A1 (de) * | 1981-02-10 | 1982-08-19 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von gegebenenfalls p-chlorsubstituiertem 2,6-diaminotoluol |
| DE3127026A1 (de) * | 1981-07-09 | 1983-01-20 | Bayer Ag, 5090 Leverkusen | Verrfahren zur herstellung von m-chlorsubstituiertenanilinen |
| FR2521132A1 (fr) * | 1982-02-05 | 1983-08-12 | Rhone Poulenc Agrochimie | Procede de preparation de metahalogeno-anilines |
| GB2118542B (en) * | 1982-02-18 | 1985-12-04 | Mitsui Toatsu Chemicals | Process for preparing of 3,3'-diamino diphenylsulfones |
| FR2532305A1 (fr) * | 1982-08-24 | 1984-03-02 | Rhone Poulenc Agrochimie | Procede de preparation d'anilines metachlorees |
| JPH0565250A (ja) * | 1991-01-28 | 1993-03-19 | Ishihara Sangyo Kaisha Ltd | 3,5−ジフルオロアニリンの製造方法 |
| US5089653A (en) * | 1991-04-04 | 1992-02-18 | Dow Elanco | Process for the selective reduction of the 4-halogen in 2,4-dihaloanilines |
| JPH05220565A (ja) * | 1992-02-13 | 1993-08-31 | Sansha Electric Mfg Co Ltd | 融解金属注入装置 |
| DE19911865A1 (de) * | 1999-03-17 | 2000-09-28 | Degussa | Verfahren zur katalytischen Hydrierung von Dinitrotoluol sowie Katalysator |
| RU2214864C1 (ru) * | 2002-07-22 | 2003-10-27 | Институт катализа им. Г.К. Борескова СО РАН | Катализатор и способ гидродехлорирования хлорароматических соединений |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3148217A (en) * | 1961-11-16 | 1964-09-08 | Gen Aniline & Film Corp | Catalytic hydrogenation of halonitrobenzene compounds |
| US3839193A (en) * | 1970-04-10 | 1974-10-01 | Universal Oil Prod Co | Hydrocarbon conversion with a trimetallic catalytic composite |
| BE792080A (fr) * | 1971-11-30 | 1973-05-29 | Rhone Progil | Procede de deshalogenation de composes aromatiques polyhalogenes |
| US3867312A (en) * | 1972-02-07 | 1975-02-18 | Ethyl Corp | Exhaust gas catalyst support |
| DE2344926C3 (de) * | 1973-09-06 | 1981-05-07 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von 3-Halogen- bzw. 3,5-Dihalogen-phenolen |
| US3912783A (en) * | 1972-12-05 | 1975-10-14 | Bayer Ag | Process and catalyst for preparing of 3-halogen-and 3,5-dihalogen-phenols |
| GB1458633A (en) * | 1974-09-17 | 1976-12-15 | Ici Ltd | Process for dehalogenating aromatic compounds |
| DE2503187C3 (de) * | 1975-01-27 | 1979-05-31 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung durch Chlor meta-substituierte Aniline |
| FR2334415A1 (fr) * | 1975-12-08 | 1977-07-08 | Raffinage Cie Francaise | Nouveaux catalyseurs, leur procede de preparation et leur application a la transformation de charges d'hydrocarbures |
-
1977
- 1977-09-22 FR FR7729399A patent/FR2403990A1/fr active Granted
-
1978
- 1978-09-12 US US05/941,843 patent/US4206147A/en not_active Expired - Lifetime
- 1978-09-19 DD DD78207927A patent/DD138974A5/xx unknown
- 1978-09-19 BR BR7806120A patent/BR7806120A/pt unknown
- 1978-09-20 EP EP78420009A patent/EP0001372B1/fr not_active Expired
- 1978-09-20 DE DE7878420009T patent/DE2860202D1/de not_active Expired
- 1978-09-21 IL IL55618A patent/IL55618A/xx unknown
- 1978-09-21 AT AT683978A patent/AT360504B/de not_active IP Right Cessation
- 1978-09-21 DK DK419378A patent/DK419378A/da not_active Application Discontinuation
- 1978-09-21 JP JP53116457A patent/JPS5846499B2/ja not_active Expired
- 1978-09-21 HU HU78PI641A patent/HU178079B/hu unknown
- 1978-09-21 IE IE1902/78A patent/IE47477B1/en unknown
- 1978-09-21 CA CA311,824A patent/CA1130775A/en not_active Expired
- 1978-09-21 GB GB7837654A patent/GB2007668A/en not_active Withdrawn
- 1978-09-21 ES ES473535A patent/ES473535A1/es not_active Expired
- 1978-09-22 IT IT28006/78A patent/IT1099500B/it active
- 1978-09-22 SU SU782668604A patent/SU942583A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| IE47477B1 (en) | 1984-03-21 |
| EP0001372B1 (fr) | 1980-10-01 |
| BR7806120A (pt) | 1979-05-02 |
| AT360504B (de) | 1981-01-12 |
| SU942583A3 (ru) | 1982-07-07 |
| US4206147A (en) | 1980-06-03 |
| CA1130775A (en) | 1982-08-31 |
| IE781902L (en) | 1979-03-22 |
| EP0001372A2 (fr) | 1979-04-04 |
| IT1099500B (it) | 1985-09-18 |
| FR2403990B1 (es) | 1983-01-21 |
| ATA683978A (de) | 1980-06-15 |
| IL55618A (en) | 1982-02-28 |
| JPS5463030A (en) | 1979-05-21 |
| DE2860202D1 (en) | 1981-01-08 |
| IL55618A0 (en) | 1978-12-17 |
| HU178079B (en) | 1982-02-28 |
| EP0001372A3 (en) | 1979-04-18 |
| IT7828006A0 (it) | 1978-09-22 |
| FR2403990A1 (fr) | 1979-04-20 |
| DD138974A5 (de) | 1979-12-05 |
| JPS5846499B2 (ja) | 1983-10-17 |
| DK419378A (da) | 1979-03-23 |
| GB2007668A (en) | 1979-05-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FD1A | Patent lapsed |
Effective date: 19971103 |