FR3131585B1 - Époxydes cycloaliphatiques polymériques - Google Patents

Époxydes cycloaliphatiques polymériques Download PDF

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Publication number
FR3131585B1
FR3131585B1 FR2114670A FR2114670A FR3131585B1 FR 3131585 B1 FR3131585 B1 FR 3131585B1 FR 2114670 A FR2114670 A FR 2114670A FR 2114670 A FR2114670 A FR 2114670A FR 3131585 B1 FR3131585 B1 FR 3131585B1
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FR
France
Prior art keywords
polymeric
cycloaliphatic epoxides
independently
relates
cycloaliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2114670A
Other languages
English (en)
Other versions
FR3131585A1 (fr
Inventor
Kelly Squires
Petr Sehnal
Sen Liu
Richard Plenderleith
Kangtai Ren
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR2114670A priority Critical patent/FR3131585B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to CN202280007048.8A priority patent/CN116547323A/zh
Priority to EP22844164.8A priority patent/EP4457220A1/fr
Priority to JP2024539763A priority patent/JP2025501280A/ja
Priority to US18/723,943 priority patent/US20250059317A1/en
Priority to PCT/EP2022/087808 priority patent/WO2023126369A1/fr
Priority to KR1020247025452A priority patent/KR20240131397A/ko
Priority to IL313918A priority patent/IL313918A/en
Priority to TW111150696A priority patent/TWI899526B/zh
Publication of FR3131585A1 publication Critical patent/FR3131585A1/fr
Application granted granted Critical
Publication of FR3131585B1 publication Critical patent/FR3131585B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C07D303/06—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms in which the oxirane rings are condensed with a carbocyclic ring system having three or more relevant rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F122/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F122/10—Esters
    • C08F122/1006—Esters of polyhydric alcohols or polyhydric phenols, e.g. ethylene glycol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3218—Carbocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/16—Cyclic ethers having four or more ring atoms
    • C08G65/18—Oxetanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Epoxy Resins (AREA)
  • Polyethers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Époxydes Cycloaliphatiques Polymériques La présente invention concerne un époxyde cycloaliphatique alcoxylé selon la formule suivante (I) : (I) chaque R1 et R2 étant indépendamment choisi parmi H et Me ; L étant le radical d’un polyol ; chaque a étant indépendamment de 2 à 4 ; chaque b étant indépendamment 0 à 20 à la condition qu’au moins un b ne soit pas 0 ; c étant au moins 3. L’invention concerne également des compositions comprenant un composé de formule (I) et un procédé pour la préparation d’un produit durci. Les produits durcis selon l’invention sont en particulier des articles imprimés en 3D. Fig. 1
FR2114670A 2021-12-30 2021-12-30 Époxydes cycloaliphatiques polymériques Active FR3131585B1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
FR2114670A FR3131585B1 (fr) 2021-12-30 2021-12-30 Époxydes cycloaliphatiques polymériques
EP22844164.8A EP4457220A1 (fr) 2021-12-30 2022-12-23 Époxydes cycloaliphatiques polymères
JP2024539763A JP2025501280A (ja) 2021-12-30 2022-12-23 ポリマー脂環式エポキシド
US18/723,943 US20250059317A1 (en) 2021-12-30 2022-12-23 Polymeric cycloaliphatic epoxides
CN202280007048.8A CN116547323A (zh) 2021-12-30 2022-12-23 聚合物型脂环族环氧化物
PCT/EP2022/087808 WO2023126369A1 (fr) 2021-12-30 2022-12-23 Époxydes cycloaliphatiques polymères
KR1020247025452A KR20240131397A (ko) 2021-12-30 2022-12-23 폴리머 지환족 에폭사이드
IL313918A IL313918A (en) 2021-12-30 2022-12-23 Polymeric cycloaliphatic epoxides
TW111150696A TWI899526B (zh) 2021-12-30 2022-12-29 聚合性環脂族環氧化物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2114670A FR3131585B1 (fr) 2021-12-30 2021-12-30 Époxydes cycloaliphatiques polymériques
FR2114670 2021-12-30

