FR2507600A1 - Procede de preparation de l'anhydride phtalique a partir de l'orthoxylene, du naphtalene et leurs melanges par oxydation en presence d'un catalyseur specifique, catalyseur obtenu dans la mise en oeuvre de ce procede et appareillage pour la mise en oeuvre de ce procede - Google Patents

Procede de preparation de l'anhydride phtalique a partir de l'orthoxylene, du naphtalene et leurs melanges par oxydation en presence d'un catalyseur specifique, catalyseur obtenu dans la mise en oeuvre de ce procede et appareillage pour la mise en oeuvre de ce procede Download PDF

Info

Publication number: FR2507600A1
Authority: FR; France
Prior art keywords: naphthalene; xylene; catalyst; ortho; implementation
Prior art date: 1981-06-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

FR8210324A

Other languages

English (en)

French (fr)

Inventor

Francesco Benedetti

Ezio Polacco

Angelo Celli

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Carbochimica Italiana SpA

Original Assignee

Carbochimica Italiana SpA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-06-16

Filing date

1982-06-14

Publication date

1982-12-17

1982-06-14 Application filed by Carbochimica Italiana SpA filed Critical Carbochimica Italiana SpA

1982-12-17 Publication of FR2507600A1 publication Critical patent/FR2507600A1/fr

Status Withdrawn legal-status Critical Current

Links

UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 title claims abstract description 70
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 title claims abstract description 64
239000003054 catalyst Substances 0.000 title claims abstract description 32
238000000034 method Methods 0.000 title claims description 22
230000008569 process Effects 0.000 title claims description 17
238000007254 oxidation reaction Methods 0.000 title claims description 13
230000003647 oxidation Effects 0.000 title claims description 12
238000002360 preparation method Methods 0.000 title claims description 3
239000000203 mixture Substances 0.000 title abstract description 13
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 title abstract description 12
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 title abstract description 12
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 18
238000004519 manufacturing process Methods 0.000 claims abstract description 15
239000000126 substance Substances 0.000 claims abstract description 4
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 claims description 8
239000004408 titanium dioxide Substances 0.000 claims description 8
239000011148 porous material Substances 0.000 claims description 5
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 4
150000008064 anhydrides Chemical class 0.000 claims description 2
238000010438 heat treatment Methods 0.000 claims description 2
229910052720 vanadium Inorganic materials 0.000 claims description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
238000004064 recycling Methods 0.000 claims 2
238000011144 upstream manufacturing Methods 0.000 claims 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
229910052719 titanium Inorganic materials 0.000 abstract 1
239000010936 titanium Substances 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 9
229940078552 o-xylene Drugs 0.000 description 8
239000000047 product Substances 0.000 description 6
239000008096 xylene Substances 0.000 description 6
238000009434 installation Methods 0.000 description 3
238000002336 sorption--desorption measurement Methods 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000003344 environmental pollutant Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
231100000719 pollutant Toxicity 0.000 description 2
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
239000005711 Benzoic acid Substances 0.000 description 1
101100289200 Caenorhabditis elegans lite-1 gene Proteins 0.000 description 1
229930192627 Naphthoquinone Natural products 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
241001080061 Talides Species 0.000 description 1
229910010413 TiO 2 Inorganic materials 0.000 description 1
230000004913 activation Effects 0.000 description 1
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
150000004056 anthraquinones Chemical class 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000001354 calcination Methods 0.000 description 1
239000002775 capsule Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000003795 desorption Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000012806 monitoring device Methods 0.000 description 1
125000000896 monocarboxylic acid group Chemical group 0.000 description 1
150000002791 naphthoquinones Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
-1 oxy- Chemical class 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000003908 quality control method Methods 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
239000007921 spray Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Furan Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

FR8210324A 1981-06-16 1982-06-14 Procede de preparation de l'anhydride phtalique a partir de l'orthoxylene, du naphtalene et leurs melanges par oxydation en presence d'un catalyseur specifique, catalyseur obtenu dans la mise en oeuvre de ce procede et appareillage pour la mise en oeuvre de ce procede Withdrawn FR2507600A1 (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT8122358A IT1226043B (it)	1981-06-16	1981-06-16	Procedimento per l'ottenimento di anidride ftalica partendo da ortoxilolo, naftalina e loro miscele per ossidazione in presenza di un catalizzatore specifico e catalizzatore ottenuto con la messa in opera del procedimento

Publications (1)

Publication Number	Publication Date
FR2507600A1 true FR2507600A1 (fr)	1982-12-17

Family

ID=11195178

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FR8210324A Withdrawn FR2507600A1 (fr)	1981-06-16	1982-06-14	Procede de preparation de l'anhydride phtalique a partir de l'orthoxylene, du naphtalene et leurs melanges par oxydation en presence d'un catalyseur specifique, catalyseur obtenu dans la mise en oeuvre de ce procede et appareillage pour la mise en oeuvre de ce procede

Country Status (12)

Country	Link
US (1)	US4472587A (cs)
JP (1)	JPS5874675A (cs)
AU (1)	AU8463382A (cs)
BE (1)	BE893521A (cs)
BR (1)	BR8203499A (cs)
CS (1)	CS228934B2 (cs)
DE (1)	DE3219540A1 (cs)
FR (1)	FR2507600A1 (cs)
GB (1)	GB2104066B (cs)
IT (1)	IT1226043B (cs)
YU (1)	YU130882A (cs)
ZA (1)	ZA823512B (cs)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4728503A (en) *	1984-11-02	1988-03-01	Mitsubishi Jukogyo Kabushiki Kaisha	Filter medium for treating an exhaust gas
US4705770A (en) *	1986-07-07	1987-11-10	Aristech Chemical Corporation	Method of making anatase-titania attrition-resistant catalyst composition
JPS63253080A (ja) *	1987-04-10	1988-10-20	Nippon Steel Chem Co Ltd	無水フタル酸の製造方法
DE3719476A1 (de) *	1987-06-11	1988-12-29	Huels Chemische Werke Ag	Verfahren zur herstellung von phthalsaeureanhydrid durch gasphasenoxidation eines o-xylol-naphthalin-gemisches
JPH01190677A (ja) *	1988-01-27	1989-07-31	Nippon Steel Chem Co Ltd	無水フタル酸の製造法
DE4034787A1 (de) *	1990-11-02	1992-05-07	Zimmer Ag	Verfahren zur erzeugung homogener o-xylol-naphthalin-luft-gemische fuer die phthalsaeureanhydrid-herstellung
CZ282750B6 (cs) *	1991-10-25	1997-09-17	Nippon Shokubai Co., Ltd.	Způsob přípravy ftalanhydridu oxidací směsi ortho-xylenu s naftalenem v plynné fázi
DE19823275A1 (de)	1998-05-26	1999-12-02	Basf Ag	Verfahren zur Herstellung von Phthalsäureanhydrid durch katalytische Gasphasenoxidation von x-Xylol-/-Naphthalin-Gemischen
KR20130094705A (ko)	2010-04-13	2013-08-26	바스프 에스이	프탈산 무수물 제조를 위한 기상 산화 반응기의 제어 방법
CN108794439B (zh) *	2017-05-02	2021-09-21	中国科学院大连化学物理研究所	一种苯酞的制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1144706B (de) *	1960-09-16	1963-03-07	American Cyanamid Co	Verfahren zur Herstellung von Phthalsaeureanhydrid
GB1063153A (en) *	1965-02-26	1967-03-30	Ici Ltd	Catalytic process for the manufacture of phthalic anhydride
FR2303594A1 (fr) *	1975-03-13	1976-10-08	Basf Ag	Catalyseurs vanadiques et titaniques sur support

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2106796C3 (de) *	1971-02-12	1981-09-24	Wacker-Chemie GmbH, 8000 München	Verfahren zur Herstellung Festbettkatalysatoren mit einem Überzug aus Vanadiumpentoxid und Titandioxid
DE2238067C3 (de) *	1972-08-02	1979-04-12	Wacker-Chemie Gmbh, 8000 Muenchen	Verfahren zur Herstellung von Phthalsäureanhydrid
DE2546268C3 (de) *	1975-10-16	1983-11-24	Basf Ag, 6700 Ludwigshafen	Verfahren zur Herstellung von Phthalsäureanhydrid aus o-Xylol oder Naphthalin
DE2914683A1 (de) *	1979-04-11	1980-10-16	Basf Ag	Vanadium- und titan- und/oder zirkonhaltiger traegerkatalysator

1981
- 1981-06-16 IT IT8122358A patent/IT1226043B/it active
1982
- 1982-05-18 US US06/379,396 patent/US4472587A/en not_active Expired - Fee Related
- 1982-05-19 ZA ZA823512A patent/ZA823512B/xx unknown
- 1982-05-25 DE DE19823219540 patent/DE3219540A1/de not_active Withdrawn
- 1982-06-07 AU AU84633/82A patent/AU8463382A/en not_active Abandoned
- 1982-06-14 FR FR8210324A patent/FR2507600A1/fr not_active Withdrawn
- 1982-06-14 CS CS824398A patent/CS228934B2/cs unknown
- 1982-06-15 GB GB08217265A patent/GB2104066B/en not_active Expired
- 1982-06-15 BE BE0/208353A patent/BE893521A/fr not_active IP Right Cessation
- 1982-06-15 YU YU01308/82A patent/YU130882A/xx unknown
- 1982-06-15 BR BR8203499A patent/BR8203499A/pt unknown
- 1982-06-16 JP JP57104647A patent/JPS5874675A/ja active Pending

