FI65190C - Uppteckningsmaterial - Google Patents
Uppteckningsmaterial Download PDFInfo
- Publication number
- FI65190C FI65190C FI783739A FI783739A FI65190C FI 65190 C FI65190 C FI 65190C FI 783739 A FI783739 A FI 783739A FI 783739 A FI783739 A FI 783739A FI 65190 C FI65190 C FI 65190C
- Authority
- FI
- Finland
- Prior art keywords
- color
- agent according
- labeling agent
- group
- excipient
- Prior art date
Links
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 38
- 239000006185 dispersion Substances 0.000 claims description 34
- 239000003795 chemical substances by application Substances 0.000 claims description 31
- 239000000203 mixture Substances 0.000 claims description 29
- 239000010410 layer Substances 0.000 claims description 28
- 239000002243 precursor Substances 0.000 claims description 27
- -1 fluorane compound Chemical class 0.000 claims description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 13
- 230000015572 biosynthetic process Effects 0.000 claims description 13
- 238000000354 decomposition reaction Methods 0.000 claims description 13
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 12
- 239000002356 single layer Substances 0.000 claims description 10
- WNZQDUSMALZDQF-UHFFFAOYSA-N isobenzofuranone Natural products C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 claims description 9
- 239000003550 marker Substances 0.000 claims description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 8
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- AEOCXXJPGCBFJA-UHFFFAOYSA-N ethionamide Chemical compound CCC1=CC(C(N)=S)=CC=N1 AEOCXXJPGCBFJA-UHFFFAOYSA-N 0.000 claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 5
- 150000002367 halogens Chemical class 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 150000002596 lactones Chemical group 0.000 claims description 5
- 150000002989 phenols Chemical class 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 125000003435 aroyl group Chemical group 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- SHWZFQPXYGHRKT-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;nickel Chemical group [Ni].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O SHWZFQPXYGHRKT-FDGPNNRMSA-N 0.000 claims description 2
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 2
- XMOWAIVXKJWQBJ-UHFFFAOYSA-N 1-ethyl-2-methylindole Chemical compound C1=CC=C2N(CC)C(C)=CC2=C1 XMOWAIVXKJWQBJ-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000005160 aryl oxy alkyl group Chemical group 0.000 claims description 2
- 125000004104 aryloxy group Chemical group 0.000 claims description 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 2
- 125000005841 biaryl group Chemical group 0.000 claims description 2
- 230000015556 catabolic process Effects 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 238000006731 degradation reaction Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 2
- 229910052753 mercury Inorganic materials 0.000 claims description 2
- UIEKYBOPAVTZKW-UHFFFAOYSA-L naphthalene-2-carboxylate;nickel(2+) Chemical compound [Ni+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 UIEKYBOPAVTZKW-UHFFFAOYSA-L 0.000 claims description 2
- 125000005609 naphthenate group Chemical group 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- 229940049964 oleate Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 238000002372 labelling Methods 0.000 claims 24