Publications (2)

Publication Number Publication Date
FR3131585A1 FR3131585A1 (fr) 2023-07-07
FR3131585B1 true FR3131585B1 (fr) 2025-02-28

Family

ID=80999580

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2114670A Active FR3131585B1 (fr) 2021-12-30 2021-12-30 Époxydes cycloaliphatiques polymériques

Country Status (9)

Country Link
US (1) US20250059317A1 (fr)
EP (1) EP4457220A1 (fr)
JP (1) JP2025501280A (fr)
KR (1) KR20240131397A (fr)
CN (1) CN116547323A (fr)
FR (1) FR3131585B1 (fr)
IL (1) IL313918A (fr)
TW (1) TWI899526B (fr)
WO (1) WO2023126369A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117682871A (zh) * 2023-12-22 2024-03-12 辽宁省轻工科学研究院有限公司 应用于3d打印的低收缩光固化陶瓷浆料、制备方法及零缺陷陶瓷制品成型方法
EP4725976A1 (fr) * 2024-10-11 2026-04-15 Arkema France Epoxydes polymeres cycloaliphatiques
WO2026078121A1 (fr) * 2024-10-11 2026-04-16 Arkema France Époxydes cycloaliphatiques polymériques

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU639882A1 (ru) * 1977-08-05 1978-12-30 Предприятие П/Я В-2304 Полипропиленгликоль-3,4эпоксигексагидробензоаты- олигомеры дл синтеза термоударостойких высокоэластичных эпоксиполимеров
CA1243147A (fr) * 1983-02-07 1988-10-11 Union Carbide Corporation Compositions photocopolymerisables a base de substances organiques epoxydes et hydroxyles, et de derives de substitution de mono-epoxyde cycloaliphatique comme diluants reactifs
US6201070B1 (en) * 1996-11-20 2001-03-13 Union Carbide Chemicals & Plastics Technology Corporation Method for enhancing the toughness of cycloaliphatic epoxide-based coatings
DE19648283A1 (de) * 1996-11-21 1998-05-28 Thera Ges Fuer Patente Polymerisierbare Massen auf der Basis von Epoxiden
JP2004010783A (ja) * 2002-06-07 2004-01-15 Showa Denko Kk オキセタン化合物を含む重合性組成物、その硬化物と製造方法
CN106125509B (zh) * 2009-12-17 2019-12-17 帝斯曼知识产权资产管理有限公司 用于加成法制造的可led固化的液体树脂组合物
CN102791460B (zh) * 2009-12-29 2015-05-27 圣万提注塑工业有限公司 流体流道加热装置
EP2956823B2 (fr) 2013-02-12 2019-07-03 CARBON3D, Inc. Impression à interface liquide continue
BR112015018105A2 (pt) 2013-02-12 2017-07-18 Carbon3D Inc método e aparelho para fabricação tridimensional
US10316214B2 (en) 2016-03-08 2019-06-11 3D Systems, Incorporated Non-isocyanate polyurethane inks for 3D printing
JP2020097692A (ja) * 2018-12-19 2020-06-25 株式会社ダイセル 立体造形用組成物
EP3875552A1 (fr) * 2020-03-04 2021-09-08 Lambson Limited Émulsions de photo-initiateur

Also Published As

Publication number Publication date
KR20240131397A (ko) 2024-08-30
TW202330698A (zh) 2023-08-01
TWI899526B (zh) 2025-10-01
IL313918A (en) 2024-08-01
JP2025501280A (ja) 2025-01-17
US20250059317A1 (en) 2025-02-20
FR3131585A1 (fr) 2023-07-07
EP4457220A1 (fr) 2024-11-06
CN116547323A (zh) 2023-08-04
WO2023126369A1 (fr) 2023-07-06

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