FR2387973A1 - Procede de preparation de pyrones a partir d'alcools 2,5-dialkoxyfurfuryliques substitues en position 3 - Google Patents
Procede de preparation de pyrones a partir d'alcools 2,5-dialkoxyfurfuryliques substitues en position 3Info
- Publication number
- FR2387973A1 FR2387973A1 FR7810404A FR7810404A FR2387973A1 FR 2387973 A1 FR2387973 A1 FR 2387973A1 FR 7810404 A FR7810404 A FR 7810404A FR 7810404 A FR7810404 A FR 7810404A FR 2387973 A1 FR2387973 A1 FR 2387973A1
- Authority
- FR
- France
- Prior art keywords
- pyrones
- preparing
- hydroxy
- dialkoxyfurfuryl
- alcohols substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
- C07D309/34—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D309/36—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms
- C07D309/40—Oxygen atoms attached in positions 3 and 4, e.g. maltol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyrane Compounds (AREA)
- Saccharide Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Furan Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Seasonings (AREA)
Abstract
L'invention concerne un procédé de préparation de pyrones. On obtient par mise en contact des alcools 2,5-dialkoxy-furfuryliques substitués en position 3 correspondants avec un acide des beta -dihydropyrones en opérant entre - 50 et + 25 degrés C ou des gamma-pyrones en effectuant une hydrolyse complète par chauffage. Application par exemple à la production du maltol ou 2-methyl-3-hydroxy-4H-pyranne-4-one, substance rehaussant le goût et l'arôme de divers produits alimentaires, à partir de 2-(1-hydroxy-éthyl)-2,3,5-trialkoxy-furannes ou de 2-(1-hydroxy-éthyl)2,5-dialkoxy-3-halogéno-furannes.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/741,348 US4126624A (en) | 1976-11-12 | 1976-11-12 | Preparation of gamma-pyrones from 3-substituted furans |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2387973A1 true FR2387973A1 (fr) | 1978-11-17 |
| FR2387973B1 FR2387973B1 (fr) | 1983-02-25 |
Family
ID=24980357
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7733949A Granted FR2385710A1 (fr) | 1976-11-12 | 1977-11-10 | Procede de preparation de pyrones a partir d'alcools furfuryliques substitues en position 3 |
| FR7810404A Granted FR2387973A1 (fr) | 1976-11-12 | 1978-04-07 | Procede de preparation de pyrones a partir d'alcools 2,5-dialkoxyfurfuryliques substitues en position 3 |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7733949A Granted FR2385710A1 (fr) | 1976-11-12 | 1977-11-10 | Procede de preparation de pyrones a partir d'alcools furfuryliques substitues en position 3 |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US4126624A (fr) |
| JP (2) | JPS5363381A (fr) |
| AR (1) | AR217267A1 (fr) |
| AU (1) | AU499476B1 (fr) |
| BE (1) | BE860699A (fr) |
| BR (1) | BR7707529A (fr) |
| CA (1) | CA1109478A (fr) |
| DD (1) | DD134349A5 (fr) |
| DE (1) | DE2750553C2 (fr) |
| DK (1) | DK502077A (fr) |
| ES (1) | ES464045A1 (fr) |
| FI (1) | FI773367A7 (fr) |
| FR (2) | FR2385710A1 (fr) |
| GB (1) | GB1543897A (fr) |
| IE (1) | IE46411B1 (fr) |
| IT (1) | IT1109435B (fr) |
| LU (1) | LU78503A1 (fr) |
| MX (1) | MX4750E (fr) |
| NL (1) | NL167163C (fr) |
| NO (1) | NO773868L (fr) |
| PL (1) | PL202091A1 (fr) |
| PT (1) | PT67234B (fr) |
| SE (1) | SE7711964L (fr) |
| TR (1) | TR19727A (fr) |
| ZA (1) | ZA776744B (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5481273A (en) * | 1977-12-12 | 1979-06-28 | Shin Etsu Chem Co Ltd | Preparation of pyranone halide |
| JPS59192558U (ja) * | 1983-06-07 | 1984-12-20 | 株式会社多川工業 | 粉砕機等のア−ム旋回装置 |
| JP2586607B2 (ja) * | 1987-10-30 | 1997-03-05 | 日産化学工業株式会社 | 光学活性アルコールの製造法 |
| BR9408521A (pt) * | 1994-01-31 | 1997-08-19 | Pfizer | Método para sintetizar gama-pironas |
| CN107089962B (zh) * | 2017-04-18 | 2019-09-10 | 山东新和成药业有限公司 | 一种由分子氧氧化制备麦芽酚及同系物的方法 |
| CN111533719B (zh) * | 2020-04-29 | 2022-04-01 | 广东省肇庆华格生物科技有限公司 | 一种乙基麦芽酚的合成工艺 |
| CN112778257A (zh) * | 2021-01-21 | 2021-05-11 | 香港科技大学 | 一种将糠醇氧化为二氢吡喃酮类衍生物的绿色方法 |
| CN118005589A (zh) * | 2023-12-27 | 2024-05-10 | 大连理工大学 | 一种由取代2,5-二氢呋喃甲醇一步制备6-甲氧基二氢吡喃酮的合成方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3491122A (en) * | 1966-09-14 | 1970-01-20 | Monsanto Co | Synthesis of 4-pyrones |
| US3547912A (en) * | 1968-07-29 | 1970-12-15 | American Home Prod | Derivatives of 2h-pyran-3(6h)-ones and preparation thereof |
| US3832357A (en) * | 1971-05-26 | 1974-08-27 | Daicel Ltd | Process for preparation of 3-hydroxy-2-alkyl-4-pyrone |
-
1976
- 1976-11-12 US US05/741,348 patent/US4126624A/en not_active Expired - Lifetime
-
1977
- 1977-10-14 AU AU29689/77A patent/AU499476B1/en not_active Expired
- 1977-10-24 SE SE7711964A patent/SE7711964L/xx unknown
- 1977-11-03 PT PT67234A patent/PT67234B/pt unknown
- 1977-11-03 MX MX776518U patent/MX4750E/es unknown
- 1977-11-08 IT IT51737/77A patent/IT1109435B/it active
- 1977-11-08 JP JP13405277A patent/JPS5363381A/ja active Granted
- 1977-11-08 TR TR19727A patent/TR19727A/xx unknown
- 1977-11-09 FI FI773367A patent/FI773367A7/fi not_active Application Discontinuation
- 1977-11-09 GB GB46568/77A patent/GB1543897A/en not_active Expired
- 1977-11-10 BR BR7707529A patent/BR7707529A/pt unknown
- 1977-11-10 FR FR7733949A patent/FR2385710A1/fr active Granted
- 1977-11-10 CA CA290,679A patent/CA1109478A/fr not_active Expired
- 1977-11-10 BE BE182521A patent/BE860699A/fr not_active IP Right Cessation
- 1977-11-11 DE DE2750553A patent/DE2750553C2/de not_active Expired
- 1977-11-11 ZA ZA00776744A patent/ZA776744B/xx unknown
- 1977-11-11 LU LU78503A patent/LU78503A1/fr unknown
- 1977-11-11 AR AR269941A patent/AR217267A1/es active
- 1977-11-11 NO NO773868A patent/NO773868L/no unknown
- 1977-11-11 NL NL7712427.A patent/NL167163C/xx not_active IP Right Cessation
- 1977-11-11 ES ES464045A patent/ES464045A1/es not_active Expired
- 1977-11-11 DK DK502077A patent/DK502077A/da not_active Application Discontinuation
- 1977-11-11 IE IE2296/77A patent/IE46411B1/en unknown
- 1977-11-11 DD DD77202032A patent/DD134349A5/xx unknown
- 1977-11-12 PL PL20209177A patent/PL202091A1/xx unknown
-
1978
- 1978-04-07 FR FR7810404A patent/FR2387973A1/fr active Granted
-
1979
- 1979-05-16 JP JP54060248A patent/JPS5814434B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FI773367A7 (fi) | 1978-05-13 |
| FR2385710B1 (fr) | 1983-01-07 |
| BE860699A (fr) | 1978-05-10 |
| PT67234A (en) | 1977-12-01 |
| FR2387973B1 (fr) | 1983-02-25 |
| DE2750553C2 (de) | 1983-06-30 |
| IE46411B1 (en) | 1983-06-01 |
| JPS5516588B2 (fr) | 1980-05-02 |
| JPS5363381A (en) | 1978-06-06 |
| JPS5511568A (en) | 1980-01-26 |
| MX4750E (es) | 1982-08-31 |
| NL167163B (nl) | 1981-06-16 |
| JPS5814434B2 (ja) | 1983-03-18 |
| AR217267A1 (es) | 1980-03-14 |
| US4126624A (en) | 1978-11-21 |
| CA1109478A (fr) | 1981-09-22 |
| TR19727A (tr) | 1979-11-23 |
| FR2385710A1 (fr) | 1978-10-27 |
| ES464045A1 (es) | 1978-08-01 |
| NL7712427A (nl) | 1978-05-17 |
| ZA776744B (en) | 1978-10-25 |
| GB1543897A (en) | 1979-04-11 |
| DE2750553A1 (de) | 1978-05-18 |
| SE7711964L (sv) | 1978-05-13 |
| DD134349A5 (de) | 1979-02-21 |
| NL167163C (nl) | 1981-11-16 |
| PL202091A1 (pl) | 1979-06-04 |
| NO773868L (no) | 1978-05-16 |
| BR7707529A (pt) | 1978-06-20 |
| PT67234B (en) | 1979-04-16 |
| LU78503A1 (fr) | 1979-06-13 |
| IE772296L (en) | 1978-05-12 |
| DK502077A (da) | 1978-05-13 |
| IT1109435B (it) | 1985-12-16 |
| AU499476B1 (en) | 1979-04-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |