FR2405268A1 - Procede de polymerisation du chlorure de vinyle - Google Patents
Procede de polymerisation du chlorure de vinyleInfo
- Publication number
- FR2405268A1 FR2405268A1 FR7828578A FR7828578A FR2405268A1 FR 2405268 A1 FR2405268 A1 FR 2405268A1 FR 7828578 A FR7828578 A FR 7828578A FR 7828578 A FR7828578 A FR 7828578A FR 2405268 A1 FR2405268 A1 FR 2405268A1
- Authority
- FR
- France
- Prior art keywords
- polymerization
- vinyl chloride
- acrylates
- calcium
- polymerization process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 239000011575 calcium Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical class [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 abstract 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 1
- 239000004593 Epoxy Substances 0.000 abstract 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La polymérisation du chlorure de vinyle monomère est effectuée par polymérisation en suspension ou en émulsion, éventuellement en présence d'un comonomère à insaturation monoéthylénique, en présence d'un mélange d'acrylates de calcium et de zinc. La présence des acrylates de calcium et de zinc permet d'obtenir un produit plus stable à la chaleur et de réduire la quantité de dépôt de polymère formé pendant la polymérisation. La stabilité thermique est encore améliorée en effectuant la polymérisation en présence, en plus des acrylates, d'un composé époxy contenant un groupe vinyle ou allyle réactif. Application : polymère de chlorure de vinyle thermiquement stable.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/839,855 US4146698A (en) | 1977-10-06 | 1977-10-06 | Process for the polymerization of vinyl chloride in the presence of calcium & zinc acrylate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2405268A1 true FR2405268A1 (fr) | 1979-05-04 |
| FR2405268B1 FR2405268B1 (fr) | 1985-05-17 |
Family
ID=25280801
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7828578A Granted FR2405268A1 (fr) | 1977-10-06 | 1978-10-06 | Procede de polymerisation du chlorure de vinyle |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4146698A (fr) |
| JP (1) | JPS5462291A (fr) |
| AU (1) | AU520528B2 (fr) |
| BE (1) | BE871054A (fr) |
| CA (1) | CA1120644A (fr) |
| CH (1) | CH638541A5 (fr) |
| DE (1) | DE2843033A1 (fr) |
| DK (1) | DK444978A (fr) |
| FR (1) | FR2405268A1 (fr) |
| GB (1) | GB2005699B (fr) |
| IL (1) | IL55262A (fr) |
| IT (1) | IT7851399A0 (fr) |
| NL (1) | NL7810065A (fr) |
| NO (1) | NO783382L (fr) |
| SE (1) | SE7810443L (fr) |
| YU (1) | YU40048B (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55162451A (en) * | 1979-05-31 | 1980-12-17 | Sekisui Chem Co Ltd | Interlayer composition for safety laminated glass |
| GB2206122A (en) * | 1987-06-22 | 1988-12-29 | Aqualon Co | Process for preparation of polymers by suspension polymerization of a vinyl monomer in the presence of a hydrophobically modified water-soluble, nonionic cellulose ether polymer in combination with an electrolyte and polymers prepared by same |
| JP3062917B2 (ja) * | 1994-09-01 | 2000-07-12 | 日本ペイント株式会社 | 加水分解型金属含有樹脂および防汚塗料組成物 |
| DE60326878D1 (de) * | 2002-12-04 | 2009-05-07 | Blue Goo L L C | Metallacrylate als härter für polybutadiene, melamine und epoxyverbindungen |
| US7396869B2 (en) * | 2002-12-04 | 2008-07-08 | Denovus Llc | Metallic acrylate curing agents and usage thereof in intermediate compositions |
| US7528189B2 (en) * | 2002-12-04 | 2009-05-05 | Blue Goo, Llc | Metal-acrylate curing agents |
| DE10309858A1 (de) * | 2003-03-06 | 2004-09-23 | Wacker Polymer Systems Gmbh & Co. Kg | Thermostabile Vinylchlorid-Mischpolymerisate |
| US20060062998A1 (en) * | 2004-06-10 | 2006-03-23 | Taylor Donald W | Reinforcement for composite materials and method for making the reforcement |
| CN106519127B (zh) * | 2016-12-01 | 2018-08-24 | 贵州华锐达环保装饰材料有限公司 | 制备钙锌环氧共聚核壳乳液及改性木塑材料的方法 |
| CN107417843A (zh) * | 2017-06-16 | 2017-12-01 | 杭州电化集团有限公司 | 一种不含有机锡的氯醚树脂制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4937989A (fr) * | 1972-08-16 | 1974-04-09 | ||
| JPS5038745A (fr) * | 1973-08-10 | 1975-04-10 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE663220C (de) * | 1935-10-19 | 1938-08-02 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von gegen Licht und Hitze bestaendigen Polymerisationsprodukten aus Vinylchlorid |