- 238000001035 drying Methods 0.000 claims 3
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 2
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 claims 1
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 claims 1
- 241000721662 Juniperus Species 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims 1
- 125000005506 phthalide group Chemical group 0.000 claims 1
- 125000001391 thioamide group Chemical group 0.000 claims 1
- 229940075466 undecylenate Drugs 0.000 claims 1
- 239000003086 colorant Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000002844 melting Methods 0.000 description 10
- 230000008018 melting Effects 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical class F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000155 melt Substances 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 150000003556 thioamides Chemical class 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 2
- SSIZLKDLDKIHEV-UHFFFAOYSA-N 2,6-dibromophenol Chemical compound OC1=C(Br)C=CC=C1Br SSIZLKDLDKIHEV-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- CONFUNYOPVYVDC-UHFFFAOYSA-N 3,3-bis(1-ethyl-2-methylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC=C2C(C3(C4=CC=CC=C4C(=O)O3)C3=C(C)N(C4=CC=CC=C43)CC)=C(C)N(CC)C2=C1 CONFUNYOPVYVDC-UHFFFAOYSA-N 0.000 description 2
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 description 2
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 2
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 2
- 125000004926 indolenyl group Chemical group 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000006239 protecting group Chemical group 0.000 description 2
- 239000000700 radioactive tracer Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- PKKDWPSOOQBWFB-UHFFFAOYSA-N 2,4-dichloro-6-[(3,5-dichloro-2-hydroxyphenyl)methyl]phenol Chemical compound OC1=C(Cl)C=C(Cl)C=C1CC1=CC(Cl)=CC(Cl)=C1O PKKDWPSOOQBWFB-UHFFFAOYSA-N 0.000 description 1
- QHCDYIRWTPEABF-UHFFFAOYSA-N 2-(4-chlorophenyl)ethanethioamide Chemical compound NC(=S)CC1=CC=C(Cl)C=C1 QHCDYIRWTPEABF-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- UABVUROTLVCZSU-UHFFFAOYSA-N 2-phenoxypropanethioamide Chemical compound NC(=S)C(C)OC1=CC=CC=C1 UABVUROTLVCZSU-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- SVOBELCYOCEECO-UHFFFAOYSA-N 4-[1-(4-hydroxy-3-methylphenyl)cyclohexyl]-2-methylphenol Chemical compound C1=C(O)C(C)=CC(C2(CCCCC2)C=2C=C(C)C(O)=CC=2)=C1 SVOBELCYOCEECO-UHFFFAOYSA-N 0.000 description 1
- 229940073735 4-hydroxy acetophenone Drugs 0.000 description 1
- NTDQQZYCCIDJRK-UHFFFAOYSA-N 4-octylphenol Chemical compound CCCCCCCCC1=CC=C(O)C=C1 NTDQQZYCCIDJRK-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 206010057040 Temperature intolerance Diseases 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- IMHDGJOMLMDPJN-UHFFFAOYSA-N biphenyl-2,2'-diol Chemical group OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 description 1
- JFIOVJDNOJYLKP-UHFFFAOYSA-N bithionol Chemical compound OC1=C(Cl)C=C(Cl)C=C1SC1=CC(Cl)=CC(Cl)=C1O JFIOVJDNOJYLKP-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 230000008543 heat sensitivity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000013047 polymeric layer Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000003232 water-soluble binding agent Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/34—Multicolour thermography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/34—Multicolour thermography
- B41M5/345—Multicolour thermography by thermal transfer of dyes or pigments
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Color Printing (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/861,046 US4151748A (en) | 1977-12-15 | 1977-12-15 | Two color thermally sensitive record material system |
| US86104677 | 1977-12-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI783739A7 FI783739A7 (fi) | 1979-06-16 |
| FI65190B FI65190B (fi) | 1983-12-30 |
| FI65190C true FI65190C (fi) | 1984-04-10 |
Family
ID=25334724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI783739A FI65190C (fi) | 1977-12-15 | 1978-12-05 | Uppteckningsmaterial |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US4151748A (de) |
| JP (1) | JPS5822357B2 (de) |
| AT (1) | AT373827B (de) |
| AU (1) | AU512720B2 (de) |
| BE (1) | BE872635A (de) |
| BR (1) | BR7808195A (de) |
| CA (1) | CA1121158A (de) |
| CH (1) | CH628574A5 (de) |
| DE (1) | DE2853120C2 (de) |
| DK (1) | DK561678A (de) |
| ES (1) | ES476050A1 (de) |
| FI (1) | FI65190C (de) |
| FR (1) | FR2415009B1 (de) |
| GB (2) | GB2011105B (de) |
| HK (2) | HK74484A (de) |
| IE (1) | IE47515B1 (de) |
| LU (1) | LU80650A1 (de) |
| NL (1) | NL170827C (de) |
| SE (1) | SE443535B (de) |
| ZA (1) | ZA786661B (de) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4251092A (en) * | 1976-12-29 | 1981-02-17 | Sterling Drug Inc. | Pressure sensitive carbonless duplicating systems and thermal marking systems |
| US4232552A (en) * | 1978-09-28 | 1980-11-11 | Akzona Incorporated | Temperature indicating compositions of matter |
| JPS6043318B2 (ja) * | 1978-07-18 | 1985-09-27 | 富士写真フイルム株式会社 | 感熱記録紙 |
| JPS5527253A (en) * | 1978-08-18 | 1980-02-27 | Fuji Photo Film Co Ltd | Heat sensitizing recording sheet |
| US4286017A (en) * | 1978-09-25 | 1981-08-25 | Honshu Seishi Kabushiki Kaisha | Heat-sensitive recording paper |
| US4339207A (en) * | 1978-09-28 | 1982-07-13 | Akzona Incorporated | Temperature indicating compositions of matter |
| US4362645A (en) * | 1978-09-28 | 1982-12-07 | Akzona, Inc. | Temperature indicating compositions of matter |
| JPS5581194A (en) * | 1978-12-14 | 1980-06-18 | Ricoh Co Ltd | Polychromic heat sensitive recording material |
| US4363664A (en) * | 1980-01-25 | 1982-12-14 | Sterling Drug Inc. | Novel compositions and processes |
| US4424990A (en) | 1980-01-30 | 1984-01-10 | Raychem Corporation | Thermochromic compositions |
| JPS5736694A (en) * | 1980-08-15 | 1982-02-27 | Mitsui Toatsu Chem Inc | Heat-sensitive recording material |
| JPS5738187A (en) * | 1980-08-19 | 1982-03-02 | Mitsui Toatsu Chem Inc | Heat-sensitive recording material |
| JPS5739987A (en) * | 1980-08-25 | 1982-03-05 | Mitsui Toatsu Chem Inc | Heat-sensitive recording material |
| JPS5741996A (en) * | 1980-08-27 | 1982-03-09 | Mitsui Toatsu Chem Inc | Heat-sensitive recording medium |
| US4450023A (en) * | 1981-06-12 | 1984-05-22 | N.V. Raychem S.A. | Thermochromic composition |
| GB2116735B (en) * | 1982-02-27 | 1986-11-26 | Arthur R Zingher | Optically annotatable recording film |
| US4533640A (en) * | 1984-02-21 | 1985-08-06 | Shafer Jules A | Accumulated thermal exposure responder and method of use |
| US4711815A (en) * | 1985-03-07 | 1987-12-08 | Matsushita Electric Industrial Co., Ltd. | Recording medium |
| JP2566628B2 (ja) * | 1988-08-24 | 1996-12-25 | 保土谷化学工業株式会社 | フレオラン化合物および記録材料 |
| JPH0647464B2 (ja) * | 1990-03-20 | 1994-06-22 | 工業技術院長 | 示温材料及びその製造方法 |
| GB9116626D0 (en) * | 1991-08-01 | 1991-09-18 | Univ Strathclyde | Improvements in and relating to ropes |
| US5290704A (en) * | 1993-03-19 | 1994-03-01 | Valence Technology, Inc. | Method of detecting organic solvent vapors |
| US5441418A (en) * | 1993-05-20 | 1995-08-15 | Binney & Smith Inc. | Thermochromic drawing device |
| US5514635A (en) * | 1993-12-29 | 1996-05-07 | Optum Corporation | Thermal writing surface and method for making the same |
| US5601867A (en) * | 1995-06-22 | 1997-02-11 | The United States Of America As Represented By The Secretary Of The Navy | Method and apparatus for generating fingerprints and other skin prints |
| US6294502B1 (en) | 1998-05-22 | 2001-09-25 | Bayer Aktiengesellschaft | Thermally-responsive record material |
| US6737274B1 (en) | 1999-02-04 | 2004-05-18 | United States Of America As Represented By The Secretary Of The Army | Comparator for time-temperature indicator |
| US6937153B2 (en) * | 2002-06-28 | 2005-08-30 | Appleton Papers Inc. | Thermal imaging paper laminate |
| US7094732B2 (en) | 2002-10-02 | 2006-08-22 | General Data Company, Inc. | Direct thermal imaging on plastic film |
| US7108190B2 (en) * | 2003-02-28 | 2006-09-19 | Appleton Papers Inc. | Token array and method employing authentication tokens bearing scent formulation information |
| US20040251309A1 (en) * | 2003-06-10 | 2004-12-16 | Appleton Papers Inc. | Token bearing magnetc image information in registration with visible image information |
| US20040259975A1 (en) * | 2003-06-18 | 2004-12-23 | Robillard Jean J. | System and method for forming photobleachable ink compositions |
| US7923412B1 (en) * | 2004-02-12 | 2011-04-12 | Kazdin Richard H | Creating background colors on thermal printing material |
| JP4851465B2 (ja) | 2004-11-08 | 2012-01-11 | フレッシュポイント・ホールディングス・ソシエテ・アノニム | 時間温度指示装置 |
| US8500895B2 (en) | 2006-05-22 | 2013-08-06 | Marken-Imaje Corporation | Methods of marking and related structures and compositions |
| US9418576B2 (en) * | 2008-05-14 | 2016-08-16 | Avery Dennison Corporation | Dissolvable thermal direct adhesive label and label assembly including the same |
| AU2009256212B2 (en) | 2008-06-04 | 2015-12-10 | Jp Laboratories Inc. | A monitoring system based on etching of metals |
| CN102077060B (zh) | 2008-06-04 | 2014-10-29 | G·帕特尔 | 一种基于腐蚀金属的监测系统 |
| US9034790B2 (en) | 2013-03-14 | 2015-05-19 | Appvion, Inc. | Thermally-responsive record material |
| US9126451B2 (en) | 2013-12-18 | 2015-09-08 | Appvion, Inc. | Thermal recording materials |
| US9534156B2 (en) | 2014-09-17 | 2017-01-03 | Appvion, Inc. | Linerless record material |
| USD785287S1 (en) * | 2015-08-04 | 2017-05-02 | Dana Ronci | Backless bathing suit |
| KR102404989B1 (ko) | 2018-03-23 | 2022-06-07 | 압비온 오퍼레이션즈, 인크. | 상태의 선택적인 변화를 기초로 하는 직접적인 열적 기록 매체 |
| US20200019077A1 (en) | 2018-07-11 | 2020-01-16 | Appvion Operations, Inc. | Media Adapted for Both Direct Thermal Recording and Memjet-Type Printing |
| EP4021734A1 (de) | 2019-09-25 | 2022-07-06 | Appvion, LLC | Direkte thermische aufzeichnungsmedien mit perforierten partikeln |
| US11376879B2 (en) | 2019-11-22 | 2022-07-05 | Appvion, Llc | Water-dispersible direct thermal or inkjet printable media |
| US12115803B2 (en) | 2020-12-10 | 2024-10-15 | Appvion, Llc | Fade-resistant water-dispersible phenol-free direct thermal media |
| US12151498B2 (en) | 2020-12-10 | 2024-11-26 | Appvion, Llc | Multi-purpose phenol-free direct thermal recording media |
| KR102945498B1 (ko) | 2020-12-10 | 2026-03-30 | 압비온, 엘엘씨 | 다목적 무-페놀 직접 감열 기록 매체 |
| DE202020006063U1 (de) | 2020-12-10 | 2024-08-27 | Appvion, Llc | Phenol-freie Mehrzweck-Thermodirekt-Aufzeichnungsmedien |
| JP2025528105A (ja) | 2022-08-10 | 2025-08-26 | アプヴィオン エルエルシー | 耐油性のためのジアリール尿素の組合せを用いた直接感熱記録媒体 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1924793A (en) * | 1927-06-30 | 1933-08-29 | Laske Frans | Paint for indicating heat |
| US1844199A (en) * | 1928-08-30 | 1932-02-09 | Rca Corp | Pyro-recording paper |
| US1897843A (en) * | 1930-08-07 | 1933-02-14 | Eastman Kodak Co | Light sensitive tropochromic coating |
| US1880449A (en) * | 1930-08-07 | 1932-10-04 | Eastman Kodak Co | Tropochromic coating |
| US1917370A (en) * | 1932-07-13 | 1933-07-11 | Eastman Kodak Co | Duplicating process |
| US3121650A (en) * | 1960-07-28 | 1964-02-18 | Minnesota Mining & Mfg | Right-reading reproduction of printed originals |
| US3471422A (en) * | 1961-05-22 | 1969-10-07 | Tempil Corp | Time-temperature responsive color changing typographic printing ink composition |
| BE623057A (de) * | 1961-10-05 | |||
| FR1373659A (fr) * | 1961-10-05 | 1964-10-02 | Ncr Co | Feuille de reproduction colorée thermiquement |
| BE639346A (de) * | 1962-11-19 | |||
| GB1053905A (de) * | 1964-05-11 | |||
| FR1440892A (fr) * | 1964-05-11 | 1966-06-03 | Ncr Co | Matérau d'enregistrement |
| JPS4833206B1 (de) * | 1970-04-28 | 1973-10-12 | ||
| GB1337757A (en) * | 1970-10-19 | 1973-11-21 | Columbia Ribbon Carbon Mfg | Thermographic copy sheets |
| JPS507216Y2 (de) * | 1971-03-18 | 1975-03-03 | ||
| US3843384A (en) * | 1971-06-14 | 1974-10-22 | Matsushita Electric Industrial Co Ltd | Heat-sensitive two color recording paper |
| JPS556076B1 (de) * | 1971-07-13 | 1980-02-13 | ||
| JPS5412819B2 (de) * | 1971-08-05 | 1979-05-25 | ||
| CA987103A (en) * | 1972-02-17 | 1976-04-13 | Kinichi Adachi | Dichromatic thermo-sensitive paper |
| JPS4969A (de) * | 1972-04-13 | 1974-01-05 | ||
| GB1432771A (en) * | 1972-06-26 | 1976-04-22 | Agfa Gevaert | Recording method |
| JPS4946659B2 (de) * | 1972-07-10 | 1974-12-11 | ||
| JPS4937917A (de) * | 1972-08-10 | 1974-04-09 | ||
| FR2211673B1 (de) * | 1972-12-22 | 1976-04-23 | Robillard Jean | |
| CH578432A5 (de) * | 1973-03-05 | 1976-08-13 | Ciba Geigy Ag | |
| JPS49122345A (de) * | 1973-03-23 | 1974-11-22 | ||
| US4010033A (en) * | 1973-08-03 | 1977-03-01 | Agence Nationale De Valorisation De La Recherche (Anvar) | Photosensitive layer and method of forming a photographic image therefrom |
| US4020232A (en) * | 1974-05-17 | 1977-04-26 | Mitsubishi Paper Mills, Ltd. | Heat-sensitive recording sheets |
| FR2271938A1 (en) * | 1974-05-24 | 1975-12-19 | Issec | Thermochromic compsns. for thermographic recording - giving variety of colours with phenolic cpds. and chelating cpds. |
| JPS5223806B2 (de) * | 1974-05-30 | 1977-06-27 | ||
| JPS515792A (ja) * | 1974-07-05 | 1976-01-17 | Mitsubishi Heavy Ind Ltd | Mekanikarudoraibushikihansosochi |
| JPS5211231A (en) * | 1975-07-16 | 1977-01-28 | Matsushita Electric Ind Co Ltd | Thermoplastic resin composition |
| GB1563175A (en) * | 1977-03-04 | 1980-03-19 | Lawton W | Heat-sensitive recording composition with mixed colour precursors |
-
1977
- 1977-12-15 US US05/861,046 patent/US4151748A/en not_active Expired - Lifetime
-
1978
- 1978-11-23 IE IE2316/78A patent/IE47515B1/en unknown
- 1978-11-27 ZA ZA00786661A patent/ZA786661B/xx unknown
- 1978-12-01 GB GB7846938A patent/GB2011105B/en not_active Expired
- 1978-12-01 GB GB8041273A patent/GB2064153B/en not_active Expired
- 1978-12-05 FI FI783739A patent/FI65190C/fi not_active IP Right Cessation
- 1978-12-06 SE SE7812551A patent/SE443535B/sv unknown
- 1978-12-07 AU AU42280/78A patent/AU512720B2/en not_active Expired
- 1978-12-08 DE DE2853120A patent/DE2853120C2/de not_active Expired
- 1978-12-08 BE BE192221A patent/BE872635A/xx not_active IP Right Cessation
- 1978-12-11 JP JP53152133A patent/JPS5822357B2/ja not_active Expired
- 1978-12-11 CA CA000317723A patent/CA1121158A/en not_active Expired
- 1978-12-12 AT AT0884278A patent/AT373827B/de not_active IP Right Cessation
- 1978-12-13 LU LU80650A patent/LU80650A1/xx unknown
- 1978-12-13 CH CH1267678A patent/CH628574A5/fr not_active IP Right Cessation
- 1978-12-14 DK DK561678A patent/DK561678A/da not_active Application Discontinuation
- 1978-12-14 NL NLAANVRAGE7812167,A patent/NL170827C/xx not_active IP Right Cessation
- 1978-12-14 FR FR7835233A patent/FR2415009B1/fr not_active Expired
- 1978-12-14 BR BR7808195A patent/BR7808195A/pt unknown
- 1978-12-15 ES ES476050A patent/ES476050A1/es not_active Expired
-
1984
- 1984-09-27 HK HK744/84A patent/HK74484A/xx unknown
- 1984-09-27 HK HK736/84A patent/HK73684A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SE7812551L (sv) | 1979-06-16 |
| IE782316L (en) | 1979-06-15 |
| DE2853120C2 (de) | 1983-06-09 |
| CA1121158A (en) | 1982-04-06 |
| NL170827C (nl) | 1983-01-03 |
| IE47515B1 (en) | 1984-04-04 |
| GB2011105A (en) | 1979-07-04 |
| AT373827B (de) | 1984-02-27 |
| NL7812167A (nl) | 1979-06-19 |
| GB2064153A (en) | 1981-06-10 |
| FI65190B (fi) | 1983-12-30 |
| DK561678A (da) | 1979-06-16 |
| FR2415009A1 (fr) | 1979-08-17 |
| US4151748A (en) | 1979-05-01 |
| FI783739A7 (fi) | 1979-06-16 |
| AU4228078A (en) | 1979-06-21 |
| ATA884278A (de) | 1983-07-15 |
| FR2415009B1 (fr) | 1985-11-22 |
| ES476050A1 (es) | 1979-06-16 |
| LU80650A1 (fr) | 1979-04-13 |
| BR7808195A (pt) | 1979-07-31 |
| JPS5822357B2 (ja) | 1983-05-09 |
| DE2853120A1 (de) | 1979-06-21 |
| AU512720B2 (en) | 1980-10-23 |
| CH628574A5 (fr) | 1982-03-15 |
| SE443535B (sv) | 1986-03-03 |
| BE872635A (fr) | 1979-03-30 |
| GB2064153B (en) | 1983-01-12 |
| NL170827B (nl) | 1982-08-02 |
| HK73684A (en) | 1984-10-05 |
| GB2011105B (en) | 1982-05-26 |
| JPS5492264A (en) | 1979-07-21 |
| HK74484A (en) | 1984-10-05 |
| ZA786661B (en) | 1979-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM | Patent lapsed | ||
| MM | Patent lapsed |
Owner name: APPLETON PAPERS INC. |