FI76354C - Katalytkomponent foer ziegler-natta katalyter och foerfarande foer polymerisering av -olefiner. - Google Patents

Katalytkomponent foer ziegler-natta katalyter och foerfarande foer polymerisering av -olefiner. Download PDF

Info

Publication number: FI76354C
Authority: FI; Finland
Prior art keywords: compound; catalytic component; ziegler; catalyst; foer
Prior art date: 1986-12-31

Application number

FI865361A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI76354B (fi

FI865361A0 (fi

Inventor

Luciano Luciani

Barbro Loefgren

Original Assignee

Neste Oy

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-12-31

Filing date

1986-12-31

Publication date

1988-10-10

1986-12-31 Application filed by Neste Oy filed Critical Neste Oy

1986-12-31 Priority to FI865361A priority Critical patent/FI76354C/fi

1986-12-31 Publication of FI865361A0 publication Critical patent/FI865361A0/fi

1987-11-26 Priority to IT8722761A priority patent/IT1224643B/it

1987-11-30 Priority to BE8701359A priority patent/BE1000160A7/fr

1987-12-10 Priority to PCT/FI1987/000167 priority patent/WO1988005056A1/fr

1987-12-14 Priority to FR8717402A priority patent/FR2609035A1/fr

1987-12-29 Priority to JP62336800A priority patent/JPS63175008A/ja

1988-06-30 Publication of FI76354B publication Critical patent/FI76354B/fi

1988-10-10 Application granted granted Critical

1988-10-10 Publication of FI76354C publication Critical patent/FI76354C/fi

Links

230000003197 catalytic effect Effects 0.000 title claims 9
239000011954 Ziegler–Natta catalyst Substances 0.000 title description 3
-1 titanium halides Chemical class 0.000 claims description 28
239000000203 mixture Substances 0.000 claims description 18
239000010936 titanium Substances 0.000 claims description 16
229910052719 titanium Inorganic materials 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 10
150000002901 organomagnesium compounds Chemical class 0.000 claims description 10
229910000077 silane Inorganic materials 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 7
239000000460 chlorine Substances 0.000 claims description 6
230000000379 polymerizing effect Effects 0.000 claims description 6
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 6
238000011282 treatment Methods 0.000 claims description 6
OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 claims description 5
NLSXASIDNWDYMI-UHFFFAOYSA-N triphenylsilanol Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(O)C1=CC=CC=C1 NLSXASIDNWDYMI-UHFFFAOYSA-N 0.000 claims description 5
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
150000002681 magnesium compounds Chemical class 0.000 claims description 4
150000004756 silanes Chemical class 0.000 claims description 4
239000007787 solid Substances 0.000 claims description 3
125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
229910052744 lithium Inorganic materials 0.000 claims description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 3
229910052801 chlorine Inorganic materials 0.000 claims 3
125000000217 alkyl group Chemical group 0.000 claims 1
239000011230 binding agent Substances 0.000 claims 1
150000004796 dialkyl magnesium compounds Chemical class 0.000 claims 1
239000003054 catalyst Substances 0.000 description 63
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 32
238000006116 polymerization reaction Methods 0.000 description 27
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 17
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 17
239000011777 magnesium Substances 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 10
229920000642 polymer Polymers 0.000 description 10
229910052749 magnesium Inorganic materials 0.000 description 9
238000003756 stirring Methods 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000000047 product Substances 0.000 description 5
239000002002 slurry Substances 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
239000005977 Ethylene Substances 0.000 description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
239000004743 Polypropylene Substances 0.000 description 4
150000001336 alkenes Chemical class 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000000034 method Methods 0.000 description 4
KCIKCCHXZMLVDE-UHFFFAOYSA-N silanediol Chemical compound O[SiH2]O KCIKCCHXZMLVDE-UHFFFAOYSA-N 0.000 description 4
SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 4
239000002879 Lewis base Substances 0.000 description 3
229910020175 SiOH Inorganic materials 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
150000007527 lewis bases Chemical class 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
150000003623 transition metal compounds Chemical class 0.000 description 3
UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
235000011147 magnesium chloride Nutrition 0.000 description 2
KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 description 2
239000002245 particle Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
229910052723 transition metal Inorganic materials 0.000 description 2
150000003624 transition metals Chemical class 0.000 description 2
RTAQCQOZRWKSTQ-UHFFFAOYSA-N CC(C)C[Mg]CC(C)C Chemical compound CC(C)C[Mg]CC(C)C RTAQCQOZRWKSTQ-UHFFFAOYSA-N 0.000 description 1
MIEFVQIJSAGPBZ-UHFFFAOYSA-N CCC[Mg] Chemical compound CCC[Mg] MIEFVQIJSAGPBZ-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
241000282326 Felis catus Species 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229910018557 Si O Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
230000004913 activation Effects 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
LJWBIAMZBJWAOW-UHFFFAOYSA-N benzhydryloxysilane Chemical compound C=1C=CC=CC=1C(O[SiH3])C1=CC=CC=C1 LJWBIAMZBJWAOW-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
229910001629 magnesium chloride Inorganic materials 0.000 description 1
KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 description 1
RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 description 1
KMYFNYFIPIGQQZ-UHFFFAOYSA-N magnesium;octane Chemical compound [Mg+2].CCCCCCC[CH2-].CCCCCCC[CH2-] KMYFNYFIPIGQQZ-UHFFFAOYSA-N 0.000 description 1
239000000155 melt Substances 0.000 description 1
229910001507 metal halide Inorganic materials 0.000 description 1
150000005309 metal halides Chemical class 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000000178 monomer Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
150000003022 phthalic acids Chemical class 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000010076 replication Effects 0.000 description 1
150000004819 silanols Chemical class 0.000 description 1
LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
239000005052 trichlorosilane Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

FI865361A 1986-12-31 1986-12-31 Katalytkomponent foer ziegler-natta katalyter och foerfarande foer polymerisering av -olefiner. FI76354C (fi)

Priority Applications (6)

Application Number	Priority Date	Filing Date	Title
FI865361A FI76354C (fi)	1986-12-31	1986-12-31	Katalytkomponent foer ziegler-natta katalyter och foerfarande foer polymerisering av -olefiner.
IT8722761A IT1224643B (it)	1986-12-31	1987-11-26	Componente di catalizzatore per catalizzatori ziegler natta emetodo per polimerizzare alfa olefine.
BE8701359A BE1000160A7 (fr)	1986-12-31	1987-11-30	Composant catalytique pour catalyseurs de ziegler-natta et procede pour la polymerisation d'alpha-olefines.
PCT/FI1987/000167 WO1988005056A1 (fr)	1986-12-31	1987-12-10	CONSTITUANT CATALYSEUR POUR CATALYSES DE TYPE ZIEGLER-NATTA ET PROCEDE DE POLYMERISATION D'alpha-OLEFINES
FR8717402A FR2609035A1 (fr)	1986-12-31	1987-12-14	Composant catalytique pour composition de catalyseur de ziegler-natta sans support, composition contenant ce composant et procede de polymerisation d'a-olefines en presence de cette composition
JP62336800A JPS63175008A (ja)	1986-12-31	1987-12-29	α−オレフィン重合方法および触媒成分

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FI865361		1986-12-31
FI865361A FI76354C (fi)	1986-12-31	1986-12-31	Katalytkomponent foer ziegler-natta katalyter och foerfarande foer polymerisering av -olefiner.

Publications (3)

Publication Number	Publication Date
FI865361A0 FI865361A0 (fi)	1986-12-31
FI76354B FI76354B (fi)	1988-06-30
FI76354C true FI76354C (fi)	1988-10-10

Family

ID=8523727

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI865361A FI76354C (fi)	1986-12-31	1986-12-31	Katalytkomponent foer ziegler-natta katalyter och foerfarande foer polymerisering av -olefiner.

Country Status (6)

Country	Link
JP (1)	JPS63175008A (fr)
BE (1)	BE1000160A7 (fr)
FI (1)	FI76354C (fr)
FR (1)	FR2609035A1 (fr)
IT (1)	IT1224643B (fr)
WO (1)	WO1988005056A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5063188A (en) *	1990-04-06	1991-11-05	Texas Alkyls, Inc.	Catalyst component for ethylene polyermization and copolymerization
JP3943230B2 (ja) *	1998-02-26	2007-07-11	東邦チタニウム株式会社	オレフィン類重合用固体触媒成分及び触媒
CN107522801B (zh) *	2016-06-22	2020-07-31	中国石化扬子石油化工有限公司	一种丙烯丁烯共聚催化剂体系及其在制备丙烯丁烯共聚物的应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS58448B2 (ja) *	1976-09-27	1983-01-06	三井化学株式会社	ポリオレフインの製造方法
JPS53136086A (en) *	1977-05-04	1978-11-28	Mitsubishi Chem Ind Ltd	Production of olefin polymer
JPS5470389A (en) *	1977-11-16	1979-06-06	Mitsubishi Chem Ind Ltd	Production of olefin polymer
JPS57165407A (en) *	1981-04-04	1982-10-12	Mitsubishi Chem Ind Ltd	Preparation of olefinic polymer
US4477586A (en) *	1982-08-27	1984-10-16	Phillips Petroleum Company	Polymerization of olefins
US4525557A (en) *	1984-02-27	1985-06-25	Gulf Oil Corporation	Catalyst and process for the polymerization of ethylene
JPH062774B2 (ja) *	1985-03-12	1994-01-12	三井東圧化学株式会社	オレフインの重合方法

1986
- 1986-12-31 FI FI865361A patent/FI76354C/fi not_active IP Right Cessation
1987
- 1987-11-26 IT IT8722761A patent/IT1224643B/it active
- 1987-11-30 BE BE8701359A patent/BE1000160A7/fr not_active IP Right Cessation
- 1987-12-10 WO PCT/FI1987/000167 patent/WO1988005056A1/fr not_active Ceased
- 1987-12-14 FR FR8717402A patent/FR2609035A1/fr active Pending
- 1987-12-29 JP JP62336800A patent/JPS63175008A/ja active Pending

Also Published As

Publication number	Publication date
WO1988005056A1 (fr)	1988-07-14
BE1000160A7 (fr)	1988-06-28
JPS63175008A (ja)	1988-07-19
IT8722761A0 (it)	1987-11-26
FR2609035A1 (fr)	1988-07-01
IT1224643B (it)	1990-10-18
FI76354B (fi)	1988-06-30
FI865361A0 (fi)	1986-12-31

Legal Events

Date	Code	Title	Description
2004-08-31	MM	Patent lapsed	Owner name: NESTE OY

Publication	Publication Date	Title
JP3397846B2 (ja)	2003-04-21	触媒組成物およびポリオレフィンの製造方法
CN1093138C (zh)	2002-10-23	由非水解方式形成的聚烷基铝氧烷组合物
KR0140393B1 (ko)	1998-07-01	올레핀 중합체의 제조방법
RU2668553C2 (ru)	2018-10-02	Способ получения алюмоксанов
CS226436B2 (en)	1984-03-19	Method of preparing catalysts of stereoregular alpha-olefin polymerization
KR0131683B1 (ko)	1998-04-13	개질된 실리카계 촉매 및 이의 용도
EP0105727A2 (fr)	1984-04-18	Supports de catalyseur solubles dans les hydrocarbures et catalyseurs de polymérisation en résultants
JP2002513823A (ja)	2002-05-14	オレフィン重合用の三座配位子含有金属触媒錯体
JPH11263742A (ja)	1999-09-28	新規の電子供与体
JPH05287019A (ja)	1993-11-02	オレフィン重合用触媒およびオレフィン重合体の製造法
EP0502009B1 (fr)	1996-01-31	Procede de preparation d'un constituant catalytique destine a la polymerisation des olefines, constituant catalytique de polymerisation ainsi produit et utilisation de celui-ci
CN103073661A (zh)	2013-05-01	氯化镁基加合物及由其制备的催化剂组分
JP2004504420A (ja)	2004-02-12	触媒系及びその重合方法への使用
FI76354B (fi)	1988-06-30	Katalytkomponent foer ziegler-natta katalyter och foerfarande foer polymerisering av -olefiner.
JP2002519359A (ja)	2002-07-02	１以上のシルセスキオキサン配位子を含有する金属錯体
CA2457727A1 (fr)	2003-02-27	Procede d'elimination d'amines pour la fabrication de catalyseurs a site unique
JPH04227607A (ja)	1992-08-17	エチレンの重合および共重合のための触媒成分
JP3361579B2 (ja)	2003-01-07	オレフィン重合用触媒およびオレフィン重合体の製造法
JP4166086B2 (ja)	2008-10-15	非メタロセン、その製造法及びそのオレフィンの重合への使用法
KR20050025120A (ko)	2005-03-11	마그네슘 디클로라이드-알콜 부가물 및 이로부터 수득되는촉매 성분
CN100523011C (zh)	2009-08-05	催化剂组分的制备方法和由此获得的组分
KR19990075427A (ko)	1999-10-15	올레핀 중합용 촉매의 제조 방법
FI76099B (fi)	1988-05-31	Katalysatorkomponenter foer polymerisationskatalysatorer foer -olefiner och foerfarande foer framstaellning av dessa.
CN101412768B (zh)	2012-05-30	一种镁化合物负载型非茂金属催化剂及其制备方法
FI76100B (fi)	1988-05-31	Katalytkomponenter foer polymerisationskatalyt foer -olefiner och foerfarande foer framstaellning av dessa.