FR2417518A2 - Procede d'obtention en continu de polyamides derives de la paraphenylenediamine - Google Patents
Procede d'obtention en continu de polyamides derives de la paraphenylenediamineInfo
- Publication number
- FR2417518A2 FR2417518A2 FR7805000A FR7805000A FR2417518A2 FR 2417518 A2 FR2417518 A2 FR 2417518A2 FR 7805000 A FR7805000 A FR 7805000A FR 7805000 A FR7805000 A FR 7805000A FR 2417518 A2 FR2417518 A2 FR 2417518A2
- Authority
- FR
- France
- Prior art keywords
- phenylenediamine
- cacl2
- soln
- nmp
- diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 title abstract 3
- 239000004952 Polyamide Substances 0.000 title abstract 3
- 229920002647 polyamide Polymers 0.000 title abstract 3
- 239000002904 solvent Substances 0.000 title abstract 3
- LXEJRKJRKIFVNY-UHFFFAOYSA-N terephthaloyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C=C1 LXEJRKJRKIFVNY-UHFFFAOYSA-N 0.000 title abstract 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 title abstract 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 3
- 239000001110 calcium chloride Substances 0.000 abstract 3
- 229910001628 calcium chloride Inorganic materials 0.000 abstract 3
- 235000011148 calcium chloride Nutrition 0.000 abstract 3
- 150000004985 diamines Chemical class 0.000 abstract 3
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 abstract 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 1
- BEWOBXRVEXRJFN-UHFFFAOYSA-N 3-amino-n'-(4-aminophenyl)-n-phenylhexanediamide Chemical compound C=1C=CC=CC=1NC(=O)CC(N)CCC(=O)NC1=CC=C(N)C=C1 BEWOBXRVEXRJFN-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- PWAXUOGZOSVGBO-UHFFFAOYSA-N adipoyl chloride Chemical compound ClC(=O)CCCCC(Cl)=O PWAXUOGZOSVGBO-UHFFFAOYSA-N 0.000 abstract 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 238000001149 thermolysis Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
L'invention concerne un procédé en continu d'obtention de polyparaphénylènetéréphtalamide et ses copolymères de viscosité inhérente d'au moins 3. On fait réagir en quantités stoechiométriques du chlorure de téréphtaloyle et/ou d adipoyle sur une solution de paraphénylènediamine et/ou de diamino-4,4'-adipanilide et d'un prépolymère formé à partir d'au moins un chlorure et au moins une diamine parmi ceux cités ci-dessus dans un mélange de N-méthylpyrrolidone-2 et de chlorure de calcium homogène et substantiellement anhydre, avec un rapport molaire CaCl 2 motif :
Priority Applications (16)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7805000A FR2417518A2 (fr) | 1978-02-20 | 1978-02-20 | Procede d'obtention en continu de polyamides derives de la paraphenylenediamine |
| US05/897,500 US4297479A (en) | 1977-04-27 | 1978-04-18 | Process for the continuous production of aromatic polyamides in a mixture of calcium chloride and N-methylpyrrolidone-2 |
| GB16319/78A GB1602917A (en) | 1977-04-27 | 1978-04-25 | Process for the continuous production of polyamides derived from paraphenylenediamine |
| IE826/78A IE46741B1 (en) | 1977-04-27 | 1978-04-26 | Process for the continuous production of polyamides derived from para-phenylenediamine |
| CA302,069A CA1096542A (fr) | 1977-04-27 | 1978-04-26 | Polycondensation dans un melange de n- methylpyrrolidone et de cacl.sub.2 en continu |
| JP4880678A JPS5496A (en) | 1977-04-27 | 1978-04-26 | Method of continuously making polyamides derived from paraaphenylene diamine |
| BR7802623A BR7802623A (pt) | 1977-04-27 | 1978-04-26 | Processo para a obtencao em continuo de uma poliamida |
| DK180978A DK180978A (da) | 1977-04-27 | 1978-04-26 | Fremgangsmaade til kontinuerlig fremstilling af polyamider |
| SE7804807A SE444176B (sv) | 1977-04-27 | 1978-04-26 | Forfarande for kontinuerlig framstellning av en losning av en polyamid i blandning med n-metyl-2-pyrrolidon och kalciumklorid |
| NL7804476A NL7804476A (nl) | 1977-04-27 | 1978-04-26 | Werkwijze voor de continue bereiding van polymeren af- geleid van p-fenyleendiamine. |
| LU79531A LU79531A1 (fr) | 1977-04-27 | 1978-04-26 | Procede d'obtention en continu de polyamides derives de la para-phenylenediamine |
| CH451978A CH630933A5 (fr) | 1977-04-27 | 1978-04-26 | Procede d'obtention en continu de polyamides derives de la para-phenylenediamine. |
| DE19782818670 DE2818670A1 (de) | 1977-04-27 | 1978-04-27 | Verfahren zur kontinuierlichen herstellung von polyamiden, die sich vom p-phenylendiamin ableiten |
| IT22752/78A IT1113074B (it) | 1977-04-27 | 1978-04-27 | Procedimento per ottenere con marcia continua poliammidi derivate dall p-fenilendiammina |
| AT0304178A AT379156B (de) | 1977-04-27 | 1978-04-27 | Verfahren zur herstellung eines verspinnbaren polyamids |
| ES469213A ES469213A1 (es) | 1977-04-27 | 1978-04-27 | Procedimiento de obtencion en continuo de poliamida. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7805000A FR2417518A2 (fr) | 1978-02-20 | 1978-02-20 | Procede d'obtention en continu de polyamides derives de la paraphenylenediamine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2417518A2 true FR2417518A2 (fr) | 1979-09-14 |
| FR2417518B2 FR2417518B2 (fr) | 1981-01-16 |
Family
ID=9204882
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7805000A Granted FR2417518A2 (fr) | 1977-04-27 | 1978-02-20 | Procede d'obtention en continu de polyamides derives de la paraphenylenediamine |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2417518A2 (fr) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2301548A1 (fr) * | 1975-02-21 | 1976-09-17 | Akzo Nv | Procede de preparation de poly (p-phenylene terephtalamide) |
-
1978
- 1978-02-20 FR FR7805000A patent/FR2417518A2/fr active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2301548A1 (fr) * | 1975-02-21 | 1976-09-17 | Akzo Nv | Procede de preparation de poly (p-phenylene terephtalamide) |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2417518B2 (fr) | 1981-01-16 |
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