FR2361482A1 - Procede de recuperation du zinc - Google Patents
Procede de recuperation du zincInfo
- Publication number
- FR2361482A1 FR2361482A1 FR7724648A FR7724648A FR2361482A1 FR 2361482 A1 FR2361482 A1 FR 2361482A1 FR 7724648 A FR7724648 A FR 7724648A FR 7724648 A FR7724648 A FR 7724648A FR 2361482 A1 FR2361482 A1 FR 2361482A1
- Authority
- FR
- France
- Prior art keywords
- manganese
- zinc
- solution
- electrolytic
- electrolytic cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title abstract 5
- 239000011701 zinc Substances 0.000 title abstract 5
- 229910052725 zinc Inorganic materials 0.000 title abstract 5
- 238000011084 recovery Methods 0.000 title 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 6
- 239000000243 solution Substances 0.000 abstract 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000011572 manganese Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 229910001437 manganese ion Inorganic materials 0.000 abstract 1
- 235000007079 manganese sulphate Nutrition 0.000 abstract 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical class [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 235000009529 zinc sulphate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/21—Manganese oxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Unknown Constitution (AREA)
Abstract
Le procédé selon l'invention se distingue en ce qu'on lessive cette matière avec une solution aqueuse d'acide sulfurique pour produire une solution aqueuse contenant des sulfates de zinc et de manganèse dissous, cette solution contenant environ 30 à 100 g/l d'ions zinc et environ 5 à 45 g/l d'ions manganèse, on fait passer ladite solution à travers des cellules à électrolyse qui se suivent, on électrolyse cette solution dans la première de ces cellules dans des conditions inhibant la formation de bioxyde de manganèse et favorisant le dépôt de zinc, on électrolyse la solution obtenue dans une autre desdites cellules à électrolyse dans des conditions favorisant la formation de bioxyde de manganèse, on récupère le zinc de ladite première cellule à électrolyse et le bioxyde de manganèse de ladite première cellule à électrolyse et le bioxyde de manganèse de ladite seconde cellule à electrolyse. Ce procédé est destiné au traitement de matières contenant du zinc et une proportion relativement forte de manganèse.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA258,881A CA1066656A (fr) | 1976-08-11 | 1976-08-11 | Recuperation electrolytique du bioxyde de zinc et du manganese |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2361482A1 true FR2361482A1 (fr) | 1978-03-10 |
| FR2361482B1 FR2361482B1 (fr) | 1981-12-18 |
Family
ID=4106630
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7724648A Granted FR2361482A1 (fr) | 1976-08-11 | 1977-08-10 | Procede de recuperation du zinc |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4071421A (fr) |
| JP (1) | JPS5321035A (fr) |
| AU (1) | AU506037B2 (fr) |
| BE (1) | BE857654A (fr) |
| CA (1) | CA1066656A (fr) |
| DE (1) | DE2736232A1 (fr) |
| ES (1) | ES461542A1 (fr) |
| FI (1) | FI772386A7 (fr) |
| FR (1) | FR2361482A1 (fr) |
| GB (1) | GB1525458A (fr) |
| IE (1) | IE45306B1 (fr) |
| NL (1) | NL7708712A (fr) |
| NO (1) | NO772810L (fr) |
| PH (1) | PH13567A (fr) |
| YU (1) | YU174677A (fr) |
| ZA (1) | ZA774333B (fr) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4149945A (en) * | 1978-04-13 | 1979-04-17 | Kennecott Copper Corporation | Hydrometallurgical brass dust reclamation |
| US4149880A (en) * | 1978-07-19 | 1979-04-17 | Kennecott Copper Corporation | Recovery of copper from arsenic containing metallurgical waste materials |
| CA1141172A (fr) * | 1978-12-20 | 1983-02-15 | Gerald L. Bolton | Separation des ions de manganese en presence dans le zinc et dans les solutions a teneur de manganese |
| US4274931A (en) * | 1979-01-24 | 1981-06-23 | National Institute For Metallurgy | Leaching process for zinc sulphide containing materials |
| US4330379A (en) * | 1979-01-24 | 1982-05-18 | National Institute For Metallurgy | Leaching of zinc containing sulphide minerals |
| US4225342A (en) * | 1979-09-21 | 1980-09-30 | Texasgulf Inc. | Treatment of zinc plant leach residues for recovery of the contained metal values |
| CH679158A5 (fr) * | 1989-07-20 | 1991-12-31 | Recytec S A C O Orfigest S A | |
| US5419882A (en) * | 1994-04-22 | 1995-05-30 | Noranda Inc. | Method for the removal of thallium |
| JPH10504060A (ja) * | 1994-08-15 | 1998-04-14 | アール・アンド・オー・マイニング・プロセシング・リミテッド | 硫化亜鉛含有鉱石及び精鉱から硫酸塩への硫化亜鉛の湿式製錬転化 |
| CA2221779C (fr) * | 1995-06-07 | 2004-09-28 | Cominco Ltd. | Regulation de l'oxydoreduction dans le depot de metaux par electrolyse |