| GB595447A (en) | 1943-12-03 | 1947-12-05 | Distillers Co Yeast Ltd | Improvements in or relating to the manufacture of synthetic resins |
| US2585506A (en) * | 1948-06-21 | 1952-02-12 | Shell Dev | Stabilization of halogen-containing organic materials |
| US2604463A (en) * | 1949-04-28 | 1952-07-22 | Canadian Ind | Cross-linkable and cross-linked vinyl type copolymers |
| US2687405A (en) * | 1950-02-16 | 1954-08-24 | Du Pont | Allyl glycidyl ether/acrylate ester copolymers |
| US2562897A (en) * | 1950-05-06 | 1951-08-07 | Du Pont | Copolymers of vinyl chloride, allyl glycidyl ether, and allyl esters of hydroxyalkanoic acids |
| US2589237A (en) * | 1950-08-25 | 1952-03-18 | Du Pont | Vinyl chloride-allyl glycidyl ether copolymers |
| US2607754A (en) * | 1951-06-29 | 1952-08-19 | Du Pont | Copolymers of vinyl chloride, allyl glycidyl ether, and an allyloxyalkanoic acid |
| US2669549A (en) * | 1951-12-21 | 1954-02-16 | Monsanto Chemicals | Stabilized halogen-containing resins |
| US2993034A (en) * | 1955-06-02 | 1961-07-18 | Swern Daniel | Copolymers of vinyl chloride and vinyl epoxystearate |
| US3065213A (en) * | 1959-09-02 | 1962-11-20 | Hercules Powder Co Ltd | Homopolymers of allyl glycidyl ether |
| US3294658A (en) * | 1963-07-22 | 1966-12-27 | Dow Chemical Co | Selective polymerization of unsaturated epoxides |
| US3370731A (en) * | 1966-06-06 | 1968-02-27 | John J. Ehrbar | Safety closure device for a container |
| FR2032513A6 (en) | 1969-01-16 | 1970-11-27 | Aquitaine Petrole | Internally stabilised vinyl chloride terpolymers |
| US3642741A (en) * | 1968-12-23 | 1972-02-15 | Chevron Res | Copolymers of vinyl chloride and epoxy-alpha-olefins |
| US3705137A (en) * | 1969-12-04 | 1972-12-05 | Mitsui Mining & Smelting Co | Precipitation copolymerization of metal salts of unsaturated carboxylic acids |
| DE91560C (fr) * | 1970-05-07 | |||
| US3862066A (en) * | 1971-05-26 | 1975-01-21 | Universal Pvc Resins | Method for making rigid vinyl chloride polymer compounds |
| GB1460221A (en) | 1974-01-21 | 1976-12-31 | British Petroleum Co | Stabilised vinyl chloride polymers |
-
1977
- 1977-10-06 US US05/839,855 patent/US4146698A/en not_active Expired - Lifetime
-
1978
- 1978-08-01 IL IL55262A patent/IL55262A/xx unknown
- 1978-08-04 AU AU38647/78A patent/AU520528B2/en not_active Expired
- 1978-09-27 YU YU2282/78A patent/YU40048B/xx unknown
- 1978-10-03 DE DE19782843033 patent/DE2843033A1/de not_active Withdrawn
- 1978-10-04 GB GB7839199A patent/GB2005699B/en not_active Expired
- 1978-10-05 SE SE7810443A patent/SE7810443L/xx unknown
- 1978-10-05 CH CH1037778A patent/CH638541A5/de not_active IP Right Cessation
- 1978-10-05 NO NO783382A patent/NO783382L/no unknown
- 1978-10-05 NL NL7810065A patent/NL7810065A/xx not_active Application Discontinuation
- 1978-10-05 CA CA000312720A patent/CA1120644A/fr not_active Expired
- 1978-10-05 JP JP12311678A patent/JPS5462291A/ja active Pending
- 1978-10-06 BE BE2057337A patent/BE871054A/xx not_active IP Right Cessation
- 1978-10-06 FR FR7828578A patent/FR2405268A1/fr active Granted
- 1978-10-06 DK DK444978A patent/DK444978A/da not_active Application Discontinuation
- 1978-10-06 IT IT7851399A patent/IT7851399A0/it unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4937989A (fr) * | 1972-08-16 | 1974-04-09 | ||
| JPS5038745A (fr) * | 1973-08-10 | 1975-04-10 |
Non-Patent Citations (2)
| Title |
|---|
| CA1974 * |
| CA1975 * |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2405268B1 (fr) | 1985-05-17 |
| US4146698A (en) | 1979-03-27 |
| DE2843033A1 (de) | 1979-04-19 |
| GB2005699A (en) | 1979-04-25 |
| AU3864778A (en) | 1980-02-07 |
| NO783382L (no) | 1979-04-09 |
| BE871054A (nl) | 1979-04-06 |
| IT7851399A0 (it) | 1978-10-06 |
| JPS5462291A (en) | 1979-05-19 |
| NL7810065A (nl) | 1979-04-10 |
| YU40048B (en) | 1985-06-30 |
| CH638541A5 (de) | 1983-09-30 |
| AU520528B2 (en) | 1982-02-04 |
| YU228278A (en) | 1982-06-30 |
| DK444978A (da) | 1979-04-07 |
| IL55262A (en) | 1981-10-30 |
| GB2005699B (en) | 1982-03-31 |
| IL55262A0 (en) | 1978-10-31 |
| CA1120644A (fr) | 1982-03-23 |
| SE7810443L (sv) | 1979-04-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |