FI63427C - Stabil latex bildad av en kopolymer av en monomerblandning ochdess anvaendning som bindemedel i pappersbelaeggningsblan dnngar - Google Patents

Stabil latex bildad av en kopolymer av en monomerblandning ochdess anvaendning som bindemedel i pappersbelaeggningsblan dnngar Download PDF

Info

Publication number: FI63427C
Authority: FI; Finland
Prior art keywords: latex; acid; beta; parts; sample
Prior art date: 1976-05-03

Application number

FI771354A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI771354A7 (fr

FI63427B (fi

Inventor

John Hen

Original Assignee

Uniroyal Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-05-03

Filing date

1977-04-28

Publication date

1983-06-10

1977-04-28 Application filed by Uniroyal Inc filed Critical Uniroyal Inc

1977-11-04 Publication of FI771354A7 publication Critical patent/FI771354A7/fi

1983-02-28 Application granted granted Critical

1983-02-28 Publication of FI63427B publication Critical patent/FI63427B/fi

1983-06-10 Publication of FI63427C publication Critical patent/FI63427C/fi

Links

239000004816 latex Substances 0.000 title claims description 85
229920000126 latex Polymers 0.000 claims description 87
239000000203 mixture Substances 0.000 claims description 36
239000000178 monomer Substances 0.000 claims description 25
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 24
239000011230 binding agent Substances 0.000 claims description 20
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 19
239000008199 coating composition Substances 0.000 claims description 13
239000000049 pigment Substances 0.000 claims description 10
229920001577 copolymer Polymers 0.000 claims description 9
UBARWEBNHKQFNN-UHFFFAOYSA-N 3-prop-2-enoylperoxypropanoic acid Chemical compound OC(=O)CCOOC(=O)C=C UBARWEBNHKQFNN-UHFFFAOYSA-N 0.000 claims description 6
MAIIXYUYRNFKPL-UPHRSURJSA-N (z)-4-(2-hydroxyethoxy)-4-oxobut-2-enoic acid Chemical compound OCCOC(=O)\C=C/C(O)=O MAIIXYUYRNFKPL-UPHRSURJSA-N 0.000 claims description 4
LBNDGEZENJUBCO-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethyl]butanedioic acid Chemical compound CC(=C)C(=O)OCCC(C(O)=O)CC(O)=O LBNDGEZENJUBCO-UHFFFAOYSA-N 0.000 claims description 3
125000001931 aliphatic group Chemical group 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims description 3
150000001993 dienes Chemical class 0.000 claims description 3
IEQWWMKDFZUMMU-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethyl)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)CCOC(=O)C=C IEQWWMKDFZUMMU-UHFFFAOYSA-N 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
229910052739 hydrogen Inorganic materials 0.000 claims description 2
239000001257 hydrogen Substances 0.000 claims description 2
229910014033 C-OH Inorganic materials 0.000 claims 1
229910014570 C—OH Inorganic materials 0.000 claims 1
125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
239000011248 coating agent Substances 0.000 description 30
238000000576 coating method Methods 0.000 description 30
239000000123 paper Substances 0.000 description 28
239000011575 calcium Substances 0.000 description 15
239000007787 solid Substances 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
239000002253 acid Substances 0.000 description 10
CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 8
238000007720 emulsion polymerization reaction Methods 0.000 description 8
229920002472 Starch Polymers 0.000 description 7
239000002174 Styrene-butadiene Substances 0.000 description 7
239000000975 dye Substances 0.000 description 7
239000000976 ink Substances 0.000 description 7
239000008107 starch Substances 0.000 description 7
235000019698 starch Nutrition 0.000 description 7
229920003048 styrene butadiene rubber Polymers 0.000 description 7
238000012360 testing method Methods 0.000 description 7
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
239000000853 adhesive Substances 0.000 description 6
230000001070 adhesive effect Effects 0.000 description 6
-1 alkyl radical Chemical class 0.000 description 6
239000000126 substance Substances 0.000 description 6
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 6
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 4
230000000694 effects Effects 0.000 description 4
239000003995 emulsifying agent Substances 0.000 description 4
238000000034 method Methods 0.000 description 4
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 4
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
239000003973 paint Substances 0.000 description 3
239000011087 paperboard Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
235000017557 sodium bicarbonate Nutrition 0.000 description 3
229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
NCLKWKSYWOTWBN-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)-3-propanoyloxypropanoic acid Chemical compound CCC(=O)OC(CC(O)=O)OC(=O)C(C)=C NCLKWKSYWOTWBN-UHFFFAOYSA-N 0.000 description 2
UASPDHZXGLMLML-UHFFFAOYSA-N 3-propanoyloxy-3-prop-2-enoyloxypropanoic acid Chemical compound CCC(=O)OC(CC(O)=O)OC(=O)C=C UASPDHZXGLMLML-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
239000004159 Potassium persulphate Substances 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
239000012736 aqueous medium Substances 0.000 description 2
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
DIYQYKWRIDJJNQ-UHFFFAOYSA-N carboxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOC(=O)O DIYQYKWRIDJJNQ-UHFFFAOYSA-N 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
239000004927 clay Substances 0.000 description 2
230000015271 coagulation Effects 0.000 description 2
238000005345 coagulation Methods 0.000 description 2
239000000839 emulsion Substances 0.000 description 2
235000019394 potassium persulphate Nutrition 0.000 description 2
150000003254 radicals Chemical class 0.000 description 2
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 2
238000013112 stability test Methods 0.000 description 2
239000011115 styrene butadiene Substances 0.000 description 2
150000003440 styrenes Chemical class 0.000 description 2
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
239000002562 thickening agent Substances 0.000 description 2
ZWKNLRXFUTWSOY-QPJJXVBHSA-N (e)-3-phenylprop-2-enenitrile Chemical compound N#C\C=C\C1=CC=CC=C1 ZWKNLRXFUTWSOY-QPJJXVBHSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
KJBVWWUEAMETAY-UHFFFAOYSA-N 3-(2-methylprop-2-enoylperoxy)butanoic acid Chemical compound C(C(=C)C)(=O)OOC(CC(=O)O)C KJBVWWUEAMETAY-UHFFFAOYSA-N 0.000 description 1
CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 description 1
239000005995 Aluminium silicate Substances 0.000 description 1
QIZGVLUFZSWIHY-UHFFFAOYSA-N C(C)(=O)C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 Chemical compound C(C)(=O)C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 QIZGVLUFZSWIHY-UHFFFAOYSA-N 0.000 description 1
MAIQXAJWHBSIFX-UHFFFAOYSA-N C(C=C)(=O)OC(C(=O)O)C.C(CC)(=O)O.C(C=C)(=O)OCC(=O)O Chemical compound C(C=C)(=O)OC(C(=O)O)C.C(CC)(=O)O.C(C=C)(=O)OCC(=O)O MAIQXAJWHBSIFX-UHFFFAOYSA-N 0.000 description 1
OSGAMWWXNRGQFK-UHFFFAOYSA-N C(C=C)(=O)OOC(CC(=O)O)(OC(CC)=O)OC(CC)=O Chemical compound C(C=C)(=O)OOC(CC(=O)O)(OC(CC)=O)OC(CC)=O OSGAMWWXNRGQFK-UHFFFAOYSA-N 0.000 description 1
HFHSZRGGTSCVMW-UHFFFAOYSA-N C(C=C)(=O)OOC(CC(=O)O)C Chemical compound C(C=C)(=O)OOC(CC(=O)O)C HFHSZRGGTSCVMW-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
108010073771 Soybean Proteins Proteins 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
150000001260 acyclic compounds Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
229910001870 ammonium persulfate Inorganic materials 0.000 description 1
239000012874 anionic emulsifier Substances 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
239000000872 buffer Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
235000011148 calcium chloride Nutrition 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
WUILYKHTEDWVOM-UHFFFAOYSA-N carboxy prop-2-enoate Chemical compound OC(=O)OC(=O)C=C WUILYKHTEDWVOM-UHFFFAOYSA-N 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000011111 cardboard Substances 0.000 description 1
239000005018 casein Substances 0.000 description 1
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
235000021240 caseins Nutrition 0.000 description 1
150000001767 cationic compounds Chemical class 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
125000004093 cyano group Chemical group *C#N 0.000 description 1
235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
SQEDZTDNVYVPQL-UHFFFAOYSA-N dodecylbenzene;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1 SQEDZTDNVYVPQL-UHFFFAOYSA-N 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000003292 glue Substances 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
150000004680 hydrogen peroxides Chemical class 0.000 description 1
229910001411 inorganic cation Inorganic materials 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
229910001869 inorganic persulfate Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
238000001459 lithography Methods 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
239000002609 medium Substances 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
HSTRMLNFORCAMM-UHFFFAOYSA-N methyl 3-prop-2-enoyloxypropanoate Chemical compound COC(=O)CCOC(=O)C=C HSTRMLNFORCAMM-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
238000002156 mixing Methods 0.000 description 1
125000000896 monocarboxylic acid group Chemical group 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000003002 pH adjusting agent Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical class [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000000047 product Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
235000019710 soybean protein Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000004291 sulphur dioxide Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Paper (AREA)
Polymerisation Methods In General (AREA)
Paints Or Removers (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