| US5912402A (en) * | 1995-10-30 | 1999-06-15 | Drinkard Metalox, Inc. | Metallurgical dust recycle process |
| EP0885976B1 (fr) * | 1997-06-20 | 2002-03-06 | Sulfacid S.A.I.F.C. | Production électrolytique de zinc métallique pur à partir de solutions zincifères contaminées en manganèse précédée d'une démanganisation électrolytique à l'état froid |
| WO2001073165A1 (fr) * | 1999-05-05 | 2001-10-04 | Michael John Thom | Extraction de manganese dans des electrolytes |
| GB0031413D0 (en) | 2000-12-21 | 2001-02-07 | Aea Technology Plc | Electrochemical processing |
| CA2459899C (fr) * | 2001-09-13 | 2010-11-23 | Intec Ltd | Procede d'extraction de zinc |
| RU2298585C9 (ru) * | 2001-09-13 | 2007-08-10 | Интек Лтд | Способ извлечения цинка |
| CN1321224C (zh) * | 2004-08-02 | 2007-06-13 | 西安建筑科技大学 | 废旧电池综合处理中锌和二氧化锰分离、提纯方法 |
| RU2301287C2 (ru) * | 2005-07-26 | 2007-06-20 | Лидия Алексеевна Воропанова | Электрохимический способ очистки водных растворов цинка от марганца |
| CN102347521A (zh) * | 2011-10-08 | 2012-02-08 | 佛山市邦普循环科技有限公司 | 一种电动汽车用动力型锰酸锂电池中锰和锂的回收方法 |
| US11430997B2 (en) | 2019-11-01 | 2022-08-30 | Battery Reclamation Research Associates Llc | Process for separating and recycling a spent alkaline battery |
| JP2023525046A (ja) * | 2020-05-07 | 2023-06-14 | ベフェサ・ジンク・メタル・エルエルシー | 硫酸マンガンを調製するための方法、システム、及び装置 |
| CN115369237B (zh) * | 2022-09-21 | 2023-08-22 | 云南驰宏资源综合利用有限公司 | 一种锌冶炼锰离子产耗平衡的方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE466279C (de) * | 1927-05-05 | 1928-10-03 | Urlyn Clifton Tainton | Verfahren zum elektrolytischen Faellen von Zink |
| FR1299751A (fr) * | 1961-06-30 | 1962-07-27 | Montevecchio Soc It Del Piombo | Procédé pour la production électrolytique de zinc purissime |
| FR1538886A (fr) * | 1966-10-22 | 1968-09-06 | Union Carbide Canada Ltd | Procédé électrolytique de production simultanée de bioxyde de manganèse et de zinc |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US556092A (en) * | 1896-03-10 | Oscar frolich | ||
| US3065155A (en) * | 1960-09-02 | 1962-11-20 | Manganese Chemicals Corp | Electrolytic manganese dioxide process |
| US3438878A (en) * | 1966-10-27 | 1969-04-15 | Union Carbide Canada Ltd | Simultaneous refining of zinc and manganese dioxide |
| US3844912A (en) * | 1973-06-27 | 1974-10-29 | Mitsui Mining & Smelting Co | Process for treating electrolytic manganese dioxide |
-
1973
- 1973-08-03 PH PH20072A patent/PH13567A/en unknown
-
1976
- 1976-08-11 CA CA258,881A patent/CA1066656A/fr not_active Expired
- 1976-09-17 US US05/724,423 patent/US4071421A/en not_active Expired - Lifetime
-
1977
- 1977-07-14 YU YU174677A patent/YU174677A/xx unknown
- 1977-07-15 IE IE1477/77A patent/IE45306B1/en unknown
- 1977-07-19 ZA ZA00774333A patent/ZA774333B/xx unknown
- 1977-07-28 GB GB3180077A patent/GB1525458A/en not_active Expired
- 1977-08-05 NL NL7708712A patent/NL7708712A/xx not_active Application Discontinuation
- 1977-08-08 FI FI772386A patent/FI772386A7/fi not_active Application Discontinuation
- 1977-08-09 AU AU27734/77A patent/AU506037B2/en not_active Expired
- 1977-08-10 JP JP9520977A patent/JPS5321035A/ja active Pending
- 1977-08-10 FR FR7724648A patent/FR2361482A1/fr active Granted
- 1977-08-10 NO NO772810A patent/NO772810L/no unknown
- 1977-08-10 BE BE180054A patent/BE857654A/fr not_active IP Right Cessation
- 1977-08-11 ES ES461542A patent/ES461542A1/es not_active Expired
- 1977-08-11 DE DE19772736232 patent/DE2736232A1/de not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE466279C (de) * | 1927-05-05 | 1928-10-03 | Urlyn Clifton Tainton | Verfahren zum elektrolytischen Faellen von Zink |
| FR1299751A (fr) * | 1961-06-30 | 1962-07-27 | Montevecchio Soc It Del Piombo | Procédé pour la production électrolytique de zinc purissime |
| FR1538886A (fr) * | 1966-10-22 | 1968-09-06 | Union Carbide Canada Ltd | Procédé électrolytique de production simultanée de bioxyde de manganèse et de zinc |
Also Published As
| Publication number | Publication date |
|---|---|
| IE45306L (en) | 1978-02-11 |
| DE2736232A1 (de) | 1978-02-16 |
| AU506037B2 (en) | 1979-12-13 |
| FI772386A7 (fr) | 1978-02-12 |
| YU174677A (en) | 1982-06-30 |
| IE45306B1 (en) | 1982-07-28 |
| ES461542A1 (es) | 1978-06-01 |
| ZA774333B (en) | 1978-06-28 |
| JPS5321035A (en) | 1978-02-27 |
| BE857654A (fr) | 1977-12-01 |
| FR2361482B1 (fr) | 1981-12-18 |
| NL7708712A (nl) | 1978-02-14 |
| PH13567A (en) | 1980-06-26 |
| AU2773477A (en) | 1979-02-15 |
| NO772810L (no) | 1978-02-14 |
| GB1525458A (en) | 1978-09-20 |
| US4071421A (en) | 1978-01-31 |
| CA1066656A (fr) | 1979-11-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |