HK102793A - Lubricant and fuel additives derived from o,o-dialkyldithiophosphoric acid and a norbornyl reactant - Google Patents

Lubricant and fuel additives derived from o,o-dialkyldithiophosphoric acid and a norbornyl reactant

Info

Publication number
HK102793A
HK102793A HK1027/93A HK102793A HK102793A HK 102793 A HK102793 A HK 102793A HK 1027/93 A HK1027/93 A HK 1027/93A HK 102793 A HK102793 A HK 102793A HK 102793 A HK102793 A HK 102793A
Authority
HK
Hong Kong
Prior art keywords
moiety
hydrocarbyl
compound
imide
alkyl
Prior art date
Application number
HK1027/93A
Other languages
German (de)
English (en)
Inventor
Richard Michael Lange
William Charles Tritt
Stephen Augustine Di Biase
Original Assignee
The Lubrizol Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Lubrizol Corporation filed Critical The Lubrizol Corporation
Publication of HK102793A publication Critical patent/HK102793A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C07F9/177—Esters of thiophosphoric acids with cycloaliphatic alcohols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
    • C10L1/265—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen and/or sulfur bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/10—Thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/10—Thio derivatives
    • C10M137/105—Thio derivatives not containing metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
    • C—CHEMISTRY; METALLURGY
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
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    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
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    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
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    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/26—Amines
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    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
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    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
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    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
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    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
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    • C10M2219/046—Overbased sulfonic acid salts
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    • C10N2040/046—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/08—Hydraulic fluids, e.g. brake-fluids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/251—Alcohol-fuelled engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C10N2040/28—Rotary engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Combustion & Propulsion (AREA)
  • Lubricants (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Claims (13)

  1. Une composition lubrifiante comportant une quantité prépondérante d'une huile de viscosité lubrifiante et une quantité plus faible d'un composé de formule: dans laquelle R est, indépendamment, un alkyle ou un aryle et X et Y sont indépendamment choisis parmi l'hydrogène, l'hydroxycarbyl carboxy, une partie carboxamide N-substituée, une partie thio- ou dithiocarbamate, une partie thioamide, une partie acide ou ester thio, un radical hydrocarbyle renfermant du phosphore, ou représentent conjointement un imide ou un imide à substitution N-hydrocarbyle, sous la condition que, lorsque X est un alkyl carboxyle, Y n'est pas un alkyl carboxy ni de l'hydrogène, et Y et X ne sont pas à la fois de l'hydrogène.
  2. La composition selon la revendication 1, dans laquelle X et Y sont indépendamment un hydroxyalkyl carboxy.
  3. La composition selon la revendication 2, dans laquelle X et Y sont identiques et sont de l'hydroxyéthyl carboxy.
  4. Une méthode pour améliorer les propriétés de support de charge d'une composition lubrifiante de viscosité lubrifiante en les mélangeant avec une plus faible quantité d'un agent de pression extrême et anti-usure de formule dans laquelle R est, indépendamment, un alkyle ou un aryle et X et Y sont indépendamment choisis parmi l'hydrogène, l'hydroxycarbyl carboxy, une partie carboxamide N-substituée, une partie thio- ou dithiocarbamate, une partie thioamide, une partie acide ou ester thio, un radical hydrocarbyle renfermant du phosphore, ou représentent conjointement un imide ou un imide à substitution N-hydrocarbyle, sous la condition que, lorsque X est un alkyle carboxyle, Y n'est pas un alkyl carboxy ni de l'hydrogène, et Y et X ne sont pas à la fois de l'hydrogène.
  5. La méthode selon la revendication 4, dans laquelle X et Y sont identiques et sont de l'hydroxyéthyl carboxy.
  6. Un composé de la formule: dans laquelle R est, indépendamment, un alkyle ou un aryle et X et Y sont indépendamment choisi parmi une partie carboxamide N-substitué, une partie thioamide, une partie thioester, une partie dithioester, une partie dithiocarbamate renfermant de l'hydroxycarbyle, de l'hydrocarbylthio, une partie phosphate, une partie phosphite, une partie phosphonate, une partie dithiophosphonate, une partie phosphoramide, ou représentent conjointement un imide ou un N-hydrocarbyl imide.
  7. Le composé selon la revendication 6, dans laquelle X et Y sont, indépendamment, une partie phosphonate, une partie carboxy amide N-substitué, ou sont conjointement, un imide ou un N-hydrocarbyl imide.
  8. Un additif lubrifiant comportant le composé de l'une quelconque des revendications 6 et 7.
  9. Un concentré pour la formulation de compositions lubrifiantes, comportant de 1% à 99% en poids d'un solvant/diluant organique, pratiquement inerte et liquide dans les conditions normales et au moins un composé de l'une quelconque des revendications 6 et 7.
  10. Une composition lubrifiante comportant une quantité prépondérante d'une huile de viscosité lubrifiante et une quantité plus faible d'au moins un composé de l'une quelconque des revendications 6 et 7 ou au moins un concentré de la revendication 9.
  11. Une méthode pour améliorer les propriétés de support de charge d'une composition lubrifiante, qui consiste à mélanger avec une quantité prépondérante d'une composition lubrifiante, une quantité plus faible du composé ou du concentré de l'une quelconque des revendications 6, 7 et 9.
  12. Un fluide fonctionnel aqueux comportant une quantité plus faible d'au moins un composé spécifié dans l'une quelconque des revendications 1, 2, 3, 6 et 7.
  13. Une composition de graisse, comportant une quantité plus faible d'au moins un composé spécifié dans l'une quelconque des revendications 1, 2, 3, 6 et 7.
HK1027/93A 1986-07-11 1993-09-30 Lubricant and fuel additives derived from o,o-dialkyldithiophosphoric acid and a norbornyl reactant HK102793A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/884,685 US4729840A (en) 1986-07-11 1986-07-11 Lubricant and fuel additives derived from O,O-dialkyldithiophosphoric acid and a norbornyl reactant
PCT/US1987/001580 WO1988000611A2 (fr) 1986-07-11 1987-07-02 Additifs pour lubrifiants et carburants derives de l'acide o,o-dialkyldithiophosphorique et d'un reactif de norbornyle

Publications (1)

Publication Number Publication Date
HK102793A true HK102793A (en) 1993-10-08

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HK1027/93A HK102793A (en) 1986-07-11 1993-09-30 Lubricant and fuel additives derived from o,o-dialkyldithiophosphoric acid and a norbornyl reactant

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Country Link
US (1) US4729840A (fr)
EP (1) EP0321462B1 (fr)
JP (1) JP2614882B2 (fr)
AT (1) ATE87027T1 (fr)
AU (1) AU603819B2 (fr)
CA (1) CA1308727C (fr)
DE (1) DE3784937T2 (fr)
ES (1) ES2010723A6 (fr)
HK (1) HK102793A (fr)
IN (1) IN168375B (fr)
MX (1) MX163959B (fr)
WO (1) WO1988000611A2 (fr)
ZA (1) ZA875004B (fr)

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JP2795890B2 (ja) * 1989-04-12 1998-09-10 出光興産株式会社 水性金属加工油剤
EP0595770B1 (fr) * 1992-10-30 1998-01-14 Ciba SC Holding AG Nouveaux dithiophosphates comme additifs anti-usure
DE4409961A1 (de) * 1994-03-23 1995-09-28 Rhein Chemie Rheinau Gmbh Metallfreie Dithiophosphorsäurederivate
US5715785A (en) * 1994-04-07 1998-02-10 Gregg, Jr.; George L. Method of lubricating machinery in the presence of an electrical charge
US5641731A (en) * 1994-11-04 1997-06-24 Ashland, Inc. Motor oil performance-enhancing formulation
US5962377A (en) * 1995-05-31 1999-10-05 Ashland Inc. Lubricant additive formulation
US6660695B2 (en) * 2002-03-15 2003-12-09 Infineum International Ltd. Power transmission fluids of improved anti-shudder properties
US10434520B2 (en) 2016-08-12 2019-10-08 Arr-Maz Products, L.P. Collector for beneficiating carbonaceous phosphate ores

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US2644002A (en) * 1951-08-29 1953-06-30 American Cyanamid Co Thiophosphatosuccinimides
US2767206A (en) * 1953-12-30 1956-10-16 Shell Dev Alicyclic esters of phosphoric acids
NL222328A (fr) * 1957-03-08
GB1055094A (en) * 1965-02-23 1967-01-11 Shell Int Research Novel phosphorus-containing esters
US3406225A (en) * 1965-11-26 1968-10-15 Velsicol Chemical Corp Cyclic prosphorus acid esters
US3916017A (en) * 1969-12-24 1975-10-28 Ethyl Corp Polycyclic compounds
JPS4911226B1 (fr) * 1970-06-24 1974-03-15
US3803270A (en) * 1971-08-04 1974-04-09 M Iliopulos Halo-substituted bicyclo alpha-hydroxyalkyl phosphonic acid diesters
US4035488A (en) * 1971-09-30 1977-07-12 Ciba-Geigy Corporation Insecticidal and acaricidal substituted phenyl thiophosphoric acid esters
US4067972A (en) * 1972-01-26 1978-01-10 Ciba-Geigy Corporation O-(Methyl or ethyl)-S-(propyl or butyl)-O-alkyl-(thio/sulfinyl/sulfonyl)-methylphenyl-thiophosphates
US3821322A (en) * 1972-09-08 1974-06-28 Ethyl Corp Polycyclic compounds
US3943202A (en) * 1972-11-03 1976-03-09 Ciba-Geigy Corporation O-methyl/ethyl-s-propyl/butyl-o-phenyl thiophosphates and dithiophosphates having an ether group or the phenyl ring
US3962105A (en) * 1975-03-25 1976-06-08 The Lubrizol Corporation Lubricating compositions
US4028258A (en) * 1975-12-03 1977-06-07 Texaco Inc. Alkylene oxide adducts of phosphosulfurized N-(hydroxyalkyl) alkenylsuccinimides
DE2556961A1 (de) * 1975-12-18 1977-06-30 Bayer Ag O-alkyl-o-phenylthionophosphonsaeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide
US4123526A (en) * 1975-12-24 1978-10-31 Stauffer Chemical Company Thionophosphate insecticide activators

Also Published As

Publication number Publication date
MX163959B (es) 1992-07-06
IN168375B (fr) 1991-03-23
DE3784937D1 (de) 1993-04-22
EP0321462A1 (fr) 1989-06-28
JP2614882B2 (ja) 1997-05-28
JPH01503141A (ja) 1989-10-26
ES2010723A6 (es) 1989-12-01
WO1988000611A2 (fr) 1988-01-28
US4729840A (en) 1988-03-08
EP0321462B1 (fr) 1993-03-17
ZA875004B (en) 1988-01-14
ATE87027T1 (de) 1993-04-15
WO1988000611A3 (fr) 1988-03-24
AU603819B2 (en) 1990-11-29
DE3784937T2 (de) 1993-06-24
AU7643487A (en) 1988-02-10
CA1308727C (fr) 1992-10-13

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