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1144706B (de) *	1960-09-16	1963-03-07	American Cyanamid Co	Verfahren zur Herstellung von Phthalsaeureanhydrid
GB1063153A (en) *	1965-02-26	1967-03-30	Ici Ltd	Catalytic process for the manufacture of phthalic anhydride
FR2303594A1 (fr) *	1975-03-13	1976-10-08	Basf Ag	Catalyseurs vanadiques et titaniques sur support

Also Published As

Publication number	Publication date
CS228934B2 (en)	1984-05-14
IT8122358A0 (it)	1981-06-16
YU130882A (en)	1985-04-30
JPS5874675A (ja)	1983-05-06
ZA823512B (en)	1983-03-30
BR8203499A (pt)	1983-06-07
GB2104066A (en)	1983-03-02
AU8463382A (en)	1982-12-23
GB2104066B (en)	1985-08-21
DE3219540A1 (de)	1983-03-24
BE893521A (fr)	1982-10-01
IT1226043B (it)	1990-12-10
US4472587A (en)	1984-09-18

Legal Events

Date	Code	Title	Description
1987-04-24	ST	Notification of lapse

Publication	Publication Date	Title
FR2507600A1 (fr)	1982-12-17	Procede de preparation de l'anhydride phtalique a partir de l'orthoxylene, du naphtalene et leurs melanges par oxydation en presence d'un catalyseur specifique, catalyseur obtenu dans la mise en oeuvre de ce procede et appareillage pour la mise en oeuvre de ce procede
EP0512911B1 (fr)	1995-08-09	Procédé et dispositif de déshydrogénation d'hydrocarbures aliphatiques en hydrocarbures oléfiniques
AU2007263230B2 (en)	2012-06-28	Method for the continuous production of unsaturated carboxylic acid anhydrides
US5190668A (en)	1993-03-02	Method for the removal of volatile organic compounds from water
JPS5590621A (en)	1980-07-09	Production of carbon fiber
SG114452A1 (en)	2005-09-28	Method and apparatus for controlling the concentration ratio of reactants in a feed-stream to a reactor
ATE264289T1 (de)	2004-04-15	Herstellung von vinylacetat in einem mit einem filter und einer verteilungsschicht ausgestattetem katalytischen reaktor
ATE169839T1 (de)	1998-09-15	Membraneinheit mit einer grossen betriebsflexibilität
ES2148907T3 (es)	2000-10-16	Procedimiento para la acetoxilacion de olefinas.
EP0057152A2 (fr)	1982-08-04	Fermenteur anaérobie à garnissage
FR2596047A1 (fr)	1987-09-25	Procede de production de styrene
KR890015992A (ko)	1989-11-27	고온에서 일어나는 반응의 수행방법 및 고온에서의 감열성 제품제조용 장치
EP0036352B1 (fr)	1983-06-01	Procédé de préparation de trifluorométhylbenzènes à partir des trichloro- ou tribromo-méthylbenzènes correspondants
RU2279424C2 (ru)	2006-07-10	Способ получения соединения (мет)акролеина или (мет)акриловой кислоты
KR20000022519A (ko)	2000-04-25	산을 형성하기 위해 탄화수소를 산화시키는 방법 및 장치
JPH03232839A (ja)	1991-10-16	不飽和脂肪酸類のオゾン化法
MX9702157A (es)	1998-04-30	Optimizacion de contenido de agua en la oxidacion basada en oxigeno de p-xileno.
EP1848530B1 (fr)	2010-11-03	Procede de preparation de l'acide acrylique comprenant une oxydation partielle du propane en propylene
SU906994A1 (ru)	1982-02-23	Способ получени 4-бромфталевого ангидрида
JPS6210026A (ja)	1987-01-19	ナフタリンの気化方法
SU948879A1 (ru)	1982-08-07	Способ управлени процессом получени термической фосфорной кислоты из фосфорсодержащих шламов
JPS56156232A (en)	1981-12-02	Continuous preparation of o-toluic acid
JPH01190677A (ja)	1989-07-31	無水フタル酸の製造法
JP2742463B2 (ja)	1998-04-22	エチレングリコールの精製方法
JPS62270546A (ja)	1987-11-24	パ−フルオロプロピオン酸フロリドの製造方法