FI771354A 1976-05-03 1977-04-28 Stabil latex bildad av en kopolymer av en monomerblandning ochdess anvaendning som bindemedel i pappersbelaeggningsblan dnngar FI63427C (fi)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US68281176		1976-05-03
US05/682,811 US4065423A (en)	1976-05-03	1976-05-03	Paper coating latex compositions containing copolymers of monovinylidene aromatic monomer, aliphatic conjugated diene and an aryloyloxycarboxylic acid monomer

Publications (3)

Publication Number	Publication Date
FI771354A7 FI771354A7 (fr)	1977-11-04
FI63427B FI63427B (fi)	1983-02-28
FI63427C true FI63427C (fi)	1983-06-10

Family

ID=24741233

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI771354A FI63427C (fi)	1976-05-03	1977-04-28	Stabil latex bildad av en kopolymer av en monomerblandning ochdess anvaendning som bindemedel i pappersbelaeggningsblan dnngar

Country Status (11)

Country	Link
US (1)	US4065423A (fr)
JP (1)	JPS52134695A (fr)
BE (1)	BE854111A (fr)
CA (1)	CA1049176A (fr)
DE (1)	DE2719274C3 (fr)
FI (1)	FI63427C (fr)
FR (1)	FR2350362A1 (fr)
GB (1)	GB1547098A (fr)
IT (1)	IT1083375B (fr)
NL (1)	NL162156C (fr)
SE (1)	SE427038B (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4436857A (en)	1978-08-07	1984-03-13	The General Tire & Rubber Company	Coating rubber with a composition which resists removal by water
CA1135712A (fr) *	1979-05-29	1982-11-16	Peter J. Schirmann	Monomeres et polymeres d'ester actives
DE3033121A1 (de) *	1980-09-03	1982-04-22	Basf Ag, 6700 Ludwigshafen	Waessrige emulgatorarme dispersionen von carboxylgruppen aufweisenden butadien-styrol-emulsionscopolymerisaten und ihre verwendung als bindemittel fuer korrosionsschutzfarben
US4331738A (en) *	1980-12-04	1982-05-25	The General Tire & Rubber Company	Blend of a carboxylated copolymer latex and of an acrylate copolymer latex for coating rubber and product
JPS57167488A (en) *	1981-04-06	1982-10-15	Asahi Dow Ltd	Paper coating liquid composition
JPH0692463B2 (ja) *	1983-05-20	1994-11-16	大日本インキ化学工業株式会社	被覆用共重合体
CA1333822C (fr) *	1986-11-07	1995-01-03	Robert S. Beyersdorf	Compositions de latex utiles comme liant dans des panneaux composites qui gardent leur forme et leur resistance
JPH0813865B2 (ja) *	1987-05-06	1996-02-14	日本合成ゴム株式会社	共重合体ラテックス
CA1332647C (fr) *	1988-04-19	1994-10-18	Peter Ronald Jeffrey Blanpain	Polymerisation alcaline de polymeres carboxyles
US5015713A (en) *	1988-04-19	1991-05-14	Polysar Financial Services S.A.	Alkaline polymerization of carboxylated polymers
DE19522400A1 (de) *	1995-06-21	1997-01-02	Basf Ag	Verwendung von Papierstreichmassen mit hohem Butadiengehalt im Tiefdruck
GB9707036D0 (en) *	1997-04-07	1997-05-28	Zeneca Resins Bv	Aqueous crosslinkable coating compositions
DE10052310A1 (de) *	2000-10-21	2002-05-02	Basf Ag	Fußbodenklebstoffe auf Basis von Styrol-Butadiencopolymerisaten
US12460100B2 (en) *	2019-09-20	2025-11-04	Synthomer Sdn. Bhd.	Polymer latex for the preparation of an elastomeric film having excellent stress retention properties and softness
MY205976A (en) *	2021-10-06	2024-11-21	Synthomer Sdn Bhd	Polymer latex for the preparation of an elastomeric film having microbial resistance

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2141546A (en) *	1936-06-05	1938-12-27	Du Pont	Acryloxy carboxylic acids and their esters
NL283505A (fr) *	1961-09-22
US3392048A (en) *	1965-01-08	1968-07-09	Gen Tire & Rubber Co	Pigment-coated paper products having a binder of protein and a conjugated diene polymer that can form a reversible colloidal solution
AU474688B2 (en) *	1973-08-15	1975-02-20	Sumitomo Naugatuck Co. Ltd.	Copolymer latex and paper coating composition thereof

