HK2585A - Cyclohexylcyclohexanoates, process for their preparation and liquid-crystal mixture containing them - Google Patents

Cyclohexylcyclohexanoates, process for their preparation and liquid-crystal mixture containing them

Info

Publication number
HK2585A
HK2585A HK25/85A HK2585A HK2585A HK 2585 A HK2585 A HK 2585A HK 25/85 A HK25/85 A HK 25/85A HK 2585 A HK2585 A HK 2585A HK 2585 A HK2585 A HK 2585A
Authority
HK
Hong Kong
Prior art keywords
groups
atoms
animal
products
formula
Prior art date
Application number
HK25/85A
Other languages
German (de)
English (en)
Inventor
Dr. Osman Maged A.
Laszlo Dr. Revesz
Original Assignee
Merck Patent Gesellschaft Mit Beschrankter Haftung
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck Patent Gesellschaft Mit Beschrankter Haftung filed Critical Merck Patent Gesellschaft Mit Beschrankter Haftung
Publication of HK2585A publication Critical patent/HK2585A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
    • C07D295/096—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D295/155—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals with the ring nitrogen atoms and the carbon atoms with three bonds to hetero atoms separated by carbocyclic rings or by carbon chains interrupted by carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • C09K19/3001—Cyclohexane rings
    • C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
    • C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C09K19/3441—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom
    • C09K19/3483—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom the heterocyclic ring being a non-aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Crystal Substances (AREA)

Claims (5)

1. Composés anisotropes de formule (1) où X et Y représentent chacun des radicaux alcoyle de 1 à 12 atomes de carbone, des radicaux alcoxy de 1 à 12 atomes de carbone, des radicaux monoalcoylamino de 1 à 12 atomes de carbone dans la partie alcoyle, des atomes d'halogène, des radicaux nitrile ou des radicaux nitro ou bien des radicaux cycliques de formule : où R représente l'atome d'hydrogène, un atome d'halogène, le radical nitrile ou nitro ou un radical alcoyle ou alcoxy de 1 à 12 atomes de carbone, Z1 représente le radical ―COO― ou ―OOC― et Z2 est identique à Z1 ou représente une liaison covalente simple, avec la restriction que seul l'un des radicaux X, Y est un radical cyclohexyle.
2. Mélange de cristaux liquides, caractérisé en ce qu'il comprend au moins un composé anisotrope de formule (1) où X et Y représentent chacun des radicaux alcoyle de 1 à 12 atomes de carbone, des radicaux alcoxy de 1 à 12 atomes de carbone, des radicaux N-monoalcoylamino de 1 à 12 atomes de carbone dans la partie alcoyle, des atomes d'halogène, des radicaux nitrile ou des radicaux nitro, ou bien des radicaux cycliques de formule : où R représente l'atome d'hydrogène, un atome d'halogène, le radical nitrile ou nitro ou un radical alcoyle ou alcoxy de 1 à 12 atomes de carbone, Z1 représente le radical -COO- ou -OOC- et Z2 est identique à Z1 ou représente une liaison covalente simple, avec la restriction que seul l'un des radicaux X, Y est un radical cyclique.
3. Procédé de préparation de composés anisotropes de formule (1) où X et Y représentent chacun des radicaux alcoyle de 1 à 12 atomes de carbone, des radicaux alcoxy de 1 à 12 atomes de carbone, des radicaux N-monoalcoylamino de 1 à 12 atomes de carbone dans la partie alcoyle, des atomes d'halogène, des radicaux nitrile ou des radicaux nitro ou bien des radicaux cycliques de formule : où R représente l'atome d'hydrogène, un atome d'halogène, le radical nitrile ou nitro ou un radical alcoyle ou alcoxy de 1 à 12 atomes de carbone, Z1 représente le radical -COO- ou -OOC- et Z2 est identique à Z1 ou représente une liaison covalente simple, avec la restriction que seul un des radicaux X, Y est un radical cyclique, caractérisé par la condensation d'un acide cyclohexanecarboxylique de formule (2) où X a la signification attribuée ci-dessus, ou d'un dérivé fonctionnel de cet acide, avec un cyclohexanol de formule (3) où Y a la signification attribuée ci-dessus.
4. Procédé suivant la revendication 3, caractérisé en ce qu'on utilise comme dérivé fonctionnel du composé (2) l'halogénure d'acide correspondant, en particulier le chlorure d'acide.
5. Procédé suivant la revendication 4, caractérisé en ce qu'on exécute la condensation en présence d'une base organique comme la pyridine.
HK25/85A 1979-07-18 1985-01-10 Cyclohexylcyclohexanoates, process for their preparation and liquid-crystal mixture containing them HK2585A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH667279 1979-07-18

