FR3146072B1 - Composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium. - Google Patents

Composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium.

Info

Publication number
FR3146072B1
FR3146072B1 FR2301758A FR2301758A FR3146072B1 FR 3146072 B1 FR3146072 B1 FR 3146072B1 FR 2301758 A FR2301758 A FR 2301758A FR 2301758 A FR2301758 A FR 2301758A FR 3146072 B1 FR3146072 B1 FR 3146072B1
Authority
FR
France
Prior art keywords
liquid composition
lithium
organic liquid
selective extraction
lithium salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2301758A
Other languages
English (en)
Other versions
FR3146072A1 (fr
Inventor
Souza Guillaume De
Jacky Pouessel
Jean-Marie Grassot
Adeline Laurencot
Justine Loche
Dominique Mabire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Adionics SAS
Original Assignee
Adionics SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adionics SAS filed Critical Adionics SAS
Priority to FR2301758A priority Critical patent/FR3146072B1/fr
Priority to CA3263957A priority patent/CA3263957A1/fr
Priority to US19/100,829 priority patent/US20260042036A1/en
Priority to ARP230102032A priority patent/AR130097A1/es
Priority to PCT/IB2023/057828 priority patent/WO2024028786A1/fr
Priority to JP2025505979A priority patent/JP2025527275A/ja
Priority to EP23767966.7A priority patent/EP4565723A1/fr
Priority to KR1020257006640A priority patent/KR20250097792A/ko
Priority to CN202380057353.2A priority patent/CN119768543A/zh
Priority to KR1020257028943A priority patent/KR20250160909A/ko
Priority to PCT/IB2024/051821 priority patent/WO2024180451A2/fr
Priority to EP24713720.1A priority patent/EP4673239A2/fr
Priority to JP2025545111A priority patent/JP2026506871A/ja
Priority to AU2024229114A priority patent/AU2024229114A1/en
Priority to CN202480014451.2A priority patent/CN120752078A/zh
Priority to ARP240100450A priority patent/AR131961A1/es
Publication of FR3146072A1 publication Critical patent/FR3146072A1/fr
Priority to CL2024002753A priority patent/CL2024002753A1/es
Priority to CL2025000288A priority patent/CL2025000288A1/es
Priority to MX2025001348A priority patent/MX2025001348A/es
Priority to MX2025007131A priority patent/MX2025007131A/es
Application granted granted Critical
Publication of FR3146072B1 publication Critical patent/FR3146072B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0446—Juxtaposition of mixers-settlers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0492—Applications, solvents used
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C235/06—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C235/14—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/182—Radicals derived from carboxylic acids
    • C07D295/185—Radicals derived from carboxylic acids from aliphatic carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Physical Water Treatments (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

------ Composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium La présente invention porte sur une composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium di-ionique comprenant un cation lithium et un anion complémentaire du cation lithium choisi notamment parmi Cl-, I-, Br-, CN-, NO3-, HCO3- à partir d’une saumure riche en lithium à traiter, ladite composition comprenant (A) au moins un composé extractant du cation lithium, choisi parmi les composés de formule : dans laquelle R1, R2, R3, R4, R5 et R6 sont tels que défini dans la description ; (B) au moins un composé organique, protique et hydrophobe, solvatant l’anion complémentaire du cation lithium ; et (C) au moins un diluant organique polaire hydrophobe ayant un point éclair à pression atmosphérique supérieur à 60°C, de préférence supérieur à 75°C, de façon davantage préférée supérieur à 90°C.
FR2301758A 2022-08-03 2023-02-27 Composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium. Active FR3146072B1 (fr)

Priority Applications (20)

Application Number Priority Date Filing Date Title
FR2301758A FR3146072B1 (fr) 2023-02-27 2023-02-27 Composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium.
US19/100,829 US20260042036A1 (en) 2022-08-03 2023-08-02 Method for selectively extracting a salt to be extracted from saltwater or brine
ARP230102032A AR130097A1 (es) 2022-08-03 2023-08-02 Proceso para la extracción selectiva de una sal a extraer de un agua salada o salmuera
PCT/IB2023/057828 WO2024028786A1 (fr) 2022-08-03 2023-08-02 Procédé d'extraction sélective d'un sel à extraire à partir d'une eau salée ou saumure
JP2025505979A JP2025527275A (ja) 2022-08-03 2023-08-02 塩水またはブラインから抽出すべき塩を選択的に抽出する方法
EP23767966.7A EP4565723A1 (fr) 2022-08-03 2023-08-02 Procédé d'extraction sélective d'un sel à extraire à partir d'une eau salée ou saumure
KR1020257006640A KR20250097792A (ko) 2022-08-03 2023-08-02 염수 또는 염물로부터 추출될 염을 선택적으로 추출하기 위한 방법
CN202380057353.2A CN119768543A (zh) 2022-08-03 2023-08-02 从盐水或咸水中选择性提取盐的方法
CA3263957A CA3263957A1 (fr) 2022-08-03 2023-08-02 Method for selectively extracting a salt to be extracted from saltwater or brine
EP24713720.1A EP4673239A2 (fr) 2023-02-27 2024-02-26 Composition liquide organique hydrophobe pour l'extraction sélective d'un sel de lithium
KR1020257028943A KR20250160909A (ko) 2023-02-27 2024-02-26 리튬염의 선택적 추출을 위한 소수성 유기 액체 조성물
JP2025545111A JP2026506871A (ja) 2023-02-27 2024-02-26 リチウム塩を選択的抽出するための疎水性有機液体組成物。
AU2024229114A AU2024229114A1 (en) 2023-02-27 2024-02-26 Hydrophobic organic liquid composition for the selective extraction of a lithium salt
CN202480014451.2A CN120752078A (zh) 2023-02-27 2024-02-26 用于选择性萃取锂盐的疏水性有机液体组合物
PCT/IB2024/051821 WO2024180451A2 (fr) 2023-02-27 2024-02-26 Composition liquide organique hydrophobe pour l'extraction sélective d'un sel de lithium
ARP240100450A AR131961A1 (es) 2023-02-27 2024-02-27 Composición líquida orgánica hidrófoba para la extracción selectiva de una sal de litio
CL2024002753A CL2024002753A1 (es) 2023-02-27 2024-09-12 Composición líquida orgánica hidrófoba para la extracción selectiva de una sal de litio.
CL2025000288A CL2025000288A1 (es) 2022-08-03 2025-01-30 Proceso para extracción selectiva de una sal a extraer de un agua salada o salmuera
MX2025001348A MX2025001348A (es) 2022-08-03 2025-01-31 Proceso para la extracción selectiva de una sal a extraer de un agua salada o salmuera
MX2025007131A MX2025007131A (es) 2023-02-27 2025-06-18 Composicion liquida organica hidrofoba para la extraccion selectiva de una sal de litio

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2301758 2023-02-27
FR2301758A FR3146072B1 (fr) 2023-02-27 2023-02-27 Composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium.

Publications (2)

Publication Number Publication Date
FR3146072A1 FR3146072A1 (fr) 2024-08-30
FR3146072B1 true FR3146072B1 (fr) 2026-02-27

Family

ID=86468846

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2301758A Active FR3146072B1 (fr) 2022-08-03 2023-02-27 Composition liquide organique hydrophobe pour l’extraction sélective d’un sel de lithium.

Country Status (10)

Country Link
EP (1) EP4673239A2 (fr)
JP (1) JP2026506871A (fr)
KR (1) KR20250160909A (fr)
CN (1) CN120752078A (fr)
AR (1) AR131961A1 (fr)
AU (1) AU2024229114A1 (fr)
CL (1) CL2024002753A1 (fr)
FR (1) FR3146072B1 (fr)
MX (1) MX2025007131A (fr)
WO (1) WO2024180451A2 (fr)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3306712A (en) 1963-12-30 1967-02-28 Dow Chemical Co Extraction of lithium halides from calcium-containing brines in the presence of urea and alcohol-ketone
US3793433A (en) 1971-07-23 1974-02-19 Atomic Energy Commission Extraction of lithium from neutral brines using a beta diketone and trioctylphosphine oxide
AT516420B1 (de) 2014-10-20 2016-11-15 Anton Paar Gmbh Verfahren und Vorrichtung zur Ermittlung der Dichte eines Fluids
AT517082B1 (de) 2015-05-20 2016-11-15 Anton Paar Gmbh Messgerät zur Untersuchung von fluiden Proben
FR3054140B1 (fr) * 2016-07-22 2018-08-31 Adionics Methode d’extraction de sels et composition extractante regeneree en temperature
CN106498184B (zh) 2016-12-07 2019-04-26 青海柴达木兴华锂盐有限公司 一种锂的萃取体系
WO2019226863A1 (fr) 2018-05-23 2019-11-28 Board of Regents, The University of the Texas System Composés pour l'extraction solide-liquide et l'extraction liquide-liquide sélectives de chlorure de lithium
CN110656239B (zh) * 2019-11-01 2020-11-20 中国科学院过程工程研究所 一种萃取-反萃分离纯化提取锂的方法

Also Published As

Publication number Publication date
KR20250160909A (ko) 2025-11-14
EP4673239A2 (fr) 2026-01-07
AR131961A1 (es) 2025-05-21
AU2024229114A1 (en) 2025-06-12
CL2024002753A1 (es) 2024-12-20
CN120752078A (zh) 2025-10-03
FR3146072A1 (fr) 2024-08-30
JP2026506871A (ja) 2026-02-27
WO2024180451A3 (fr) 2024-10-31
MX2025007131A (es) 2026-01-07
WO2024180451A2 (fr) 2024-09-06

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