FI63263C - Elektroplaederingsloesning innehaollande trivalent krom i laogkoncentration - Google Patents
Elektroplaederingsloesning innehaollande trivalent krom i laogkoncentration Download PDFInfo
- Publication number
- FI63263C FI63263C FI793514A FI793514A FI63263C FI 63263 C FI63263 C FI 63263C FI 793514 A FI793514 A FI 793514A FI 793514 A FI793514 A FI 793514A FI 63263 C FI63263 C FI 63263C
- Authority
- FI
- Finland
- Prior art keywords
- chromium
- solution
- plating
- content
- layer
- Prior art date
Links
- 239000011651 chromium Substances 0.000 claims description 110
- 229910052804 chromium Inorganic materials 0.000 claims description 106
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 104
- 239000000243 solution Substances 0.000 claims description 67
- 238000009713 electroplating Methods 0.000 claims description 13
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 12
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 12
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 10
- 235000003704 aspartic acid Nutrition 0.000 claims description 10
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 10
- 235000001014 amino acid Nutrition 0.000 claims description 6
- 150000001413 amino acids Chemical class 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- YRTKBCIAQCXVCM-UHFFFAOYSA-K chromium(3+);trithiocyanate Chemical compound [Cr+3].[S-]C#N.[S-]C#N.[S-]C#N YRTKBCIAQCXVCM-UHFFFAOYSA-K 0.000 claims description 5
- 239000006172 buffering agent Substances 0.000 claims description 3
- 239000003446 ligand Substances 0.000 claims 1
- 238000007747 plating Methods 0.000 description 40
- 238000000034 method Methods 0.000 description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000002310 reflectometry Methods 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 5
- 229940024606 amino acid Drugs 0.000 description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 5
- 239000004327 boric acid Substances 0.000 description 5
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 3
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- CKLJMWTZIZZHCS-UHFFFAOYSA-N Aspartic acid Chemical compound OC(=O)C(N)CC(O)=O CKLJMWTZIZZHCS-UHFFFAOYSA-N 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000010951 brass Substances 0.000 description 2
- 150000001844 chromium Chemical class 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 1
- 101100373490 Enterobacteria phage T4 y06C gene Proteins 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229960001230 asparagine Drugs 0.000 description 1
- 235000009582 asparagine Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- BFGKITSFLPAWGI-UHFFFAOYSA-N chromium(3+) Chemical compound [Cr+3] BFGKITSFLPAWGI-UHFFFAOYSA-N 0.000 description 1
- IAQWMWUKBQPOIY-UHFFFAOYSA-N chromium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Cr+4] IAQWMWUKBQPOIY-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- ZVCDLGYNFYZZOK-UHFFFAOYSA-M sodium cyanate Chemical compound [Na]OC#N ZVCDLGYNFYZZOK-UHFFFAOYSA-M 0.000 description 1
- RROSXLCQOOGZBR-UHFFFAOYSA-N sodium;isothiocyanate Chemical compound [Na+].[N-]=C=S RROSXLCQOOGZBR-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- 239000011593 sulfur Chemical group 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
- C25D3/06—Electroplating: Baths therefor from solutions of chromium from solutions of trivalent chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/605—Surface topography of the layers, e.g. rough, dendritic or nodular layers
- C25D5/611—Smooth layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Paints Or Removers (AREA)
- External Artificial Organs (AREA)
- Chemically Coating (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI824259A FI65286C (fi) | 1978-11-11 | 1982-12-10 | Elektroplaeteringsfoerfarande vari anvaends trivalent krom i laog koncentration |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7844177 | 1978-11-11 | ||
| GB7844177A GB2033427B (en) | 1978-11-11 | 1978-11-11 | Chromium electroplating |
| GB7932300 | 1979-09-18 | ||
| GB7932300A GB2038361B (en) | 1978-11-11 | 1979-09-18 | Trivalent chromium plating bath |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI793514A7 FI793514A7 (fi) | 1980-05-12 |
| FI63263B FI63263B (fi) | 1983-01-31 |
| FI63263C true FI63263C (fi) | 1983-05-10 |
Family
ID=26269549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI793514A FI63263C (fi) | 1978-11-11 | 1979-11-09 | Elektroplaederingsloesning innehaollande trivalent krom i laogkoncentration |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4278512A (no) |
| AR (1) | AR222694A1 (no) |
| BR (1) | BR7907324A (no) |
| CA (1) | CA1150185A (no) |
| CH (1) | CH644157A5 (no) |
| DK (1) | DK151975C (no) |
| ES (1) | ES485756A1 (no) |
| FI (1) | FI63263C (no) |
| FR (1) | FR2441003A1 (no) |
| GB (1) | GB2038361B (no) |
| MX (1) | MX153195A (no) |
| NO (1) | NO151473C (no) |
| SE (1) | SE429981B (no) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2093861B (en) * | 1981-02-09 | 1984-08-22 | Canning Materials W Ltd | Bath for electrodeposition of chromium |
| GB2110242B (en) * | 1981-11-18 | 1985-06-12 | Ibm | Electroplating chromium |
| GB2109816B (en) * | 1981-11-18 | 1985-01-23 | Ibm | Electrodeposition of chromium |
| GB2109815B (en) * | 1981-11-18 | 1985-09-04 | Ibm | Electrodepositing chromium |
| GB2109817B (en) * | 1981-11-18 | 1985-07-03 | Ibm | Electrodeposition of chromium |
| ATE33686T1 (de) * | 1982-02-09 | 1988-05-15 | Ibm | Elektrolytische abscheidung von chrom und seinen legierungen. |
| FR2529581A1 (fr) * | 1982-06-30 | 1984-01-06 | Armines | Bain d'electrolyse a base de chrome trivalent |
| CH665656A5 (fr) * | 1983-12-29 | 1988-05-31 | Heinz Emmenegger | Bain d'or acide et utilisation de ce bain en electroplastie. |
| US5294326A (en) * | 1991-12-30 | 1994-03-15 | Elf Atochem North America, Inc. | Functional plating from solutions containing trivalent chromium ion |
| JP2000017482A (ja) * | 1998-06-26 | 2000-01-18 | Nippon Piston Ring Co Ltd | 耐摩耗性、疲労強度に優れた積層構造を有するクロムめっき皮膜 |
| CN101638801A (zh) * | 2008-07-30 | 2010-02-03 | 深圳富泰宏精密工业有限公司 | 壳体的表面处理方法 |
| US8273235B2 (en) * | 2010-11-05 | 2012-09-25 | Roshan V Chapaneri | Dark colored chromium based electrodeposits |
| US8512541B2 (en) | 2010-11-16 | 2013-08-20 | Trevor Pearson | Electrolytic dissolution of chromium from chromium electrodes |
| EP2705176B1 (en) | 2011-05-03 | 2016-04-13 | ATOTECH Deutschland GmbH | Electroplating bath and method for producing dark chromium layers |
| DE102012008544A1 (de) | 2012-05-02 | 2013-11-07 | Umicore Galvanotechnik Gmbh | Verchromte Verbundwerkstoffe ohne Nickelschicht |
| EP3147388A1 (en) * | 2015-09-25 | 2017-03-29 | Enthone, Incorporated | Flexible color adjustment for dark cr(iii)-platings |
| KR20200052588A (ko) | 2018-11-07 | 2020-05-15 | 윤종오 | 3가 크롬 합금 도금액, Cr-Ti-Au 합금 도금액, Cr-Ti-Ni 합금 도금액, Cr-Ti-Co 합금 도금액 및 도금 제품 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1431639A (en) * | 1974-12-11 | 1976-04-14 | Ibm Uk | Electroplating chromium and its alloys |
| US4062737A (en) * | 1974-12-11 | 1977-12-13 | International Business Machines Corporation | Electrodeposition of chromium |
| US4141803A (en) * | 1975-12-03 | 1979-02-27 | International Business Machines Corporation | Method and composition for electroplating chromium and its alloys and the method of manufacture of the composition |
| US4161432A (en) * | 1975-12-03 | 1979-07-17 | International Business Machines Corporation | Electroplating chromium and its alloys |
| GB1596995A (en) * | 1977-06-14 | 1981-09-03 | Ibm | Electroplating chromium and its alloys |
-
1979
- 1979-09-18 GB GB7932300A patent/GB2038361B/en not_active Expired
- 1979-10-18 US US06/086,092 patent/US4278512A/en not_active Expired - Lifetime
- 1979-10-26 CH CH962279A patent/CH644157A5/de not_active IP Right Cessation
- 1979-10-30 FR FR7927385A patent/FR2441003A1/fr active Granted
- 1979-11-07 ES ES485756A patent/ES485756A1/es not_active Expired
- 1979-11-08 SE SE7909250A patent/SE429981B/sv not_active IP Right Cessation
- 1979-11-09 DK DK475879A patent/DK151975C/da active
- 1979-11-09 FI FI793514A patent/FI63263C/fi not_active IP Right Cessation
- 1979-11-09 MX MX179977A patent/MX153195A/es unknown
- 1979-11-09 NO NO793615A patent/NO151473C/no unknown
- 1979-11-12 BR BR7907324A patent/BR7907324A/pt not_active IP Right Cessation
- 1979-11-13 CA CA000339759A patent/CA1150185A/en not_active Expired
-
1980
- 1980-03-14 AR AR280309A patent/AR222694A1/es active
Also Published As
| Publication number | Publication date |
|---|---|
| DK151975C (da) | 1988-06-06 |
| BR7907324A (pt) | 1980-07-15 |
| FR2441003B1 (no) | 1982-12-03 |
| GB2038361A (en) | 1980-07-23 |
| NO151473C (no) | 1985-04-17 |
| SE7909250L (sv) | 1980-05-12 |
| GB2038361B (en) | 1983-08-17 |
| FR2441003A1 (fr) | 1980-06-06 |
| ES485756A1 (es) | 1980-07-01 |
| SE429981B (sv) | 1983-10-10 |
| AR222694A1 (es) | 1981-06-15 |
| DK151975B (da) | 1988-01-18 |
| FI793514A7 (fi) | 1980-05-12 |
| DK475879A (da) | 1980-05-12 |
| NO151473B (no) | 1985-01-02 |
| NO793615L (no) | 1980-05-13 |
| MX153195A (es) | 1986-08-21 |
| US4278512A (en) | 1981-07-14 |
| CA1150185A (en) | 1983-07-19 |
| CH644157A5 (de) | 1984-07-13 |
| FI63263B (fi) | 1983-01-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: INTERNATIONAL BUSINESS MACHINES |