1976
- 1976-05-03 US US05/682,811 patent/US4065423A/en not_active Expired - Lifetime
- 1976-07-26 CA CA76257764A patent/CA1049176A/fr not_active Expired
1977
- 1977-04-28 FI FI771354A patent/FI63427C/fi not_active IP Right Cessation
- 1977-04-28 SE SE7704951A patent/SE427038B/xx unknown
- 1977-04-29 FR FR7713094A patent/FR2350362A1/fr active Granted
- 1977-04-29 BE BE177136A patent/BE854111A/fr not_active IP Right Cessation
- 1977-04-29 DE DE2719274A patent/DE2719274C3/de not_active Expired
- 1977-05-02 JP JP5114877A patent/JPS52134695A/ja active Granted
- 1977-05-02 IT IT67979/77A patent/IT1083375B/it active
- 1977-05-02 GB GB18299/77A patent/GB1547098A/en not_active Expired
- 1977-05-03 NL NL7704881.A patent/NL162156C/xx not_active IP Right Cessation

Also Published As

Publication number	Publication date
GB1547098A (en)	1979-06-06
FR2350362A1 (fr)	1977-12-02
NL162156B (nl)	1979-11-15
FR2350362B1 (fr)	1979-03-09
FI771354A7 (fr)	1977-11-04
US4065423A (en)	1977-12-27
DE2719274A1 (de)	1977-11-10
NL162156C (nl)	1980-04-15
SE427038B (sv)	1983-02-28
SE7704951L (sv)	1977-11-04
NL7704881A (nl)	1977-11-07
IT1083375B (it)	1985-05-21
CA1049176A (fr)	1979-02-20
JPS546272B2 (fr)	1979-03-27
JPS52134695A (en)	1977-11-11
DE2719274C3 (de)	1982-05-19
FI63427B (fi)	1983-02-28
BE854111A (fr)	1977-10-31
DE2719274B2 (de)	1981-07-23

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: UNIROYAL, INC.

Publication	Publication Date	Title
EP0019716B2 (fr)	1990-04-04	Dispersions polymères aqueuses et compositions pour revêtir du papier
FI63427C (fi)	1983-06-10	Stabil latex bildad av en kopolymer av en monomerblandning ochdess anvaendning som bindemedel i pappersbelaeggningsblan dnngar
US5726259A (en)	1998-03-10	Bimodal latex binder
US7060762B2 (en)	2006-06-13	Preparation of aqueous styrene-butadiene polymer dispersions
EP0040419B1 (fr)	1985-07-31	Latex de polymère hétérogène à base d'interpolymères relativement durs et mous comprenant un monomère monovinylidène aromatique et un monomère diène aliphatique conjugué et compositions de revêtement pour le papier contenant ces latex
US5302655A (en)	1994-04-12	Monovinylidene aromatic and conjugated diene copolymer coating compositions comprising sulfoalkyl monomeric emulsifier
US3255130A (en)	1966-06-07	Ethylene propylene copolymer latices containing polar groups
US5274027A (en)	1993-12-28	Monovinylidene aromatic and conjugated diene copolymer coating compositions comprising sulfoalkyl monomeric emulsifier
US7375148B2 (en)	2008-05-20	Method for producing aqueous styrene-butadiene-iv polymer dispersions
JPH0157691B2 (fr)	1989-12-07
US4448923A (en)	1984-05-15	Interpolymer latex, process for its preparation and use of the latex for coating paper
US3305500A (en)	1967-02-21	Coating compositions comprising butadiene-1, 3 copolymer, starch and mineral pigment
US3719628A (en)	1973-03-06	Ethylene/vinyl chloride/acrylamide interpolymer and styrene/butadiene/unsaturated acid terpolymer polyblend
FI60024C (fi)	1981-11-10	Latexaemneskomposition avsedd foer belaeggning av papper
JP2552841B2 (ja)	1996-11-13	紙用塗工組成物
EP0109463B1 (fr)	1986-10-01	Compositions polymères utilisables comme liants dans des compositions de couchage du papier et compositions de couchage ainsi préparées
JP2745634B2 (ja)	1998-04-28	紙塗被用共重合体ラテックスおよび紙塗被用組成物
KR910005583B1 (ko)	1991-07-31	불포화 카복실산의 시아노알킬 에스테르를 함유하는 수성-분산 중합체 조성물
EP0290115A2 (fr)	1988-11-09	Compositions pour couchage de papier
JPH02169800A (ja)	1990-06-29	紙塗工用ラテックス
SU1379390A1 (ru)	1988-03-07	Мелованный волокнистый материал
US4631312A (en)	1986-12-23	Polymeric compositions useful as binders in coating colors and coating colors prepared therefrom
KR900004686B1 (ko)	1990-07-02	코팅컬러에서 결합제로 유용한 폴리머 조성물
JPH03273005A (ja)	1991-12-04	共重合体ラテックスの製造法
JPH0441508A (ja)	1992-02-12	新規共重合体ラテックスの製造方法