Publications (1)

Publication Number Publication Date
HK2585A true HK2585A (en) 1985-01-18

Family

ID=4313221

Family Applications (1)

Application Number Title Priority Date Filing Date
HK25/85A HK2585A (en) 1979-07-18 1985-01-10 Cyclohexylcyclohexanoates, process for their preparation and liquid-crystal mixture containing them

Country Status (6)

Country Link
US (1) US4349452A (fr)
EP (1) EP0023730B1 (fr)
JP (1) JPS5616443A (fr)
DE (2) DE2933611A1 (fr)
HK (1) HK2585A (fr)
SG (1) SG79584G (fr)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2933611A1 (de) * 1979-07-18 1981-02-12 Bbc Brown Boveri & Cie Cyclohexylcyclohexanoate
DE3034222A1 (de) * 1979-09-24 1981-04-02 VEB Werk für Fernsehelektronik im VEB Kombinat Mikroelektronik, DDR 1160 Berlin Kristallin-fluessige subst.-trans-n-alkylcyclohexane bzw. subst.-3-subst.-benzoyloxy-(trans-4-n-alkylcyclohexane)
US4400061A (en) * 1980-01-30 1983-08-23 Her Majesty's Government of the UK. Liquid crystal ester compounds exhibiting a low or negative dielectric anisotropy and liquid crystal materials and devices incorporating such compounds
JPS56129287A (en) * 1980-03-14 1981-10-09 Hitachi Ltd Nematic liquid crystal composition
JPS574960A (en) * 1980-06-09 1982-01-11 Chisso Corp 4'''-cyanobiphenyl trans-4-(trans-4'-alkylcyclohexyl)- cyclohexanecarboxylate
DE3022818C2 (de) * 1980-06-19 1986-11-27 Merck Patent Gmbh, 6100 Darmstadt Flüssigkristall-Anzeigeelement
JPS5721359A (en) * 1980-07-15 1982-02-04 Chisso Corp 4'''-cyano-4"-biphenylyl 4-(trans-4'-alkylcyclohexyl)benzoate
JPS5755607U (fr) * 1980-09-18 1982-04-01
DE3100142A1 (de) * 1981-01-07 1982-08-12 Merck Patent Gmbh, 6100 Darmstadt Cyclohexylcarbonitrilderivate, diese enthaltende dielektrika und elektrooptisches anzeigeelement
DE3266741D1 (en) * 1981-03-13 1985-11-14 Secr Defence Brit Liquid crystal compositions
US4528114A (en) * 1981-12-18 1985-07-09 Hoffmann-La Roche Inc. Acetylenes
JPS58140045A (ja) * 1982-02-15 1983-08-19 Kanto Kagaku Kk 液晶化合物，液晶組成物並びに液晶表示素子
DE3205766A1 (de) * 1982-02-18 1983-08-25 Merck Patent Gmbh, 6100 Darmstadt Benzonitrile
DE3206269A1 (de) * 1982-02-20 1983-09-01 Merck Patent Gmbh, 6100 Darmstadt Bicyclohexylderivate
JPS58191781A (ja) * 1982-04-30 1983-11-09 Sharp Corp 液晶組成物
DE3220155A1 (de) * 1982-05-28 1983-12-01 Merck Patent Gmbh, 6100 Darmstadt Piperidinderivate
DE3225290A1 (de) * 1982-07-07 1984-01-12 Merck Patent Gmbh Ringverbindungen
EP0103681B1 (fr) * 1982-07-28 1986-07-30 F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft Monoesters tétra- et pentacycliques
EP0107759B1 (fr) * 1982-08-26 1992-12-16 MERCK PATENT GmbH Dérivés du cyclohexane et leur application comme components de cristaux liquides
US4550981A (en) * 1982-09-30 1985-11-05 Hoffmann-La Roche Inc. Liquid crystalline esters and mixtures
GB2132612B (en) * 1982-10-30 1986-01-22 Dainippon Ink & Chemicals Nematic liquid crystalline cyclohexyl esters
EP0122389B1 (fr) * 1983-03-16 1987-08-05 F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft Composants de cristaux liquides ayant une chaîne alcénylique
US4623477A (en) * 1983-10-07 1986-11-18 Chisso Corporation Ester compounds having a pyrimidine ring
DE3522510A1 (de) * 1984-07-11 1986-01-16 VEB Werk für Fernsehelektronik im VEB Kombinat Mikroelektronik, DDR 1160 Berlin Kristallin-fluessige 2-substituierte-5-(1-alkyl-piperid-yl)1,3- dioxane
US4764619A (en) * 1985-03-26 1988-08-16 Asahi Glass Company Ltd. Optically active compounds, smectic liquid crystal compositions containing them and smectic liquid crystal display devices
US4680137A (en) * 1985-06-10 1987-07-14 Chisso Corporation Liquid crystal ester compound
DE3644522A1 (de) * 1986-12-24 1988-07-14 Hoechst Ag Verwendung von optisch aktiven 1-acylprolinestern als dotierstoffe in fluessigkristallmischungen und neue optisch aktive 1-acyl-prolinester
US5342544A (en) * 1991-10-28 1994-08-30 Asahi Denka Kogyo Kabushiki Kaisha Liquid crystal composition
GB201009488D0 (en) * 2010-06-07 2010-07-21 Merck Patent Gmbh Switch element comprising a liquid-crystaline medium
CN102295554B (zh) * 2011-05-30 2013-10-09 苏州大学 高富勒烯含量液晶及其制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD105701A1 (fr) * 1973-07-02 1974-05-05
US4013582A (en) * 1976-06-17 1977-03-22 Rca Corporation Liquid crystal compounds and electro-optic devices incorporating them
US4113647A (en) * 1976-08-13 1978-09-12 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Liquid crystalline materials
DE2636684C3 (de) * 1976-08-14 1980-06-19 Merck Patent Gmbh, 6100 Darmstadt Phenylcyclohexanderivate und ihre Verwendung in flüssigkristallinen Dielektrika
US4029595A (en) * 1976-09-17 1977-06-14 Rca Corporation Novel liquid crystal compounds and electro-optic devices incorporating them
DE2702598C2 (de) * 1977-01-22 1984-10-25 Merck Patent Gmbh, 6100 Darmstadt Cyclohexylcyclohexane und diese enthaltende Dielektrika
JPS5421978A (en) * 1977-07-19 1979-02-19 Canon Inc Liquid crystal composition
DE2800553A1 (de) * 1978-01-07 1979-07-12 Merck Patent Gmbh Cyclohexanderivate
US4293434A (en) * 1978-08-08 1981-10-06 VEB Werk fur Fernsehelektronik Berlin im VEB Kombinat Mikroelektronik Liquid crystal compounds
JPS5554379A (en) * 1978-10-18 1980-04-21 Seiko Epson Corp Liquid crystal composition
DE2933611A1 (de) * 1979-07-18 1981-02-12 Bbc Brown Boveri & Cie Cyclohexylcyclohexanoate

Also Published As

Publication number Publication date
EP0023730B1 (fr) 1982-11-03
SG79584G (en) 1985-04-26
US4349452A (en) 1982-09-14
DE3061032D1 (en) 1982-12-09
JPH0437062B2 (fr) 1992-06-18
EP0023730A1 (fr) 1981-02-11
DE2933611A1 (de) 1981-02-12
JPS5616443A (en) 1981-02-17

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